DE69330024T3 - Mehrstufiges Olefin-Polymerisationsverfahren - Google Patents
Mehrstufiges Olefin-Polymerisationsverfahren Download PDFInfo
- Publication number
- DE69330024T3 DE69330024T3 DE69330024T DE69330024T DE69330024T3 DE 69330024 T3 DE69330024 T3 DE 69330024T3 DE 69330024 T DE69330024 T DE 69330024T DE 69330024 T DE69330024 T DE 69330024T DE 69330024 T3 DE69330024 T3 DE 69330024T3
- Authority
- DE
- Germany
- Prior art keywords
- polymerization process
- olefin polymerization
- stage olefin
- stage
- polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
- C08F255/04—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms on to ethene-propene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/08—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having four or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F287/00—Macromolecular compounds obtained by polymerising monomers on to block polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/04—Philipps catalyst
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP31061692 | 1992-11-19 | ||
JP31063292 | 1992-11-19 |
Publications (3)
Publication Number | Publication Date |
---|---|
DE69330024D1 DE69330024D1 (de) | 2001-04-19 |
DE69330024T2 DE69330024T2 (de) | 2001-08-02 |
DE69330024T3 true DE69330024T3 (de) | 2006-06-14 |
Family
ID=26566394
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69330024T Expired - Lifetime DE69330024T3 (de) | 1992-11-19 | 1993-11-19 | Mehrstufiges Olefin-Polymerisationsverfahren |
Country Status (5)
Country | Link |
---|---|
US (3) | US5464905A (de) |
EP (2) | EP0605952B2 (de) |
CA (1) | CA2103380C (de) |
DE (1) | DE69330024T3 (de) |
ES (1) | ES2157211T3 (de) |
Families Citing this family (68)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5847053A (en) * | 1991-10-15 | 1998-12-08 | The Dow Chemical Company | Ethylene polymer film made from ethylene polymer blends |
US6545088B1 (en) * | 1991-12-30 | 2003-04-08 | Dow Global Technologies Inc. | Metallocene-catalyzed process for the manufacture of EP and EPDM polymers |
US6001941A (en) * | 1992-11-19 | 1999-12-14 | Mitsui Chemicals, Inc. | Ethylene α-olefin copolymer obtained by copolymerizing ethylene with an α-olefin |
CA2103401C (en) * | 1992-11-19 | 2002-12-17 | Mamoru Takahashi | Ethylene copolymer composition |
CA2103379C (en) * | 1992-11-19 | 2000-05-23 | Toshiyuki Tsutsui | Catalyst for olefin polymerization, process for olefin polymerization using the same, ethylene/.alpha.-olefin copolymer, graft modified ethylene/.alpha.-olefin copolymer, and ethylene copolymer composition |
CA2103380C (en) * | 1992-11-19 | 2002-07-02 | Mitsui Chemicals, Inc. | Ethylene/.alpha.-olefin copolymer composition, graft modified ethylene/.alpha.-olefin copolymer composition, ethylene copolymer composition, and multi-stage olefin polymerization process |
JP3472935B2 (ja) * | 1994-02-18 | 2003-12-02 | 三井化学株式会社 | エチレン系重合体およびその製造方法、エチレン重合用固体状チタン触媒成分ならびにエチレン重合用触媒 |
US5614297A (en) * | 1994-05-19 | 1997-03-25 | Viskase Corporation | Polyolefin stretch film |
IT1270253B (it) | 1994-06-20 | 1997-04-29 | Spherilene Srl | Copolimeri dell'etilene e procedimento per la preparazione di polimeri dell'etilene |
US6063871A (en) † | 1995-07-24 | 2000-05-16 | Mitsui Petrochemical Industries, Inc. | Metallocene polyethylene blend compositions |
JPH09151294A (ja) * | 1995-09-29 | 1997-06-10 | Mitsubishi Chem Corp | タルク含有プロピレン系樹脂組成物 |
US5795941A (en) * | 1995-10-03 | 1998-08-18 | The Dow Chemical Company | Crosslinkable bimodal polyolefin compositions |
DE19548788A1 (de) † | 1995-12-27 | 1997-07-03 | Hoechst Ag | Folien und Schichten |
JPH09183816A (ja) * | 1995-12-28 | 1997-07-15 | Mitsui Petrochem Ind Ltd | エチレン・α−オレフィン共重合体およびこの共重合体から得られるフィルム |
HUP9900394A3 (en) * | 1996-01-22 | 2000-08-28 | Dow Chemical Co | Polyolefin elastomer blends exhibiting improved properties |
US20050163996A1 (en) * | 1996-01-25 | 2005-07-28 | I-Hwa Lee | Adhesive compositions based on blends of grafted substantially linear polyethylenes and non-grafted conventional polyethylenes |
US6545091B1 (en) | 1996-01-25 | 2003-04-08 | E. I. Du Pont De Nemours & Co. | Adhesive compositions based on blends of grafted metallocene catalyzed and non-grafted conventional polyethylenes |
DE69722311T2 (de) * | 1996-06-27 | 2004-03-18 | Atofina | Coextrusionsbindemittel, seine Verwendung für Mehrschichtstrukturen und Mehrschichtstrukturen daraus hergestellt |
ES2247613T3 (es) * | 1996-11-25 | 2006-03-01 | Total Petrochemicals Research Feluy | Composiciones de polietileno de densidad medio para aplicaciones de pelicula. |
EP0844258A1 (de) * | 1996-11-25 | 1998-05-27 | Fina Research S.A. | Polyethylenmischungen für Filme |
TW425414B (en) * | 1997-02-18 | 2001-03-11 | Chisso Corp | Preactivated catalyst for olefin (co)polymerization, catalyst for olefin (co)polymerization and olefin (co)polymer composition and their manufacturing method |
US5744551A (en) * | 1997-03-28 | 1998-04-28 | Union Carbide Chemicals & Plastics Technology Corporation | High strength polyethylene film |
EP0881237A1 (de) * | 1997-05-26 | 1998-12-02 | Fina Research S.A. | Verfahren zur Herstellung von bimodalen Polyolefinen mit Metallocenkatalysatoren in zwei Reaktionszonen |
GB9712663D0 (en) * | 1997-06-16 | 1997-08-20 | Borealis As | Process |
US6147179A (en) * | 1997-06-25 | 2000-11-14 | Eastman Chemical Company | Monolayer film |
KR20010022071A (ko) † | 1997-07-21 | 2001-03-15 | 그래햄 이. 테일러 | 넓은 분자량 분포도 및 조성상 균일성을 갖는 에틸렌상호중합체 조성물, 이의 제조 방법 및 이로부터 제조된제품 |
US6197887B1 (en) | 1997-09-12 | 2001-03-06 | Eastman Chemical Company | Compositions having particular utility as stretch wrap cling film |
US6204335B1 (en) | 1997-09-12 | 2001-03-20 | Eastman Chemical Company | Compositions of linear ultra low density polyethylene and propylene polymers and films therefrom |
US6070394A (en) * | 1997-09-12 | 2000-06-06 | Eastman Chemical Company | Lownoise stretch wrapping process |
US6153702A (en) * | 1997-09-12 | 2000-11-28 | Eastman Chemical Company | Polymers, and novel compositions and films therefrom |
EP0926169B1 (de) * | 1997-12-25 | 2005-02-23 | Mitsui Chemicals, Inc. | Ethylen/Alpha-Olefin Copolymer und Verfahren zu seiner Herstellung |
TW542844B (en) * | 1997-12-25 | 2003-07-21 | Mitsui Chemicals Inc | Ethylene/alpha-olefin copolymer and process for preparing the same |
US6166142A (en) | 1998-01-27 | 2000-12-26 | E. I. Du Pont De Nemours And Company | Adhesive compositions based on blends of grafted metallocene catalyzed and polar ethylene copolymers |
US6288171B2 (en) | 1998-07-01 | 2001-09-11 | Advanced Elastomer Systems, L.P. | Modification of thermoplastic vulcanizates using random propylene copolymers |
EP0989140A1 (de) * | 1998-09-25 | 2000-03-29 | Fina Research S.A. | Herstellung von bimodalem Polyethylen |
EP0989141A1 (de) * | 1998-09-25 | 2000-03-29 | Fina Research S.A. | Herstellung von multimodalem Polyäthylen |
DE69908649T2 (de) * | 1998-12-16 | 2004-04-29 | Borealis Technology Oy | Mehrstufenverfahren zur darstellung von polyolefinen mit hoher schmelzfestigkeit |
US6258903B1 (en) | 1998-12-18 | 2001-07-10 | Univation Technologies | Mixed catalyst system |
FI990003A (fi) | 1999-01-04 | 2000-07-05 | Borealis Polymers Oy | Polymeerikoostumus, menetelmä sen valmistamiseksi ja siitä valmistetut kalvot |
WO2004081063A1 (ja) * | 1999-01-19 | 2004-09-23 | Mamoru Takahashi | エチレン系樹脂製包装用フィルム |
CA2288684A1 (en) * | 1999-03-10 | 2000-09-10 | Mitsui Chemicals, Incorporated | Uses of ethylene/.alpha.-olefin copolymer and uses of ethylene copolymer composition |
CN100453566C (zh) * | 1999-06-17 | 2009-01-21 | 三井化学株式会社 | 乙烯聚合物及其用途 |
GB9917851D0 (en) * | 1999-07-29 | 1999-09-29 | Borealis As | Process |
US6369176B1 (en) | 1999-08-19 | 2002-04-09 | Dupont Dow Elastomers Llc | Process for preparing in a single reactor polymer blends having a broad molecular weight distribution |
SG97919A1 (en) † | 1999-08-31 | 2003-08-20 | Sumitomo Chemical Co | Ethylene-alpha-olefin copolymer and polyethylene composition |
US6218472B1 (en) | 1999-09-24 | 2001-04-17 | Fina Research, S.A. | Production of multimodal polyethylene |
US6340730B1 (en) | 1999-12-06 | 2002-01-22 | Univation Technologies, Llc | Multiple catalyst system |
US6455638B2 (en) | 2000-05-11 | 2002-09-24 | Dupont Dow Elastomers L.L.C. | Ethylene/α-olefin polymer blends comprising components with differing ethylene contents |
GB0016153D0 (en) | 2000-06-30 | 2000-08-23 | Borealis Tech Oy | Process |
EP1734061B1 (de) | 2000-09-07 | 2010-04-07 | Mitsui Chemicals, Inc. | Polare Gruppen enthaltendes Olefin-Copolymer, Verfahren zu seiner Herstellung, dieses Copolymer enthaltende thermoplastische Harzzusammensetzung und deren Verwendung |
US7132486B2 (en) | 2000-10-06 | 2006-11-07 | Univation Technologies, Llc | Linear low density polyethylenes with high melt strength and high melt index ratio |
US6734265B1 (en) | 2000-10-06 | 2004-05-11 | Univation Technologies, Llc. | Linear low density polyethylenes with high melt strength and high melt index ratio |
US6884747B2 (en) * | 2000-10-06 | 2005-04-26 | Univation Technologies, Llc | Linear low density polyethylenes with high melt strength and high melt index ratio |
CA2338094C (en) * | 2001-02-23 | 2009-09-15 | Nova Chemicals Corporation | Catalyst for olefin polymerization |
US6649694B2 (en) | 2001-12-21 | 2003-11-18 | Eastman Chemical Company | Process for producing ethylene-α-olefin interpolymer films |
US7223822B2 (en) | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
EP1620479B1 (de) | 2002-10-15 | 2013-07-24 | ExxonMobil Chemical Patents Inc. | Polyolefinklebstoffzusammensetzungen und daraus hergestellte gegenstände |
US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
TW200504093A (en) * | 2003-05-12 | 2005-02-01 | Dow Global Technologies Inc | Polymer composition and process to manufacture high molecular weight-high density polyethylene and film therefrom |
EP1496068A1 (de) * | 2003-07-09 | 2005-01-12 | Total Petrochemicals Research Feluy | Verfahren zur Herstellung bimodaler Polyolefine mit metallocenen Komplexen mit zwei Reaktionszonen |
EP1910431B1 (de) | 2005-07-19 | 2013-11-27 | ExxonMobil Chemical Patents Inc. | Poly-alpha-olefin-zusammensetzungen und herstellungsverfahren dafür |
US7473745B2 (en) * | 2005-09-02 | 2009-01-06 | Equistar Chemicals, Lp | Preparation of multimodal polyethylene |
EP1834970B1 (de) * | 2006-03-15 | 2014-05-14 | Styrolution GmbH | Ein Verfahren zur Herstellung von Polyolefin-Polyvinylaromatischen-Blockcopolymeren |
WO2007136460A1 (en) * | 2006-05-23 | 2007-11-29 | Exxonmobil Chemical Patents Inc. | Elastomeric modifier and process for manufacture |
US8022154B2 (en) * | 2008-11-06 | 2011-09-20 | Exxonmobil Chemical Patents Inc. | Ethylene polymers, their production and use |
MX2012000250A (es) * | 2009-06-29 | 2012-01-25 | Chevron Philips Chemical Company Lp | Sistemas catalizadores duales de metaloceno para disminuir el indice de fusion e incrementar las velocidades de produccion de polimero. |
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-
1993
- 1993-11-18 CA CA002103380A patent/CA2103380C/en not_active Expired - Fee Related
- 1993-11-18 US US08/154,467 patent/US5464905A/en not_active Expired - Lifetime
- 1993-11-19 EP EP93309248A patent/EP0605952B2/de not_active Expired - Lifetime
- 1993-11-19 EP EP00116650A patent/EP1050558A1/de not_active Withdrawn
- 1993-11-19 ES ES93309248T patent/ES2157211T3/es not_active Expired - Lifetime
- 1993-11-19 DE DE69330024T patent/DE69330024T3/de not_active Expired - Lifetime
-
1995
- 1995-05-25 US US08/449,921 patent/US5708080A/en not_active Expired - Lifetime
-
1997
- 1997-06-11 US US08/872,937 patent/US5834557A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
ES2157211T3 (es) | 2001-08-16 |
CA2103380C (en) | 2002-07-02 |
EP0605952B2 (de) | 2005-10-05 |
US5464905A (en) | 1995-11-07 |
EP1050558A1 (de) | 2000-11-08 |
EP0605952A3 (de) | 1995-06-28 |
US5834557A (en) | 1998-11-10 |
CA2103380A1 (en) | 1994-05-20 |
US5708080A (en) | 1998-01-13 |
EP0605952A2 (de) | 1994-07-13 |
EP0605952B1 (de) | 2001-03-14 |
DE69330024T2 (de) | 2001-08-02 |
DE69330024D1 (de) | 2001-04-19 |
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