DE69329361D1 - Organische Übergangsmetallverbindung mit pi-gebundenem heterozyklischen Ligandenund damit verbundenes Verfahren zur Polymerisation von Olefinen - Google Patents
Organische Übergangsmetallverbindung mit pi-gebundenem heterozyklischen Ligandenund damit verbundenes Verfahren zur Polymerisation von OlefinenInfo
- Publication number
- DE69329361D1 DE69329361D1 DE69329361T DE69329361T DE69329361D1 DE 69329361 D1 DE69329361 D1 DE 69329361D1 DE 69329361 T DE69329361 T DE 69329361T DE 69329361 T DE69329361 T DE 69329361T DE 69329361 D1 DE69329361 D1 DE 69329361D1
- Authority
- DE
- Germany
- Prior art keywords
- olefins
- polymerization
- transition metal
- metal compound
- associated process
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2419—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/46—Titanium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/48—Zirconium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP16989792 | 1992-06-05 | ||
JP04235118A JP3120587B2 (ja) | 1992-06-05 | 1992-08-12 | オレフィン重合触媒およびオレフィンの重合方法 |
JP04293198A JP3120601B2 (ja) | 1992-10-30 | 1992-10-30 | オレフィン重合触媒およびオレフィンの重合方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69329361D1 true DE69329361D1 (de) | 2000-10-12 |
DE69329361T2 DE69329361T2 (de) | 2001-03-01 |
Family
ID=27323261
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69329361T Expired - Fee Related DE69329361T2 (de) | 1992-06-05 | 1993-06-07 | Organische Übergangsmetallverbindung mit pi-gebundenem heterozyklischen Ligandenund damit verbundenes Verfahren zur Polymerisation von Olefinen |
Country Status (4)
Country | Link |
---|---|
US (1) | US5434116A (de) |
EP (1) | EP0574794B1 (de) |
KR (1) | KR960015739B1 (de) |
DE (1) | DE69329361T2 (de) |
Families Citing this family (97)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0816386B1 (de) * | 1993-03-23 | 1998-12-16 | Asahi Kasei Kogyo Kabushiki Kaisha | Olefinpolymerisationskatalysator mit mehrzähnigem Ligand |
SG81874A1 (en) * | 1993-08-02 | 2001-07-24 | Shell Int Research | Catalyst compositions |
EP0638593A1 (de) * | 1993-08-02 | 1995-02-15 | Shell Internationale Researchmaatschappij B.V. | Katalysatorzusammensetzungen |
EP0664304B1 (de) * | 1993-12-27 | 1999-08-04 | Mitsui Chemicals, Inc. | Katalysator und Verfahren zur Olefinpolymerisation |
US5539124A (en) * | 1994-12-19 | 1996-07-23 | Occidental Chemical Corporation | Polymerization catalysts based on transition metal complexes with ligands containing pyrrolyl ring |
KR960041204A (ko) * | 1995-05-02 | 1996-12-19 | 고사이 아키오 | 올레핀 중합 촉매 및 이를 사용하는 폴리올레핀의 제조방법 |
DE19516801A1 (de) * | 1995-05-08 | 1996-11-14 | Hoechst Ag | Organometallverbindung |
ATE184012T1 (de) * | 1995-06-28 | 1999-09-15 | Shell Int Research | Organometallverbindung enthaltende katalysatorzusammensetzungen |
US6417130B1 (en) | 1996-03-25 | 2002-07-09 | Exxonmobil Oil Corporation | One pot preparation of bimetallic catalysts for ethylene 1-olefin copolymerization |
JPH1053614A (ja) * | 1996-05-29 | 1998-02-24 | Shell Internatl Res Maatschappij Bv | 共役ジエンポリマーの水素化のためのプロセスとこのプロセスで使用するのに適した触媒組成物 |
EP0912244A4 (de) | 1996-07-15 | 2001-09-12 | Mobil Oil Corp | Mit comonomer vorbehandelter bimetallischer katalysator zum blasformen und filme |
US6759499B1 (en) * | 1996-07-16 | 2004-07-06 | Exxonmobil Chemical Patents Inc. | Olefin polymerization process with alkyl-substituted metallocenes |
US5618958A (en) * | 1996-08-08 | 1997-04-08 | Hoechst Celanese Corporation | Chiralrhenium catalysts and processes for preparing the same |
ID22443A (id) * | 1996-11-15 | 1999-10-14 | Montelll Technology Co Bv | Metallosena heterosiklik dan polimerisasi katalis |
US6432862B1 (en) * | 1996-12-17 | 2002-08-13 | E. I. Du Pont De Nemours And Company | Cobalt catalysts for the polymerization of olefins |
US6417305B2 (en) * | 1996-12-17 | 2002-07-09 | E. I. Du Pont De Nemours And Company | Oligomerization of ethylene |
US6214761B1 (en) * | 1996-12-17 | 2001-04-10 | E. I. Du Pont De Nemours And Company | Iron catalyst for the polymerization of olefins |
US5851945A (en) * | 1997-02-07 | 1998-12-22 | Exxon Chemical Patents Inc. | Olefin polymerization catalyst compositions comprising group 5 transition metal compounds stabilized in their highest metal oxidation state |
US6451938B1 (en) | 1997-02-25 | 2002-09-17 | Exxon Mobil Chemical Patents Inc. | Polymerization catalyst system comprising heterocyclic fused cyclopentadienide ligands |
AU6463898A (en) * | 1997-03-17 | 1998-10-12 | Exxon Chemical Patents Inc. | Transition metal metallacyclopentadienyl compounds |
CA2200373C (en) * | 1997-03-19 | 2005-11-15 | Rupert Edward Von Haken Spence | Heteroligand |
CA2204803C (en) * | 1997-05-08 | 2005-11-15 | Nova Chemicals Ltd. | Process to prepare bridged phosphole-cyclopentadienyl compounds |
US6030918A (en) * | 1997-06-25 | 2000-02-29 | The Regents Of The University Of California | Gallium based low-interaction anions |
US6103657A (en) | 1997-07-02 | 2000-08-15 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst for the production of olefin polymers |
US6268447B1 (en) | 1998-12-18 | 2001-07-31 | Univation Technologies, L.L.C. | Olefin polymerization catalyst |
US6051525A (en) | 1997-07-14 | 2000-04-18 | Mobil Corporation | Catalyst for the manufacture of polyethylene with a broad or bimodal molecular weight distribution |
US6153551A (en) | 1997-07-14 | 2000-11-28 | Mobil Oil Corporation | Preparation of supported catalyst using trialkylaluminum-metallocene contact products |
CA2228802C (en) * | 1998-02-04 | 2006-04-25 | Stephen John Brown | Solution polymerization of ethylene |
US6511936B1 (en) | 1998-02-12 | 2003-01-28 | University Of Delaware | Catalyst compounds with β-diminate anionic ligands and processes for polymerizing olefins |
CN1291221A (zh) * | 1998-02-20 | 2001-04-11 | 海索布技术股份有限公司 | 使用有机金属液体吸收剂的热泵 |
ES2572756T3 (es) * | 1998-05-18 | 2016-06-02 | Chevron Phillips Chemical Company Lp | Proceso para la polimerización de un monómero con una composición de catalizador que contiene un compuesto organometálico, un compuesto de organoaluminio y un compuesto de óxido sólido tratado |
US6300271B1 (en) * | 1998-05-18 | 2001-10-09 | Phillips Petroleum Company | Compositions that can produce polymers |
CA2243775C (en) * | 1998-07-21 | 2007-06-12 | Nova Chemicals Ltd. | Phosphinimine/heteroatom catalyst component |
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US6303719B1 (en) | 1998-12-18 | 2001-10-16 | Univation Technologies | Olefin polymerization catalyst system |
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CA2285723C (en) | 1999-10-07 | 2009-09-15 | Nova Chemicals Corporation | Multimodal polyolefin pipe |
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US6583082B2 (en) | 2000-12-01 | 2003-06-24 | The Governors Of The University Of Alberta | Functional organic particles for catalyst supports |
FR2820137B1 (fr) * | 2001-01-26 | 2005-12-23 | Atofina | Biphospholes pontes et metallocenes prepares a partir de ce ceux-ci |
CA2334049C (en) | 2001-02-02 | 2010-03-23 | Nova Chemicals Corporation | Halosulfonic acid treated catalyst support for olefin polymerization |
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CA2739969C (en) | 2011-05-11 | 2018-08-21 | Nova Chemicals Corporation | Improving reactor operability in a gas phase polymerization process |
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US9127106B2 (en) | 2011-06-09 | 2015-09-08 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
US9243092B2 (en) | 2011-06-09 | 2016-01-26 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
US9321859B2 (en) | 2011-06-09 | 2016-04-26 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
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US8895679B2 (en) | 2012-10-25 | 2014-11-25 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
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US8877672B2 (en) | 2013-01-29 | 2014-11-04 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
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CA2874344C (en) | 2014-12-15 | 2021-08-31 | Nova Chemicals Corporation | Spheroidal catalyst for olefin polymerization |
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CA2891002C (en) | 2015-05-13 | 2022-09-06 | Veronica Rose Zimmerman | Modeling a bed plate and its use |
TW201800424A (zh) | 2016-02-18 | 2018-01-01 | 努發化工(國際)公司 | 溶液聚合法 |
WO2019086987A1 (en) | 2017-11-06 | 2019-05-09 | Nova Chemicals (International) S.A. | Polyolefin preparation process |
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FR2495618A1 (fr) * | 1980-12-10 | 1982-06-11 | Poudres & Explosifs Ste Nale | Procede de synthese des diphospha-1,1'-ferrocenes |
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DE3726067A1 (de) | 1987-08-06 | 1989-02-16 | Hoechst Ag | Verfahren zur herstellung von 1-olefinpolymeren |
DE3726325A1 (de) | 1987-08-07 | 1989-02-16 | Hoechst Ag | Verfahren zur herstellung eines olefinpolymers |
JP2587251B2 (ja) | 1987-11-09 | 1997-03-05 | チッソ株式会社 | 立体規則性オレフィン重合体製造用触媒 |
IT8919252A0 (it) | 1989-01-31 | 1989-01-31 | Ilano | Catalizzatori per la polimerizzazione di olefine. |
US5036034A (en) * | 1989-10-10 | 1991-07-30 | Fina Technology, Inc. | Catalyst for producing hemiisotactic polypropylene |
ES2086397T5 (es) | 1989-10-30 | 2005-07-16 | Fina Technology, Inc. | Adicion de alkiloaluminio para un catalizador metaloceno mejorado. |
US5086135A (en) | 1989-12-26 | 1992-02-04 | Mobil Oil Corporation | Zirconium-based catalyst composition for polymerizing olefins and polymerization therewith |
-
1993
- 1993-06-02 US US08/070,286 patent/US5434116A/en not_active Expired - Lifetime
- 1993-06-05 KR KR1019930010156A patent/KR960015739B1/ko not_active IP Right Cessation
- 1993-06-07 EP EP93109144A patent/EP0574794B1/de not_active Expired - Lifetime
- 1993-06-07 DE DE69329361T patent/DE69329361T2/de not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
KR960015739B1 (ko) | 1996-11-20 |
EP0574794B1 (de) | 2000-09-06 |
US5434116A (en) | 1995-07-18 |
DE69329361T2 (de) | 2001-03-01 |
EP0574794A1 (de) | 1993-12-22 |
KR940005640A (ko) | 1994-03-22 |
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