CA2100030A1 - Two-stroke cycle lubricant composed of a vegetable oil and an additive package - Google Patents
Two-stroke cycle lubricant composed of a vegetable oil and an additive packageInfo
- Publication number
- CA2100030A1 CA2100030A1 CA002100030A CA2100030A CA2100030A1 CA 2100030 A1 CA2100030 A1 CA 2100030A1 CA 002100030 A CA002100030 A CA 002100030A CA 2100030 A CA2100030 A CA 2100030A CA 2100030 A1 CA2100030 A1 CA 2100030A1
- Authority
- CA
- Canada
- Prior art keywords
- nitrogen
- carbon atoms
- group
- phenol
- amino
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/045—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution and non-macromolecular compounds
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M101/00—Lubricating compositions characterised by the base-material being a mineral or fatty oil
- C10M101/04—Fatty oil fractions
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/04—Hydroxy compounds
- C10M129/10—Hydroxy compounds having hydroxy groups bound to a carbon atom of a six-membered aromatic ring
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- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/26—Carboxylic acids; Salts thereof
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/52—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of 30 or more atoms
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- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/52—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of 30 or more atoms
- C10M133/54—Amines
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- C—CHEMISTRY; METALLURGY
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- C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
- C10M135/08—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium containing a sulfur-to-oxygen bond
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- C10M135/10—Sulfonic acids or derivatives thereof
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- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/12—Reaction products
- C10M159/16—Reaction products obtained by Mannich reactions
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- C10M159/22—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products containing phenol radicals
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- C10M169/04—Mixtures of base-materials and additives
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
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- C10M2215/226—Morpholines
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- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
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- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/046—Polyamines, i.e. macromoleculars obtained by condensation of more than eleven amine monomers
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
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- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/042—Sulfate esters
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- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/046—Overbasedsulfonic acid salts
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- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
- C10M2219/088—Neutral salts
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
- C10M2219/089—Overbased salts
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
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- C10N2010/00—Metal present as such or in compounds
- C10N2010/06—Groups 3 or 13
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/252—Diesel engines
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- C—CHEMISTRY; METALLURGY
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/255—Gasoline engines
- C10N2040/26—Two-strokes or two-cycle engines
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- C—CHEMISTRY; METALLURGY
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2070/00—Specific manufacturing methods for lubricant compositions
- C10N2070/02—Concentrating of additives
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Fats And Perfumes (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
This invention relates to a nitrogen-containing soluble organic composition comprising a combination of:
(A) at least one natural oil comprising an animal oil or vegetable oil comprising a, triglyceride of the formula wherein R1, R2 and R3 are independently saturated or unsaturated aliphatic hydrocarbyl groups containing from about 8 to about 24 carbon atoms and (B)(I) a detergent/dispersant comprising at least one acylated, nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms made by reacting a carboxylic acylating agent with at least one amino compound containing at least one -NH group, said acylating agent being linked to said amino compound through an imido, amido, amidine, or acyloxy ammonium linkage.
In another embodiment, the invention comprises a nitrogen-containing soluble organic composition comprising a combination of:
(A) the: natural oil as described above with (B) at least one detergent-dispersant selected from the group consisting of (I) the acylated, nitrogen-containing compound as described above, (II) at least one neutral or basic metal salt of an organic sulfur acid, phenol or carboxylic acid:
(III) at least one hydrocarbyl-substituted amine wherein the hydrocarbyl substituent is substantially aliphatic and contains at least 12 carbon atoms with the proviso that said amine is not the amino phenol (C); and (IV) at least one nitrogen-containing condensate of a phenol, aldehyde and amino compound having at least one -NH group; and (C) at least one amino phenol of the general formula
(A) at least one natural oil comprising an animal oil or vegetable oil comprising a, triglyceride of the formula wherein R1, R2 and R3 are independently saturated or unsaturated aliphatic hydrocarbyl groups containing from about 8 to about 24 carbon atoms and (B)(I) a detergent/dispersant comprising at least one acylated, nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms made by reacting a carboxylic acylating agent with at least one amino compound containing at least one -NH group, said acylating agent being linked to said amino compound through an imido, amido, amidine, or acyloxy ammonium linkage.
In another embodiment, the invention comprises a nitrogen-containing soluble organic composition comprising a combination of:
(A) the: natural oil as described above with (B) at least one detergent-dispersant selected from the group consisting of (I) the acylated, nitrogen-containing compound as described above, (II) at least one neutral or basic metal salt of an organic sulfur acid, phenol or carboxylic acid:
(III) at least one hydrocarbyl-substituted amine wherein the hydrocarbyl substituent is substantially aliphatic and contains at least 12 carbon atoms with the proviso that said amine is not the amino phenol (C); and (IV) at least one nitrogen-containing condensate of a phenol, aldehyde and amino compound having at least one -NH group; and (C) at least one amino phenol of the general formula
Applications Claiming Priority (2)
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US91096092A | 1992-07-09 | 1992-07-09 | |
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CA002100030A Expired - Lifetime CA2100030C (en) | 1992-07-09 | 1993-07-07 | Two-stroke cycle lubricant composed of a vegetable oil and an additive package |
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EP (1) | EP0578495B1 (en) |
JP (1) | JPH06200279A (en) |
CN (1) | CN1033704C (en) |
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AU (1) | AU670791B2 (en) |
CA (1) | CA2100030C (en) |
DE (1) | DE69318628T2 (en) |
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SG (1) | SG48751A1 (en) |
TW (1) | TW253907B (en) |
ZA (1) | ZA934917B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5976560A (en) * | 1998-01-30 | 1999-11-02 | Han; Nam Fong | Vegetable derived petroleum jelly replacement |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
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TW291495B (en) * | 1994-08-03 | 1996-11-21 | Lubrizol Corp | |
US5658864A (en) * | 1995-03-24 | 1997-08-19 | Ethyl Corporation | Biodegradable pour point depressants for industrial fluids derived from biodegradable base oils |
DE19747854A1 (en) | 1997-10-30 | 1999-05-12 | Fuchs Petrolub Ag | Method and device for the lubrication and simultaneous fuel supply of a vegetable oil-compatible internal combustion engine |
JP2000080391A (en) * | 1998-09-04 | 2000-03-21 | Showa Shell Sekiyu Kk | Lubricating oil for two-cycle engine and diluent composition used for same |
GB2416172B (en) * | 2004-07-13 | 2009-04-22 | Alan Edwin Jemmett | Rapeseed oil lubricant |
GB2421028A (en) * | 2004-12-08 | 2006-06-14 | Derek Lowe | Fuel for two-stroke engines |
WO2006065958A2 (en) * | 2004-12-14 | 2006-06-22 | C. M. Intellectual Property And Research, Inc. | Composition and methods for improved lubrication, pour point, and fuel performance |
JP4801919B2 (en) * | 2005-03-29 | 2011-10-26 | Jx日鉱日石エネルギー株式会社 | Lubricants for agricultural or forestry machinery |
JP2006274058A (en) * | 2005-03-29 | 2006-10-12 | Nippon Oil Corp | Lubricant for horticultural and silvicultural machines |
US8778034B2 (en) | 2006-09-14 | 2014-07-15 | Afton Chemical Corporation | Biodegradable fuel performance additives |
US8671467B2 (en) | 2007-11-20 | 2014-03-18 | Her Majesty The Queen In Right Of Canada, As Represented By The Minister Of National Defence | Head protection system |
CN101245282B (en) * | 2008-03-25 | 2011-05-25 | 佛山市顺德区远茂化工实业有限公司 | Metallic fiber drawing lubricant agent |
CN104911001B (en) * | 2015-06-05 | 2018-04-24 | 广西大学 | Miller cycle engine lubricant compositions |
CN113512460B (en) * | 2021-08-13 | 2022-10-21 | 福建科恩优路润滑油有限公司 | Anti-wear clean type vehicle lubricating oil and preparation process thereof |
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BE781636A (en) * | 1972-04-04 | 1972-07-31 | Labofina Sa | LUBRICATING COMPOSITIONS FOR TWO STROKE ENGINES. |
IN145085B (en) * | 1976-01-28 | 1978-08-19 | Lubrizol Corp | |
FI66899C (en) * | 1983-02-11 | 1984-12-10 | Kasvisoeljy Vaextolje Ab Oy | SMOERJMEDEL MED TRIGLYCERIDER SOM HUVUDKONPONENT |
US5155244A (en) * | 1990-02-28 | 1992-10-13 | Karlshamns Ab | Preparation of antioxidant glyceride derivatives utilizing esterification |
DE69232260T2 (en) * | 1991-08-09 | 2002-07-25 | Lubrizol Corp | THE USE OF FUNCTIONAL LIQUIDS WITH TRIGLYCERIDES AND DIFFERENT ADDITIVES AS TRACTOR LUBRICANTS |
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- 1993-07-07 CA CA002100030A patent/CA2100030C/en not_active Expired - Lifetime
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5976560A (en) * | 1998-01-30 | 1999-11-02 | Han; Nam Fong | Vegetable derived petroleum jelly replacement |
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DE69318628T2 (en) | 1999-02-11 |
ZA934917B (en) | 1994-02-09 |
CA2100030C (en) | 2003-10-21 |
ES2116412T3 (en) | 1998-07-16 |
CN1033704C (en) | 1997-01-01 |
SG48751A1 (en) | 1998-05-18 |
EP0578495B1 (en) | 1998-05-20 |
CN1081465A (en) | 1994-02-02 |
ATE166382T1 (en) | 1998-06-15 |
EP0578495A1 (en) | 1994-01-12 |
DE69318628D1 (en) | 1998-06-25 |
AU670791B2 (en) | 1996-08-01 |
TW253907B (en) | 1995-08-11 |
JPH06200279A (en) | 1994-07-19 |
AU4177893A (en) | 1994-01-13 |
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