DE69318628D1 - A two-stroke cycle lubricant composed of a vegetable oil and additional conditioning - Google Patents

A two-stroke cycle lubricant composed of a vegetable oil and additional conditioning

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Publication number
DE69318628D1
DE69318628D1 DE69318628T DE69318628T DE69318628D1 DE 69318628 D1 DE69318628 D1 DE 69318628D1 DE 69318628 T DE69318628 T DE 69318628T DE 69318628 T DE69318628 T DE 69318628T DE 69318628 D1 DE69318628 D1 DE 69318628D1
Authority
DE
Germany
Prior art keywords
nitrogen
carbon atoms
group
phenol
amino
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69318628T
Other languages
German (de)
Other versions
DE69318628T2 (en
Inventor
Iii William Bricker Chamberlin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lubrizol Corp
Original Assignee
Lubrizol Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lubrizol Corp filed Critical Lubrizol Corp
Publication of DE69318628D1 publication Critical patent/DE69318628D1/en
Application granted granted Critical
Publication of DE69318628T2 publication Critical patent/DE69318628T2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/045—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution and non-macromolecular compounds
    • C—CHEMISTRY; METALLURGY
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M101/00—Lubricating compositions characterised by the base-material being a mineral or fatty oil
    • C10M101/04—Fatty oil fractions
    • C—CHEMISTRY; METALLURGY
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    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/04—Hydroxy compounds
    • C10M129/10—Hydroxy compounds having hydroxy groups bound to a carbon atom of a six-membered aromatic ring
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    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/26—Carboxylic acids; Salts thereof
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    • C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/52—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of 30 or more atoms
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    • C10M133/52—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of 30 or more atoms
    • C10M133/54—Amines
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    • C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
    • C10M135/08—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium containing a sulfur-to-oxygen bond
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    • C10M159/24—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products containing sulfonic radicals
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    • C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
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    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
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    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
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    • C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
    • C10M2219/088—Neutral salts
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    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C10N2040/252—Diesel engines
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    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C10N2040/255—Gasoline engines
    • C10N2040/26—Two-strokes or two-cycle engines
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    • C10N2070/00—Specific manufacturing methods for lubricant compositions
    • C10N2070/02—Concentrating of additives

Abstract

This invention relates to a nitrogen-containing soluble organic composition comprising a combination of: (A) at least one natural oil comprising an animal oil or vegetable oil comprising a triglyceride of the formula <CHEM> wherein R<1>, R<2> and R<3> are independently saturated or unsaturated aliphatic hydrocarbyl groups containing from about 8 to about 24 carbon atoms and (B)(I) a detergent/dispersant comprising at least one acylated, nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms made by reacting a carboxylic acylating agent with at least one amino compound containing at least one -NH group, said acylating agent being linked to said amino compound through an imido, amido, amidine, or acyloxy ammonium linkage. In another embodiment, the invention comprises a nitrogen-containing soluble organic composition comprising a combination of: (A) the natural oil as described above with (B) at least one detergent-dispersant selected from the group consisting of (I) the acylated, nitrogen-containing compound as described above, (II) at least one neutral or basic metal salt of an organic sulfur acid, phenol or carboxylic acid; (III) at least one hydrocarbyl-substituted amine wherein the hydrocarbyl substituent is substantially aliphatic and contains at least 12 carbon atoms with the proviso that said amine is not the amino phenol (C); and (IV) at least one nitrogen-containing condensate of a phenol, aldehyde and amino compound having at least one -NH group; and (C) at least one amino phenol of the general formula <CHEM> wherein R<4> is a substantially saturated, hydrocarbon-based substituent of at least 10 aliphatic carbon atoms; a, b and c are each independently in integer of one up to three time the number of aromatic nuclei present in Ar with the proviso that the sum of a, b and c does not exceed the unsaturated valences of Ar; and Ar is an aromatic moiety having 0-3 optional substituents selected from the group consisting of lower alkyl, lower alkoxyl, nitro, halo or combinations of two or more of said substituents.
DE69318628T 1992-07-09 1993-07-08 Two-stroke cycle lubricant composed of a vegetable oil and additional conditioning Expired - Fee Related DE69318628T2 (en)

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JP (1) JPH06200279A (en)
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TW291495B (en) * 1994-08-03 1996-11-21 Lubrizol Corp
US5658864A (en) * 1995-03-24 1997-08-19 Ethyl Corporation Biodegradable pour point depressants for industrial fluids derived from biodegradable base oils
DE19747854A1 (en) * 1997-10-30 1999-05-12 Fuchs Petrolub Ag Method and device for the lubrication and simultaneous fuel supply of a vegetable oil-compatible internal combustion engine
CA2225352C (en) * 1998-01-30 2003-10-21 Nam Fong Han Vegetable derived petroleum jelly replacement
JP2000080391A (en) * 1998-09-04 2000-03-21 Showa Shell Sekiyu Kk Lubricating oil for two-cycle engine and diluent composition used for same
GB2416172B (en) * 2004-07-13 2009-04-22 Alan Edwin Jemmett Rapeseed oil lubricant
GB2421028A (en) * 2004-12-08 2006-06-14 Derek Lowe Fuel for two-stroke engines
BRPI0517173A (en) * 2004-12-14 2008-09-30 C M Intellectual Property And composition and methods for better lubrication, pour point and fuel performance
JP4801919B2 (en) * 2005-03-29 2011-10-26 Ｊｘ日鉱日石エネルギー株式会社 Lubricants for agricultural or forestry machinery
JP2006274058A (en) * 2005-03-29 2006-10-12 Nippon Oil Corp Lubricant for horticultural and silvicultural machines
US8778034B2 (en) 2006-09-14 2014-07-15 Afton Chemical Corporation Biodegradable fuel performance additives
US8671467B2 (en) 2007-11-20 2014-03-18 Her Majesty The Queen In Right Of Canada, As Represented By The Minister Of National Defence Head protection system
CN101245282B (en) * 2008-03-25 2011-05-25 佛山市顺德区远茂化工实业有限公司 Metallic fiber drawing lubricant agent
CN104911001B (en) * 2015-06-05 2018-04-24 广西大学 Miller cycle engine lubricant compositions
CN113512460B (en) * 2021-08-13 2022-10-21 福建科恩优路润滑油有限公司 Anti-wear clean type vehicle lubricating oil and preparation process thereof

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BE781636A (en) * 1972-04-04 1972-07-31 Labofina Sa LUBRICATING COMPOSITIONS FOR TWO STROKE ENGINES.
IN145085B (en) * 1976-01-28 1978-08-19 Lubrizol Corp
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JPH06502683A (en) * 1991-08-09 1994-03-24 ザ ルブリゾル コーポレイション Functional fluids with triglycerides, detergent-prevention additives, and viscosity-improving additives

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CN1033704C (en) 1997-01-01
TW253907B (en) 1995-08-11
ATE166382T1 (en) 1998-06-15
CN1081465A (en) 1994-02-02
CA2100030A1 (en) 1994-01-10
CA2100030C (en) 2003-10-21
AU4177893A (en) 1994-01-13
SG48751A1 (en) 1998-05-18
EP0578495B1 (en) 1998-05-20
EP0578495A1 (en) 1994-01-12
JPH06200279A (en) 1994-07-19
ZA934917B (en) 1994-02-09
ES2116412T3 (en) 1998-07-16
DE69318628T2 (en) 1999-02-11
AU670791B2 (en) 1996-08-01

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