DE746474C - Highly heat-resistant mortar for magnesite brick masonry - Google Patents

Highly heat-resistant mortar for magnesite brick masonry

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Publication number
DE746474C
DE746474C DEK158364D DEK0158364D DE746474C DE 746474 C DE746474 C DE 746474C DE K158364 D DEK158364 D DE K158364D DE K0158364 D DEK0158364 D DE K0158364D DE 746474 C DE746474 C DE 746474C
Authority
DE
Germany
Prior art keywords
magnesite
iron
highly heat
mortar
resistant mortar
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEK158364D
Other languages
German (de)
Inventor
Dr Phil Helmut Stuetzel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Krupp Stahl AG
Original Assignee
Krupp Stahl AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Krupp Stahl AG filed Critical Krupp Stahl AG
Priority to DEK158364D priority Critical patent/DE746474C/en
Application granted granted Critical
Publication of DE746474C publication Critical patent/DE746474C/en
Expired legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Drilling And Exploitation, And Mining Machines And Methods (AREA)

Description

(RGBI Π S. 150)(RGBI Π p. 150)

DEUTSCHES REICH AUSGEGEBEN AM
10. AUGUST 1944
GERMAN REICH ISSUED ON
AUGUST 10, 1944

REICHSPATENTAMTREICH PATENT OFFICE

PATENTSCHRIFTPATENT LETTERING

Vr 746 KLASSE 80 b GRUPPE 8wVR 746 CLASS 80 b GROUP 8w

■ K158364 VJbßob■ K158364 VJbßob

Dr. phil. Helmut Stütze! in EssenDr. phil. Helmut support! in food

ist als Erfinder genannt wordenhas been named as the inventor

Fried. Krupp AG. in EssenFried. Krupp AG. in food

Hochhitzebeständiger Mörtel für MagnesitsteinmauerwerkHighly heat-resistant mortar for magnesite brick masonry

Patentiert im Deutschen Reich vom 8. August 1940 an Patenterteilung bekanntgemacht am 30. Dezember 1943Patented in the German Reich on August 8, 1940 Patent issued December 30, 1943

Es ist bekannt, bei der ,Herstellung feuerfester Erzeugnisse aus Magnesiumorthosilikat der Ausgangsmasse feinverteilte Metalle der Eisengruppe beizumischen, da deren Überführung in Metall-Sauerstoff-Verbindungen fetterf este Verkittungen bewirkt. Es ist ferner nicht mehr 'neu, zur -feuerfesten Verbindung von Magnesitsteinmauerwerk an."Stelle'von Mörtel aus Magnesit und Ton Zwischenlagen aus Eisenblech zu verwenden, da durch Oxydation und Reaktion dieser Bleche, mit .den Magnesitsteinen ein inniger Verband erreicht wird. Da solche Bleche jedoch bei hohen Temperaturen stark quellen, so daß z. B. unter Zuhilfenahme solcher Eisenbleche hergestellte Gewölbe von Martinöfen zu stark steigen, ist vorgeschlagen worden,; statt der Bleche Drahtgeflechte zu verwenden. Beide Verfahren sind aber in der Ausführung umständlich' und daher kostspielig. v It is known in the production of refractory products from magnesium orthosilicate to add finely divided metals of the iron group to the starting material, since their conversion into metal-oxygen compounds causes grease-proof cementation. Furthermore, it is no longer 'new' to use a refractory connection of magnesite brick masonry. 'Instead of using mortar made of magnesite and clay, intermediate layers made of sheet iron are used, since an intimate bond with the magnesite bricks is achieved through oxidation and reaction of these sheets Such sheets, however, swell strongly at high temperatures, so that, for example, the vaults of Martin ovens made with the help of such iron sheets rise too much, it has been proposed to use wire mesh instead of the sheets costly. v

JNFäch einem weiteren.bekannten Verfahren wird zum Auf mauern von feuerfestem Magnesitsteinmauerwerk eine Paste aus Eisenpulver, ■ beispielsweise aus feingemahlenem Eisenschwamm angewandt oder dem Mörtel Metalle in zerkleinerter Form wie auch in Form von Drehspänen, Walzensinter, Hammerschlag beigemischt. Aber aMch bei dieser Ausführungsart kann sich die durch Oxydation bedingte Volumenzunahme unangenehm bemerkbar machen, indem die zu verbindenden Steine auseinandergedrängtwerden. Außerdem ist feines Eisenpulver, das bessere Ergebnisse liefert als Eisenschwamm oder nicht genügend fein zerteiltes Eisen, verhältnismäß ig teuer. /JNFäch another known process a paste made of iron powder is used to build up refractory magnesite brickwork, ■ For example, applied from finely ground iron sponge or the mortar Metals in crushed form as well as in the form of turnings, roller sintering, hammer blows mixed in. But also with this one Execution mode can make the increase in volume caused by oxidation uncomfortable noticeable by pushing the stones to be connected apart. Also is fine iron powder that gives better results than sponge iron or not enough finely divided iron, relatively expensive. /

Nach der vorliegenden Erfindung werden diese. Nachteile dadurch beseitigt, daß für Mauerwerk aus Magnesit- oder magnesithaltigen Steinen hochhitzebeständiger Mörtel verwendet wird/der aus Eisenoxyden besteht und der mit Wasser oder 'einer bindenden Flüssigkeit angemacht ist. Im Gegensatz zu den bekannten Verfahren wird daher erfindungsgemäß'der hochhitzebeständige Mörtel aus Eisenoxyden hergestellt, dadurch dieAccording to the present invention, these. Disadvantages eliminated by the fact that for Masonry made of magnesite or magnesite bricks, highly heat-resistant mortar is used / which consists of iron oxides and which with water or a binding Liquid is turned on. In contrast to the known methods, therefore, according to the invention Highly heat-resistant mortar made from iron oxides, thereby the

Oxydation ganz vorweggenommen und die Reaktion von Eisenoxyd mit dem Magnesiumoxyd der Steine unter Bildung von Magnoferrit der Formel Mg Q · Fe2 O3 erleichtert, da voii vornherein Eisenoxyd zur Reaktion zur Verfügung steht. Als Eisenoxyde kommen vor allem der billige Hammerschlag oder Walzensinter in gemahlener Form oder auch gepulverte Abfallerze genügender ■ Reinheit,Oxidation is anticipated and the reaction of iron oxide with the magnesium oxide of the stones with the formation of magnoferrite of the formula Mg Q · Fe 2 O 3 is facilitated, since iron oxide is available for the reaction from the outset. The iron oxides are mainly cheap hammer blows or roller sintering in ground form or powdered waste ores of sufficient ■ purity,

ίο Schwefelkiesabbrände u. dgl. billige Stoffe in Frage.ίο Pebble burns and similar cheap substances in Question.

Der durch die Erfindung gegebene technische Fortschritt besteht zunächst darin, daß trotz der Verwendung billiger Rohstoffe und bei einfacher Arbeitsweise ein besseres und haltbareres Mauerwerk erzielt werden kann als bei der Mauerung nach den bekannten Arbeitsverfahren. Es ist ferner von Vorteil, daß die bei den bekannten Verfahren auftretende und größtenteils unerwünschte Volumen-.zunahme des Mauerwerks vermieden wird.The technical progress given by the invention consists first of all in that despite the use of cheap raw materials and with a simple way of working, a better and more durable masonry can be achieved than with the masonry according to the known Working method. It is also advantageous that the known method occurs and largely undesirable increase in volume of the masonry is avoided.

Claims (3)

Patentansprüche:Patent claims: i. Hochhitzebeständiger Mörtel für Mauerwerk aus Magnesit- oder magnesithaltigen Steinen, dadurch gekennzeichnet, daß er aus Eisenoxyden besteht und mit ' Wasser oder einer bindenden Flüssigkeit angemacht ist.i. Highly heat-resistant mortar for masonry made of magnesite or magnesite Stones, characterized in that it consists of iron oxides and with ' Water or a binding liquid. 2. Mörtel nach Anspruch i, dadurch gekennzeichnet, daß als Eisenoxyd gepulverter Hammerschlag oder Walzensinter verwendet wird.2. Mortar according to claim i, characterized in that that as iron oxide powdered hammer blow or roller sintering is used. 3. Mörtel nach Anspruch 1, dadurch gekennzeichnet, daß als Eisenoxyd geeignete bxydische Eisenerzpulver, Schwefelkiesabbrände o, dgl. verwendet werdend3. Mortar according to claim 1, characterized in that that hydroxydic iron ore powder, sulfur gravel burns o, the like. Are used as iron oxide Zur Abgrenzung des Anmeldungsgegen-Standes vom Stand der Technik sind im Erteilungsverfahren folgende Druckschriften in Betracht gezogen worden:-To differentiate the subject matter of the application from the state of the art are in the granting procedure the following publications have been considered: - deutsche Patentschrift ..... Nr. 273 364;German patent specification ..... No. 273 364; österreichische - - 106468;Austrian - - 106468; USA,- - -i 205 056;USA, - - -i 205 056; Dammer, Bruno u. Tietze, Oskar, Die nutzbaren Mineralien (1927), Stuttgart, Bd. IDammer, Bruno and Tietze, Oskar, The Usable Minerals (1927), Stuttgart, Vol. I ■■ S. 367;■■ p. 367; Ztschrft. Das Betonwerk (1930), S. 536; Tonindustrie-Zeitung (1931), S. 96 r. Sp. Abs. 4.Ztschrft. Das Betonwerk (1930), p. 536; Tonindustrie-Zeitung (1931), p. 96 r. Sp. Paragraph 4.
DEK158364D 1940-08-08 1940-08-08 Highly heat-resistant mortar for magnesite brick masonry Expired DE746474C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEK158364D DE746474C (en) 1940-08-08 1940-08-08 Highly heat-resistant mortar for magnesite brick masonry

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEK158364D DE746474C (en) 1940-08-08 1940-08-08 Highly heat-resistant mortar for magnesite brick masonry

Publications (1)

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DE746474C true DE746474C (en) 1944-08-10

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1009999B (en) * 1953-11-24 1957-06-06 Koppers Gmbh Heinrich Process for the production of refractory ceramic masses

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE273364C (en) *
US1205056A (en) * 1916-10-06 1916-11-14 Charles B Stowe Process for making refractory materials.
AT106468B (en) * 1924-09-01 1927-05-25 Harbison Walker Refractories Fireproof fabric.

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE273364C (en) *
US1205056A (en) * 1916-10-06 1916-11-14 Charles B Stowe Process for making refractory materials.
AT106468B (en) * 1924-09-01 1927-05-25 Harbison Walker Refractories Fireproof fabric.

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1009999B (en) * 1953-11-24 1957-06-06 Koppers Gmbh Heinrich Process for the production of refractory ceramic masses

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