DE894591C - Process for the production of water-insoluble coatings of resulting water-containing emulsions - Google Patents
Process for the production of water-insoluble coatings of resulting water-containing emulsionsInfo
- Publication number
- DE894591C DE894591C DED4258D DED0004258D DE894591C DE 894591 C DE894591 C DE 894591C DE D4258 D DED4258 D DE D4258D DE D0004258 D DED0004258 D DE D0004258D DE 894591 C DE894591 C DE 894591C
- Authority
- DE
- Germany
- Prior art keywords
- water
- production
- insoluble
- containing emulsions
- insoluble coatings
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000839 emulsion Substances 0.000 title claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 8
- 238000000576 coating method Methods 0.000 title claims description 6
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 238000000034 method Methods 0.000 title claims description 3
- 239000002253 acid Substances 0.000 claims description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 6
- 239000011230 binding agent Substances 0.000 claims description 6
- 150000007513 acids Chemical class 0.000 claims description 3
- 150000003863 ammonium salts Chemical class 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 125000005842 heteroatom Chemical group 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 239000000344 soap Substances 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 125000004429 atom Chemical group 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 239000000025 natural resin Substances 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000012170 montan wax Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- HPSBYYHIHGQARI-UHFFFAOYSA-N 2-octoxyacetic acid Chemical compound CCCCCCCCOCC(O)=O HPSBYYHIHGQARI-UHFFFAOYSA-N 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 150000004653 carbonic acids Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- -1 color bodies Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- WEZYFYMYMKUAHY-UHFFFAOYSA-N tert-butyl 2,4-dibenzylpiperazine-1-carboxylate Chemical compound C1C(CC=2C=CC=CC=2)N(C(=O)OC(C)(C)C)CCN1CC1=CC=CC=C1 WEZYFYMYMKUAHY-UHFFFAOYSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/022—Emulsions, e.g. oil in water
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Description
Verfahren zur Herstellung wasserunlösliche Überzüge ergebender wasserhaltiger Emulsionen Es wurde gefunden, daß zur Herstellung wasserunlöslicher Überzüge solche Emulsionen von .gebräuchlichen wasserunlöslichen organischen Bindemitteln besonders geeignet sind, die unter Zusatz von Ammoniumsalzen wasserunlöslicher, durch Heteroatome, insbesondere Sauerstoff, unterbrochener Carbonsäuren mit höchstens i2 Koh.lenstoffatomen oder Gemischen der genannten Säuren bereitet sind. Diese Säuren., von denen beispielsweise Butoxyessigsäure, Octyloxyessigsäure, Alkoxyessigsäure mit 7 bis g. Kohlenstoffatomen im Alkylrest, ß-Octyloxypropi.onsäure, ß-But.oxybuttersäure, Naphthenyl.oxyessigsäure genannt sein mögen, zeichnen sich dadurch aus, :daß sie in den gebräuchlichen wasserunlöslichen organischen Bindemitteln sehr gut löslich sind und in Form ihrer Ammoniumsalze ausgezeichnete Emulgatoren und Lösungsvermittler darstellen..Process for the production of water-containing coatings which are insoluble in water Emulsions It has been found that such coatings can be used for the production of water-insoluble coatings Emulsions of common water-insoluble organic binders in particular are suitable which, with the addition of ammonium salts, are less soluble in water, due to heteroatoms, in particular oxygen, interrupted carboxylic acids with a maximum of 12 carbon atoms or mixtures of the acids mentioned are prepared. These acids., Of which for example Butoxyacetic acid, octyloxyacetic acid, alkoxyacetic acid with 7 to g. Carbon atoms in the alkyl radical, ß-octyloxypropionic acid, ß-butoxybutyric acid, naphthenyloxyacetic acid may be mentioned, are characterized by: that they are in the usual water-insoluble Organic binders are very soluble and excellent in the form of their ammonium salts Represent emulsifiers and solubilizers.
An Bindemitteln für die Herstellung der 'hier in. Rede stehendenwasserhaltigenEmulsionen kommen in Betracht: Montanwachs, Erdwachs, -Säureharze und .künstliche Harze, wie z. B. Anilinharz, Phenolformaldehydh arz, Alkydharze, Polymerisationsprodukte, Chlorkautschuk, Asp'Ualte, Peche. Auch Gemische dieser Stoffe sind verwendbar, ebenso wie übl-icheZusatzstoffe, wie Pigmente, Farlb'körper, Plastifikatoren, zugegen sein können.Of binders for the production of the water-containing emulsions under discussion here The following can be considered: montan wax, earth wax, acid resins and artificial resins, such as z. B. aniline resin, phenol-formaldehyde resin, alkyd resins, polymerization products, chlorinated rubber, Asp'Ualte, bad luck. Mixtures of these substances can also be used, as can common additives, such as pigments, color bodies, plasticizers, can be present.
Der Vorteil der erfindungsgemäß beschriebenen Emulsionen besteht darin, daß die Ammoniumseifen der durch Heteroat,oime unterbrochenen C.arbonsäugen beim Trocknungsvorgang auch nach Abspalturig des -Ammoniaks klare Lösungen bzw. Überzüge ergeben.The advantage of the emulsions described according to the invention is that that the ammonium soaps of the carbonic acids interrupted by heteroat, oime at the Drying process, even after the ammonia has been split off, clear solutions or coatings result.
Die Herstellung der Emulsionen, -die sowohl solche vom Typus Wasser-in-Öl al-s auch Öl-in-Wasser sein können, und ihre Anwendung enfblgt in allgemein bekannter Weise. Beispiele r. 5o Gewichtsteile Roh montanwach!; werden mit 5 Gewichtsteilen A1'koxyessigsäure, die im Alkylrest 7 bis 9 Kohlenstoffato(me enthält, verschmolzen und der Schmelze bei etwa 85° unter gutem Umrühren qo Gewichtsteile wäßriges 5@higes Ammoniak zugemischt. Die gebildete Emulsion- rührt man noch so lange nach, .bis sie gewöhnliche Temperatur erreicht hat. Sie kann alsdann als Bindemittel -für wasser- und wischfeste Anstriche Verwendung finden.The production of emulsions, both of the water-in-oil type al-s can also be oil-in-water, and their use is generally known Way. Examples r. 5o parts by weight of raw montan wax !; are with 5 parts by weight Al'koxyacetic acid, which contains 7 to 9 carbon atoms in the alkyl radical, fused and the melt at about 85 ° with thorough stirring qo parts by weight of aqueous 5% Ammonia mixed in. The emulsion formed is stirred for as long as .bis it has reached ordinary temperature. It can then be used as a binding agent for water and smudge-proof paints are used.
2. In 5o Gewichtsteilen eines Alkyd@harzes werden in der Wärme 5 Gewichtsteile der 2-Äthylhexyloxyes@sigsäure gelöst und der Lösung, bei etwa 5o° 2o Gewichtsteile einer 511/oigen wäßrigen Ammoniaklösung unter gutem Umrühren zugefügt. Es entsteht eine homogene Emulsion, die sich als Bindemittel für Außenanstriche mit Vorteil verwenden läßt.2. In 50 parts by weight of an alkyd resin, 5 parts by weight are added when heated the 2-Äthylhexyloxyes @ sigsäure dissolved and the solution, at about 5o ° 2o parts by weight a 511% aqueous ammonia solution was added with thorough stirring. It arises a homogeneous emulsion, which is useful as a binder for exterior paints lets use.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DED4258D DE894591C (en) | 1942-11-14 | 1942-11-14 | Process for the production of water-insoluble coatings of resulting water-containing emulsions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DED4258D DE894591C (en) | 1942-11-14 | 1942-11-14 | Process for the production of water-insoluble coatings of resulting water-containing emulsions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE894591C true DE894591C (en) | 1953-10-26 |
Family
ID=7030916
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DED4258D Expired DE894591C (en) | 1942-11-14 | 1942-11-14 | Process for the production of water-insoluble coatings of resulting water-containing emulsions |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE894591C (en) |
-
1942
- 1942-11-14 DE DED4258D patent/DE894591C/en not_active Expired
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE865193C (en) | Process for the preparation of a stabilized rubber milk composition blended with ammonia | |
| DE894591C (en) | Process for the production of water-insoluble coatings of resulting water-containing emulsions | |
| DE1696193A1 (en) | Satin white coating slips with good viscosity stability | |
| DE626585C (en) | Process for the preparation of polymerization products from styrene | |
| CH354878A (en) | Process for improving modified glycerol phthalate resins | |
| DE838215C (en) | Process for the production of aqueous phenolic resin dispersions | |
| DE585167C (en) | Process for the production of gravure inks | |
| DE959393C (en) | Process for the production of pigment dyes | |
| DE198470C (en) | ||
| DE554721C (en) | Process for the production of aqueous pigment suspensions | |
| DE1520069C3 (en) | Process for the production of deformable synthetic resin compositions | |
| DE536273C (en) | Process for the production of mineral oil sulfonic acids | |
| AT150603B (en) | Process for the production of a lacquer. | |
| DE2100439B2 (en) | Process for the production of preparations from disperse dyes and the use of these preparations | |
| DE625979C (en) | Process for the production of good running, high gloss, basic pigments, e.g. Zinc white, containing oil paint | |
| AT158421B (en) | Process for the production of a rubber-containing binder for fiber materials. | |
| DE423081C (en) | Process for the preparation of sulfoalkyl and sulfoaryl ethers from resinous condensation products derived from phenols | |
| DE841289C (en) | Process for the production of new amide cores | |
| DE543807C (en) | Process for the manufacture of printing inks using sulphite cellulose waste liquor | |
| DE933391C (en) | Use of copolymers as binders for printing inks | |
| DE712692C (en) | Process for the production of air-drying coating agents and leveling compounds | |
| DE636259C (en) | Process for the production of sulfuric acid compounds from polymerized unsaturated oxyfatty acids | |
| CH384116A (en) | Process for the production of aqueous emulsions or dispersions | |
| DE720110C (en) | Process for the production of phosphatide preparations which are soluble or easily dispersible in water | |
| DE2144421C3 (en) | Stable, concentrated, acidic stock solutions of anionic dyes, processes for their preparation and their uses |