DE69407192T2 - Katalysatorzusammensetzungen - Google Patents

Katalysatorzusammensetzungen

Info

Publication number
DE69407192T2
DE69407192T2 DE69407192T DE69407192T DE69407192T2 DE 69407192 T2 DE69407192 T2 DE 69407192T2 DE 69407192 T DE69407192 T DE 69407192T DE 69407192 T DE69407192 T DE 69407192T DE 69407192 T2 DE69407192 T2 DE 69407192T2
Authority
DE
Germany
Prior art keywords
catalyst compositions
group
heterocyclopentadienyl
oligomerisation
polymerisation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69407192T
Other languages
English (en)
Other versions
DE69407192D1 (de
Inventor
Boer Eric De
Boer Henricus De
Hero Heeres
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Polyolefine GmbH
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Application granted granted Critical
Publication of DE69407192D1 publication Critical patent/DE69407192D1/de
Publication of DE69407192T2 publication Critical patent/DE69407192T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63908—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts
DE69407192T 1993-08-02 1994-07-29 Katalysatorzusammensetzungen Expired - Fee Related DE69407192T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP93202285A EP0638593A1 (de) 1993-08-02 1993-08-02 Katalysatorzusammensetzungen
PCT/EP1994/002545 WO1995004087A1 (en) 1993-08-02 1994-07-29 Catalyst compositions
US08/792,259 US5756417A (en) 1993-08-02 1997-01-31 Catalyst compositions

Publications (2)

Publication Number Publication Date
DE69407192D1 DE69407192D1 (de) 1998-01-15
DE69407192T2 true DE69407192T2 (de) 1998-03-26

Family

ID=26133950

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69407192T Expired - Fee Related DE69407192T2 (de) 1993-08-02 1994-07-29 Katalysatorzusammensetzungen

Country Status (12)

Country Link
US (1) US5756417A (de)
EP (2) EP0638593A1 (de)
JP (1) JP3686081B2 (de)
CN (1) CN1043232C (de)
AT (1) ATE160790T1 (de)
AU (1) AU682395B2 (de)
BR (1) BR9407165A (de)
CA (1) CA2168564A1 (de)
DE (1) DE69407192T2 (de)
DK (1) DK0717754T3 (de)
ES (1) ES2110257T3 (de)
WO (1) WO1995004087A1 (de)

Families Citing this family (33)

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KR960041204A (ko) * 1995-05-02 1996-12-19 고사이 아키오 올레핀 중합 촉매 및 이를 사용하는 폴리올레핀의 제조방법
DE19517851A1 (de) * 1995-05-16 1996-11-21 Hoechst Ag Organometallverbindung
DE69604077T2 (de) * 1995-06-28 2000-03-16 Shell Int Research Organometallverbindung enthaltende katalysatorzusammensetzungen
JPH1053614A (ja) * 1996-05-29 1998-02-24 Shell Internatl Res Maatschappij Bv 共役ジエンポリマーの水素化のためのプロセスとこのプロセスで使用するのに適した触媒組成物
DE19714058A1 (de) * 1997-04-05 1998-10-08 Bayer Ag pi-Komplex-Verbindungen
DE19627064C2 (de) 1996-07-05 1998-12-03 Bayer Ag Metallocen-Verbindungen, Verfahren zu deren Herstellung, sowie ihre Verwendung
US6174974B1 (en) 1996-07-05 2001-01-16 Bayer Aktiengesellschaft Method for producing thermoplastic elastomers
US6759499B1 (en) 1996-07-16 2004-07-06 Exxonmobil Chemical Patents Inc. Olefin polymerization process with alkyl-substituted metallocenes
US6451938B1 (en) * 1997-02-25 2002-09-17 Exxon Mobil Chemical Patents Inc. Polymerization catalyst system comprising heterocyclic fused cyclopentadienide ligands
CA2200373C (en) * 1997-03-19 2005-11-15 Rupert Edward Von Haken Spence Heteroligand
CA2204803C (en) * 1997-05-08 2005-11-15 Nova Chemicals Ltd. Process to prepare bridged phosphole-cyclopentadienyl compounds
US6191245B1 (en) 1997-09-04 2001-02-20 The Dow Chemical Company α-Olefin/vinylidene aromatic monomer and/or hindered aliphatic or cycloaliphatic vinylidene monomer interpolymers
DE19757218A1 (de) * 1997-12-22 1999-06-24 Bayer Ag Verfahren zur Herstellung von Elastomeren
DE19757524A1 (de) * 1997-12-23 1999-06-24 Bayer Ag eta-Komplex-Verbindungen
US6211311B1 (en) * 1999-05-25 2001-04-03 Equistar Chemicals, L.P. Supported olefin polymerization catalysts
WO2001046273A1 (en) 1999-12-20 2001-06-28 Exxon Chemical Patents Inc. Processes for the preparation polyolefin resins using supported ionic catalysts
DE10033982A1 (de) * 2000-07-13 2002-01-24 Basf Ag Verfahren zur Herstellung von Additionsprodukten ethylenisch ungesättigter Verbindungen
KR100375453B1 (ko) * 2000-12-19 2003-03-10 현대자동차주식회사 버스의 사이드 플랩도어 취부장치
DE10244214A1 (de) * 2002-09-23 2004-04-01 Bayer Ag Übergangsmetallverbindungen mit Donor-Akzeptor-Wechselwirkung und speziellem Substitutionsmuster
EP1422249A1 (de) * 2002-11-20 2004-05-26 ATOFINA Research Neues Metallocenkatalysatorsystem
US7053158B2 (en) 2003-09-22 2006-05-30 Agency For Science, Technology And Research Carborane trianion based catalyst
EP1833858A2 (de) 2004-12-16 2007-09-19 Exxonmobil Chemical Patents Inc. Halogensubstituierte metallocenverbindungen für die olefinpolymerisation
US7538168B2 (en) 2005-12-14 2009-05-26 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
US7667064B2 (en) 2005-12-14 2010-02-23 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
US7868197B2 (en) 2005-12-14 2011-01-11 Exxonmobil Chemical Patents Inc. Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization
US7550544B2 (en) 2005-12-14 2009-06-23 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
US7763562B2 (en) 2005-12-14 2010-07-27 Exxonmobil Chemical Patents Inc. Heteroatom bridged metallocene compounds for olefin polymerization
US7812104B2 (en) 2008-01-18 2010-10-12 Exxonmobil Chemical Patents Inc. Production of propylene-based polymers
EP2239569A1 (de) * 2009-04-09 2010-10-13 Lophius Biosciences GmbH Verfahren zur Übertragung von Polypeptiden in Zellen
KR102058142B1 (ko) * 2015-09-02 2019-12-20 주식회사 엘지화학 리간드 화합물, 올레핀 올리고머화용 촉매계, 및 이를 이용한 올레핀 올리고머화 방법
US20220275114A1 (en) * 2019-07-31 2022-09-01 Dow Global Technologies Llc Polymerization of ethylene in solution processes using a ziegler-natta catalyst and a hydrogenation catalyst
KR20220095195A (ko) 2019-10-31 2022-07-06 셰브런 오로나이트 컴퍼니 엘엘씨 작용화된 올레핀 올리고머
CN115555053A (zh) * 2022-09-22 2023-01-03 中化泉州石化有限公司 一种配体化合物及其应用

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5349100A (en) * 1991-01-02 1994-09-20 Exxon Chemical Patents Inc. Chiral metallocene compounds and preparation thereof by creation of a chiral center by enantioselective hydride transfer
US5434116A (en) * 1992-06-05 1995-07-18 Tosoh Corporation Organic transition metal compound having π-bonding heterocyclic ligand and method of polymerizing olefin by using the same
EP0590486A3 (en) * 1992-09-24 1994-08-24 Idemitsu Kosan Co Polymerization catalysts and process for producing polymers
CA2125246C (en) * 1993-06-07 2001-07-03 Junichi Imuta Transition metal compound and olefin polymerization catalyst using the same

Also Published As

Publication number Publication date
ATE160790T1 (de) 1997-12-15
AU682395B2 (en) 1997-10-02
EP0717754B1 (de) 1997-12-03
CN1128539A (zh) 1996-08-07
WO1995004087A1 (en) 1995-02-09
CA2168564A1 (en) 1995-02-09
AU7610394A (en) 1995-02-28
EP0638593A1 (de) 1995-02-15
JP3686081B2 (ja) 2005-08-24
ES2110257T3 (es) 1998-02-01
EP0717754A1 (de) 1996-06-26
DE69407192D1 (de) 1998-01-15
US5756417A (en) 1998-05-26
JPH08510006A (ja) 1996-10-22
DK0717754T3 (da) 1998-02-23
BR9407165A (pt) 1996-09-17
CN1043232C (zh) 1999-05-05

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8327 Change in the person/name/address of the patent owner

Owner name: BASELL POLYOLEFINE GMBH, 50389 WESSELING, DE

8339 Ceased/non-payment of the annual fee