DE69029324D1 - Polymerisierungsverfahren und -katalysator - Google Patents

Polymerisierungsverfahren und -katalysator

Info

Publication number
DE69029324D1
DE69029324D1 DE69029324T DE69029324T DE69029324D1 DE 69029324 D1 DE69029324 D1 DE 69029324D1 DE 69029324 T DE69029324 T DE 69029324T DE 69029324 T DE69029324 T DE 69029324T DE 69029324 D1 DE69029324 D1 DE 69029324D1
Authority
DE
Germany
Prior art keywords
catalyst
polymerization method
hindrance
elastomeric
polymerized
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69029324T
Other languages
English (en)
Other versions
DE69029324T2 (de
Inventor
Robert Job
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell USA Inc
Original Assignee
Shell Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Oil Co filed Critical Shell Oil Co
Application granted granted Critical
Publication of DE69029324D1 publication Critical patent/DE69029324D1/de
Publication of DE69029324T2 publication Critical patent/DE69029324T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE69029324T 1989-04-25 1990-04-19 Polymerisierungsverfahren und -katalysator Expired - Fee Related DE69029324T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/342,832 US5270276A (en) 1989-04-25 1989-04-25 Process for the production of elastomeric, primarily syndiotactic polypropylene and catalysts for use in said process
PCT/US1990/002036 WO1990012816A1 (en) 1989-04-25 1990-04-19 Polymerization process and catalyst

Publications (2)

Publication Number Publication Date
DE69029324D1 true DE69029324D1 (de) 1997-01-16
DE69029324T2 DE69029324T2 (de) 1997-04-30

Family

ID=23343460

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69029324T Expired - Fee Related DE69029324T2 (de) 1989-04-25 1990-04-19 Polymerisierungsverfahren und -katalysator

Country Status (10)

Country Link
US (1) US5270276A (de)
EP (1) EP0470171B1 (de)
JP (1) JP3021037B2 (de)
KR (1) KR940003857B1 (de)
AT (1) ATE145925T1 (de)
AU (1) AU650234B2 (de)
CA (1) CA2053266C (de)
DE (1) DE69029324T2 (de)
ES (1) ES2097146T3 (de)
WO (1) WO1990012816A1 (de)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5270276A (en) * 1989-04-25 1993-12-14 Shell Oil Company Process for the production of elastomeric, primarily syndiotactic polypropylene and catalysts for use in said process
EP0729985A3 (de) * 1990-12-26 1997-05-07 Shell Oil Co Äthylen-Propylencopolymerzusammensetzungen
USH1583H (en) * 1993-06-01 1996-08-06 Shell Oil Company Elastomeric polybutylene polymer
CA2131668C (en) * 1993-12-23 1999-03-02 Carol Galli Isolation structure using liquid phase oxide deposition
ES2151084T3 (es) * 1994-12-20 2000-12-16 Montell Technology Company Bv Polipropileno de mezcla de reactor y procedimiento para su preparacion.
US6265512B1 (en) 1997-10-23 2001-07-24 3M Innovative Company Elastic polypropylenes and catalysts for their manufacture
US6387529B1 (en) * 1997-12-24 2002-05-14 Exxon Mobil Oil Corporation Biaxially oriented HDPE multilayer film
EP0931814A1 (de) * 1998-01-21 1999-07-28 Fina Research S.A. Polyolefine und ihre Verwendung
US6436864B1 (en) 1999-10-06 2002-08-20 Sri International Unsaturated nitrogenous compounds as electron donors for use with ziegler-natta catalysts
KR20010057153A (ko) * 1999-12-18 2001-07-04 유현식 프로필렌 중합 및 공중합 방법
KR100377288B1 (ko) * 2000-06-12 2003-03-26 삼성종합화학주식회사 프로필렌의 중합 또는 공중합방법
US20030022786A1 (en) * 2001-05-03 2003-01-30 Epstein Ronald A. Catalyst for propylene polymerization
US7166553B2 (en) * 2002-05-06 2007-01-23 Union Carbide Chemicals & Plastics Technology Corporation Mixed catalyst compositions for the production of polyolefins
EP1660545A1 (de) * 2003-08-29 2006-05-31 Dow Global Technologies Inc. Verfahren zur herstellung von teilgetrocknetem leicht dispergierbaren olefinpolymerisationsprokatalysator
EP2221328B1 (de) 2004-03-17 2017-04-19 Dow Global Technologies LLC Katalysatorzusammensetzung mit Kettenübertragungsreagenz zur Herstellung von Ethylen-Multiblock-Copolymeren
CA2559576C (en) * 2004-03-17 2013-02-12 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation
WO2005090426A1 (en) 2004-03-17 2005-09-29 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation
US7915192B2 (en) 2004-03-17 2011-03-29 Dow Global Technologies Llc Catalyst composition comprising shuttling agent for ethylene copolymer formation
EP3424966B1 (de) 2005-03-17 2020-05-27 Dow Global Technologies Llc Katalysatorzusammensetzung mit transportwirkstoff zur taktischen/ataktischen multiblock-copolymer-formierung
US9410009B2 (en) 2005-03-17 2016-08-09 Dow Global Technologies Llc Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation
EP2894176B1 (de) 2005-03-17 2022-06-01 Dow Global Technologies LLC Katalysatorzusammensetzung mit reversiblem Kettenübertragungsreagenz für die regio-irreguläre Multiblock-Copolymer-Synthese
US7662895B2 (en) * 2005-11-22 2010-02-16 Exxonmobil Chemical Patents Inc. Syndiotactic propylene elastomers
US7605215B2 (en) * 2006-12-08 2009-10-20 Sumitomo Chemical Company, Limited Process for producing olefin copolymerization catalyst and process for producing olefin copolymer
US7732540B2 (en) * 2006-12-08 2010-06-08 Sumitomo Chemical Company, Limited Process for producing olefin copolymerization catalyst and process for producing olefin copolymer
JP5799866B2 (ja) * 2012-03-15 2015-10-28 日本ポリプロ株式会社 α−オレフィン重合用固体触媒成分、α−オレフィン重合用固体触媒成分の製造方法、α−オレフィン重合用触媒およびα−オレフィン重合体の製造方法
BR112022021357A2 (pt) 2020-04-30 2022-12-06 Dow Global Technologies Llc Sistemas pró-catalisador e catalisador, métodos para sintetizar um sistema pró-catalisador e um polímero de poliolefina, e, método para produzir um sistema catalisador

Family Cites Families (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3112301A (en) * 1963-11-26 Table
IT557911A (de) * 1954-06-08 1900-01-01
NZ126521A (de) * 1959-06-06
NL273776A (de) * 1961-01-30
US3305538A (en) * 1961-11-22 1967-02-21 Montedison Spa Polymerization process
US3329741A (en) * 1963-05-08 1967-07-04 Rexall Drug Chemical Process for preparing rubbery polymers with a catalyst comprising ti(or)4
US3364190A (en) * 1964-04-27 1968-01-16 Standard Oil Co Process for polymerizing propylene to syndiotactic polypropylene
US3240773A (en) * 1964-07-22 1966-03-15 Shell Oil Co Polymerization of alpha-monoolefins in the presence of titanium trichloride, organometallic reducing agent comprising zinc dihydrocarbyl, and an organic amine
US3534006A (en) * 1966-03-25 1970-10-13 Toray Industries Methods of polymerizing alpha-olefins with a transition metal and a bis(dialkylaluminumoxy)alkane compound
US3355121A (en) * 1966-10-13 1967-11-28 Sonoco Products Co Expansible chuck for tubular core
US4107413A (en) * 1971-06-25 1978-08-15 Montedison S.P.A. Process for the stereoregular polymerization of alpha olefins
US4226963A (en) * 1971-06-25 1980-10-07 Montedison S.P.A. Process for the stereoregular polymerization of alpha-olephins
NL160286C (de) * 1971-06-25
US4317898A (en) * 1972-01-31 1982-03-02 Standard Oil Company (Indiana) Catalyst and process for the polymerization of olefins
IE40215B1 (en) * 1973-12-04 1979-04-11 Ici Ltd Olefine polymer, olefine polymerisation process and catalyst
GB1486194A (en) * 1973-12-04 1977-09-21 Ici Ltd Olefine polymer olefine polymerisation process and catalyst
DD124254A5 (de) * 1974-01-18 1977-02-09
US3932307A (en) * 1974-05-20 1976-01-13 E. I. Du Pont De Nemours And Company Tetra(neophyl) zirconium and its use in process for the polymerization of olefins
US3971767A (en) * 1974-05-20 1976-07-27 E. I. Du Pont De Nemours And Company Olefin polymerization catalyst system and process for polymerization of olefins
US3950269A (en) * 1974-05-20 1976-04-13 E. I. Du Pont De Nemours & Co. Olefin polymerization catalyst system and process for polymerization of olefins
US4011383A (en) * 1974-05-20 1977-03-08 E. I. Du Pont De Nemours And Company Tetra(neophyl) zirconium and its use in process for the polymerization of olefins
US4017525A (en) * 1975-05-20 1977-04-12 E. I. Dupont De Nemours And Company Tetra(neophyl) zirconium
US4189556A (en) * 1976-06-16 1980-02-19 Standard Oil Company (Indiana) Polymerization process
JPS5952166B2 (ja) * 1976-06-29 1984-12-18 三井化学株式会社 ポリオレフインの製造方法
US4335225A (en) * 1978-06-20 1982-06-15 E. I. Du Pont De Nemours And Company Elastomeric polypropylene
US4310439A (en) * 1979-03-07 1982-01-12 Exxon Research & Engineering Co. Novel trialkyl aluminum cocatalyst
EP0019312B1 (de) * 1979-04-30 1983-08-17 Shell Internationale Researchmaatschappij B.V. Katalysatorzusammensetzungen für Olefinpolymerisation und Verfahren zur Polymerisation von Olefinen unter Verwendung solcher Zusammensetzungen
CA1141093A (en) * 1979-05-17 1983-02-08 Brian L. Goodall Olefin polymerization catalyst compositions and a process for the polymerization of olefins employing such compositions
US4255281A (en) * 1979-07-03 1981-03-10 Standard Oil Company (Indiana) Alpha-olefin polymerization catalyst and process
FR2460964A1 (fr) * 1979-07-06 1981-01-30 Naphtachimie Sa Copolymeres elastomeres d'ethylene et de propylene, leur fabrication et leurs applications
US4487845A (en) * 1980-05-09 1984-12-11 Stauffer Chemical Company Method of enhancing stereospecificity of a catalyst system
US4347160A (en) * 1980-06-27 1982-08-31 Stauffer Chemical Company Titanium halide catalyst system
US4325836A (en) * 1980-07-18 1982-04-20 Stauffer Chemical Company Novel titanium halide containing catalyst
US4394291A (en) * 1981-03-04 1983-07-19 Phillips Petroleum Company Polyolefin polymerization process and catalyst
US4442276A (en) * 1982-02-12 1984-04-10 Mitsui Petrochemical Industries, Ltd. Process for polymerizing or copolymerizing olefins
US4581342A (en) * 1984-11-26 1986-04-08 Standard Oil Company (Indiana) Supported olefin polymerization catalyst
JPH06104687B2 (ja) * 1985-06-18 1994-12-21 東燃株式会社 オレフイン重合用触媒
JPH0725807B2 (ja) * 1985-12-20 1995-03-22 東燃株式会社 オレフイン重合用触媒成分の製造方法
US4710482A (en) * 1986-06-18 1987-12-01 Shell Oil Company Olefin polymerization catalyst component
GB8708778D0 (en) * 1987-04-13 1987-05-20 Ici Plc Particulate solid
US5270276A (en) * 1989-04-25 1993-12-14 Shell Oil Company Process for the production of elastomeric, primarily syndiotactic polypropylene and catalysts for use in said process

Also Published As

Publication number Publication date
EP0470171A1 (de) 1992-02-12
WO1990012816A1 (en) 1990-11-01
EP0470171A4 (en) 1992-10-28
ES2097146T3 (es) 1997-04-01
ATE145925T1 (de) 1996-12-15
US5270276A (en) 1993-12-14
AU5655790A (en) 1990-11-16
KR940003857B1 (ko) 1994-05-04
DE69029324T2 (de) 1997-04-30
CA2053266A1 (en) 1990-10-26
EP0470171B1 (de) 1996-12-04
JP3021037B2 (ja) 2000-03-15
KR920701264A (ko) 1992-08-11
AU650234B2 (en) 1994-06-16
JPH04504875A (ja) 1992-08-27
CA2053266C (en) 1999-11-30

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee