DE69709644D1 - Funktionalisierte ferrocenyldiphospine, verfahren zu ihrer herstellung und ihre verwendung - Google Patents
Funktionalisierte ferrocenyldiphospine, verfahren zu ihrer herstellung und ihre verwendungInfo
- Publication number
- DE69709644D1 DE69709644D1 DE69709644T DE69709644T DE69709644D1 DE 69709644 D1 DE69709644 D1 DE 69709644D1 DE 69709644 T DE69709644 T DE 69709644T DE 69709644 T DE69709644 T DE 69709644T DE 69709644 D1 DE69709644 D1 DE 69709644D1
- Authority
- DE
- Germany
- Prior art keywords
- metal complexes
- ferrocenyldiphosphines
- functional group
- hydrogenation
- organic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 4
- 239000002184 metal Substances 0.000 abstract 4
- 125000000524 functional group Chemical group 0.000 abstract 3
- 238000005984 hydrogenation reaction Methods 0.000 abstract 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 2
- 229910052741 iridium Inorganic materials 0.000 abstract 2
- 150000002739 metals Chemical class 0.000 abstract 2
- 229910052763 palladium Inorganic materials 0.000 abstract 2
- 229910052703 rhodium Inorganic materials 0.000 abstract 2
- 239000010948 rhodium Substances 0.000 abstract 2
- 229910052707 ruthenium Inorganic materials 0.000 abstract 2
- 229910052723 transition metal Inorganic materials 0.000 abstract 2
- 150000003624 transition metals Chemical class 0.000 abstract 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/165—Polymer immobilised coordination complexes, e.g. organometallic complexes
- B01J31/1658—Polymer immobilised coordination complexes, e.g. organometallic complexes immobilised by covalent linkages, i.e. pendant complexes with optional linking groups, e.g. on Wang or Merrifield resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2419—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member
- B01J31/2428—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member with more than one complexing phosphine-P atom
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2419—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member
- B01J31/2428—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member with more than one complexing phosphine-P atom
- B01J31/2433—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
- B01J31/2461—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring
- B01J31/2471—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring with more than one complexing phosphine-P atom
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
- B01J31/2461—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring
- B01J31/248—Bridged ring systems, e.g. 9-phosphabicyclononane
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
- C07C213/02—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reactions involving the formation of amino groups from compounds containing hydroxy groups or etherified or esterified hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C231/00—Preparation of carboxylic acid amides
- C07C231/16—Preparation of optical isomers
- C07C231/18—Preparation of optical isomers by stereospecific synthesis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
- B01J2231/643—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
- B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0202—Polynuclearity
- B01J2531/0205—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
- B01J2531/0263—Planar chiral ligands, e.g. derived from donor-substituted paracyclophanes and metallocenes or from substituted arenes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/824—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/827—Iridium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/842—Iron
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/07—Optical isomers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Hydrogenated Pyridines (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH174696 | 1996-07-10 | ||
CH206996 | 1996-08-23 | ||
PCT/EP1997/003626 WO1998001457A1 (en) | 1996-07-10 | 1997-07-09 | Functionalized ferrocenyldiphosphines, a process for their preparation and their use |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69709644D1 true DE69709644D1 (de) | 2002-02-21 |
DE69709644T2 DE69709644T2 (de) | 2002-08-14 |
Family
ID=25688547
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69709644T Expired - Fee Related DE69709644T2 (de) | 1996-07-10 | 1997-07-09 | Funktionalisierte ferrocenyldiphospine, verfahren zu ihrer herstellung und ihre verwendung |
Country Status (9)
Country | Link |
---|---|
US (1) | US6169192B1 (de) |
EP (1) | EP0912586B1 (de) |
JP (1) | JP2000514436A (de) |
AT (1) | ATE212032T1 (de) |
AU (1) | AU3621197A (de) |
CA (1) | CA2256770A1 (de) |
DE (1) | DE69709644T2 (de) |
ES (1) | ES2171267T3 (de) |
WO (1) | WO1998001457A1 (de) |
Families Citing this family (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0949241B1 (de) * | 1998-04-07 | 2003-12-10 | Firmenich Sa | Stereospezifische Isomerisierung von Allylaminen unter Verwendung von Chiralen Phospho-Liganden |
EP1002801B1 (de) * | 1998-11-19 | 2003-06-18 | Solvias AG | Chirale Diphenyldiphosphine und d-8 Metall-Komplexe davon |
WO2001004131A1 (en) * | 1999-07-14 | 2001-01-18 | Solvias Ag | Diphosphine ligands for metal complexes |
CH694251A5 (de) * | 1999-07-14 | 2004-10-15 | Eprova Ag | Herstellung von Tetrahydropterin und Derivaten. |
DE10017430A1 (de) * | 2000-04-07 | 2001-10-11 | Basf Ag | Polymerisationskatalysator |
US6562989B2 (en) | 2000-08-07 | 2003-05-13 | Yale University | Catalyst for aromatic C—O, C—N, and C—C bond formation |
US20040030199A1 (en) * | 2002-01-29 | 2004-02-12 | Maughon Robert R. | Process for reducing alpha-haloketones to secondary alpha-haloalcohols |
US6620954B1 (en) * | 2002-03-25 | 2003-09-16 | Eastman Chemical Company | Phosphinometallocenylamides as novel ligands for asymmetric catalysis |
GB0228018D0 (en) * | 2002-11-30 | 2003-01-08 | Lucite Int Uk Ltd | Carbonylation of ester |
WO2004024322A2 (en) * | 2002-09-12 | 2004-03-25 | Lucite International Uk Limited | A catalyst system comprising a 1,2-bis-(phosphinoalkyl) ferrocene ligand |
EP1651587A1 (de) | 2003-07-03 | 2006-05-03 | Lucite International UK Limited | Prozess für die hydroformylierung ethylenisch ungesättigter verbindungen |
JP2007513923A (ja) * | 2003-12-12 | 2007-05-31 | ソルヴィーアス アクチェンゲゼルシャフト | オルトメタレート及びオルト置換された芳香族化合物の製造方法 |
US7375241B2 (en) * | 2003-12-12 | 2008-05-20 | Solvias A.G. | Ferrocenyl-1,2-diphosphines, the production thereof and their use |
GB0403592D0 (en) * | 2004-02-18 | 2004-03-24 | Lucite Int Uk Ltd | A catalyst system |
GB0411951D0 (en) * | 2004-05-28 | 2004-06-30 | Lucite Int Uk Ltd | Carbonylation of ester |
KR100859748B1 (ko) * | 2004-12-29 | 2008-09-24 | 학교법인 포항공과대학교 | 불균일계 전이금속 촉매의 제조방법 |
GB0516556D0 (en) * | 2005-08-12 | 2005-09-21 | Lucite Int Uk Ltd | Improved catalyst system |
EP1957198B1 (de) | 2005-11-17 | 2018-08-22 | Lucite International UK Limited | Carbonylierung von ethylenisch ungesättigten verbindungen |
GB0607494D0 (en) | 2006-04-13 | 2006-05-24 | Lucite Int Uk Ltd | Metal complexes |
MX2009005568A (es) * | 2006-12-02 | 2009-06-05 | Lucite Int Uk Ltd | Nuevos ligandos de carbonilacion y su uso en la carbonilacion de compuestos etilenicamente insaturados. |
GB0625518D0 (en) * | 2006-12-21 | 2007-01-31 | Lucite Int Uk Ltd | Carbonylation of conjugated dienes |
DE102007022389A1 (de) * | 2007-05-10 | 2008-11-13 | Umicore Ag & Co. Kg | Ruthenium-Komplexe mit (P-P)-koordinierten Ferrocenyl-diphosphinliganden, Verfahren zu ihrer Herstellung sowie ihre Anwendung in der homogenen Katalyse |
WO2008143342A1 (ja) * | 2007-05-23 | 2008-11-27 | Dainippon Sumitomo Pharma Co., Ltd. | 3-アミノ-2,5-ジオキソピロリジン誘導体の製造方法 |
GB0812297D0 (en) * | 2008-07-04 | 2008-08-13 | Lucite Int Uk Ltd | Novel carbonylation ligand sand thier use of in the carbonylation of ethylenically unsaturated compounds |
JP5493346B2 (ja) * | 2008-12-11 | 2014-05-14 | 東ソー株式会社 | フェロセン誘導体およびその用途 |
GB201000078D0 (en) | 2010-01-05 | 2010-02-17 | Lucite Int Uk Ltd | Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporatng such ligands |
GB2503475A (en) * | 2012-06-27 | 2014-01-01 | Acal Energy Ltd | Fuel Cells for use at elevated temperatures and pressures |
EP3197903B1 (de) | 2014-09-26 | 2019-11-27 | The Chemours Company FC, LLC | Aus isocyanat abgeleitete organosilane |
CN110841719B (zh) * | 2019-11-19 | 2020-07-03 | 广西奕安泰药业有限公司 | 固相化的手性催化剂及其制备方法、手性化合物的合成方法 |
JP2023130917A (ja) * | 2022-03-08 | 2023-09-21 | 国立大学法人 東京大学 | コア/シェル型不均一系触媒およびそれを用いた光学活性化合物の製造方法 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0496699B1 (de) | 1991-01-25 | 1995-04-26 | Ciba-Geigy Ag | Silangruppen enthaltende Diphosphine, immobilisierte Diphosphine und deren Verwendung als Hydrierkatalysatoren |
EP0496700B1 (de) | 1991-01-25 | 1996-03-06 | Ciba-Geigy Ag | Silangruppen enthaltende Diphosphine, immobilisierte Diophoshine und deren Verwendung als Hydrierkatalysatoren |
EP0564406B1 (de) | 1992-04-02 | 1999-05-06 | Novartis AG | Ferrocenyldiphosphine als Liganden für homogene Katalysatoren |
SG42938A1 (en) | 1993-02-26 | 1997-10-17 | Ciba Geigy Ag | Ferrocenc diphosphines as ligands for homogeneous catalysts |
DE59408655D1 (de) | 1993-10-01 | 1999-09-30 | Novartis Ag | Mit Fluoralkyl substituierte Ferrocenyldiphosphine als Liganden für homogene Katalysatoren |
ES2150653T3 (es) | 1995-02-24 | 2000-12-01 | Novartis Ag | Ferrocenildifosfinas sililadas, ferrocenildifosfinas sililadas unidas a soportes inorganicos o polimeros organicos, asi como complejos metalicos de estas, su obtencion y empleo. |
ES2135894T3 (es) * | 1995-04-11 | 1999-11-01 | Novartis Ag | Ferrocenos dihalogenados y procedimientos para su preparacion. |
HRP960295A2 (en) | 1995-07-06 | 1997-08-31 | Ciba Geigy Ag | Process for the hydrogenation of imines in the presence of immobilized iridium-diphosphine catalysts |
-
1997
- 1997-07-09 ES ES97932789T patent/ES2171267T3/es not_active Expired - Lifetime
- 1997-07-09 CA CA002256770A patent/CA2256770A1/en not_active Abandoned
- 1997-07-09 AU AU36211/97A patent/AU3621197A/en not_active Abandoned
- 1997-07-09 US US09/214,667 patent/US6169192B1/en not_active Expired - Fee Related
- 1997-07-09 JP JP10504804A patent/JP2000514436A/ja active Pending
- 1997-07-09 DE DE69709644T patent/DE69709644T2/de not_active Expired - Fee Related
- 1997-07-09 AT AT97932789T patent/ATE212032T1/de not_active IP Right Cessation
- 1997-07-09 EP EP97932789A patent/EP0912586B1/de not_active Expired - Lifetime
- 1997-07-09 WO PCT/EP1997/003626 patent/WO1998001457A1/en active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
ES2171267T3 (es) | 2002-09-01 |
US6169192B1 (en) | 2001-01-02 |
AU3621197A (en) | 1998-02-02 |
EP0912586A1 (de) | 1999-05-06 |
WO1998001457A1 (en) | 1998-01-15 |
EP0912586B1 (de) | 2002-01-16 |
CA2256770A1 (en) | 1998-01-15 |
DE69709644T2 (de) | 2002-08-14 |
JP2000514436A (ja) | 2000-10-31 |
ATE212032T1 (de) | 2002-02-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE69709644D1 (de) | Funktionalisierte ferrocenyldiphospine, verfahren zu ihrer herstellung und ihre verwendung | |
EP0967015B1 (de) | Verwendung von Ferrocenylliganden zur katalytischen enantioselektiven Hydrierung | |
MX9401464A (es) | Difosfinas de ferroceno como ligandos para catalizadores homogeneos. | |
ATE186539T1 (de) | Neue bisphosphine für asymmetrische hydrierkatalysatoren | |
MY121112A (en) | Raney iron catalyst and a process for hydrogenating organic compounds using said catalyst. | |
Brown et al. | Enantioselective catalytic transfer hydrogenation of α, β-unsaturated carboxylic acids with formates catalyzed by novel ruthenium phosphine complexes | |
MY149091A (en) | Homogenous process for the hydrogenation of carboxylic acids and derivatives thereof | |
PL331405A1 (en) | Modified ligands of tie-2 receptor | |
DE59400617D1 (de) | Verfahren zur Herstellung edelmetallhaltiger Hydrierkatalysatoren auf Aktivkohle | |
CA2221397A1 (en) | Process for the production of aromatic halogen-amino compounds | |
AU4451396A (en) | Optically active diphosphines and method for preparing same by resolution of the racemic mixture | |
Milstein | Mild, low-pressure carbonylation of (. pi.-allyl) palladium complexes | |
HRP20010513B1 (en) | Method for producing l-phenylephrine hydrochloride | |
CA2263961A1 (en) | Cocaine receptor binding ligands | |
ATE212374T1 (de) | Herstellung von tetrahydroiso-alpha-säuren durch hydrogenierung der metallsalze von iso-alpha- säuren | |
CA2333086A1 (en) | Cocaine receptor binding ligands | |
EP0965574A3 (de) | Verfahren zur enantioselektiven Hydrierung | |
ATE229492T1 (de) | Verfahren zum herstellen einer carbonsäure | |
TWI256948B (en) | Process for preparing adrenaline | |
MY123714A (en) | Improving the color index of polyhydric alcohols by hydrogenation | |
DE59605542D1 (de) | Verfahren zur Herstellung von optisch aktivem 3-Chinuclidinol | |
AU1928697A (en) | Process for hydrogenating unsaturated plant-based compounds and regeneration of a used catalyst | |
Pousset et al. | An efficient synthesis of chiral cyclic β-amino acids via asymmetric hydrogenation | |
EP0212287A3 (de) | Verfahren zur Herstellung von aliphatischen Diamindimeren | |
AU7546200A (en) | Supported ferrocene-based catalysts for selective aldehyde hydrogenation |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition | ||
8339 | Ceased/non-payment of the annual fee |