DE741156C - Process for the production of succinimide - Google Patents

Process for the production of succinimide

Info

Publication number
DE741156C
DE741156C DEI65985D DEI0065985D DE741156C DE 741156 C DE741156 C DE 741156C DE I65985 D DEI65985 D DE I65985D DE I0065985 D DEI0065985 D DE I0065985D DE 741156 C DE741156 C DE 741156C
Authority
DE
Germany
Prior art keywords
succinimide
parts
weight
production
acrylonitrile
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEI65985D
Other languages
German (de)
Inventor
Dr Hermann Wolz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE521605D priority Critical patent/BE521605A/xx
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Priority to DEI65985D priority patent/DE741156C/en
Priority to DEC56278D priority patent/DE745156C/en
Application granted granted Critical
Publication of DE741156C publication Critical patent/DE741156C/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/34—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D207/36—Oxygen or sulfur atoms
    • C07D207/40—2,5-Pyrrolidine-diones
    • C07D207/404—2,5-Pyrrolidine-diones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms, e.g. succinimide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C7/00—Non-inflatable or solid tyres
    • B60C7/22—Non-inflatable or solid tyres having inlays other than for increasing resiliency, e.g. for armouring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Pyrrole Compounds (AREA)

Description

Verfahren zur Herstellung von Succinimid Es wurde die überraschende Beobachtung gemacht, daß man in einfacher Weise zum Succinimid gelangt, wenn man auf Acrylsäurenitril in wässieriger Lösung ein Alkalicyanid einwirken läßt. Die Umsetzung nimmt man zweckmäßig bei erhöhter Temperatur vor. Das Succinimid kann aus dem Umsletzungsgemisch leicht abgetrennt werden, z. B. durch Abdestillieren.Method of making succinimide It has been found to be surprising Observation made that one arrives at the succinimide in a simple manner if one allows an alkali metal cyanide to act on acrylonitrile in aqueous solution. the The reaction is expediently carried out at an elevated temperature. The succinimide can easily separated from the reaction mixture, e.g. B. by distilling off.

Man kann auch auf -eine Abtrennung des Succinimids verzichten und die Reaktionslösung z. B. durch Verseifen unmittelbar auf Bernsteinsäure verarbeiten. Erhitzt man die Mischung mit einem Alkohol und mit Säure, dann kann man unmittelbar zu den Estern der Bernsteinsäure gelangen.You can also do without a separation of the succinimide and the reaction solution z. B. process directly to succinic acid by saponification. If you heat the mixture with an alcohol and with an acid, then you can immediately get to the esters of succinic acid.

Beispiel i 57 Gewichtsteile Acrylsäurenitril werden mit 5oGewichtsteilen-Natriumcyanid oder 65Gewichtsteilen Kaliumcyanid in i 5o Gewichtsteilen Wasser auf So' erwärmt. Nach be- endigter Umsetzung wird das Lösungsmittel im Vakuum entfernt, die entstandene Kalilauge mit 'Schwefelsäure in Methanol abgetrennt und das Succinimid im Vakuum destilliert.Example i 57 parts by weight of acrylonitrile are heated to 50 parts by weight of sodium cyanide or 65 parts by weight of potassium cyanide in 150 parts by weight of water. After loading endigter reaction, the solvent is removed in vacuo, the resulting potassium hydroxide solution is separated with 'sulfuric acid in methanol and the succinimide was distilled in vacuo.

Beispiel 2 57 Gewichtsteile Acrylsäurenitril werden mit 5o Gewichtsteilen Natriumcyanid oder 65 Gewichtsteilen Kaliumcyanid in 15o Gewichtsteilen Wasser io bis 12 Stunden auf ioo° erhitzt und das Umsetzungsprodukt mit Schwefelsäure zu Bernsteinsäure verseift.Example 2 57 parts by weight of acrylonitrile are 50 parts by weight Sodium cyanide or 65 parts by weight of potassium cyanide in 150 parts by weight of water io heated to 100 ° for up to 12 hours and the reaction product with sulfuric acid to succinic acid saponified.

Ausbeute: etwa 700/0.Yield: about 700/0.

Claims (1)

PATENTANSPRUCH: Verfahren zur Herstellung von Succinimid, dadurch gekennzeichnet, daß man auf Acrylsäurenitril in wässriger Lösung ein Alkalicyanid :einwirken läßt.PATENT CLAIM: Process for the production of succinimide, thereby characterized in that an alkali metal cyanide is used on acrylonitrile in aqueous solution : lets act.
DEI65985D 1939-11-17 1939-11-17 Process for the production of succinimide Expired DE741156C (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
BE521605D BE521605A (en) 1939-11-17
DEI65985D DE741156C (en) 1939-11-17 1939-11-17 Process for the production of succinimide
DEC56278D DE745156C (en) 1939-11-17 1941-01-30 Solid rubber tires for vehicle wheels

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEI65985D DE741156C (en) 1939-11-17 1939-11-17 Process for the production of succinimide

Publications (1)

Publication Number Publication Date
DE741156C true DE741156C (en) 1943-11-05

Family

ID=7196447

Family Applications (1)

Application Number Title Priority Date Filing Date
DEI65985D Expired DE741156C (en) 1939-11-17 1939-11-17 Process for the production of succinimide

Country Status (2)

Country Link
BE (1) BE521605A (en)
DE (1) DE741156C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2623882A (en) * 1949-06-23 1952-12-30 Ciba Ltd Process for the manufacture of addition products of hydrocyanic acid and acrylic acid nitrile

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE59403348D1 (en) * 1993-04-28 1997-08-21 Continental Ag Solid tires

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2623882A (en) * 1949-06-23 1952-12-30 Ciba Ltd Process for the manufacture of addition products of hydrocyanic acid and acrylic acid nitrile

Also Published As

Publication number Publication date
BE521605A (en)

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