DE921475C - Production of cleaning agents on an oil basis - Google Patents

Production of cleaning agents on an oil basis

Info

Publication number
DE921475C
DE921475C DEB19596A DEB0019596A DE921475C DE 921475 C DE921475 C DE 921475C DE B19596 A DEB19596 A DE B19596A DE B0019596 A DEB0019596 A DE B0019596A DE 921475 C DE921475 C DE 921475C
Authority
DE
Germany
Prior art keywords
cleaning agents
production
carboxyl groups
oil basis
oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEB19596A
Other languages
German (de)
Inventor
Michael Dr Aschenbrenner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to DEB6216D priority Critical patent/DE854980C/en
Application filed by BASF SE filed Critical BASF SE
Priority to DEB19596A priority patent/DE921475C/en
Application granted granted Critical
Publication of DE921475C publication Critical patent/DE921475C/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09G—POLISHING COMPOSITIONS; SKI WAXES
    • C09G1/00—Polishing compositions
    • C09G1/06—Other polishing compositions
    • C09G1/08—Other polishing compositions based on wax

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)

Description

Herstellung von Putzmitteln auf Ölgrundlage Gegenstand des Patents 854980 ist die Verwendung von wachsartigen Stoffen, die erhalten werden, indem man in die bei. der Hydrierung der Oxyde des Kohlenstoffs erhältlichen, sehr hochmolekularen Kohlenwasserstoffe in. an sich bekannter Weise Carboxylgruppen in geringer Menge einführt und diese gegebenenfalls verestert, in der Putzmittelindustrie.Manufacture of oil-based cleaning agents The subject of patent 854980 is the use of waxy substances obtained by working in the. the hydrogenation of the oxides of carbon, very high molecular weight hydrocarbons obtainable in a manner known per se introduces small amounts of carboxyl groups and optionally esterifies them in the cleaning agent industry.

Es wurde nun gefunden, daß die Verwendbarkeit der Putzmittel mit diesen wachsartigen Stoffen. noch wesentlich verbessert wird, wenn die in diesen Stoffen noch vorhandenen reaktionsfähigen Carboxylgruppen ganz oder zum Teil mit Verbindungen zweiwertiger Metalle, insbesondere Verbindungen des Calciums, Strontiums, Bariums oder Magnesiums., unter Salzbildung umgesetzt sind, z. B. zweckmäßig durch Behandlung der nicht oder teilweise veresterten, Carboxylgruppen enthaltenden Produkte mit den Oxyden, Hydroxyden oder Carbonaten der zweiwertigen Metalle bei erhöhter Temperatur. Eine gleich gute Wirkung zeigen. die teilweise in die Salze übergeführten und erst danach mit ein- oder mehrwertigen Alkoholen veresterten Produkte. Auch die Verwendung von Salzgemischen, z. B. von Calcium- und Magnesiumsalzen, ist manchmal von Vorteil.It has now been found that the usability of the cleaning agents with these waxy substances. is still much improved if the in these substances remaining reactive carboxyl groups wholly or partly with compounds divalent metals, especially compounds of calcium, strontium, barium or magnesium., are reacted with salt formation, e.g. B. expedient by treatment the non-esterified or partially esterified products containing carboxyl groups the oxides, hydroxides or carbonates of the divalent metals at elevated temperature. Show an equally good effect. the partially converted into the salts and only then products esterified with mono- or polyhydric alcohols. Also the use of salt mixtures, e.g. B. calcium and magnesium salts is sometimes beneficial.

Durch diese Salze zweiwertiger Metalle werden insbesondere das Ölbindevermögen, die glanzgebenden Eigenschaften sowie vor allem der Oberflächenspiegel der mit den erfindungsgemäßen Zusätzen versehenen Putzmittel wesentlich verbessert.These salts of divalent metals in particular increase the oil binding capacity, the gloss properties and, above all, the surface level of the according to the invention Cleaning agents provided with additives are significantly improved.

Beispiel Ein durch Kohlenoxydhydrierung gewonnenes, bei etwa ioo° schmelzendes Paraffin. wird in Gegenwart eines. in der Paraffinoxydation üblichen Katalysators so lange bei i io° mit Luft geblasen, bis das Produkt die Säurezahl 5o erreicht hat. Darauf wird es mit :2 Gewichtsprozent i, 3-Butylenglykol bis zur Säurezahl 30 verestert. Das Veresterungsprodukt wird sodann. mit 2 Gewichtsprozent eines Gemisches aus gleichen Teilen Calciumhydroxyd und Strontiumhydroxyd bei 13o° behandelt, wobei Salzbildung eintritt.Example A paraffin obtained by hydrogenation of carbohydrates that melts at about 100 °. becomes in the presence of a. The usual catalyst in paraffin oxidation is blown with air at 10 ° until the product has reached the acid number 50. It is then esterified with: 2 percent by weight of i, 3-butylene glycol up to an acid number of 30. The esterification product is then. treated with 2 percent by weight of a mixture of equal parts calcium hydroxide and strontium hydroxide at 130 °, whereby salt formation occurs.

7 Gewichtsteile des so erhaltenen Produktes werden mit i Gewichtsteil Ozokerit, io Gewichtsteilen Paraffin und o,i Gewichtsteil eines Sudan: farbstoffes verschmolzen und darauf mit 75 Gewichtsteilen Terpentinöl versetzt. Man erhält eine Schuhputzmasse von ausgezeichneter Bindung, guter Glanzwirkung und gutem Oberflächenspiegel.7 parts by weight of the product thus obtained are 1 part by weight Ozokerite, 10 parts by weight of paraffin and 0.1 part by weight of a Sudan: dye melted and then mixed with 75 parts by weight of turpentine oil. You get one Shoe polishing compound with excellent binding, good gloss effect and good surface finish.

Claims (2)

PATENTANSPRÜCHE: i. Verwendung von wachsartigen Stoffen für die Herstellung von Putzmitteln auf Ölgrundlage gemäß Patent 854 980 unter Benutzung der gleichen, geringe Mengen Carboxylgruppen enthaltenden. Gemische, dadurch gekennzeichnet, daß hier solche Gemische dieser Art verwendet werden, in denen die vorhandenen Carboxylgruppen ganz oder teilweise an zweiwertige Metalle gebunden sind. PATENT CLAIMS: i. Use of waxy substances for the production of oil-based cleaning agents according to patent 854 980 using the same, small amounts of carboxyl groups. Mixtures, characterized in that mixtures of this type are used here in which the carboxyl groups present are wholly or partially bound to divalent metals. 2. Verwendung von wachsartigen Stoffen gemäß Anspruch i, dadurch gekennzeichnet, daß die Carboxylgruppen teils an zweiwertige Metalle gebunden, teils mit Alkoholen verestert sind.2. Use of waxy substances according to claim i, characterized in that that the carboxyl groups are partly bound to divalent metals, partly with alcohols are esterified.
DEB19596A 1943-07-14 1952-03-20 Production of cleaning agents on an oil basis Expired DE921475C (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DEB6216D DE854980C (en) 1943-07-14 1943-07-14 Production of cleaning agents on an oil basis
DEB19596A DE921475C (en) 1943-07-14 1952-03-20 Production of cleaning agents on an oil basis

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEB6216D DE854980C (en) 1943-07-14 1943-07-14 Production of cleaning agents on an oil basis
DEB19596A DE921475C (en) 1943-07-14 1952-03-20 Production of cleaning agents on an oil basis

Publications (1)

Publication Number Publication Date
DE921475C true DE921475C (en) 1954-12-20

Family

ID=33098939

Family Applications (2)

Application Number Title Priority Date Filing Date
DEB6216D Expired DE854980C (en) 1943-07-14 1943-07-14 Production of cleaning agents on an oil basis
DEB19596A Expired DE921475C (en) 1943-07-14 1952-03-20 Production of cleaning agents on an oil basis

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DEB6216D Expired DE854980C (en) 1943-07-14 1943-07-14 Production of cleaning agents on an oil basis

Country Status (1)

Country Link
DE (2) DE854980C (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1044321B (en) * 1954-02-22 1958-11-20 Ruhrchemie Ag Waxes for liquid, anhydrous polishing compounds
DE1123783B (en) * 1954-02-22 1962-02-15 Ruhrchemie Ag Waxes for liquid, anhydrous polishing compounds
DE1007911B (en) * 1954-02-22 1957-05-09 Ruhrchemie Ag Waxes for liquid, anhydrous polishing compounds

Also Published As

Publication number Publication date
DE854980C (en) 1952-11-10

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