DE84378C - - Google Patents
Info
- Publication number
- DE84378C DE84378C DENDAT84378D DE84378DA DE84378C DE 84378 C DE84378 C DE 84378C DE NDAT84378 D DENDAT84378 D DE NDAT84378D DE 84378D A DE84378D A DE 84378DA DE 84378 C DE84378 C DE 84378C
- Authority
- DE
- Germany
- Prior art keywords
- soda
- lactic acid
- salicylic
- acid
- double salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- YGSDEFSMJLZEOE-UHFFFAOYSA-N Salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 22
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 17
- 239000004310 lactic acid Substances 0.000 claims description 14
- 235000014655 lactic acid Nutrition 0.000 claims description 14
- 229960004889 salicylic acid Drugs 0.000 claims description 12
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 11
- 150000003839 salts Chemical class 0.000 claims description 8
- 239000011780 sodium chloride Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M NaHCO3 Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 10
- 235000017557 sodium bicarbonate Nutrition 0.000 description 5
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000000320 mechanical mixture Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- REWPEPFZCALMJB-UHFFFAOYSA-N 2-hydroxybenzoic acid;sodium Chemical compound [Na].OC(=O)C1=CC=CC=C1O REWPEPFZCALMJB-UHFFFAOYSA-N 0.000 description 1
- CRATWVMUDYSXNS-UHFFFAOYSA-M C([O-])(O)=O.[Na+].C(C(O)C)(=O)O Chemical compound C([O-])(O)=O.[Na+].C(C(O)C)(=O)O CRATWVMUDYSXNS-UHFFFAOYSA-M 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate dianion Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C65/00—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C65/01—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing hydroxy or O-metal groups
- C07C65/03—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing hydroxy or O-metal groups monocyclic and having all hydroxy or O-metal groups bound to the ring
- C07C65/05—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing hydroxy or O-metal groups monocyclic and having all hydroxy or O-metal groups bound to the ring o-Hydroxy carboxylic acids
- C07C65/10—Salicylic acid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C59/01—Saturated compounds having only one carboxyl group and containing hydroxy or O-metal groups
- C07C59/08—Lactic acid
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
PATENTAMPATENTAM
Den Gegenstand vorliegender Erfindung bildet ein Verfahren zur Darstellung eines Doppelsalzes aus milchsaurem und salicylsaurem Natron. Dieses Verfahren besteht in Folgendem: 1000 g Salicylsäure werden in so viel heifsem Wasser gelöst, dafs eine möglichst concentrirte Lösung entsteht. Hierzu setzt man Milchsäure in einer Menge, welche je nach dem gewünschten Gehalt des anzufertigenden Präparates an milchsaurem Natron gröfser oder kleiner sein kann. Dieses Gemisch neutralisirt man mit kohlensaurem Natron oder Aetznatron. Es lassen sich dann weitere Mengen von Salicylsäure und Milchsäure in ' der Flüssigkeit auflösen, welche man wiederum neutralisirt. In gleicher Weise fährt man fort, bis man schliefslich eine concentrirte Lösung von salicyl- und milchsaurem Natron besitzt. Diese Lösung wird im Wasserbade abgedampft. Man erhält daraus ein trockenes Doppelsalz,· das salicylmilchsaure Natron, welches mit »Salactol« bezeichnet werden mag. Anstatt das Natron der Salicyl- und Milchsäurelösung zuzusetzen, kann man auch in eine Natronlösung Salicyl- und-Milchsäure eintragen. Natürlich können auch Gemische aus Lösungen des salicyl- und des milchsauren Natrons, welche bekanntlich fertig im Handel zu haben sind, zur Trockne abgedampft werden.The subject matter of the present invention is a method for the preparation of a Double salt made from lactic acid and salicylic acid baking soda. This procedure consists of the following: 1000 g of salicylic acid are dissolved in so much hot water that one is as concentrated as possible Solution emerges. To do this, lactic acid is used in an amount that depends on the desired Lactic acid soda content of the preparation to be made is greater or greater can be smaller. This mixture is neutralized with carbonate of soda or caustic soda. Further amounts of salicylic acid and lactic acid can then be dissolved in the liquid, which in turn is neutralized. In the same way one continues until one finally has a concentrated solution of salicylic and lactic acid soda. This solution is evaporated in a water bath. A dry double salt is obtained from it, salicyllactic acid Soda, which may be called "Salactol". Instead of the soda the Salicylic and lactic acid solutions can also be added to a soda solution of salicylic and lactic acid enter. Of course, mixtures of solutions of the salicylic and des lactic acid soda, which is known to be readily available in stores, is evaporated to dryness will.
Dafs auf solche Weise ein Doppelsalz und kein blofses mechanisches Gemenge entsteht, geht aus Folgendem hervor:That in this way a double salt and not a mere mechanical mixture is produced, emerges from the following:
Aus einer Lösung der gemischten Salze (salicylsaures und milchsaures Natron) in 5oprocentigem Alkohol krystallisirten beim langsamen Verdunsten kreisförmige Gruppirungen von langen Nädelchen aus, die sich nach möglichstem Entfernen der Mutterlauge als aus beiden Componenten, dem milch- und salicylsauren Natron, bestehend erwiesen. Diese Nädelchen waren auch beim mikroskopischen Betrachten als einheitliche Krystallbildungen zu erkennen, denen keine anderweitigen Krystallformationen beigemischt waren. Aus Obigem mufs demnach gefolgert werden, dafs diese Krystalle als Doppelsalz und nicht als mechanisches Gemenge des milch- und salicylsauren Natrons aufzufassen sind. Zur Bestätigung diente die quantitative Bestimmung, die ein bestimmtes moleculares Verhältnifs zwischen den Componenten, dem milch- und salicylsauren Natron, nachwies. Danach bestanden die Nädelchen aus 2 MoIecülen salicylsaurem Natron und 1 Molecül milchsaurem Natron.From a solution of the mixed salts (salicylic acid and lactic acid soda) in 5% Alcohol crystallized, on slow evaporation, in circular groups of long ones Small needles that, after removing the mother liquor as much as possible, turn out to be from both components, the lactic and salicylic acid soda, proven to exist. These little needles were even when viewed microscopically, they can be recognized as uniform crystalline formations no other crystal formations were admixed. From the above it must therefore It can be concluded that these crystals are a double salt and not a mechanical mixture of lactic and salicylic acid sodium are to be understood. The quantitative was used for confirmation Determination that a certain molecular ratio between the components, the lactic and salicylic acid baking soda. The needles then consisted of 2 molecules salicylic acid baking soda and 1 mol of lactic acid baking soda.
Ein derartiges Doppelsalz hat alle Eigenschaften des salicyl- und des milchsauren Natrons, nur ist es nicht mehr hygroskopisch. Dafs dies thatsächlich der Fall ist, ist in der folgenden Weise nachgewiesen.Such a double salt has all the properties of salicylic and lactic acid Natrons, only it's no longer hygroscopic. That this is actually the case is shown in the following way.
Die eine Schale einer Waage wurde mit trockenem salicyl-milchsauren Natron beschüttet, .eben dem neuen Doppelsalz, die andere mit milchsaurem Natron. Beide Stoffe waren in trockener Form. Schon nach kurzer Zeit begann die mit dem milchsauren Natron beschüttete der beiden vorher mittelst Gewichte ausbalancirten Schalen zu sinken.One of the bowls of a balance was poured with dry salicylic lactic acid sodium bicarbonate, next to the new double salt, the other with lactic acid baking soda. Both fabrics were in dry form. After a short time, the lactic acid soda poured in began of the two bowls previously balanced by weights.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE84378C true DE84378C (en) |
Family
ID=356607
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT84378D Active DE84378C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE84378C (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999001650A1 (en) | 1997-07-03 | 1999-01-14 | Daimlerchrysler Ag | Method for regulating heat in an internal combustion engine |
| RU2469998C1 (en) * | 2008-12-01 | 2012-12-20 | Митсуи Кемикалс, Инк. | Method of producing olefins |
| US9267156B2 (en) | 2010-08-12 | 2016-02-23 | Mitsui Chemicals, Inc. | Isopropyl alcohol-producing bacterium having improved productivity by GntR destruction |
| US9567266B2 (en) | 2012-01-20 | 2017-02-14 | Mitsui Chemicals, Inc. | Olefin production method |
-
0
- DE DENDAT84378D patent/DE84378C/de active Active
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999001650A1 (en) | 1997-07-03 | 1999-01-14 | Daimlerchrysler Ag | Method for regulating heat in an internal combustion engine |
| RU2469998C1 (en) * | 2008-12-01 | 2012-12-20 | Митсуи Кемикалс, Инк. | Method of producing olefins |
| US9267156B2 (en) | 2010-08-12 | 2016-02-23 | Mitsui Chemicals, Inc. | Isopropyl alcohol-producing bacterium having improved productivity by GntR destruction |
| US9567266B2 (en) | 2012-01-20 | 2017-02-14 | Mitsui Chemicals, Inc. | Olefin production method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE2302841B2 (en) | Separation of different saccharides in a saccharide solution | |
| DE84378C (en) | ||
| DE1806760A1 (en) | Process and apparatus for the continuous production of soap | |
| DE2055292C3 (en) | Process for fractionating lignosulfonic acids | |
| DE494917C (en) | Process for the preparation of cellulose ethers | |
| CH208289A (en) | Process for the preparation of a wetting agent. | |
| DE313150C (en) | ||
| DE473261C (en) | Process for the production of monocarboxylic acids from aldoses | |
| DE149577C (en) | ||
| DE553613C (en) | Process for the production of cadmium coatings in a cyancal cadmium bath by electrolysis | |
| DE398406C (en) | Process for the production of aluminum formate solutions | |
| DE877604C (en) | Process for concentrating acetic acid | |
| DE896636C (en) | Process for the production of alkali cellulose | |
| DE679485C (en) | Process for tanning skins with basic aluminum salts | |
| DE389549C (en) | Process for the production of a tanning agent from sulphite cellulose waste liquor | |
| DE134165C (en) | ||
| DE292959C (en) | ||
| DE518769C (en) | Method of making copper lime broth | |
| DE629595C (en) | Process for the preparation of anhydrous ethyl alcohol | |
| DE630651C (en) | Process for the production of sodium nitrate | |
| DE2439652A1 (en) | Utilising regeneration fluids of ion exchangers - used in processing milk derivs., esp. whey, for food and fodder prodn | |
| AT90340B (en) | Process for the production of a tanning agent from sulphite cellulose waste liquor. | |
| DE514319C (en) | Process for the preparation of ammonium sulphate and alkali sulphate from their double salts | |
| DE455099C (en) | Process for obtaining sugar from molasses | |
| DE343150C (en) | Process for the preparation of salts of the compounds of tannic acid or gallic acid and lactic acid |