DE69638251D1 - Katalysator für die Herstellung von Ethylenoxid - Google Patents
Katalysator für die Herstellung von EthylenoxidInfo
- Publication number
- DE69638251D1 DE69638251D1 DE69638251T DE69638251T DE69638251D1 DE 69638251 D1 DE69638251 D1 DE 69638251D1 DE 69638251 T DE69638251 T DE 69638251T DE 69638251 T DE69638251 T DE 69638251T DE 69638251 D1 DE69638251 D1 DE 69638251D1
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- production
- ethylene oxide
- ethylene
- oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 title 1
- 239000003054 catalyst Substances 0.000 title 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
- B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/688—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0205—Impregnation in several steps
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/612—Surface area less than 10 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/633—Pore volume less than 0.5 ml/g
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP24605595 | 1995-09-25 |
Publications (1)
Publication Number | Publication Date |
---|---|
DE69638251D1 true DE69638251D1 (de) | 2010-10-14 |
Family
ID=17142799
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69634623T Expired - Lifetime DE69634623T2 (de) | 1995-09-25 | 1996-09-25 | Katalysator für die Herstellung von Ethylenoxid |
DE69638251T Expired - Lifetime DE69638251D1 (de) | 1995-09-25 | 1996-09-25 | Katalysator für die Herstellung von Ethylenoxid |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69634623T Expired - Lifetime DE69634623T2 (de) | 1995-09-25 | 1996-09-25 | Katalysator für die Herstellung von Ethylenoxid |
Country Status (4)
Country | Link |
---|---|
US (1) | US5705661A (de) |
EP (2) | EP0764464B1 (de) |
CA (1) | CA2186331C (de) |
DE (2) | DE69634623T2 (de) |
Families Citing this family (59)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0937498B1 (de) * | 1998-02-20 | 2004-08-18 | Nippon Shokubai Co., Ltd. | Silberkatalysator zur Herstellung von Ethylenoxid , Verfahren zu seiner Herstellung und Verfahren zur Herstellung von Ethylenoxid |
AU747207B2 (en) | 1998-10-05 | 2002-05-09 | Sasol Technology (Proprietary) Limited | Impregnation process for catalysts |
US20030165877A1 (en) * | 1999-09-24 | 2003-09-04 | Serge Muyldermans | Recombinant phages capable of entering host cells via specific interaction with an artificial receptor |
DE60109704D1 (de) | 2000-10-25 | 2005-05-04 | Mitsubishi Chem Corp | Verfahren zur Oxidation von Olefinen unter Verwendung eines Silber und Alkalimetall(e) enthaltenden Katalysator |
US6987080B2 (en) * | 2002-03-01 | 2006-01-17 | Scientific Design Company, Inc. | Ethylene oxide catalyst carrier preparation |
US6750173B2 (en) † | 2002-04-08 | 2004-06-15 | Scientific Design Company, Inc. | Ethylene oxide catalyst |
US20040002422A1 (en) * | 2002-06-27 | 2004-01-01 | Conoco Inc. | Method for large-scale production of combustion deposited metal-metal oxide catalysts |
TWI346574B (en) | 2003-03-31 | 2011-08-11 | Shell Int Research | A catalyst composition, a process for preparing the catalyst composition and a use of the catalyst composition |
US6846774B2 (en) * | 2003-04-23 | 2005-01-25 | Scientific Design Co., Inc. | Ethylene oxide catalyst |
MX260863B (es) | 2003-05-07 | 2008-09-26 | Shell Int Research | Catalizadores que contienen plata, su elaboracion y uso de los mismos. |
US20040225138A1 (en) * | 2003-05-07 | 2004-11-11 | Mcallister Paul Michael | Reactor system and process for the manufacture of ethylene oxide |
US20040224841A1 (en) * | 2003-05-07 | 2004-11-11 | Marek Matusz | Silver-containing catalysts, the manufacture of such silver-containing catalysts, and the use thereof |
TW200602123A (en) * | 2004-04-01 | 2006-01-16 | Shell Int Research | Process for preparing a catalyst, the catalyst, and a use of the catalyst |
TW200613056A (en) * | 2004-04-01 | 2006-05-01 | Shell Int Research | A process for preparing a silver catalyst, the catalyst, and a use of the catalyst for olefin oxidation |
TW200600190A (en) * | 2004-04-01 | 2006-01-01 | Shell Int Research | Process for preparing a silver catalyst, the catalyst, and use thereof in olefin oxidation |
CA2575165C (en) * | 2004-08-12 | 2014-03-18 | Velocys Inc. | Process for converting ethylene to ethylene oxide using microchannel process technology |
KR20070057974A (ko) * | 2004-09-24 | 2007-06-07 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 성형 입자의 선택방법, 시스템 설치방법, 이러한시스템에서 기체성 공급원료를 반응시키는 방법, 컴퓨터프로그램 제품 및 컴퓨터 시스템 |
WO2006083153A1 (en) | 2005-02-07 | 2006-08-10 | Inktec Co., Ltd. | Organic silver complexes, their preparation methods and their methods for forming thin layers |
KR100727466B1 (ko) | 2005-02-07 | 2007-06-13 | 주식회사 잉크테크 | 유기 은 착체 화합물, 이의 제조방법 및 이를 이용한박막형성방법 |
US7691294B2 (en) * | 2005-03-04 | 2010-04-06 | Inktec Co., Ltd. | Conductive inks and manufacturing method thereof |
US7759284B2 (en) * | 2005-05-09 | 2010-07-20 | Scientific Design Company, Inc. | Calcination in an inert gas in the presence of a small concentration of an oxidizing component |
CN101360562B (zh) * | 2006-04-10 | 2013-02-06 | 三菱化学株式会社 | 环氧乙烷制造用催化剂及其制造方法、以及环氧乙烷的制造方法 |
EP2679305A1 (de) * | 2006-04-10 | 2014-01-01 | Mitsubishi Chemical Corporation | Katalysator zur Herstellung von Ethylenoxid, Verfahren zur Herstellung des Katalysators und Verfahren zur Herstellung von Ethylenoxid |
CN103252235B (zh) * | 2006-04-18 | 2015-09-16 | 陶氏环球技术公司 | 环氧烷催化剂及其应用 |
US7977274B2 (en) * | 2006-09-29 | 2011-07-12 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Catalyst with bimodal pore size distribution and the use thereof |
US10532989B2 (en) | 2007-05-09 | 2020-01-14 | Shell Oil Company | Epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine |
CA2686825C (en) * | 2007-05-09 | 2016-09-13 | Shell Internationale Research Maatschappij B.V. | An epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine |
BRPI0912391B1 (pt) * | 2008-05-07 | 2018-04-17 | Shell Internationale Research Maatschappij B.V. | Processo para epoxidação de uma olefina |
WO2009137427A2 (en) * | 2008-05-07 | 2009-11-12 | Shell Oil Company | A process for the start-up of an epoxidation process, a process for the production of ethylene oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine |
EP2300447A1 (de) * | 2008-07-14 | 2011-03-30 | Basf Se | Verfahren zur herstellung von ethylenoxid |
US8524927B2 (en) * | 2009-07-13 | 2013-09-03 | Velocys, Inc. | Process for making ethylene oxide using microchannel process technology |
US8629079B2 (en) | 2011-04-14 | 2014-01-14 | Basf Se | Process for producing a catalyst for the oxidation of ethylene to ethylene oxide |
US8987482B2 (en) | 2011-10-28 | 2015-03-24 | Basf Se | Process for producing a supported silver catalyst |
WO2013061294A1 (de) * | 2011-10-28 | 2013-05-02 | Basf Se | Verfahren zur herstellung eines geträgerten silberkatalysators |
EP2938435A4 (de) * | 2012-12-31 | 2016-10-05 | Scient Design Co | Calcinierungsverfahren zur herstellung eines verbesserten ethylenoxidkatalysators |
WO2016063043A2 (en) | 2014-10-20 | 2016-04-28 | Velocys Technologies Limited | Process of removing heat |
US9592493B2 (en) | 2014-12-16 | 2017-03-14 | Eastman Kodak Company | Forming silver catalytic sites from silver phosphite carboxylates |
US9586200B2 (en) | 2014-12-16 | 2017-03-07 | Eastman Kodak Company | Forming catalytic sites from reducible silver complexes |
US9387460B2 (en) | 2014-12-16 | 2016-07-12 | Eastman Kodak Company | Metal catalytic composition with silver-oxime complex |
US9377688B1 (en) | 2014-12-16 | 2016-06-28 | Eastman Kodak Company | Metal catalytic composition with silver N-heterocycle complex |
US9624582B2 (en) | 2014-12-16 | 2017-04-18 | Eastman Kodak Company | Non-aqueous metal catalytic composition with oxyazinium photoreducing agent |
US9587315B2 (en) | 2014-12-16 | 2017-03-07 | Eastman Kodak Company | Forming silver catalytic sites from reducible silver-oximes |
US9586201B2 (en) | 2014-12-16 | 2017-03-07 | Eastman Kodak Company | Forming catalytic sites from reducible silver-heterocyclic complexes |
US9375704B1 (en) | 2014-12-16 | 2016-06-28 | Eastman Kodak Company | Metal catalytic composition with silver carboxylate-trialkyl(triaryl)phosphite complex |
CA2984609A1 (en) | 2015-05-01 | 2016-11-10 | Velocys Technologies, Ltd. | Process for operating an integrated gas-to-liquids facility |
US9982349B2 (en) | 2015-05-11 | 2018-05-29 | Eastman Kodak Company | Method for making electrically-conductive articles |
US9566569B2 (en) | 2015-05-11 | 2017-02-14 | Eastman Kodak Company | Metal catalytic compositions and articles therefrom |
WO2018031234A1 (en) | 2016-08-09 | 2018-02-15 | Eastman Kodak Company | Silver ion carboxylate primary alkylamine complexes |
US10186342B2 (en) | 2016-08-09 | 2019-01-22 | Eastman Kodak Company | Photosensitive reducible silver ion-containing compositions |
US10087331B2 (en) | 2016-08-09 | 2018-10-02 | Eastman Kodak Company | Methods for forming and using silver metal |
US10356899B2 (en) | 2016-08-09 | 2019-07-16 | Eastman Kodak Company | Articles having reducible silver ion complexes or silver metal |
US9718842B1 (en) | 2016-08-09 | 2017-08-01 | Eastman Kodak Company | Silver ion carboxylate primary alkylamine complexes |
EP3496951B1 (de) | 2016-08-09 | 2021-06-23 | Eastman Kodak Company | Silberionkomplexe mit carboxylat und n-heteroaromat und verwendungen |
US10311990B2 (en) | 2016-08-09 | 2019-06-04 | Eastman Kodak Company | Photosensitive reducible silver ion-containing compositions |
US10314173B2 (en) | 2016-08-09 | 2019-06-04 | Eastman Kodak Company | Articles with reducible silver ions or silver metal |
US9809606B1 (en) | 2016-08-09 | 2017-11-07 | Eastman Kodak Company | Silver ion carboxylate N-heteroaromatic complexes |
EP3548498B1 (de) | 2016-11-29 | 2021-04-21 | Eastman Kodak Company | Silberion-alpha-oxycarboxylat-oxim komplexe für fotolithografische verfahren zur erzeugung von elektrisch leitenden metallischen strukturen |
CN110035998B (zh) | 2016-12-02 | 2024-02-20 | 国际壳牌研究有限公司 | 调节乙烯环氧化催化剂的方法和生产环氧乙烷的相关方法 |
WO2019020793A1 (en) | 2017-07-28 | 2019-01-31 | Basf Se | PROCESS FOR PRODUCING A MOLDED CATALYST BODY COMPRISING SILVER APPLIED TO AN ALUMINUM CARRIER |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE793658A (fr) * | 1972-01-07 | 1973-07-04 | Shell Int Research | Catalyseur utilisable pour la production d'oxyde d'ethylene |
US4212772A (en) * | 1976-05-19 | 1980-07-15 | Basf Aktiengesellschaft | Catalyst for the manufacture of ethylene oxide |
US4168247A (en) * | 1976-05-28 | 1979-09-18 | Imperial Chemical Industries Limited | Catalysts for the production of alkylene oxides |
DE2819595A1 (de) * | 1977-05-12 | 1978-12-07 | Basf Ag | Katalysator zur herstellung von aethylenoxid |
US4916243A (en) * | 1979-03-20 | 1990-04-10 | Union Carbide Chemicals And Plastics Company Inc. | New catalyst composition and process for oxidation of ethylene to ethylene oxide |
JPS57140654A (en) * | 1981-02-25 | 1982-08-31 | Mitsubishi Petrochem Co Ltd | Silver catalyst for preparation of ethylene oxide |
JPS57180434A (en) * | 1981-04-30 | 1982-11-06 | Mitsubishi Petrochem Co Ltd | Silver catalyst for production of ethylene oxide |
JPS59190983A (ja) * | 1983-04-12 | 1984-10-29 | Mitsubishi Petrochem Co Ltd | エチレンオキシド製造用反応器に使用する充填材 |
EP0172565B1 (de) * | 1984-08-21 | 1991-03-13 | Mitsubishi Petrochemical Co., Ltd. | Silberkatalysator für die Herstellung von Ethylenoxid aus Ethylen und Verfahren zu dessen Herstellung |
JPH0678271B2 (ja) * | 1986-07-12 | 1994-10-05 | 三菱油化株式会社 | シユウ酸銀の製造法 |
IL84232A (en) * | 1986-10-31 | 1992-06-21 | Shell Int Research | Catalyst and process for the catalytic production of ethylene oxide |
GB8626687D0 (en) * | 1986-11-07 | 1986-12-10 | Shell Int Research | Preparing silver catalyst |
US4908343A (en) * | 1987-02-20 | 1990-03-13 | Union Carbide Chemicals And Plastics Company Inc. | Catalyst composition for oxidation of ethylene to ethylene oxide |
JP2561678B2 (ja) * | 1987-11-06 | 1996-12-11 | 三菱化学株式会社 | エチレンオキシド製造用銀触媒 |
US5145824A (en) * | 1991-01-22 | 1992-09-08 | Shell Oil Company | Ethylene oxide catalyst |
DE4106508A1 (de) * | 1991-03-01 | 1992-09-03 | Basf Ag | Silberkatalysator |
US5502020A (en) * | 1993-04-14 | 1996-03-26 | Mitsubishi Petrochemical Co., Ltd. | Catalyst for production of ethylene oxide and process for producing the catalyst |
PH11994048580B1 (en) * | 1993-07-07 | 2001-01-12 | Shell Int Research | Epoxidation catalyst |
US5380697A (en) * | 1993-09-08 | 1995-01-10 | Shell Oil Company | Ethylene oxide catalyst and process |
US5418202A (en) * | 1993-12-30 | 1995-05-23 | Shell Oil Company | Ethylene oxide catalyst and process |
ES2155111T3 (es) * | 1994-12-15 | 2001-05-01 | Shell Int Research | Procedimiento para preparar catalizadores para la obtencion de oxido de etileno. |
-
1996
- 1996-09-20 US US08/716,890 patent/US5705661A/en not_active Expired - Lifetime
- 1996-09-24 CA CA002186331A patent/CA2186331C/en not_active Expired - Lifetime
- 1996-09-25 EP EP96115372A patent/EP0764464B1/de not_active Expired - Lifetime
- 1996-09-25 DE DE69634623T patent/DE69634623T2/de not_active Expired - Lifetime
- 1996-09-25 DE DE69638251T patent/DE69638251D1/de not_active Expired - Lifetime
- 1996-09-25 EP EP05003453A patent/EP1529565B1/de not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP1529565A1 (de) | 2005-05-11 |
DE69634623D1 (de) | 2005-05-25 |
EP1529565B1 (de) | 2010-09-01 |
EP0764464A2 (de) | 1997-03-26 |
CA2186331C (en) | 2004-10-26 |
EP0764464B1 (de) | 2005-04-20 |
DE69634623T2 (de) | 2006-03-02 |
US5705661A (en) | 1998-01-06 |
EP0764464A3 (de) | 1998-09-02 |
CA2186331A1 (en) | 1997-03-26 |
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