DK145186A - Fremgangsmaade til katalytisk oxidation - Google Patents

Fremgangsmaade til katalytisk oxidation Download PDF

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Publication number
DK145186A
DK145186A DK145186A DK145186A DK145186A DK 145186 A DK145186 A DK 145186A DK 145186 A DK145186 A DK 145186A DK 145186 A DK145186 A DK 145186A DK 145186 A DK145186 A DK 145186A
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DK
Denmark
Prior art keywords
catalytic oxidation
oxygen
groups
allylic
procedure
Prior art date
Application number
DK145186A
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English (en)
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DK173704B1 (da
DK145186D0 (da
Inventor
Joseph Foricher
Claude Fuerbringer
Karlheinz Pfoertner
Original Assignee
Hoffmann La Roche
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Publication date
Application filed by Hoffmann La Roche filed Critical Hoffmann La Roche
Publication of DK145186D0 publication Critical patent/DK145186D0/da
Publication of DK145186A publication Critical patent/DK145186A/da
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Publication of DK173704B1 publication Critical patent/DK173704B1/da

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07J—STEROIDS
    • C07J9/00—Normal steroids containing carbon, hydrogen, halogen or oxygen substituted in position 17 beta by a chain of more than two carbon atoms, e.g. cholane, cholestane, coprostane
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C33/00—Unsaturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C33/02—Acyclic alcohols with carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/04—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/14—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom belonging to a ring other than a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/14—All rings being cycloaliphatic
    • C07C2602/26—All rings being cycloaliphatic the ring system containing ten carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/36—Systems containing two condensed rings the rings having more than two atoms in common
    • C07C2602/42—Systems containing two condensed rings the rings having more than two atoms in common the bicyclo ring system containing seven carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/56—Ring systems containing bridged rings
    • C07C2603/58—Ring systems containing bridged rings containing three rings
    • C07C2603/60—Ring systems containing bridged rings containing three rings containing at least one ring with less than six members
    • C07C2603/66—Ring systems containing bridged rings containing three rings containing at least one ring with less than six members containing five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/56—Ring systems containing bridged rings
    • C07C2603/58—Ring systems containing bridged rings containing three rings
    • C07C2603/76—Ring systems containing bridged rings containing three rings containing at least one ring with more than six ring members
    • C07C2603/78—Ring systems containing bridged rings containing three rings containing at least one ring with more than six ring members containing seven-membered rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Indole Compounds (AREA)
  • Pyrrole Compounds (AREA)
  • Steroid Compounds (AREA)
  • Epoxy Compounds (AREA)
DK198601451A 1985-04-17 1986-03-26 Fremgangsmåde til katalytisk oxidation af allyliske grupper DK173704B1 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH163785 1985-04-17
CH163785 1985-04-17

Publications (3)

Publication Number Publication Date
DK145186D0 DK145186D0 (da) 1986-03-26
DK145186A true DK145186A (da) 1986-10-18
DK173704B1 DK173704B1 (da) 2001-07-09

Family

ID=4215114

Family Applications (1)

Application Number Title Priority Date Filing Date
DK198601451A DK173704B1 (da) 1985-04-17 1986-03-26 Fremgangsmåde til katalytisk oxidation af allyliske grupper

Country Status (6)

Country Link
US (1) US5030739A (da)
EP (1) EP0198351B1 (da)
JP (1) JPH0774168B2 (da)
AT (1) ATE47380T1 (da)
DE (1) DE3666417D1 (da)
DK (1) DK173704B1 (da)

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US5585371A (en) * 1990-08-29 1996-12-17 Humanetics Corporation Treatment of immune system with Δ5-androstenes
BR9507663A (pt) 1994-05-19 1997-10-07 Merck & Co Inc Processo para a oxidação de um alceno delta-5-esteroidal para o correspondente alceno delta-5-7-ceto-esteroidal e composto
JP3935940B2 (ja) * 1995-12-18 2007-06-27 フイルメニツヒ ソシエテ アノニム ヌートカトンの製造法
KR100472895B1 (ko) * 1996-02-07 2005-05-16 다이셀 가가꾸 고교 가부시끼가이샤 산화촉매계 및 그를 사용한 산화방법
SG60101A1 (en) 1996-08-20 1999-02-22 Daicel Chem A process for separating an oxidation reaction product and an oxidation catalyst
EP1574494A1 (en) 1997-01-14 2005-09-14 Daicel Chemical Industries, Ltd. Adamantane derivative
EP0927711A4 (en) * 1997-03-11 2004-12-08 Daicel Chem ADAMANT DERIVATIVES AND METHOD FOR THEIR PRODUCTION
US5869709A (en) * 1997-05-07 1999-02-09 Humanetics Corporation Process for effecting allylic oxidation
US6686486B1 (en) 1997-05-07 2004-02-03 Padma Marwah Process for effecting allylic oxidation
JP3892938B2 (ja) * 1997-05-13 2007-03-14 ダイセル化学工業株式会社 オキソ化用触媒およびそれを用いたケトン類の製造方法
DE19723961A1 (de) * 1997-06-06 1998-12-10 Consortium Elektrochem Ind Verfahren zur Herstellung von aromatischen und heteroaromatischen Aldehyden und Ketonen
DE69830207T2 (de) * 1997-07-09 2006-02-23 Mitsui Chemicals, Inc. Verfahren zur Herstellung von Hydroperoxiden
US6252119B1 (en) 1997-07-28 2001-06-26 Salvador Jorge Antonio Riberiro Copper-catalysed allylic oxidation using alkyl hydroperoxide
JP5133947B2 (ja) * 1998-02-13 2013-01-30 株式会社ダイセル ビニル基又はエポキシ基含有多環式化合物の製造法
JP4626896B2 (ja) * 1998-02-13 2011-02-09 ダイセル化学工業株式会社 アシル化剤とそれを用いたアシル化法、及びアダマンタン誘導体
US6384251B1 (en) * 1998-03-18 2002-05-07 Humanetics Corporation Process for effecting allylic oxidation using dicarboxylic acid imides and chromium reagents
AT406957B (de) * 1998-11-25 2000-11-27 Dsm Fine Chem Austria Gmbh Verfahren zur oxidation von methyl-, methylen- oder methingruppen enthaltenden substraten
DE59902734D1 (de) * 1998-11-25 2002-10-24 Dsm Fine Chem Austria Gmbh Verfahren zur Oxidation von Methyl-, Methylen- oder Methingruppen enthaltenden Substraten
DE10015874A1 (de) 2000-03-30 2001-10-11 Creavis Tech & Innovation Gmbh Verfahren zur Herstellung von aromatischen Alkoholen insbesondere Phenol
DE10015880A1 (de) 2000-03-30 2001-10-11 Creavis Tech & Innovation Gmbh Verfahren zur Oxidation von Kohlenwasserstoffen
JP4524020B2 (ja) * 2000-04-04 2010-08-11 ダイセル化学工業株式会社 イミド系触媒の再生方法及びイミド系触媒を用いた製造プロセス
WO2001074487A1 (fr) 2000-04-04 2001-10-11 Daicel Chemical Industries, Ltd. Procede de separation d'un compose imide
JP4640877B2 (ja) * 2000-06-14 2011-03-02 ダイセル化学工業株式会社 イミド化合物を触媒として用いた有機化合物の製造法
JP4651181B2 (ja) * 2000-11-01 2011-03-16 ダイセル化学工業株式会社 反応生成物と触媒との分離方法
JP4601805B2 (ja) 2000-11-24 2010-12-22 ダイセル化学工業株式会社 シクロヘキサンの酸化方法
AU2002244247B2 (en) 2001-03-01 2007-12-13 Harbor Biosciences, Inc. Use of certain steroids for treatment of blood cell deficiencies
DE10131522A1 (de) * 2001-07-02 2003-01-16 Creavis Tech & Innovation Gmbh Verfahren zur Herstellung gesättigter Alkohole, Ketone, Aldehyde und Carbonsäuren
DE10139212A1 (de) * 2001-08-09 2003-02-27 Creavis Tech & Innovation Gmbh Herstellung von Peroxiden des Ethylbenzols und deren Verwendung
US7538084B2 (en) * 2003-03-17 2009-05-26 Amr Technology, Inc. Cyclosporins
WO2006039164A2 (en) * 2004-09-29 2006-04-13 Amr Technology, Inc. Novel cyclosporin analogues and their pharmaceutical uses
US7378391B2 (en) * 2004-09-29 2008-05-27 Amr Technology, Inc. Cyclosporin alkyne analogues and their pharmaceutical uses
US7361636B2 (en) * 2004-10-06 2008-04-22 Amr Technology, Inc. Cyclosporin alkynes and their utility as pharmaceutical agents
US7696166B2 (en) * 2006-03-28 2010-04-13 Albany Molecular Research, Inc. Use of cyclosporin alkyne/alkene analogues for preventing or treating viral-induced disorders
US7696165B2 (en) * 2006-03-28 2010-04-13 Albany Molecular Research, Inc. Use of cyclosporin alkyne analogues for preventing or treating viral-induced disorders
US7579016B2 (en) * 2007-07-13 2009-08-25 The United States Of America As Represented By The Secretary Of Agriculture Methods for repelling arthropods using isolongifolenone analogs
US7378557B1 (en) * 2007-07-13 2008-05-27 The United States Of America As Represented By The Secretary Of Agriculture Methods for preparing isolongifolenone and its use in repelling arthropods
CN101687784B (zh) * 2007-08-22 2014-11-12 埃克森美孚化学专利公司 烃的氧化
WO2009058531A1 (en) * 2007-10-31 2009-05-07 Exxonmobil Chemical Patents Inc. Oxidation of hydrocarbons
JP2011500816A (ja) * 2007-10-31 2011-01-06 エクソンモービル・ケミカル・パテンツ・インク 炭化水素の酸化
EP2098504A1 (en) * 2008-03-06 2009-09-09 ExxonMobil Chemical Patents Inc. Oxidation of hydrocarbons
ITMI20080461A1 (it) * 2008-03-18 2009-09-19 Polimeri Europa Spa Processo per la produzione di idroperossidi di alchilbenzeni in condizioni blande ed in presenza di nuovi sistemi catalitici
WO2010019489A2 (en) * 2008-08-13 2010-02-18 Salk Institute For Biological Studies Method for making terpene derivatives
CN102177120B (zh) * 2008-10-10 2015-01-28 埃克森美孚化学专利公司 烃的氧化
MY158652A (en) * 2008-12-15 2016-10-31 Exxonmobil Chemical Patents Inc Oxidation of alkylaromatic compounds
US8057829B2 (en) * 2008-12-30 2011-11-15 Sterling International Inc. Methods for repelling insects using sesquiterpene hydrocarbons and their derivatives
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CN103917549B (zh) 2011-11-09 2016-12-07 巴斯夫欧洲公司 制备氧代乙烯基紫罗兰醇及其o-保护衍生物的方法
EP3023407A4 (en) * 2013-07-18 2017-03-15 Daicel Corporation Method for producing oxide
CN103788163B (zh) * 2014-01-27 2015-11-18 浙江大学 7-酮基甾类化合物的制备方法
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DE2704406A1 (de) * 1977-02-03 1978-08-10 Basf Ag Verfahren zur einfuehrung einer carbonylgruppe in einen cyclohexenring
JPS56145269A (en) * 1980-03-25 1981-11-11 Hoffmann La Roche Manufacture of 3,5,5-trimethyl-4-((e)-3-oxo-1- butenyl)-2-cyclohexene-1-one
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EP0067258B1 (en) * 1981-06-17 1985-04-17 Indian Explosives Limited The preparation of cyclic ketones by catalytic oxidation of deltacarene (-3)

Also Published As

Publication number Publication date
ATE47380T1 (de) 1989-11-15
EP0198351A3 (en) 1988-06-08
EP0198351A2 (de) 1986-10-22
DK173704B1 (da) 2001-07-09
JPH0774168B2 (ja) 1995-08-09
DE3666417D1 (en) 1989-11-23
US5030739A (en) 1991-07-09
JPS61238733A (ja) 1986-10-24
DK145186D0 (da) 1986-03-26
EP0198351B1 (de) 1989-10-18

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