DE69630451D1 - Eine strobilurinanalogverbindung enthaltende synergistischefungizide zusammensetzung - Google Patents

Eine strobilurinanalogverbindung enthaltende synergistischefungizide zusammensetzung

Info

Publication number
DE69630451D1
DE69630451D1 DE69630451T DE69630451T DE69630451D1 DE 69630451 D1 DE69630451 D1 DE 69630451D1 DE 69630451 T DE69630451 T DE 69630451T DE 69630451 T DE69630451 T DE 69630451T DE 69630451 D1 DE69630451 D1 DE 69630451D1
Authority
DE
Germany
Prior art keywords
strobilurine
fungicidal composition
analog compound
synergistic fungicidal
synergistic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69630451T
Other languages
English (en)
Other versions
DE69630451T2 (de
Inventor
Patrice Duvert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer SAS
Original Assignee
Bayer CropScience SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer CropScience SA filed Critical Bayer CropScience SA
Publication of DE69630451D1 publication Critical patent/DE69630451D1/de
Application granted granted Critical
Publication of DE69630451T2 publication Critical patent/DE69630451T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
    • A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
    • A01N43/70—Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16—Heavy metals; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L17/00—Materials for surgical sutures or for ligaturing blood vessels ; Materials for prostheses or catheters
    • A61L17/14—Post-treatment to improve physical properties
    • A61L17/145—Coating
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L29/00—Materials for catheters, medical tubing, cannulae, or endoscopes or for coating catheters
    • A61L29/08—Materials for coatings
    • A61L29/10—Inorganic materials
    • A61L29/106—Inorganic materials other than carbon
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/0021—Reactive sputtering or evaporation
    • C23C14/0036—Reactive sputtering
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/02—Pretreatment of the material to be coated
    • C23C14/024—Deposition of sublayers, e.g. to promote adhesion of the coating
    • C23C14/025—Metallic sublayers
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/0688—Cermets, e.g. mixtures of metal and one or more of carbides, nitrides, oxides or borides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/08—Oxides
    • C23C14/086—Oxides of zinc, germanium, cadmium, indium, tin, thallium or bismuth
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14—Metallic material, boron or silicon
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14—Metallic material, boron or silicon
    • C23C14/16—Metallic material, boron or silicon on metallic substrates or on substrates of boron or silicon
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/58—After-treatment
    • C23C14/5873—Removal of material
    • C23C14/588—Removal of material by mechanical treatment
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B18/00—Surgical instruments, devices or methods for transferring non-mechanical forms of energy to or from the body
    • A61B2018/00053—Mechanical features of the instrument of device
    • A61B2018/00107—Coatings on the energy applicator
    • A61B2018/00119—Coatings on the energy applicator with metal oxide nitride
DE69630451T 1995-07-24 1996-07-23 Eine strobilurinanalogverbindung enthaltende synergistischefungizide zusammensetzung Expired - Lifetime DE69630451T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR9509183A FR2737086B1 (fr) 1995-07-24 1995-07-24 Composition fongicide comprenant un compose analogue de la strobilurine
FR9509183 1995-07-24
PCT/FR1996/001155 WO1997003563A1 (fr) 1995-07-24 1996-07-23 Composition fongicide synergique comprenant un compose analogue de la strobilurine

Publications (2)

Publication Number Publication Date
DE69630451D1 true DE69630451D1 (de) 2003-11-27
DE69630451T2 DE69630451T2 (de) 2004-08-19

Family

ID=9481472

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69630451T Expired - Lifetime DE69630451T2 (de) 1995-07-24 1996-07-23 Eine strobilurinanalogverbindung enthaltende synergistischefungizide zusammensetzung

Country Status (26)

Country Link
US (3) US6015802A (de)
EP (1) EP0841853B1 (de)
JP (1) JP3911020B2 (de)
KR (1) KR100495894B1 (de)
CN (1) CN1089995C (de)
AR (1) AR002909A1 (de)
AU (1) AU715861B2 (de)
BR (1) BR9609798A (de)
CA (1) CA2224890C (de)
CO (1) CO4480686A1 (de)
DE (1) DE69630451T2 (de)
EA (1) EA001546B1 (de)
ES (1) ES2205052T3 (de)
FR (1) FR2737086B1 (de)
HK (1) HK1016836A1 (de)
HR (1) HRP960351B1 (de)
HU (1) HU228586B1 (de)
IL (1) IL123032A0 (de)
MA (1) MA23945A1 (de)
MX (1) MX9800680A (de)
PT (1) PT841853E (de)
RO (1) RO116244B1 (de)
TR (1) TR199800107T2 (de)
UA (1) UA52611C2 (de)
WO (1) WO1997003563A1 (de)
ZA (1) ZA966203B (de)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19722225A1 (de) 1997-05-28 1998-12-03 Basf Ag Fungizide Mischungen
GB9718366D0 (en) 1997-08-29 1997-11-05 Ciba Geigy Ag Novel combinations
JP4522504B2 (ja) * 1997-12-01 2010-08-11 石原産業株式会社 有害生物防除用組成物および有害生物の防除方法
IT1304593B1 (it) * 1997-12-01 2001-03-19 Ishihara Sangyo Kaisha Composizione per combattere bio-organismi dannosi
PT1071332E (pt) * 1998-04-16 2005-09-30 Bayer Cropscience Sa Nova utilizacao de compostos antifungicos e/ou antibactericidas e/ou antivirais
FR2787295A1 (fr) * 1998-12-22 2000-06-23 Rhone Poulenc Agrochimie Composition fongicide synergique comprenant un compose analogue de la strobilurine
FR2831768B1 (fr) * 2001-11-08 2004-10-29 Aventis Cropscience Sa Composition fongicide comprenant au moins un compose fongici de de la famille des anilinopyrimidines et au moins un derive de l'acide phosphoreux et utilisation de cette composition pour la lutte contre les maladies des plantes
TW200306155A (en) * 2002-03-19 2003-11-16 Du Pont Benzamides and advantageous compositions thereof for use as fungicides
EP1496745B1 (de) * 2002-04-10 2011-01-26 Basf Se Verfahren zur erhöhung der widerstandskraft von pflanzen gegen die phytotoxizität von agrochemikalien
EP1358801A1 (de) * 2002-04-30 2003-11-05 Bayer CropScience S.A. Fungizide Zusammensetzung
AU2004304676A1 (en) * 2003-11-27 2005-07-07 Basf Aktiengesellschaft Fungicidal mixtures for controlling rice pathogens
CA2590312A1 (en) * 2004-12-23 2006-07-06 Basf Aktiengesellschaft Fungicidal mixtures
PL1850669T3 (pl) * 2005-02-11 2015-06-30 Bayer Cropscience Ltd Kompozycja grzybobójcza zawierająca pochodną pirydylometylobenzamidu oraz pochodną tiazolokarboksamidu
US7443671B2 (en) * 2005-10-31 2008-10-28 Hewlett-Packard Development Company, L.P. Axial duct cooling fan
AU2009256715A1 (en) * 2008-06-12 2009-12-17 Basf Se Calcium salts of phosphorous acid for increasing the effect of fungicides
BRPI1105523A2 (pt) 2011-12-12 2013-11-12 Oxiteno Sa Ind E Comercio Composição espessante para uso em formulações agroquímicas, uso de uma composição espessante, e, formulações agroquímicas contendo composição espessante
CN108689950B (zh) * 2018-05-15 2021-06-11 河南省科学院高新技术研究中心 [(6-取代-嘧啶-4-基氧)苯基]-3-甲氧基丙烯酸甲酯

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US33989A (en) * 1861-12-24 Improvement it machines for punching boiler-plates
USRE33989E (en) 1986-07-16 1992-07-07 Basf Aktiengesellschaft Oxime ethers and fungicides containing these compounds
DE3623921A1 (de) * 1986-07-16 1988-01-21 Basf Ag Oximether und diese enthaltende fungizide
ATE141589T1 (de) * 1989-05-17 1996-09-15 Shionogi & Co Alkoxyiminoacetamid-derivate und ihre verwendung als pilztötendes mittel
GB9122430D0 (en) * 1990-11-16 1991-12-04 Ici Plc Chemical process
EP0741970B1 (de) * 1993-12-02 2002-04-24 Sumitomo Chemical Company Limited Bakterizide zusammensetzung

Also Published As

Publication number Publication date
HRP960351A2 (en) 1998-02-28
EP0841853A1 (de) 1998-05-20
MX9800680A (es) 1998-04-30
AU715861B2 (en) 2000-02-10
CA2224890C (fr) 2010-11-09
FR2737086B1 (fr) 1997-08-22
HU228586B1 (en) 2013-04-29
WO1997003563A1 (fr) 1997-02-06
UA52611C2 (uk) 2003-01-15
US6565892B2 (en) 2003-05-20
KR100495894B1 (ko) 2005-09-26
EP0841853B1 (de) 2003-10-22
BR9609798A (pt) 1999-03-16
JPH11511125A (ja) 1999-09-28
CN1089995C (zh) 2002-09-04
US6156740A (en) 2000-12-05
HUP9901394A2 (hu) 1999-08-30
AR002909A1 (es) 1998-04-29
CA2224890A1 (fr) 1997-02-06
DE69630451T2 (de) 2004-08-19
ES2205052T3 (es) 2004-05-01
HRP960351B1 (en) 2004-04-30
HK1016836A1 (en) 1999-11-12
JP3911020B2 (ja) 2007-05-09
EA199800150A1 (ru) 1998-08-27
US6015802A (en) 2000-01-18
EA001546B1 (ru) 2001-04-23
TR199800107T2 (xx) 1998-07-21
HUP9901394A3 (en) 2000-03-28
ZA966203B (en) 1997-05-02
PT841853E (pt) 2004-01-30
IL123032A0 (en) 1998-09-24
KR19990035904A (ko) 1999-05-25
AU6662896A (en) 1997-02-18
FR2737086A1 (fr) 1997-01-31
RO116244B1 (ro) 2000-12-29
MA23945A1 (fr) 1997-04-01
US20010046978A1 (en) 2001-11-29
CO4480686A1 (es) 1997-07-09
CN1193890A (zh) 1998-09-23

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Owner name: BAYER S.A.S., LYON, FR