DE69111946D1 - Rhodium-katalysierte Olefindimierisierung. - Google Patents

Rhodium-katalysierte Olefindimierisierung.

Info

Publication number
DE69111946D1
DE69111946D1 DE69111946T DE69111946T DE69111946D1 DE 69111946 D1 DE69111946 D1 DE 69111946D1 DE 69111946 T DE69111946 T DE 69111946T DE 69111946 T DE69111946 T DE 69111946T DE 69111946 D1 DE69111946 D1 DE 69111946D1
Authority
DE
Germany
Prior art keywords
rhodium
catalyzed olefin
olefin dimerization
dimerization
catalyzed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69111946T
Other languages
English (en)
Other versions
DE69111946T2 (de
Inventor
Maurice S Brookhart
Sylviane Sabo-Eti Sabo-Etienne
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
University of North Carolina at Chapel Hill
University of North Carolina System
Original Assignee
University of North Carolina at Chapel Hill
University of North Carolina System
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by University of North Carolina at Chapel Hill, University of North Carolina System filed Critical University of North Carolina at Chapel Hill
Publication of DE69111946D1 publication Critical patent/DE69111946D1/de
Application granted granted Critical
Publication of DE69111946T2 publication Critical patent/DE69111946T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/593—Dicarboxylic acid esters having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C67/347—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by addition to unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/0073—Rhodium compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)
DE69111946T 1990-09-11 1991-09-11 Rhodium-katalysierte Olefindimierisierung. Expired - Fee Related DE69111946T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/580,919 US5099061A (en) 1990-09-11 1990-09-11 Rhodium-catalyzed olefin dimerization

Publications (2)

Publication Number Publication Date
DE69111946D1 true DE69111946D1 (de) 1995-09-14
DE69111946T2 DE69111946T2 (de) 1996-02-22

Family

ID=24323124

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69111946T Expired - Fee Related DE69111946T2 (de) 1990-09-11 1991-09-11 Rhodium-katalysierte Olefindimierisierung.

Country Status (7)

Country Link
US (1) US5099061A (de)
EP (1) EP0475386B1 (de)
JP (1) JP3091538B2 (de)
KR (1) KR100210215B1 (de)
CA (1) CA2051148C (de)
DE (1) DE69111946T2 (de)
ES (1) ES2077753T3 (de)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2704222B1 (fr) * 1993-04-23 1995-06-30 Inst Francais Du Petrole Procédé de codimérisation de diènes et d'oléfines.
DE10254853A1 (de) 2002-11-25 2004-06-03 Basf Ag Verbessertes Verfahren zur Herstellung von Cyclopentenonen
DE10258316A1 (de) 2002-12-13 2004-06-24 Basf Ag Verfahren zur Herstellung von1,6-Hexandiol
DE10328714A1 (de) * 2003-06-25 2005-01-13 Basf Ag Verfahren zur Abtrennung eines Rhodium enthaltenden Homogenkatalysators
DE10328715A1 (de) * 2003-06-25 2005-01-13 Basf Ag Verfahren zur kontinuierlichen Herstellung einer Verbindung, die mindestens zwei funktionelle Gruppen trägt

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3013066A (en) * 1961-03-23 1961-12-12 Du Pont Dimerization of alpha olefins with a group viii noble metal salt
GB1214443A (en) * 1968-01-30 1970-12-02 Toa Gosei Chem Ind Process for preparing a dimer and trimer of an acrylic acid ester
US3636122A (en) * 1970-05-28 1972-01-18 Du Pont Preparation of 1 4-hexadiene from ethylene and butadiene with selected cyclopentadienylrhodium catalysts
DE3336691A1 (de) * 1983-10-08 1985-04-25 Studiengesellschaft Kohle mbH, 4330 Mülheim Verfahren zur katalytischen dimerisation von acrylsaeurederivaten und verwendung der erhaltenen dimeren
GB8515139D0 (en) * 1985-06-14 1985-07-17 Shell Int Research Preparation of unsaturated compounds
US4638084A (en) * 1985-09-12 1987-01-20 Shell Oil Company Process for dimerizing acrylates and methacrylates
FR2596390B1 (fr) * 1986-03-27 1989-02-17 Rhone Poulenc Chimie Procede de (co)dimerisation catalytique d'un acrylate d'alkyle inferieur et composition catalytique

Also Published As

Publication number Publication date
US5099061A (en) 1992-03-24
EP0475386A3 (en) 1993-05-12
JPH0625087A (ja) 1994-02-01
ES2077753T3 (es) 1995-12-01
CA2051148A1 (en) 1992-03-12
EP0475386A2 (de) 1992-03-18
EP0475386B1 (de) 1995-08-09
KR920006263A (ko) 1992-04-27
CA2051148C (en) 2001-11-06
DE69111946T2 (de) 1996-02-22
KR100210215B1 (ko) 1999-07-15
JP3091538B2 (ja) 2000-09-25

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee