DE69617713T2 - Übergangsmetallkomplexe, katalysatoren für die olefinpolymerisation und verfahren zur herstellung von olefinpolymeren - Google Patents

Übergangsmetallkomplexe, katalysatoren für die olefinpolymerisation und verfahren zur herstellung von olefinpolymeren

Info

Publication number
DE69617713T2
DE69617713T2 DE69617713T DE69617713T DE69617713T2 DE 69617713 T2 DE69617713 T2 DE 69617713T2 DE 69617713 T DE69617713 T DE 69617713T DE 69617713 T DE69617713 T DE 69617713T DE 69617713 T2 DE69617713 T2 DE 69617713T2
Authority
DE
Germany
Prior art keywords
catalysts
transition metal
metal complexes
olefin
producing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69617713T
Other languages
English (en)
Other versions
DE69617713D1 (de
Inventor
Hiroaki Katayama
Akio Imai
Hidenori Hanaoka
Norio Kawamura
Akira Miyashita
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Sumitomo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd
Application granted granted Critical
Publication of DE69617713D1 publication Critical patent/DE69617713D1/de
Publication of DE69617713T2 publication Critical patent/DE69617713T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
    • C07F9/532—Cycloaliphatic phosphine oxides or thioxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts
DE69617713T 1995-08-31 1996-08-30 Übergangsmetallkomplexe, katalysatoren für die olefinpolymerisation und verfahren zur herstellung von olefinpolymeren Expired - Fee Related DE69617713T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP22416395 1995-08-31
PCT/JP1996/002439 WO1997008179A1 (fr) 1995-08-31 1996-08-30 Complexes de metaux de transition, catalyseur de polymerisation des olefines et procede de production de polymeres d'olefines

Publications (2)

Publication Number Publication Date
DE69617713D1 DE69617713D1 (de) 2002-01-17
DE69617713T2 true DE69617713T2 (de) 2002-08-08

Family

ID=16809521

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69617713T Expired - Fee Related DE69617713T2 (de) 1995-08-31 1996-08-30 Übergangsmetallkomplexe, katalysatoren für die olefinpolymerisation und verfahren zur herstellung von olefinpolymeren

Country Status (6)

Country Link
US (1) US6066704A (de)
EP (1) EP0852230B1 (de)
KR (1) KR100453414B1 (de)
CN (1) CN1080724C (de)
DE (1) DE69617713T2 (de)
WO (1) WO1997008179A1 (de)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0963990B8 (de) * 1997-01-14 2004-12-29 Sumitomo Chemical Company, Limited Verfahren zur herstellung von cyclopentadienylmetallsalzen und verfahren zur herstellung von cyclopentadienderivaten durch verwendung derselben
US6489261B1 (en) * 1997-12-01 2002-12-03 Dsm N.V. Catalyst composition comprising a reduced transition metal complex and a cocatalyst
SG72966A1 (en) 1998-07-08 2000-05-23 Sumitomo Chemical Co Transition metal compound olefin polymerization catalyst component olefin polymerization catalyst and process for producing olefin polymer
WO2000069870A1 (en) * 1999-05-13 2000-11-23 The Dow Chemical Company Metal complexes containing bridging heteroatom for olefin-polymerization-process
EP1303543A1 (de) * 2000-07-17 2003-04-23 Univation Technologies LLC Katalysatorsystem und seine verwendung in einem polymerisationsverfahren
US7439379B2 (en) * 2001-09-14 2008-10-21 Sumitomo Chemical Co., Ltd. Transition metal complex, catalyst for olefin polymerization, and process for producing olefin polymer with the same
CN1160381C (zh) * 2001-09-27 2004-08-04 中国石油化工股份有限公司 含双席夫碱配体的烯烃聚合催化剂及制备方法与应用
EP1614699B9 (de) * 2003-03-28 2009-12-16 Mitsui Chemicals, Inc. Propylencopolymer, polypropylenzusammensetzung, verwendung davon, übergangsmetallverbindungen und katalysatoren für die olefinpolymerisation
KR100789241B1 (ko) * 2005-07-08 2008-01-02 주식회사 엘지화학 전이금속 화합물, 이를 포함하는 촉매 조성물 및 이를이용한 올레핀 중합

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS557756A (en) * 1978-07-04 1980-01-19 Toshiba Corp Projector
US5055438A (en) * 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
DE3801587A1 (de) * 1988-01-21 1989-08-03 Hoechst Ag Neue aminosaeureglyceride, verfahren zu ihrer herstellung, sie enthaltende arzneimittel und deren verwendung
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
KR0123370B1 (ko) * 1990-06-22 1997-11-12 벤 씨, 카덴헤드 올레핀 중합을 위한 알루미늄-비함유 모노사이클로 펜타디에닐 메탈로센 촉매
JP2545006B2 (ja) * 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
US5374696A (en) * 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
JP3188092B2 (ja) * 1994-02-25 2001-07-16 三菱重工業株式会社 脱水シューブレード
US5637660A (en) * 1995-04-17 1997-06-10 Lyondell Petrochemical Company Polymerization of α-olefins with transition metal catalysts based on bidentate ligands containing pyridine or quinoline moiety
IT1282666B1 (it) * 1996-02-22 1998-03-31 Enichem Spa Catalizzatore metallocenico sostituito per la (co) polimerizzazione delle olefine
US5856258A (en) * 1996-10-15 1999-01-05 Northwestern University Phenolate constrained geometry polymerization catalyst and method for preparing

Also Published As

Publication number Publication date
EP0852230B1 (de) 2001-12-05
KR19990044281A (ko) 1999-06-25
DE69617713D1 (de) 2002-01-17
EP0852230A1 (de) 1998-07-08
KR100453414B1 (ko) 2005-04-14
WO1997008179A1 (fr) 1997-03-06
CN1194650A (zh) 1998-09-30
CN1080724C (zh) 2002-03-13
US6066704A (en) 2000-05-23
EP0852230A4 (de) 1999-08-18

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Legal Events

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8364 No opposition during term of opposition
8327 Change in the person/name/address of the patent owner

Owner name: SUMITOMO CHEMICAL CO. LTD., TOKIO/TOKYO, JP

8339 Ceased/non-payment of the annual fee