DEP0037280DA - Process for the separation of cyanuric chloride from subliming iron salts - Google Patents

Process for the separation of cyanuric chloride from subliming iron salts

Info

Publication number
DEP0037280DA
DEP0037280DA DEP0037280DA DE P0037280D A DEP0037280D A DE P0037280DA DE P0037280D A DEP0037280D A DE P0037280DA
Authority
DE
Germany
Prior art keywords
cyanuric chloride
subliming
separation
iron salts
chloride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
Other languages
German (de)
Inventor
Otto Dr. Konstanz Fuchs
Hermann Dr. Konstanz Schulz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Deutsche Gold und Silber Scheideanstalt
Publication date

Links

Description

EÄ.13736^EÄ.13736 ^

Xteutsolie Gold- waä ^über«- Schcideanstalt TormalsXteutsolie Goldwaä ^ über «- Schcideanstalt Tormals

m/U * ueiesfiraitnetraee· 9 m / U * ueiesfiraitnetraee 9

Tferfcüura» «f Tyeanujng Tor. Cyanurchlorid ausTferfcüura »« f Tyeanujng gate. Cyanuric chloride

Kb i@% Mannt» d&oroytn im Cegeawart von Katalysatoren im Cjaiiiircüloriö tibtamfcftthreae Is ist auch bereite w*g«0@ÄlA gen aorden, hierbei Metßllchlcride eis Katalysatoren suKb i @% Mannt »d & oroytn in the cegeawart of catalysts in the Cjaiiiircüloriö tibtamfcftthreae Is also ready w * g« 0 @ ÄlA gen aorden, here Metßllchlcride ice catalysts see below

*t®m®mi®ii<s Tersuehc? habGii auu ergeben, dass die Polymerisation if<m Chlorcji^n ^u CyAiAUi^cIu-OrId Bit guter Ausbeute coeriialb 5oo° in GegMieart von * t®m®mi®ii <s Tersuehc? habGii auu show that the polymerization if <m Chlorcji ^ n ^ u CyAiAUi ^ cIu-OrId bit good yield coeriialb 5oo ° in GegMieart of

duroiigeführt werden k^mr Bei dieses Terfabxen JEöOht ßioh jedooli die ^u'olis^tionsteaderis tob bei 4ea .-irbeitsteatperat reu mh® cdcr weniger flüchtigen Eiseus«l£enf insbesonderek ^ m r at this Terfabxen JEöOht ßioh jedooli the ^ u'olis ^ tionsteaderis tob bei 4ea.-irbeitsteatperat reu mh® cdcr less volatile Eiseus «l £ en f in particular

stireaä beaerk^r, dass Uas 4\iroh das fIUoJati;?astireaä beaerk ^ r that Uas 4 \ iroh das fIUoJati;? a

Is mn*ä@ nun jge&&4föt dass eine n&ohtragliohQ Heini gtuo^ eines auf ui'jse W@i0e burgee teilten Cyacurchloride nioht lioh. ist.; 9ms& warn die Reaktioncproöiücte durah b«2 poröse Kohle, inebssondere Äktirkohle, leitet, U"berrasalieiiderweiße 1st sioh dabei geseilt, dass die flüoktigen liisensalae, insbesondere ^isen- 3-Cblorid,' auch bei höheren '-TeiBperatiireii^ die 0%ertoalb dor SubliiDAtionagrense, sogar oberhalb d«a Siede punk tee ten Ferrichlorid liegen, von der Kohle se «eitgehcnd adsorbiert werden, dass eise praktißah rollstäadige von dem Cyanurchlorid möglich ist Obm CyaniirohloridIs mn * ä @ nun jge && 4fö t that a n & ohtragliohQ Heini gtuo ^ a cyacuric chloride shared on ui'jse W @ i0e burgee nioht lioh. is.; 9 ms & warn the reaction proiücte because b «2 porous charcoal, in particular charcoal, conducts, U" berrasalieiiderweisse is rushed to ensure that the volatile liisensalae, in particular ^ isen-3-chloride, 'also at higher' -peratiireii ^ the 0% SubliDAtionagrense, even above the boiling points of the ferric chloride, are adsorbed by the carbon in a way that the cyanuric chloride can be practically unrolled, even as cyanuric chloride

passiert die ^ohle Wi den Arbeitetemperature^ a B 2oo und 45o° liinTerändert und naheau Quantität irhappens the ^ ohle Wi the working temperature ^ a B 2oo and 45o ° liinTerierter and near the quantity ir

Claims (1)

Itie&lsss ff ill sItie & lsss ff ill s mm ^emmmg von C^aaarohlorid uod %·& mm ^ emmmg of C ^ aaarohlorid uod% & 2oo und °2oo and ° wi« Eisen-Chlorid, inetesoadere %*t d«r voa Cyanurehloriö mm Chloreyen ia GegeatMtrt eisenhaltigen fiataljsatoreii, dadurch gekemiseioluiet, oma Öle ^iapfe, die Cyamirohlorid und die flüohtl^»wi «iron chloride, inetesoadere% * td« r voa Cyanurehloriö mm Chloreyen ia inhaled ferrous fiataljsatoreii, thereby gekemiseioluiet, oma oils ^ iapfe, the Cyamirohlorid and the flüohtl ^ » t€n? durok %mm* über poröaet € n ? durok % mm * over poröae , ktivkohie, leitet,, ktivkohie, directs,

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