DK1567616T4 - Katalytisk proces - Google Patents

Katalytisk proces Download PDF

Info

Publication number
DK1567616T4
DK1567616T4 DK03778556.5T DK03778556T DK1567616T4 DK 1567616 T4 DK1567616 T4 DK 1567616T4 DK 03778556 T DK03778556 T DK 03778556T DK 1567616 T4 DK1567616 T4 DK 1567616T4
Authority
DK
Denmark
Prior art keywords
channels
fischer
carbon monoxide
gas
tropsch synthesis
Prior art date
Application number
DK03778556.5T
Other languages
English (en)
Other versions
DK1567616T3 (da
Inventor
Michael Joseph Bowe
Clive Derek Lee-Tuffnell
Original Assignee
Compactgtl Plc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=32472134&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DK1567616(T4) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from PCT/GB2002/005443 external-priority patent/WO2003048035A1/en
Priority claimed from GBGB0314790.7A external-priority patent/GB0314790D0/en
Application filed by Compactgtl Plc filed Critical Compactgtl Plc
Application granted granted Critical
Publication of DK1567616T3 publication Critical patent/DK1567616T3/da
Publication of DK1567616T4 publication Critical patent/DK1567616T4/da

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/34—Apparatus, reactors
    • C10G2/341—Apparatus, reactors with stationary catalyst bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/248—Reactors comprising multiple separated flow channels
    • B01J19/249—Plate-type reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/248—Reactors comprising multiple separated flow channels
    • B01J19/2495—Net-type reactors
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2461—Heat exchange aspects
    • B01J2219/2465—Two reactions in indirect heat exchange with each other
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2469—Feeding means
    • B01J2219/247—Feeding means for the reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2476—Construction materials
    • B01J2219/2477—Construction materials of the catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Claims (9)

1. Fremgangsmåde til udførelse af Fischer-Tropsch syntese ved anvendelse af i det mindste én kompakt katalytisk reaktorenhed (10), der definerer kanaler (14, 14a) til Fischer-Tropsch syntesereaktionen, og i hvilken der er en gasgennemtrængelig katalysatorstruktur (16) kendetegnet ved, at en karbonmonooxid-indeholdende gas undergår Fischer-Tropsch syntese i i det mindste to på hinanden følgende trin, hvor hastigheden af gasstrømmen i det første trin er tilstrækkelig høj, til at ikke mere end 70% af karbonmo-nooxiden undergår syntesereaktionen i det første trin, at gasserne køles (25) mellem de på hinanden følgende trin for derved at kondensere vanddamp, og at hastigheden af gasstrømmen i det andet trin er tilstrækkelig høj, til at ikke mere end 70% af den resterende karbon monooxid undergår syntesereaktionen i det andet trin.
2. Fremgangsmåde ifølge krav 1, udført ved anvendelse af én enkelt reaktorenhed (10), hvori hvert trin af syntesereaktionen finder sted i et sæt af kanaler (14, 14a) inde i reaktorenheden, og gasserne køles (25) inde i en samlekasse (18) mellem på hinanden følgende trin.
3. Fremgangsmåde ifølge krav 1 eller krav 2, hvor en karbonmonooxid indeholdende gasstrøm strømmer parallelt gennem et flertal af første kanaler (14, 14a) i det første trin, og så gennem et flertal af anden kanaler (14, 14a) i det andet trin, hvor tværsnitsarealet af flertallet af anden kanaler (14, 14a) er mindre end tværsnittet af flertallet af første kanaler (14, 14a).
4. Fremgangsmåde ifølge krav 3, hvor antallet af anden kanaler (14, 14a) er mindre end antallet af første kanaler (14, 14a).
5. Fremgangsmåde ifølge ethvert af de forgående krav, hvor både det første trin og det andet trin har en space velocity, der er over 1000 /time.
6. Fremgangsmåde ifølge krav 5, hvor både det første trin og det andet trin har en space velocity, der ikke er større end 15000 /time.
7. Fremgangsmåde ifølge ethvert af de forgående krav, hvor mængden af vanddamp ikke overstiger 20 mol%.
8. Fremgangsmåde ifølge ethvert af de forgående krav, hvor hastigheden af gasstrømmen gennem både det første trin og det andet trin er tilstrækkelig høj, til at ikke mere end 65% af karbonmonooxiden undergår syntesereaktionen.
9. Fremgangsmåde til udførelse af Fischer-Tropsch syntese på en gas indeholdende hydrogen og karbonmonooxid, hvor der anvendes i det mindste én kompakt katalytisk reaktorenhed (10), der har kanaler (14, 14a) til Fischer-Tropsch syntesen, i hvilke der er en gasgennemtrængelig katalysator struktur (16), hvor syntesen udføres i i det mindste to på hinanden følgende trin, ved en gasstrømningshastighed, der er tilstrækkelig høj til at mængden af vanddamp ikke overstiger 20 mol%, og hvor gasserne mellem på hinanden følgende trin køles (25) for at kondensere vanddamp.
DK03778556.5T 2002-12-02 2003-11-27 Katalytisk proces DK1567616T4 (da)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
PCT/GB2002/005443 WO2003048035A1 (en) 2001-12-05 2002-12-02 Process and apparatus for steam-methane reforming
GBGB0314790.7A GB0314790D0 (en) 2003-06-25 2003-06-25 Catalytic reactor and process
PCT/GB2003/005198 WO2004050799A1 (en) 2002-12-02 2003-11-27 Catalytic reactor and process

Publications (2)

Publication Number Publication Date
DK1567616T3 DK1567616T3 (da) 2006-10-09
DK1567616T4 true DK1567616T4 (da) 2019-04-29

Family

ID=32472134

Family Applications (1)

Application Number Title Priority Date Filing Date
DK03778556.5T DK1567616T4 (da) 2002-12-02 2003-11-27 Katalytisk proces

Country Status (12)

Country Link
EP (1) EP1567616B2 (da)
JP (1) JP4446388B2 (da)
KR (1) KR101053040B1 (da)
AT (1) ATE337385T1 (da)
AU (1) AU2003285558B2 (da)
BR (1) BR0316828B1 (da)
CA (1) CA2505614C (da)
DE (1) DE60307885T3 (da)
DK (1) DK1567616T4 (da)
MX (1) MXPA05005870A (da)
RU (1) RU2310677C2 (da)
WO (1) WO2004050799A1 (da)

Families Citing this family (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX2007008365A (es) * 2001-01-10 2007-09-21 Compactgtl Plc Reactor catalitico.
US7014835B2 (en) 2002-08-15 2006-03-21 Velocys, Inc. Multi-stream microchannel device
US7118920B2 (en) 2002-10-22 2006-10-10 Battelle Memorial Institute Multiphasic microchannel reactions
US7294734B2 (en) 2003-05-02 2007-11-13 Velocys, Inc. Process for converting a hydrocarbon to an oxygenate or a nitrile
US7485671B2 (en) 2003-05-16 2009-02-03 Velocys, Inc. Process for forming an emulsion using microchannel process technology
US8580211B2 (en) 2003-05-16 2013-11-12 Velocys, Inc. Microchannel with internal fin support for catalyst or sorption medium
US7220390B2 (en) 2003-05-16 2007-05-22 Velocys, Inc. Microchannel with internal fin support for catalyst or sorption medium
CA2535842C (en) 2003-08-29 2012-07-10 Velocys Inc. Process for separating nitrogen from methane using microchannel process technology
US7029647B2 (en) 2004-01-27 2006-04-18 Velocys, Inc. Process for producing hydrogen peroxide using microchannel technology
US7084180B2 (en) 2004-01-28 2006-08-01 Velocys, Inc. Fischer-tropsch synthesis using microchannel technology and novel catalyst and microchannel reactor
US9023900B2 (en) 2004-01-28 2015-05-05 Velocys, Inc. Fischer-Tropsch synthesis using microchannel technology and novel catalyst and microchannel reactor
US8747805B2 (en) 2004-02-11 2014-06-10 Velocys, Inc. Process for conducting an equilibrium limited chemical reaction using microchannel technology
US7304198B2 (en) 2004-05-14 2007-12-04 Battelle Memorial Institute Staged alkylation in microchannels
GB0413400D0 (en) * 2004-06-16 2004-07-21 Accentus Plc Catalytic plant and process
US7305850B2 (en) 2004-07-23 2007-12-11 Velocys, Inc. Distillation process using microchannel technology
EP1781389A2 (en) 2004-07-23 2007-05-09 Velocys, Inc. Distillation process using microchannel technology
CN101023068B (zh) 2004-08-12 2013-02-13 万罗赛斯公司 使用微通道工艺技术将乙烯转化成环氧乙烷的方法
JP5643474B2 (ja) 2004-10-01 2014-12-17 ヴェロシス，インク． マイクロチャネルプロセス技術を用いる多相混合プロセス
EP1817102A1 (en) 2004-11-12 2007-08-15 Velocys, Inc. Process using microchannel technology for conducting alkylation or acylation reaction
CN102258968A (zh) 2004-11-16 2011-11-30 万罗赛斯公司 使用微通道技术的多相反应方法
GB0501731D0 (en) * 2005-01-31 2005-03-02 Accentus Plc Catalytic reactor
WO2006127889A2 (en) 2005-05-25 2006-11-30 Velocys Inc. Support for use in microchannel processing
GB0513484D0 (en) * 2005-07-01 2005-08-10 Accentus Plc Producing liquid hydrocarbons
WO2007008495A2 (en) 2005-07-08 2007-01-18 Velocys Inc. Catalytic reaction process using microchannel technology
US7829602B2 (en) 2007-01-19 2010-11-09 Velocys, Inc. Process and apparatus for converting natural gas to higher molecular weight hydrocarbons using microchannel process technology
GB0725140D0 (en) * 2007-12-24 2008-01-30 Compactgtl Plc Catalytic Reactor
US9908093B2 (en) 2008-04-09 2018-03-06 Velocys, Inc. Process for converting a carbonaceous material to methane, methanol and/or dimethyl ether using microchannel process technology
US8100996B2 (en) 2008-04-09 2012-01-24 Velocys, Inc. Process for upgrading a carbonaceous material using microchannel process technology
CA2739325C (en) 2008-10-10 2018-11-27 Velocys Inc. Process and apparatus employing microchannel process technology
JP5581028B2 (ja) * 2009-09-16 2014-08-27 住友精密工業株式会社 触媒反応器
GB201007196D0 (en) 2010-04-30 2010-06-16 Compactgtl Plc Gas-to-liquid technology
RU2442819C1 (ru) * 2010-07-05 2012-02-20 Учреждение Российской Академии наук Институт катализа им. Г.К. Борескова Сибирского отделения РАН (ИК СО РАН) Способ работы устройства для переработки попутных нефтяных газов
GB201107070D0 (en) * 2011-04-27 2011-06-08 Davy Process Techn Ltd FT process using can reactor
GB201112028D0 (en) 2011-07-13 2011-08-31 Gas2 Ltd Fixed bed fischer tropsch reactor
GB201120327D0 (en) 2011-11-24 2012-01-04 Compactgtl Plc Oil well product treatment
GB201214122D0 (en) 2012-08-07 2012-09-19 Oxford Catalysts Ltd Treating of catalyst support
US9676623B2 (en) 2013-03-14 2017-06-13 Velocys, Inc. Process and apparatus for conducting simultaneous endothermic and exothermic reactions
WO2016201218A2 (en) 2015-06-12 2016-12-15 Velocys, Inc. Synthesis gas conversion process
RU2610526C2 (ru) * 2015-06-18 2017-02-13 Открытое акционерное общество "Нефтяная компания "Роснефть" Катализатор для осуществления процесса Фишера-Тропша в компактном варианте и способ его получения (варианты)
RU2638217C1 (ru) 2016-12-15 2017-12-12 Публичное акционерное общество "Нефтяная компания "Роснефть" Компактный реактор для получения синтетических углеводородов в процессе Фишера-Тропша, способ активации катализатора Фишера-Тропша и способ осуществления синтеза Фишера-Тропша в компактном варианте с его использованием
FR3073152B1 (fr) * 2017-11-09 2022-03-11 Aer Unite d'hydrogenation d'oxydes de carbone a taux de conversion accru, dont la performance depend faiblement du vieillissement du catalyseur
DE102021110735A1 (de) 2021-04-27 2022-10-27 Ineratec Gmbh Verfahren zur Herstellung von Kohlenwasserstoffen

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4199523A (en) * 1975-04-29 1980-04-22 Ruhrchemie Aktiengesellschaft Process for the production of hydrocarbon mixtures
NL8400608A (nl) † 1984-02-28 1985-09-16 Shell Int Research Werkwijze voor de bereiding van koolwaterstoffen.
US5028634A (en) † 1989-08-23 1991-07-02 Exxon Research & Engineering Company Two stage process for hydrocarbon synthesis
US6331573B1 (en) † 2000-02-29 2001-12-18 Chevron U.S.A. Inc. Increased liquid sensitivity during fischer-tropsch synthesis by olefin incorporation
US6495610B1 (en) † 2000-06-19 2002-12-17 Imperial Chemical Industries Plc Methanol and hydrocarbons
FR2824755B1 (fr) * 2001-05-15 2003-08-15 Physiques Et Chimiques Reacteur a plaques et son fonctionnement dans un procede catalytique exothermique
EP1434652B1 (en) 2001-10-12 2005-02-16 GTL Microsystems AG Catalytic reactor
GB0129054D0 (en) † 2001-12-05 2002-01-23 Accentus Plc Catalytic reactor and process
US20050171217A1 (en) † 2001-12-05 2005-08-04 Bowe Michael J. Process and apparatus for steam-methane reforming

Also Published As

Publication number Publication date
AU2003285558B2 (en) 2009-07-16
EP1567616B2 (en) 2010-08-18
ATE337385T1 (de) 2006-09-15
RU2005120773A (ru) 2006-01-20
EP1567616A1 (en) 2005-08-31
EP1567616B1 (en) 2006-08-23
BR0316828B1 (pt) 2013-04-24
BR0316828A (pt) 2005-10-18
CA2505614A1 (en) 2004-06-17
DE60307885D1 (de) 2006-10-05
AU2003285558A1 (en) 2004-06-23
JP4446388B2 (ja) 2010-04-07
KR101053040B1 (ko) 2011-08-01
DE60307885T2 (de) 2007-02-01
RU2310677C2 (ru) 2007-11-20
WO2004050799A1 (en) 2004-06-17
DK1567616T3 (da) 2006-10-09
DE60307885T3 (de) 2010-12-16
KR20050085124A (ko) 2005-08-29
CA2505614C (en) 2012-04-17
MXPA05005870A (es) 2005-08-26
JP2006508234A (ja) 2006-03-09

Similar Documents

Publication Publication Date Title
DK1567616T4 (da) Katalytisk proces
CA2451416C (en) Catalytic reactor
US8021633B2 (en) Process an apparatus for steam-methane reforming
CA2568702C (en) Catalytic plant and process for performing fischer-tropsch synthesis
AU2002314372A1 (en) Catalytic reactor
NO333822B1 (no) Fremgangsmåte for å gjennomføre Fisher-Tropsch syntese
US7189271B2 (en) Catalytic reactor
AU2002365663A1 (en) Process and apparatus for steam-methane reforming
US20040251001A1 (en) Catalytic reactor
CN1720316A (zh) 催化反应器和方法
GB2441509A (en) Fischer-Tropsch synthesis