DE69313774T2 - Verfahren und Katalysator zur Umsetzung von Methan in höhere Kohlenwasserstoffe - Google Patents
Verfahren und Katalysator zur Umsetzung von Methan in höhere KohlenwasserstoffeInfo
- Publication number
- DE69313774T2 DE69313774T2 DE69313774T DE69313774T DE69313774T2 DE 69313774 T2 DE69313774 T2 DE 69313774T2 DE 69313774 T DE69313774 T DE 69313774T DE 69313774 T DE69313774 T DE 69313774T DE 69313774 T2 DE69313774 T2 DE 69313774T2
- Authority
- DE
- Germany
- Prior art keywords
- oxide
- calcium
- magnesium
- catalyst
- higher hydrocarbons
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title abstract 6
- 229930195733 hydrocarbon Natural products 0.000 title abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 title 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 2
- 229910052791 calcium Inorganic materials 0.000 abstract 2
- 239000011575 calcium Substances 0.000 abstract 2
- 229910052749 magnesium Inorganic materials 0.000 abstract 2
- 239000011777 magnesium Substances 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000292 calcium oxide Substances 0.000 abstract 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 abstract 1
- 239000008246 gaseous mixture Substances 0.000 abstract 1
- 229910000311 lanthanide oxide Inorganic materials 0.000 abstract 1
- 229910052747 lanthanoid Inorganic materials 0.000 abstract 1
- 150000002602 lanthanoids Chemical class 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 abstract 1
- 229910001947 lithium oxide Inorganic materials 0.000 abstract 1
- 239000000395 magnesium oxide Substances 0.000 abstract 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 abstract 1
- 238000005691 oxidative coupling reaction Methods 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 239000011949 solid catalyst Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
- C07C2/82—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling
- C07C2/84—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling catalytic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/10—Magnesium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
- C07C2523/04—Alkali metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S585/00—Chemistry of hydrocarbon compounds
- Y10S585/929—Special chemical considerations
- Y10S585/943—Synthesis from methane or inorganic carbon source, e.g. coal
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Hydrogen, Water And Hydrids (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITMI922488A IT1255945B (it) | 1992-10-30 | 1992-10-30 | Procedimento e catalizzatore per la trasformazione del metano in prodotti idrocarburici superiori. |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69313774D1 DE69313774D1 (de) | 1997-10-16 |
DE69313774T2 true DE69313774T2 (de) | 1998-02-26 |
Family
ID=11364198
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69313774T Expired - Fee Related DE69313774T2 (de) | 1992-10-30 | 1993-10-27 | Verfahren und Katalysator zur Umsetzung von Methan in höhere Kohlenwasserstoffe |
Country Status (8)
Country | Link |
---|---|
US (2) | US5527978A (de) |
EP (1) | EP0595425B1 (de) |
AT (1) | ATE157957T1 (de) |
DE (1) | DE69313774T2 (de) |
DK (1) | DK0595425T3 (de) |
ES (1) | ES2106956T3 (de) |
GR (1) | GR3024993T3 (de) |
IT (1) | IT1255945B (de) |
Families Citing this family (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1255945B (it) * | 1992-10-30 | 1995-11-17 | Eniricerche Spa | Procedimento e catalizzatore per la trasformazione del metano in prodotti idrocarburici superiori. |
CN1085116C (zh) * | 1996-10-09 | 2002-05-22 | 中国科学院大连化学物理研究所 | 二氧化碳选择性氧化甲烷制乙烷和乙烯催化剂 |
US20050045467A1 (en) * | 2003-09-03 | 2005-03-03 | King Fahd University Of Petroleum And Minerals | Method for the conversion of methane into hydrogen and higher hydrocarbons using UV laser |
US8912381B2 (en) * | 2009-06-29 | 2014-12-16 | Fina Technology, Inc. | Process for the oxidative coupling of methane |
US9089832B2 (en) * | 2009-06-29 | 2015-07-28 | Fina Technology, Inc. | Catalysts for oxidative coupling of hydrocarbons |
CA2800142C (en) * | 2010-05-24 | 2018-06-05 | Siluria Technologies, Inc. | Nanowire catalysts |
EP2714265A2 (de) | 2011-05-24 | 2014-04-09 | Siluria Technologies, Inc. | Katalysatoren für petrochemische katalyse |
BR112014012795B1 (pt) | 2011-11-29 | 2022-04-12 | Siluria Technologies, Inc | Material catalítico na forma de uma microesfera prensada, extrusado ou monólito e método para o acoplamento oxidativo de metano |
CA2860773C (en) | 2012-01-13 | 2020-11-03 | Siluria Technologies, Inc. | Process for separating hydrocarbon compounds |
US9446397B2 (en) | 2012-02-03 | 2016-09-20 | Siluria Technologies, Inc. | Method for isolation of nanomaterials |
EP2855005A2 (de) | 2012-05-24 | 2015-04-08 | Siluria Technologies, Inc. | Oxidative kupplung von methansystemen und verfahren dafür |
US20140121433A1 (en) | 2012-05-24 | 2014-05-01 | Siluria Technologies, Inc. | Catalytic forms and formulations |
US9670113B2 (en) | 2012-07-09 | 2017-06-06 | Siluria Technologies, Inc. | Natural gas processing and systems |
AU2013355038B2 (en) | 2012-12-07 | 2017-11-02 | Lummus Technology Llc | Integrated processes and systems for conversion of methane to multiple higher hydrocarbon products |
WO2014143880A1 (en) | 2013-03-15 | 2014-09-18 | Siluria Technologies, Inc. | Catalysts for petrochemical catalysis |
WO2015081122A2 (en) | 2013-11-27 | 2015-06-04 | Siluria Technologies, Inc. | Reactors and systems for oxidative coupling of methane |
CA3123783A1 (en) | 2014-01-08 | 2015-07-16 | Lummus Technology Llc | Ethylene-to-liquids systems and methods |
CA3225180A1 (en) | 2014-01-09 | 2015-07-16 | Lummus Technology Llc | Oxidative coupling of methane implementations for olefin production |
US10377682B2 (en) | 2014-01-09 | 2019-08-13 | Siluria Technologies, Inc. | Reactors and systems for oxidative coupling of methane |
WO2015168601A2 (en) | 2014-05-02 | 2015-11-05 | Siluria Technologies, Inc. | Heterogeneous catalysts |
CA3192508A1 (en) | 2014-09-17 | 2016-03-24 | Lummus Technology Llc | Catalysts for oxidative coupling of methane and oxidative dehydrogenation of ethane |
US10793490B2 (en) | 2015-03-17 | 2020-10-06 | Lummus Technology Llc | Oxidative coupling of methane methods and systems |
US9334204B1 (en) | 2015-03-17 | 2016-05-10 | Siluria Technologies, Inc. | Efficient oxidative coupling of methane processes and systems |
US20160289143A1 (en) | 2015-04-01 | 2016-10-06 | Siluria Technologies, Inc. | Advanced oxidative coupling of methane |
US9328297B1 (en) | 2015-06-16 | 2016-05-03 | Siluria Technologies, Inc. | Ethylene-to-liquids systems and methods |
EP3786138A1 (de) | 2015-10-16 | 2021-03-03 | Lummus Technology LLC | Oxidative kupplung von methan |
WO2017180910A1 (en) | 2016-04-13 | 2017-10-19 | Siluria Technologies, Inc. | Oxidative coupling of methane for olefin production |
EP3554672A4 (de) | 2016-12-19 | 2020-08-12 | Siluria Technologies, Inc. | Verfahren und systeme für chemische abscheidungen |
EP3630707B1 (de) | 2017-05-23 | 2023-09-06 | Lummus Technology LLC | Integration einer oxidativen kopplung von methanprozessen |
RU2020102298A (ru) | 2017-07-07 | 2021-08-10 | Люммус Текнолоджи Ллс | Системы и способы окислительного сочетания метана |
CN115463651B (zh) * | 2021-06-11 | 2024-02-13 | 中国石油化工股份有限公司 | 含有纳米级棒状氢氧化镧的催化剂及其制备方法和应用 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5077446A (en) * | 1985-03-19 | 1991-12-31 | Phillips Petroleum Company | Methane conversion |
US4780449A (en) * | 1985-06-14 | 1988-10-25 | W. R. Grace & Co.-Conn. | Catalyst for the conversion of methane |
DE3809226C2 (de) * | 1987-03-20 | 1994-10-27 | Toshiba Kawasaki Kk | Hochtemperatur-Verbrennungskatalysator und Verfahren zu seiner Herstellung |
US5068215A (en) * | 1987-06-04 | 1991-11-26 | Standard Oil Company | Catalyst for upgrading low molecular weight hydrocarbons |
IT1244484B (it) * | 1990-12-21 | 1994-07-15 | Eniricerche Spa | Procedimento e catalizzatore per la trasformazione del metano in prodotti idrocarburici superiori |
US5380692A (en) * | 1991-09-12 | 1995-01-10 | Sakai Chemical Industry Co., Ltd. | Catalyst for catalytic reduction of nitrogen oxide |
IT1255945B (it) * | 1992-10-30 | 1995-11-17 | Eniricerche Spa | Procedimento e catalizzatore per la trasformazione del metano in prodotti idrocarburici superiori. |
-
1992
- 1992-10-30 IT ITMI922488A patent/IT1255945B/it active IP Right Grant
-
1993
- 1993-10-27 EP EP93203006A patent/EP0595425B1/de not_active Expired - Lifetime
- 1993-10-27 AT AT93203006T patent/ATE157957T1/de not_active IP Right Cessation
- 1993-10-27 DE DE69313774T patent/DE69313774T2/de not_active Expired - Fee Related
- 1993-10-27 ES ES93203006T patent/ES2106956T3/es not_active Expired - Lifetime
- 1993-10-27 DK DK93203006.7T patent/DK0595425T3/da active
- 1993-10-28 US US08/142,004 patent/US5527978A/en not_active Expired - Fee Related
-
1996
- 1996-03-08 US US08/613,992 patent/US5670442A/en not_active Expired - Fee Related
-
1997
- 1997-10-09 GR GR970402636T patent/GR3024993T3/el unknown
Also Published As
Publication number | Publication date |
---|---|
ES2106956T3 (es) | 1997-11-16 |
US5670442A (en) | 1997-09-23 |
EP0595425B1 (de) | 1997-09-10 |
ITMI922488A0 (it) | 1992-10-30 |
IT1255945B (it) | 1995-11-17 |
ATE157957T1 (de) | 1997-09-15 |
GR3024993T3 (de) | 1998-01-30 |
DK0595425T3 (da) | 1998-03-09 |
ITMI922488A1 (it) | 1994-04-30 |
EP0595425A1 (de) | 1994-05-04 |
US5527978A (en) | 1996-06-18 |
DE69313774D1 (de) | 1997-10-16 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition | ||
8339 | Ceased/non-payment of the annual fee |