DE907287C - Process for finishing textiles - Google Patents

Process for finishing textiles

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Publication number
DE907287C
DE907287C DEB5964D DEB0005964D DE907287C DE 907287 C DE907287 C DE 907287C DE B5964 D DEB5964 D DE B5964D DE B0005964 D DEB0005964 D DE B0005964D DE 907287 C DE907287 C DE 907287C
Authority
DE
Germany
Prior art keywords
weight
parts
chlorohydrate
amines
textiles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEB5964D
Other languages
German (de)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to DEB5964D priority Critical patent/DE907287C/en
Application granted granted Critical
Publication of DE907287C publication Critical patent/DE907287C/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/12—Aldehydes; Ketones
    • D06M13/127—Mono-aldehydes, e.g. formaldehyde; Monoketones
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/12—Aldehydes; Ketones
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423—Amino-aldehyde resins

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Description

(WiGBl. S. 175)(WiGBl. P. 175)

AUSGEGEBEN AM 22. MÄRZ 1954ISSUED MARCH 22, 1954

S 5964 IVdf 8 kS 5964 IVdf 8 k

(Ges. v. 15. 7. 51)(Ges. V. July 15, 51)

1Es ist bereits ein Verfahren zum Veredeln von Textilien, insbesondere Cellulosefasern, vorgeschlagen worden, welches darin besteht, daß man die Textilien mit Lösungen von Formaldehyd in Gegenwart von sauer reagierenden Verbindungen und unter Zusatz von nicht harzartigen bzw. harzbildenden stickstoffhaltigen organischen Verbindungen oder mit Einwirkungsprodukten von Äthylenoxyd auf höhermolekulare Fettsäuren oder Alkohole bzw. ihren Derivaten imprägniert und gleichzeitig oder anschließend Temperaturen von ioo° und darüber aussetzt. 1 A process for finishing textiles, in particular cellulose fibers, has already been proposed, which consists in treating the textiles with solutions of formaldehyde in the presence of acidic compounds and with the addition of non-resinous or resin-forming nitrogen-containing organic compounds or with action products of ethylene oxide impregnated with higher molecular weight fatty acids or alcohols or their derivatives and at the same time or afterwards exposing them to temperatures of 100 ° and above.

Es wurde nun gefunden, daß man Textilien veredeln kann, wenn man sie mit wäßrigen Lösungen von Salzen aus Aminen mit mehr als 5 Kohlenstoffatomen und mit Aldehyden oder aldehydabgebenden Substanzen und starken Säuren tränkt und anschließend Temperaturen von etwa ioo° und darüber aussetzt. Als Salze von Aminen kommen beispielsweise die Chloride und Sulfate von solchen Aminen in Frage, die einen geraden oder verzweigten aliphatischen oder cycloaliphatischen Rest mit mehr als S Kohlenstoffatomen enthalten, die auch durch andere Atome oder Atomgruppen, z. B. O, S, NH, unterbrochen sein kann. Als solche Salze von Aminen seien beispielsweise genannt: Octylaminchlorhydrat, Dodecylaminchlorhydrat,' Stearylaminchlorhydrat, die Chlorhydrate und Sulfate der Amine, die aus technischer Stearinsäure, Kokosölfettsäure, Palmkernölfettsäure, Tranfettsäure, Naphthensäure, Montansäure oder Harzslure hergestellt sind; ferner Octylfurfurylaminchlorhydrat, Glucaminchlorhydrat und Phenylstearylaminchlorhydrat. It has now been found that textiles can be finished by using aqueous solutions of salts of amines with more than 5 carbon atoms and with aldehydes or aldehyde donors Substances and strong acids soaks and then temperatures of about 100 ° and above suspends. The chlorides and sulfates of such amines, for example, come as salts of amines Amines in question, which have a straight or branched aliphatic or cycloaliphatic radical containing more than S carbon atoms, which are also replaced by other atoms or groups of atoms, e.g. B. O, S, NH, can be interrupted. Examples of such salts of amines are: Octylamine chlorohydrate, Dodecylamine chlorohydrate, 'stearylamine chlorohydrate, the chlorohydrates and sulfates of the Amines derived from technical stearic acid, coconut oil fatty acid, palm kernel oil fatty acid, tran fatty acid, Naphthenic acid, montanic acid or rosin acid are produced; also octylfurfurylamine chlorohydrate, Glucamine chlorohydrate and phenyl stearylamine chlorohydrate.

Diese Salze können in Form ihrer Lösungen oder Emulsionen verwendet werden. Als Aldehyde kommen beispielsweise in Frage: Formaldehyd und Glyoxal; als aldehydabgebende Substanzen seien beispielsweise genannt: Dimethylolharnstoff und Dimethylolformamid. Die Aldehyde kommen in Form ihrer wäßrigen Lösungen zur Verwendung. Formaldehyd kann auch gasförmig verwendet werden.These salts can be used in the form of their solutions or emulsions. As aldehydes for example: formaldehyde and glyoxal; as aldehyde-releasing substances named for example: dimethylolurea and dimethylolformamide. The aldehydes come in Form of their aqueous solutions for use. Formaldehyde can also be used in gaseous form will.

Die nach dem oben angegebenen Verfahren behandelten Textilien zeichnen sich durch gute Knitterfestigkeit und einen angenehmen weichen Griff aus.The textiles treated by the above process are characterized by good quality Crease resistance and a pleasant soft grip.

Beispiel ιExample ι

2O Gewichtsteile Dodecylaminchlorhydrat werden in 2OO Gewichtsteilen warmem Wasser gelöst. Nach Zufügen von 300 Gewichtsteilen einer 3Sprozentigen Formaldehydlösung wird Viscosegewebe 15 Minuten lang bei normaler Temperatur behandelt, abgequetscht und zunächst bei etwa 500 getrocknet, worauf eine Heißbehandlung auf dem Spannrahmen oder auf der Zylindertrockenmaschine bei etwa 100 bis 11 o° für kurze Zeit erfolgt.20 parts by weight of dodecylamine chlorohydrate are dissolved in 200 parts by weight of warm water. After adding 300 parts by weight of a 3Sprozentigen formaldehyde solution Viscosegewebe is treated at normal temperature for 15 minutes, squeezed, and dried first at about 50 0, is carried out whereupon a heat treatment in the tenter frame or on the cylinder drying machine at about 100 to 11 ° ° for a short time.

Beispiel 2Example 2

30 Gewichtsteile Stearylaminsulfat und 30 Gewichtsteile technischen Glyoxal werden in 300 Gewichtsteilen destilliertem Wasser gelöst. Viscosegewebe wird mit dieser Lösung kurze Zeit bei normaler Temperatur imprägniert. Nach darauffolgender Wärmebehandlung bei etwa iooc erhält man ein Gewebe, das sehr gut knitterfest ist.30 parts by weight of stearylamine sulfate and 30 parts by weight of technical grade glyoxal are dissolved in 300 parts by weight of distilled water. Viscose fabric is impregnated with this solution for a short time at normal temperature. After a subsequent heat treatment at around 100 ° C , a fabric is obtained that is very crease-resistant.

Beispiel 3Example 3

80 Gewichtsteile Dimethylolharnstoff und 10 Gewichtsteile des aus Kokosölfettsäure hergestellten Aminchlorhydrate werden mit 1000 Gewichtsteilen warmem Wasser Übergossen. In der auf etwa 40 bis 500 erwärmten Lösung wird Viscosegewebe 5 Minuten lang behandelt, abgequetscht und nach kurzem Trocknen einer Heißbehandlung bei etwa 115° unter möglichst gutem Glatthalten des Gewebes unterworfen. Das Gewebe ist durch diese Behandlung gut knitterfest geworden. +580 parts by weight of dimethylolurea and 10 parts by weight of the amine chlorohydrate prepared from coconut oil fatty acid are poured over with 1000 parts by weight of warm water. In the to about 40 to 50 0 Viscosegewebe heated solution is treated for 5 minutes, squeezed out and subjected to brief drying a heat treatment at about 115 ° with good as smooth as possible holding of the tissue. This treatment has made the fabric crease-resistant. +5

Beispiel 4Example 4

8 Gewichtsteile des Chlorhydrats des technischen Amingemisches, welches aus der Kokosölfettsäure hergestellt ist, werden in 100 Gewichtsteilen Wasser gelöst. In dieser Lösung wird Viscosegewebe 10 Minuten bei 15 bis 200 behandelt. Das Gewebe wird dann abgequetscht und in einer Kammer etwa 20 Minuten mit Formaldehyddampf behandelt. Das Gewebe wird dann, wie im Beispiel ι beschrieben, einer Heißbehandlung unterworfen. Man erhält ein gut knitterfestes Gewebe von weichem Griff.8 parts by weight of the chlorohydrate of the technical amine mixture, which is produced from the coconut oil fatty acid, are dissolved in 100 parts by weight of water. In this solution Viscosegewebe is treated for 10 minutes at 15 to 20 0th The tissue is then squeezed off and treated with formaldehyde vapor in a chamber for about 20 minutes. The fabric is then, as described in Example ι, subjected to a heat treatment. A well-crease-resistant fabric with a soft handle is obtained.

Claims (1)

Patentanspruch:Claim: Verfahren zum Veredeln von Textilien, dadurch gekennzeichnet, daß man diese mit wäßrigen Lösungen von Salzen aus Aminen mit einem aliphatischen oder cycloaliphatischen Rest mit mehr als 5 Kohlenstoffatomen und starken Säuren und mit Aldehyden oder aldehydabgebenden Substanzen tränkt und anschließend Temperaturen von etwa ioo° und darüber aussetzt.Process for finishing textiles, characterized in that this is done with aqueous solutions of salts from amines with an aliphatic or cycloaliphatic radical with more than 5 carbon atoms and strong acids and with aldehydes or aldehyde donors Soaks substances and then temperatures of about 100 ° and above suspends. Angezogene Druckschriften:
Deutsche Patentschrift Nr. 492 664.Referred publications:
German patent specification No. 492 664. © 5849 3.54© 5849 3.54
DEB5964D 1933-08-19 1934-12-13 Process for finishing textiles Expired DE907287C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEB5964D DE907287C (en) 1933-08-19 1934-12-13 Process for finishing textiles

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE2118685X 1933-08-19
DE452248X 1934-12-13
DEB5964D DE907287C (en) 1933-08-19 1934-12-13 Process for finishing textiles

Publications (1)

Publication Number Publication Date
DE907287C true DE907287C (en) 1954-03-22

Family

ID=32043849

Family Applications (1)

Application Number Title Priority Date Filing Date
DEB5964D Expired DE907287C (en) 1933-08-19 1934-12-13 Process for finishing textiles

Country Status (4)

Country Link
US (2) US2118685A (en)
DE (1) DE907287C (en)
FR (2) FR777426A (en)
GB (2) GB426956A (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2420730A (en) * 1944-06-09 1947-05-20 Du Pont Treatment of polymers with acylamides and aldehydes
US3089747A (en) * 1958-04-04 1963-05-14 American Viscose Corp Method of preparing rayon plisse
BE594748A (en) * 1959-06-10
US3465036A (en) * 1964-07-07 1969-09-02 American Cyanamid Co 2-carboxyethoxymethyl-tris (2-(n-methylolcarbamoyl)-ethoxymethyl) methane
CN103243433A (en) * 2013-05-21 2013-08-14 海安县鑫荣纺织有限责任公司 Blended yarn of cotton fiber, coconut fiber and silkworm pupa protein fiber
CN114349933B (en) * 2021-12-24 2023-05-30 万华化学集团股份有限公司 Self-repairing waterborne polyurethane and preparation method and application thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE492664C (en) * 1920-05-19 1930-02-27 Hans Karplus Dr Process for the finishing of rayon, staple fiber and fabrics made from them

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE492664C (en) * 1920-05-19 1930-02-27 Hans Karplus Dr Process for the finishing of rayon, staple fiber and fabrics made from them

Also Published As

Publication number Publication date
GB426956A (en) 1935-04-11
GB452248A (en) 1936-08-19
FR46935E (en) 1936-11-07
US2143352A (en) 1939-01-10
US2118685A (en) 1938-05-24
FR777426A (en) 1935-02-19

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