DE69705798T2 - Klebstoffe - Google Patents
KlebstoffeInfo
- Publication number
- DE69705798T2 DE69705798T2 DE69705798T DE69705798T DE69705798T2 DE 69705798 T2 DE69705798 T2 DE 69705798T2 DE 69705798 T DE69705798 T DE 69705798T DE 69705798 T DE69705798 T DE 69705798T DE 69705798 T2 DE69705798 T2 DE 69705798T2
- Authority
- DE
- Germany
- Prior art keywords
- range
- weight
- molecular weight
- styrene
- average molecular
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000001070 adhesive effect Effects 0.000 title claims description 30
- 239000000853 adhesive Substances 0.000 title claims description 28
- 239000000203 mixture Substances 0.000 claims abstract description 42
- 239000004793 Polystyrene Substances 0.000 claims abstract description 34
- 229920002223 polystyrene Polymers 0.000 claims abstract description 34
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims abstract description 21
- 229920000359 diblock copolymer Polymers 0.000 claims abstract description 15
- ROGIWVXWXZRRMZ-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1 ROGIWVXWXZRRMZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000004519 manufacturing process Methods 0.000 claims abstract description 5
- 229920000346 polystyrene-polyisoprene block-polystyrene Polymers 0.000 claims abstract description 4
- 238000005859 coupling reaction Methods 0.000 claims description 29
- 230000008878 coupling Effects 0.000 claims description 27
- 238000010168 coupling process Methods 0.000 claims description 27
- 238000000034 method Methods 0.000 claims description 15
- 229920001577 copolymer Polymers 0.000 claims description 14
- 239000000758 substrate Substances 0.000 claims description 14
- 238000000576 coating method Methods 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 4
- 239000008240 homogeneous mixture Substances 0.000 claims description 3
- 239000011505 plaster Substances 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 description 37
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 28
- VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 description 16
- 229920001400 block copolymer Polymers 0.000 description 10
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 9
- 239000007788 liquid Substances 0.000 description 9
- 239000002904 solvent Substances 0.000 description 9
- 239000000178 monomer Substances 0.000 description 8
- 239000011347 resin Substances 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- 229920002633 Kraton (polymer) Polymers 0.000 description 7
- 239000007822 coupling agent Substances 0.000 description 7
- 239000003999 initiator Substances 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- -1 vinyl aromatic hydrocarbons Chemical class 0.000 description 7
- 238000009472 formulation Methods 0.000 description 6
- 238000005227 gel permeation chromatography Methods 0.000 description 6
- 150000001993 dienes Chemical class 0.000 description 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 239000005060 rubber Substances 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- AQWSFUIGRSMCST-UHFFFAOYSA-N 3-pyridin-3-ylsulfonyl-5-(trifluoromethyl)chromen-2-one Chemical compound N1=CC(=CC=C1)S(=O)(=O)C=1C(OC2=CC=CC(=C2C=1)C(F)(F)F)=O AQWSFUIGRSMCST-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 229920002799 BoPET Polymers 0.000 description 3
- 239000005041 Mylar™ Substances 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 3
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000000123 paper Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 238000005481 NMR spectroscopy Methods 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 206010040880 Skin irritation Diseases 0.000 description 2
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000001276 controlling effect Effects 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 239000012943 hotmelt Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000002655 kraft paper Substances 0.000 description 2
- 239000013627 low molecular weight specie Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 230000036556 skin irritation Effects 0.000 description 2
- 231100000475 skin irritation Toxicity 0.000 description 2
- 229920006132 styrene block copolymer Polymers 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- APQIUTYORBAGEZ-UHFFFAOYSA-N 1,1-dibromoethane Chemical compound CC(Br)Br APQIUTYORBAGEZ-UHFFFAOYSA-N 0.000 description 1
- CHRJZRDFSQHIFI-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;styrene Chemical compound C=CC1=CC=CC=C1.C=CC1=CC=CC=C1C=C CHRJZRDFSQHIFI-UHFFFAOYSA-N 0.000 description 1
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- XOBKSJJDNFUZPF-UHFFFAOYSA-N Methoxyethane Chemical compound CCOC XOBKSJJDNFUZPF-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 229920001744 Polyaldehyde Polymers 0.000 description 1
- 229920002732 Polyanhydride Polymers 0.000 description 1
- 239000002313 adhesive film Substances 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 125000003172 aldehyde group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000004414 alkyl thio group Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000005110 aryl thio group Chemical group 0.000 description 1
- 125000004104 aryloxy group Chemical group 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 150000004820 halides Chemical group 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 229920005684 linear copolymer Polymers 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 238000010128 melt processing Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000002900 organolithium compounds Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920013639 polyalphaolefin Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 229920001470 polyketone Polymers 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920002742 polystyrene-block-poly(ethylene/propylene) -block-polystyrene Polymers 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000005049 silicon tetrachloride Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 125000001302 tertiary amino group Chemical group 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229920000428 triblock copolymer Polymers 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
- C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
- C08F297/046—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes polymerising vinyl aromatic monomers and isoprene, optionally with other conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J109/00—Adhesives based on homopolymers or copolymers of conjugated diene hydrocarbons
- C09J109/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J125/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Adhesives based on derivatives of such polymers
- C09J125/02—Homopolymers or copolymers of hydrocarbons
- C09J125/04—Homopolymers or copolymers of styrene
- C09J125/08—Copolymers of styrene
- C09J125/10—Copolymers of styrene with conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
- C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/387—Block-copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/24—Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Adhesive Tapes (AREA)
- Materials For Medical Uses (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US2930396P | 1996-10-24 | 1996-10-24 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69705798D1 DE69705798D1 (de) | 2001-08-30 |
| DE69705798T2 true DE69705798T2 (de) | 2002-05-23 |
Family
ID=21848342
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69705798T Expired - Lifetime DE69705798T2 (de) | 1996-10-24 | 1997-10-23 | Klebstoffe |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US5891957A (enExample) |
| EP (1) | EP0838510B1 (enExample) |
| JP (1) | JP4213775B2 (enExample) |
| KR (1) | KR19980033052A (enExample) |
| CN (1) | CN1183447A (enExample) |
| AT (1) | ATE203559T1 (enExample) |
| BR (1) | BR9705118A (enExample) |
| DE (1) | DE69705798T2 (enExample) |
| TR (1) | TR199701249A2 (enExample) |
| TW (1) | TW345592B (enExample) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IL149113A0 (en) | 1999-10-14 | 2002-11-10 | Avery Dennison Corp | Fluid absorbing, adhesive hydrocolloid compositions |
| US6579915B2 (en) | 2000-01-31 | 2003-06-17 | H.B. Fuller Licensing & Financing Inc. | Radiation curable adhesive compositions comprising block copolymers having vinyl functionalized polydiene blocks |
| EP1299495B1 (en) | 2000-06-27 | 2008-01-16 | ExxonMobil Chemical Patents Inc. | Adhesives with improved die-cutting performance |
| US20020138896A1 (en) * | 2000-07-24 | 2002-10-03 | Holden Perriann M. | Protective attachment |
| US20040237166A1 (en) * | 2000-07-24 | 2004-12-02 | Jerry Potts | Apparel item and method of making and using same |
| US6497949B1 (en) | 2000-08-11 | 2002-12-24 | 3M Innovative Properties Company | Adhesive blends comprising hydrophilic and hydrophobic pressure sensitive adhesives |
| JP4787397B2 (ja) * | 2000-08-28 | 2011-10-05 | 日東電工株式会社 | 粘着剤組成物および粘着テープもしくはシート |
| JP2002138184A (ja) * | 2000-11-02 | 2002-05-14 | Tokai Rubber Ind Ltd | 高減衰エラストマー組成物 |
| WO2003020825A1 (en) | 2001-08-29 | 2003-03-13 | Zeon Corporation | Elastomer composition and pressure-sensitive adhesives made by using the same |
| US7013818B2 (en) | 2001-10-18 | 2006-03-21 | Guangdong Esquel Textiles Co. Ltd. | Wrinkle free garment and method of manufacture |
| US7211627B2 (en) * | 2003-02-28 | 2007-05-01 | Zeon Corporation | Elastomer composition and pressure-sensitive adhesive compositions |
| US6916750B2 (en) | 2003-03-24 | 2005-07-12 | Kimberly-Clark Worldwide, Inc. | High performance elastic laminates made from high molecular weight styrenic tetrablock copolymer |
| US7081498B2 (en) * | 2003-04-10 | 2006-07-25 | Morgan Adhesives Company | Pressure-sensitive adhesive compositions and constructions |
| KR100830024B1 (ko) * | 2004-03-03 | 2008-05-15 | 크레이튼 폴리머즈 리서치 비.브이. | 흐름성 및 탄성이 높은 블록 공중합체 |
| US20060003656A1 (en) * | 2004-06-30 | 2006-01-05 | Kimberly-Clark Worldwide, Inc. | Efficient necked bonded laminates and methods of making same |
| EP1775332B1 (en) * | 2004-08-05 | 2019-03-06 | Japan Elastomer Co., Ltd. | Pressure-sensitive adhesive composition |
| US7651653B2 (en) * | 2004-12-22 | 2010-01-26 | Kimberly-Clark Worldwide, Inc. | Machine and cross-machine direction elastic materials and methods of making same |
| CN104164035A (zh) * | 2005-11-14 | 2014-11-26 | 克拉通聚合物研究有限公司 | 制备沥青质粘合剂组合物的方法 |
| US20080300526A1 (en) * | 2007-06-01 | 2008-12-04 | Yulex Corporation | Guayule rubber and resin wet-stick bioadhesives |
| CN101981121B (zh) * | 2008-03-31 | 2013-02-06 | 日本瑞翁株式会社 | 嵌段共聚物组合物、其制备方法及薄膜 |
| US20100087768A1 (en) * | 2008-10-02 | 2010-04-08 | Forlano Paula | Transdermal drug delivery system for liquid active ingredient |
| TWI408204B (zh) | 2009-03-24 | 2013-09-11 | Tredegar Film Prod Corp | 用於具特定結構（ｔｅｘｔｕｒｅｄ）基板之保護薄膜 |
| US20110159225A1 (en) * | 2009-12-31 | 2011-06-30 | Bostik, Inc. | High Performance Foam Adhesive Tape |
| CN102892441A (zh) * | 2010-06-18 | 2013-01-23 | 科洛普拉斯特公司 | 可渗透的压敏粘合剂 |
| US8956302B2 (en) | 2010-07-19 | 2015-02-17 | Susan L. Pollyea | Triple layer protective liner for use with blood pressure cuff |
| US8272507B1 (en) | 2011-12-02 | 2012-09-25 | Visionary Products, Inc. | Kit of a plurality of detachable pockets, a detachable pocket, and associated methods |
| EP2878644B1 (en) * | 2012-07-25 | 2019-05-01 | Asahi Kasei Kabushiki Kaisha | Block copolymer composition for adhesives, and adhesive composition |
| WO2014159798A1 (en) | 2013-03-13 | 2014-10-02 | Avery Dennison Corporation | Improving adhesive properties |
| TWI496861B (zh) * | 2013-03-28 | 2015-08-21 | Chi Mei Corp | 可剝離型黏著劑組成物及其應用 |
| EP3081611A4 (en) * | 2013-12-11 | 2017-01-18 | Nichiban Co. Ltd. | Self-adhesion-type adhesive tape |
| DE102016202018A1 (de) * | 2016-02-10 | 2017-08-10 | Tesa Se | Haftklebemasse, diese enthaltende Selbstklebeprodukte und Verbunde |
| CN113493555A (zh) * | 2020-04-01 | 2021-10-12 | 李长荣化学工业股份有限公司 | 苯乙烯-异戊二烯-苯乙烯三嵌段共聚物、其制造方法、及其组成物及黏着剂组合物 |
| US11926731B2 (en) | 2020-08-25 | 2024-03-12 | Kraton Corporation | Block copolymer compositions |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4080348A (en) * | 1976-05-18 | 1978-03-21 | Johnson & Johnson | Tacky adhesive |
| US4136071A (en) * | 1976-05-18 | 1979-01-23 | Johnson & Johnson | Mixed block polymer adhesive |
| BR8807490A (pt) * | 1988-03-24 | 1990-03-27 | Shell Int Research | Composicao de copolimero em bloco,composicao adesiva e processo para sua preparacao |
| US5039750A (en) * | 1989-01-11 | 1991-08-13 | Ortho Pharmaceutical Ltd. | Natural rubber latex film products with improved tear resistance |
| US5274036A (en) * | 1992-11-17 | 1993-12-28 | Ralf Korpman Associates | Pressure sensitive adhesive |
| US5462538A (en) * | 1993-12-16 | 1995-10-31 | Mcneil-Ppc, Inc. | Molten adhesive fibers and products made therefrom |
| IT1269803B (it) * | 1994-05-20 | 1997-04-15 | Enichem Elastomers | Composizione adesiva hot melt per etichette |
-
1997
- 1997-09-30 US US08/941,497 patent/US5891957A/en not_active Expired - Lifetime
- 1997-10-22 CN CN97121154A patent/CN1183447A/zh active Pending
- 1997-10-22 KR KR1019970054171A patent/KR19980033052A/ko not_active Withdrawn
- 1997-10-22 BR BR9705118A patent/BR9705118A/pt not_active Application Discontinuation
- 1997-10-22 JP JP28967397A patent/JP4213775B2/ja not_active Expired - Fee Related
- 1997-10-23 DE DE69705798T patent/DE69705798T2/de not_active Expired - Lifetime
- 1997-10-23 EP EP97203283A patent/EP0838510B1/en not_active Expired - Lifetime
- 1997-10-23 AT AT97203283T patent/ATE203559T1/de not_active IP Right Cessation
- 1997-10-24 TR TR97/01249A patent/TR199701249A2/xx unknown
- 1997-11-04 TW TW086116347A patent/TW345592B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| ATE203559T1 (de) | 2001-08-15 |
| TR199701249A3 (tr) | 1998-05-21 |
| JPH10152663A (ja) | 1998-06-09 |
| EP0838510A1 (en) | 1998-04-29 |
| KR19980033052A (ko) | 1998-07-25 |
| JP4213775B2 (ja) | 2009-01-21 |
| TW345592B (en) | 1998-11-21 |
| CN1183447A (zh) | 1998-06-03 |
| TR199701249A2 (en) | 1998-05-21 |
| DE69705798D1 (de) | 2001-08-30 |
| EP0838510B1 (en) | 2001-07-25 |
| BR9705118A (pt) | 1998-09-15 |
| US5891957A (en) | 1999-04-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69705798T2 (de) | Klebstoffe | |
| DE69408474T2 (de) | Hydrierte multiblockpolymere für klebemittel | |
| DE68917657T2 (de) | Druckempfindliche Klebstoffe. | |
| DE69229305T2 (de) | Klebstoffzusammensetzung aus einem sequenz-polymerisiertem Blockcopolymer aus Styrol-Isopren-Styrol | |
| DE69315064T2 (de) | Haftklebemasse mit hoher scherfestigkeit | |
| DE69131433T2 (de) | Styrol-Isopren-Styrolblockcopolymerzusammensetzung für Niedrigviskose-, Niedrigtemperatur-Heissschmelzklebemittel | |
| DE60001117T2 (de) | Universelle druckempfindliche heissschmelzklebstoffe | |
| DE3687856T2 (de) | Mit makromeren verstaerkte klebefolie und klebende zusammensetzung fuer die haut. | |
| EP3374408B1 (de) | Kationisch polymerisierbare polyacrylate enthaltend alkoxysilangruppen und deren verwendung | |
| DE69314943T2 (de) | Dreiarmige Styrol-Isopren-Blockcopolymermassen mit grosser Lastaufnahmefähigkeit für Klebstoffe | |
| DE69603713T2 (de) | Haftkleber und bänder | |
| DE69326477T2 (de) | Druckempfindliche klebstoffe enthaltend flüssige und feste kautschuke | |
| DE3856246T2 (de) | Vernetzbare filmbildungszubereitungen | |
| DE69434507T2 (de) | Haftklebstoffzusammensetzung und Klebeband, das diese verwendet | |
| DE2803944C2 (de) | Klebemasse | |
| DE69106899T2 (de) | Zusammensetzungen von druckempfindlichen Schmelzklebstoffen auf Basis von Polysiloxanen, Verfahren und Produkte. | |
| DE69604278T2 (de) | Haftklebemittel umfassend ein block-copolymer, welches endblöcke mit niederem molekulargewicht enthält, und einen endblock-kompatiblen klebrigmacher oder ein öl | |
| DE3878959T2 (de) | ABA-Block-Copolymere. | |
| DE69404125T2 (de) | Folien mit hoher festigkeit aus blockcopolymerlatices | |
| DE69507572T2 (de) | Zusammensetzungen von Klebstoffen mit geringer Viscosität die asymmetrische radiale Polymere enthalten | |
| DE60011455T2 (de) | Zusammensetzung für abziehbare klebsstoffe, beschichtungen und hochleistungsklebstoffe | |
| AU637477B2 (en) | Styrene-isoprene-styrene block copolymer composition for low viscosity low application temperature hot melt adhesives | |
| DE2550546A1 (de) | Schmelzhaftkleber auf der basis von blockcopolymerisaten | |
| DE2246036A1 (de) | Klebstoffgemisch | |
| DE2827284A1 (de) | Blockpolymere mit vom gesamtmolekuel unterschiedlichem heterogenitaetsindex und verfahren zu deren herstellung |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8328 | Change in the person/name/address of the agent |
Representative=s name: DERZEIT KEIN VERTRETER BESTELLT |
|
| 8327 | Change in the person/name/address of the patent owner |
Owner name: KRATON POLYMERS RESEARCH B.V., AMSTERDAM, NL |
|
| 8328 | Change in the person/name/address of the agent |
Representative=s name: DTS MUENCHEN PATENT- UND RECHTSANWAELTE, 80538 MUENCHEN |
|
| 8328 | Change in the person/name/address of the agent |
Representative=s name: DERZEIT KEIN VERTRETER BESTELLT |
|
| 8364 | No opposition during term of opposition | ||
| 8328 | Change in the person/name/address of the agent |
Representative=s name: STOLMAR SCHEELE & PARTNER, 80331 MUENCHEN |