DK141337B - Fremgangsmåde til igangsætning af en proces til isomerisering af paraffiner. - Google Patents
Fremgangsmåde til igangsætning af en proces til isomerisering af paraffiner. Download PDFInfo
- Publication number
- DK141337B DK141337B DK12372AA DK12372A DK141337B DK 141337 B DK141337 B DK 141337B DK 12372A A DK12372A A DK 12372AA DK 12372 A DK12372 A DK 12372A DK 141337 B DK141337 B DK 141337B
- Authority
- DK
- Denmark
- Prior art keywords
- temperature
- starting material
- weight
- isomerization
- catalyst
- Prior art date
Links
- 238000000034 method Methods 0.000 title description 21
- 230000008569 process Effects 0.000 title description 17
- 238000006317 isomerization reaction Methods 0.000 title description 16
- 230000000977 initiatory effect Effects 0.000 title description 4
- 239000003054 catalyst Substances 0.000 description 32
- 239000007858 starting material Substances 0.000 description 30
- 230000003213 activating effect Effects 0.000 description 16
- 150000001875 compounds Chemical class 0.000 description 16
- 239000003795 chemical substances by application Substances 0.000 description 15
- 239000000460 chlorine Substances 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 12
- 229910052801 chlorine Inorganic materials 0.000 description 11
- 229910052739 hydrogen Inorganic materials 0.000 description 11
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 10
- 150000001491 aromatic compounds Chemical class 0.000 description 10
- 239000001257 hydrogen Substances 0.000 description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 9
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 8
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 8
- 238000005984 hydrogenation reaction Methods 0.000 description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 238000005660 chlorination reaction Methods 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 239000011593 sulfur Substances 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000010779 crude oil Substances 0.000 description 3
- 229910052809 inorganic oxide Inorganic materials 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- HNRMPXKDFBEGFZ-UHFFFAOYSA-N 2,2-dimethylbutane Chemical compound CCC(C)(C)C HNRMPXKDFBEGFZ-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 239000003570 air Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 2
- 239000012320 chlorinating reagent Substances 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 230000007420 reactivation Effects 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- DTBDAFLSBDGPEA-UHFFFAOYSA-N 3-Methylquinoline Natural products C1=CC=CC2=CC(C)=CN=C21 DTBDAFLSBDGPEA-UHFFFAOYSA-N 0.000 description 1
- 229910000873 Beta-alumina solid electrolyte Inorganic materials 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical class CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical class C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Chemical class 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 125000002015 acyclic group Chemical group 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229910001680 bayerite Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 238000001030 gas--liquid chromatography Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 150000004684 trihydrates Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
- C07C5/2724—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
- B01J27/13—Platinum group metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2767—Changing the number of side-chains
- C07C5/277—Catalytic processes
- C07C5/2791—Catalytic processes with metals
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB316171 | 1971-01-26 | ||
| GB316171 | 1971-01-26 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DK141337B true DK141337B (da) | 1980-02-25 |
| DK141337C DK141337C (OSRAM) | 1980-08-18 |
Family
ID=9753093
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK12372AA DK141337B (da) | 1971-01-26 | 1972-01-11 | Fremgangsmåde til igangsætning af en proces til isomerisering af paraffiner. |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US3789082A (OSRAM) |
| JP (1) | JPS5516194B1 (OSRAM) |
| AT (1) | AT319447B (OSRAM) |
| AU (1) | AU464284B2 (OSRAM) |
| BE (1) | BE778530A (OSRAM) |
| CA (1) | CA928728A (OSRAM) |
| DE (1) | DE2202570C3 (OSRAM) |
| DK (1) | DK141337B (OSRAM) |
| FR (1) | FR2124695A5 (OSRAM) |
| GB (1) | GB1333989A (OSRAM) |
| IT (1) | IT957509B (OSRAM) |
| NL (1) | NL173843C (OSRAM) |
| SE (1) | SE394424B (OSRAM) |
| YU (1) | YU39014B (OSRAM) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2206124B1 (OSRAM) * | 1972-11-10 | 1976-08-20 | Inst Francais Du Petrole | |
| US4324937A (en) * | 1980-01-16 | 1982-04-13 | Uop Inc. | Conversion of propane and butane into gasoline |
| US4324936A (en) * | 1980-12-29 | 1982-04-13 | Uop Inc. | Butane isomerization process |
| US4341911A (en) * | 1980-12-29 | 1982-07-27 | Uop Inc. | Hydrocarbon conversion process for the production of gasoline |
| US4347399A (en) * | 1981-06-03 | 1982-08-31 | Uop Inc | Isomerization of normal butane |
| US4612293A (en) * | 1985-09-27 | 1986-09-16 | Phillips Petroleum Company | Upgrading of spent butane isomerization catalyst to pentane isomerization catalyst |
| US4644090A (en) * | 1985-09-27 | 1987-02-17 | Phillips Petroleum Company | Upgrading of spent butane isomerization catalyst to pentane isomerization catalyst |
| US4877919A (en) * | 1988-04-25 | 1989-10-31 | Uop | Butane isomerization in the presence of C5 and C6 hydrocarbons |
| US5082989A (en) * | 1989-12-29 | 1992-01-21 | Uop | Integrated process for C4, C5 and C6 isomerization |
| US5705731A (en) * | 1995-12-06 | 1998-01-06 | Phillips Petroleum Company | Reactivation of hydrocarbon isomerization catalysts |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2939896A (en) * | 1957-12-09 | 1960-06-07 | Phillips Petroleum Co | Isomerization process and catalyst |
| US3248320A (en) * | 1960-12-01 | 1966-04-26 | British Petroleum Co | Isomerisation of paraffin hydrocarbons |
| GB1028572A (en) * | 1962-06-26 | 1966-05-04 | British Petroleum Co | Improvements relating to chlorine-containing catalysts |
| US3242229A (en) * | 1963-05-17 | 1966-03-22 | Texaco Inc | Hydrocarbon conversion process |
| US3419503A (en) * | 1966-06-30 | 1968-12-31 | Gulf Research Development Co | Activating a composite catalyst with hcl prior to a carbon chloride treatment |
| US3527715A (en) * | 1966-08-02 | 1970-09-08 | Gulf Research Development Co | Regeneration of chlorine containing metalliferous-alumina isomerization catalysts |
-
1971
- 1971-12-23 CA CA130945A patent/CA928728A/en not_active Expired
- 1971-12-30 FR FR7147654A patent/FR2124695A5/fr not_active Expired
- 1971-12-30 AU AU37475/71A patent/AU464284B2/en not_active Expired
- 1971-12-31 GB GB316171*[A patent/GB1333989A/en not_active Expired
-
1972
- 1972-01-05 US US00215650A patent/US3789082A/en not_active Expired - Lifetime
- 1972-01-07 YU YU00033/72A patent/YU39014B/xx unknown
- 1972-01-11 DK DK12372AA patent/DK141337B/da not_active IP Right Cessation
- 1972-01-12 JP JP579772A patent/JPS5516194B1/ja active Pending
- 1972-01-13 AT AT26972A patent/AT319447B/de not_active IP Right Cessation
- 1972-01-15 IT IT47745/72A patent/IT957509B/it active
- 1972-01-20 NL NLAANVRAGE7200784,A patent/NL173843C/xx not_active IP Right Cessation
- 1972-01-20 DE DE2202570A patent/DE2202570C3/de not_active Expired
- 1972-01-25 SE SE7200802A patent/SE394424B/xx unknown
- 1972-01-26 BE BE778530A patent/BE778530A/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| NL173843C (nl) | 1984-03-16 |
| YU39014B (en) | 1984-02-29 |
| BE778530A (fr) | 1972-07-26 |
| DE2202570B2 (de) | 1981-02-26 |
| NL173843B (nl) | 1983-10-17 |
| GB1333989A (en) | 1973-10-17 |
| YU3372A (en) | 1982-02-28 |
| CA928728A (en) | 1973-06-19 |
| AU3747571A (en) | 1973-07-05 |
| AT319447B (de) | 1974-12-27 |
| IT957509B (it) | 1973-10-20 |
| DE2202570A1 (de) | 1972-08-17 |
| DE2202570C3 (de) | 1982-02-25 |
| SE394424B (sv) | 1977-06-27 |
| US3789082A (en) | 1974-01-29 |
| AU464284B2 (en) | 1975-08-21 |
| NL7200784A (OSRAM) | 1972-07-28 |
| FR2124695A5 (OSRAM) | 1972-09-22 |
| DK141337C (OSRAM) | 1980-08-18 |
| JPS5516194B1 (OSRAM) | 1980-04-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PBP | Patent lapsed |