DE69220052T2 - Klebehilfsmittel auf basis von säuremodifiziertem polyalkohol-kollophoniumester und schmelzklebemassen enthaltend dieselbe - Google Patents
Klebehilfsmittel auf basis von säuremodifiziertem polyalkohol-kollophoniumester und schmelzklebemassen enthaltend dieselbeInfo
- Publication number
- DE69220052T2 DE69220052T2 DE69220052T DE69220052T DE69220052T2 DE 69220052 T2 DE69220052 T2 DE 69220052T2 DE 69220052 T DE69220052 T DE 69220052T DE 69220052 T DE69220052 T DE 69220052T DE 69220052 T2 DE69220052 T2 DE 69220052T2
- Authority
- DE
- Germany
- Prior art keywords
- rosin
- acid
- tackifier
- styrene
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 150000005846 sugar alcohols Polymers 0.000 title claims description 35
- 239000000853 adhesive Substances 0.000 title description 12
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 141
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 140
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 140
- 150000002148 esters Chemical class 0.000 claims description 79
- 239000000203 mixture Substances 0.000 claims description 69
- 239000004831 Hot glue Substances 0.000 claims description 53
- 239000002253 acid Substances 0.000 claims description 46
- 238000005886 esterification reaction Methods 0.000 claims description 34
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 30
- 229920005989 resin Polymers 0.000 claims description 25
- 239000011347 resin Substances 0.000 claims description 25
- 239000003054 catalyst Substances 0.000 claims description 20
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 19
- 229920001577 copolymer Polymers 0.000 claims description 18
- 239000001993 wax Substances 0.000 claims description 17
- 230000032050 esterification Effects 0.000 claims description 15
- -1 styrene-ethylene-butylene-styrene Chemical class 0.000 claims description 15
- 125000003118 aryl group Chemical group 0.000 claims description 14
- 238000007323 disproportionation reaction Methods 0.000 claims description 14
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 14
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 13
- 239000003784 tall oil Substances 0.000 claims description 12
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 claims description 11
- 239000003921 oil Substances 0.000 claims description 11
- 229920006132 styrene block copolymer Polymers 0.000 claims description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- 230000003197 catalytic effect Effects 0.000 claims description 9
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 9
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 8
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 claims description 8
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 6
- VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 claims description 5
- 239000002480 mineral oil Substances 0.000 claims description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 3
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 claims description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 3
- 229930195725 Mannitol Natural products 0.000 claims description 3
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 3
- UWHCKJMYHZGTIT-UHFFFAOYSA-N Tetraethylene glycol, Natural products OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 claims description 3
- 239000010775 animal oil Substances 0.000 claims description 3
- 239000012164 animal wax Substances 0.000 claims description 3
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims description 3
- 235000011187 glycerol Nutrition 0.000 claims description 3
- 239000000594 mannitol Substances 0.000 claims description 3
- 235000010355 mannitol Nutrition 0.000 claims description 3
- 239000012184 mineral wax Substances 0.000 claims description 3
- 239000000600 sorbitol Substances 0.000 claims description 3
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000008158 vegetable oil Substances 0.000 claims description 3
- 239000012178 vegetable wax Substances 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims 4
- 235000019198 oils Nutrition 0.000 claims 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims 2
- 235000007173 Abies balsamea Nutrition 0.000 claims 1
- 239000004857 Balsam Substances 0.000 claims 1
- 244000018716 Impatiens biflora Species 0.000 claims 1
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 1
- 239000002023 wood Substances 0.000 claims 1
- 239000011541 reaction mixture Substances 0.000 description 18
- 238000000034 method Methods 0.000 description 17
- 238000006243 chemical reaction Methods 0.000 description 11
- 230000001070 adhesive effect Effects 0.000 description 10
- 229920000642 polymer Polymers 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 239000012943 hotmelt Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 4
- 238000013019 agitation Methods 0.000 description 4
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 3
- 229920001038 ethylene copolymer Polymers 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 239000012188 paraffin wax Substances 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 238000010025 steaming Methods 0.000 description 3
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 3
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000008240 homogeneous mixture Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000012768 molten material Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 150000007519 polyprotic acids Polymers 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 239000000565 sealant Substances 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- IXLXHGZVLWXEJK-UHFFFAOYSA-N 1-pentyl-7-thiabicyclo[4.1.0]hepta-2,4-dien-6-ol Chemical compound C1=CC=CC2(CCCCC)C1(O)S2 IXLXHGZVLWXEJK-UHFFFAOYSA-N 0.000 description 1
- BTXXTMOWISPQSJ-UHFFFAOYSA-N 4,4,4-trifluorobutan-2-one Chemical compound CC(=O)CC(F)(F)F BTXXTMOWISPQSJ-UHFFFAOYSA-N 0.000 description 1
- LJKQIQSBHFNMDV-UHFFFAOYSA-N 7-thiabicyclo[4.1.0]hepta-2,4-dien-6-ol Chemical class C1=CC=CC2(O)C1S2 LJKQIQSBHFNMDV-UHFFFAOYSA-N 0.000 description 1
- BQACOLQNOUYJCE-FYZZASKESA-N Abietic acid Natural products CC(C)C1=CC2=CC[C@]3(C)[C@](C)(CCC[C@@]3(C)C(=O)O)[C@H]2CC1 BQACOLQNOUYJCE-FYZZASKESA-N 0.000 description 1
- 244000186140 Asperula odorata Species 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920003345 Elvax® Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 1
- 235000008526 Galium odoratum Nutrition 0.000 description 1
- RWWVEQKPFPXLGL-ONCXSQPRSA-N L-Pimaric acid Chemical compound [C@H]1([C@](CCC2)(C)C(O)=O)[C@@]2(C)[C@H]2CC=C(C(C)C)C=C2CC1 RWWVEQKPFPXLGL-ONCXSQPRSA-N 0.000 description 1
- RWWVEQKPFPXLGL-UHFFFAOYSA-N Levopimaric acid Natural products C1CCC(C(O)=O)(C)C2C1(C)C1CC=C(C(C)C)C=C1CC2 RWWVEQKPFPXLGL-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000004000 hexols Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- BQZGVMWPHXIKEQ-UHFFFAOYSA-L iron(ii) iodide Chemical compound [Fe+2].[I-].[I-] BQZGVMWPHXIKEQ-UHFFFAOYSA-L 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- 229910052808 lithium carbonate Inorganic materials 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000012462 polypropylene substrate Substances 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/04—Homopolymers or copolymers of ethene
- C09J123/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F1/00—Obtaining purification, or chemical modification of natural resins, e.g. oleo-resins
- C09F1/04—Chemical modification, e.g. esterification
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
- C09J153/025—Vinyl aromatic monomers and conjugated dienes modified
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/24—Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/26—Natural polymers, natural resins or derivatives thereof according to C08L1/00 - C08L5/00, C08L89/00, C08L93/00, C08L97/00 or C08L99/00
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Adhesives Or Adhesive Processes (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/696,657 US5120781A (en) | 1991-05-07 | 1991-05-07 | Acid-modified polyhydric alcohol rosin ester tackifiers and hot melt adhesive compositions containing those tackifiers |
| PCT/US1992/001716 WO1992019678A1 (en) | 1991-05-07 | 1992-03-03 | Acid-modified polyhydric alcohol rosin ester tackifiers and hot melt adhesive compositions containing those tackifiers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69220052D1 DE69220052D1 (de) | 1997-07-03 |
| DE69220052T2 true DE69220052T2 (de) | 1997-09-11 |
Family
ID=24798018
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69220052T Expired - Lifetime DE69220052T2 (de) | 1991-05-07 | 1992-03-03 | Klebehilfsmittel auf basis von säuremodifiziertem polyalkohol-kollophoniumester und schmelzklebemassen enthaltend dieselbe |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US5120781A (enExample) |
| EP (1) | EP0583419B1 (enExample) |
| JP (1) | JP2512671B2 (enExample) |
| CN (1) | CN1051793C (enExample) |
| BR (1) | BR9205971A (enExample) |
| DE (1) | DE69220052T2 (enExample) |
| ES (1) | ES2101853T3 (enExample) |
| FI (1) | FI106039B (enExample) |
| MX (1) | MX9202114A (enExample) |
| NO (1) | NO933988D0 (enExample) |
| PT (1) | PT100464B (enExample) |
| TW (1) | TW259810B (enExample) |
| WO (1) | WO1992019678A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006054196A1 (de) * | 2006-11-15 | 2008-05-21 | Henkel Kgaa | Schmelzhaftklebstoffe mit verbesserter Haftung |
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| KR100271178B1 (ko) * | 1994-10-07 | 2001-03-02 | 데이비드 엠 모이어 | 접착제 조성물, 이의 제조방법 및 이를 제조하기 위한 장치, 및 상기 접착제 조성물을 포함하는 흡수 제품 |
| AU732686B2 (en) * | 1994-10-07 | 2001-04-26 | Procter & Gamble Company, The | Adhesive composition, method and apparatus for manufacture thereof and absorbent articles comprising said adhesive composition |
| US5504152A (en) * | 1995-01-10 | 1996-04-02 | Arizona Chemical Company | Esterification of rosin |
| US5777013A (en) * | 1997-01-24 | 1998-07-07 | Arizona Chemical Company | Dispersion and adhesion of silica in elastomeric materials |
| AU9303398A (en) * | 1997-09-08 | 1999-03-29 | National Starch And Chemical Investment Holding Corporation | The use of natural oils in hot melt adhesives |
| EP1255795B1 (en) | 2000-02-17 | 2005-08-03 | Akzo Nobel N.V. | Polyester tackifier and adhesive composition |
| US6593407B2 (en) * | 2001-02-06 | 2003-07-15 | National Starch And Chemical Investment Holding Corporation | Hot melt adhesive composition |
| FR2830257B1 (fr) * | 2001-10-02 | 2006-12-01 | Bostik Findley | Procede d'assemblage par collage de substrats hydrophobes et oleophobes destines au marche de l'emballage |
| US6890982B2 (en) * | 2002-06-11 | 2005-05-10 | Marcus Oil And Chemical-Corp. | Wax for hot melt adhesive applications |
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| EP1394042B1 (en) * | 2002-08-30 | 2005-08-10 | Ishida Co., Ltd. | Display strip |
| US7476441B2 (en) * | 2002-08-30 | 2009-01-13 | Ishida Co., Ltd. | Display strip and display strip and product assembly |
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| EP1394043B1 (en) * | 2002-08-30 | 2006-04-26 | Ishida Co., Ltd. | Display strip |
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| US20110034669A1 (en) * | 2006-02-02 | 2011-02-10 | Dallavia Anthony J | Rosin Ester with Low Color and Process for Preparing Same |
| CN100387667C (zh) * | 2006-02-07 | 2008-05-14 | 福州大学 | 高沸醇木质素或其衍生物的松香改性树脂及其制备方法 |
| EP2066758B1 (en) * | 2006-09-27 | 2012-06-06 | H. B. Fuller Company | Hot melt pressure sensitive adhesive composition that includes vegetable wax and articles including the same |
| JP4534258B2 (ja) * | 2007-09-28 | 2010-09-01 | 荒川化学工業株式会社 | 粘着付与剤、医療用貼布剤用粘着付与剤、粘着剤または接着剤組成物および医療用貼付剤用粘着剤 |
| CN101348695B (zh) * | 2008-08-05 | 2013-07-10 | 广东省造纸研究所 | 一种改进的冷压自粘结胶带纸的涂料及制备方法 |
| DE102009006591A1 (de) * | 2009-01-29 | 2010-08-05 | Tesa Se | Haftklebemasse |
| US20100286642A1 (en) * | 2009-05-11 | 2010-11-11 | Allen Jr William Maxwell | Water-stable, oil-modified, nonreactive alkyd resin construction adhesives, and use thereof |
| BR112012010858B8 (pt) * | 2009-11-09 | 2018-10-02 | 3M Innovative Properties Co | ''artigo médico e método para aumentar a taxa de transmissão de vapor de umidade. |
| WO2011057175A1 (en) | 2009-11-09 | 2011-05-12 | 3M Innovative Properties Company | Medical articles and methods of making using miscible composition |
| US20110213120A1 (en) * | 2010-03-01 | 2011-09-01 | Arizona Chemical Company | Rosin esters for non-woven applications, methods of making and using and products therefrom |
| EP2452979A1 (en) * | 2010-11-10 | 2012-05-16 | The Procter & Gamble Company | Adhesive and use thereof |
| CN102337078B (zh) * | 2011-07-07 | 2013-10-16 | 景东力奥林产集团林业化工有限公司 | 松香树脂生产工艺 |
| WO2013049458A1 (en) * | 2011-09-29 | 2013-04-04 | The Procter & Gamble Company | Stabilized adhesives and use thereof |
| CN102676062B (zh) * | 2012-05-15 | 2014-07-30 | 普洱科茂林化有限公司 | 一种耐低温松香增粘树脂、其制备方法及用途 |
| JP6040686B2 (ja) * | 2012-09-28 | 2016-12-07 | 星光Pmc株式会社 | ロジン多価アルコールエステル樹脂、インキ乳化適性向上剤、オフセット印刷インキ用ワニス及びオフセット印刷用インキ組成物 |
| WO2014209620A1 (en) | 2013-06-28 | 2014-12-31 | 3M Innovative Properties Company | Fibrin-coated wound dressing |
| EP3274414A1 (en) * | 2015-03-26 | 2018-01-31 | Arizona Chemical Company, LLC | Compositions containing rosin ester and ethylene polymers |
| EP3274002B1 (en) | 2015-03-27 | 2021-09-22 | 3M Innovative Properties Company | Fibrin composition, method and wound articles |
| EP3385351A4 (en) | 2015-11-30 | 2019-07-31 | Harima Chemicals, Incorporated | ADHESIVE RESIN AND PRESSURE-SENSITIVE ADHESIVE COMPOSITION |
| CN108602331B (zh) * | 2015-12-31 | 2022-06-10 | 科腾化学品有限责任公司 | 树脂填充的橡胶组合物和用其制备的轮胎橡胶组合物 |
| CA3016461A1 (en) * | 2016-03-04 | 2017-09-08 | Ingevity South Carolina, Llc | Fatty acid and rosin acid ester compositions for use as plasticizers in adhesive formulations and associated methods of use |
| JP6756122B2 (ja) * | 2016-03-11 | 2020-09-16 | 東洋インキＳｃホールディングス株式会社 | ホットメルト粘着剤、およびホットメルト粘着剤付きシート |
| US10407593B2 (en) | 2016-09-23 | 2019-09-10 | Kraton Chemical, Llc | Oligoesters compositions and methods of making and using same |
| US10940233B2 (en) | 2016-10-05 | 2021-03-09 | 3M Innovative Properties Company | Fibrinogen composition, method and wound articles |
| US11827754B2 (en) | 2016-10-05 | 2023-11-28 | 3M Innovative Properties Company | Fibrin composition comprising carrier material, method and wound articles |
| KR20210003272A (ko) | 2018-05-25 | 2021-01-11 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 상 분리된 물품 |
| JP7005063B1 (ja) * | 2021-06-17 | 2022-01-21 | 積水フーラー株式会社 | ホットメルト接着剤 |
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| US3652474A (en) * | 1970-02-27 | 1972-03-28 | Us Agriculture | Hot-melt adhesive composition containing rosin polyester |
| JPS56163174A (en) * | 1980-05-22 | 1981-12-15 | Arakawa Chem Ind Co Ltd | Hot melt-type pressure sensitive adhesive |
| JPS6020977A (ja) * | 1983-07-13 | 1985-02-02 | Arakawa Chem Ind Co Ltd | 感圧性接着剤組成物 |
| JPS6028476A (ja) * | 1983-07-27 | 1985-02-13 | Arakawa Chem Ind Co Ltd | ホツトメルト接着剤組成物 |
| JPH079546B2 (ja) * | 1986-11-17 | 1995-02-01 | 日本合成化学工業株式会社 | トナ−用のバインダ− |
| JP2554928B2 (ja) * | 1988-12-30 | 1996-11-20 | ハリマ化成株式会社 | ホットメルト接着剤組成物及びその製造方法 |
-
1991
- 1991-05-07 US US07/696,657 patent/US5120781A/en not_active Expired - Lifetime
-
1992
- 1992-03-03 BR BR9205971A patent/BR9205971A/pt not_active Application Discontinuation
- 1992-03-03 WO PCT/US1992/001716 patent/WO1992019678A1/en not_active Ceased
- 1992-03-03 DE DE69220052T patent/DE69220052T2/de not_active Expired - Lifetime
- 1992-03-03 ES ES92914104T patent/ES2101853T3/es not_active Expired - Lifetime
- 1992-03-03 EP EP92914104A patent/EP0583419B1/en not_active Expired - Lifetime
- 1992-03-03 JP JP4511801A patent/JP2512671B2/ja not_active Expired - Lifetime
- 1992-03-24 TW TW081102239A patent/TW259810B/zh active
- 1992-05-05 CN CN92103048A patent/CN1051793C/zh not_active Expired - Lifetime
- 1992-05-06 MX MX9202114A patent/MX9202114A/es unknown
- 1992-05-07 PT PT100464A patent/PT100464B/pt not_active IP Right Cessation
-
1993
- 1993-11-04 NO NO1993933988A patent/NO933988D0/no unknown
- 1993-11-05 FI FI934897A patent/FI106039B/fi not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006054196A1 (de) * | 2006-11-15 | 2008-05-21 | Henkel Kgaa | Schmelzhaftklebstoffe mit verbesserter Haftung |
Also Published As
| Publication number | Publication date |
|---|---|
| PT100464A (pt) | 1993-09-30 |
| EP0583419A4 (enExample) | 1994-08-31 |
| ES2101853T3 (es) | 1997-07-16 |
| CN1051793C (zh) | 2000-04-26 |
| JP2512671B2 (ja) | 1996-07-03 |
| JPH06501515A (ja) | 1994-02-17 |
| PT100464B (pt) | 1999-08-31 |
| TW259810B (enExample) | 1995-10-11 |
| CN1069994A (zh) | 1993-03-17 |
| EP0583419A1 (en) | 1994-02-23 |
| US5120781A (en) | 1992-06-09 |
| EP0583419B1 (en) | 1997-05-28 |
| NO933988L (no) | 1993-11-04 |
| FI934897L (fi) | 1993-11-05 |
| NO933988D0 (no) | 1993-11-04 |
| DE69220052D1 (de) | 1997-07-03 |
| FI106039B (fi) | 2000-11-15 |
| FI934897A0 (fi) | 1993-11-05 |
| BR9205971A (pt) | 1994-09-27 |
| WO1992019678A1 (en) | 1992-11-12 |
| MX9202114A (es) | 1992-11-01 |
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| 8364 | No opposition during term of opposition | ||
| 8327 | Change in the person/name/address of the patent owner |
Owner name: ARIZONA CHEMICAL CO., JACKSONVILLE, FLA., US |
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| 8328 | Change in the person/name/address of the agent |
Representative=s name: HOEFER & PARTNER, 81543 MUENCHEN |