DE69028979T2 - Katalysator und Verfahren für die Olefinpolymerisation - Google Patents
Katalysator und Verfahren für die OlefinpolymerisationInfo
- Publication number
- DE69028979T2 DE69028979T2 DE69028979T DE69028979T DE69028979T2 DE 69028979 T2 DE69028979 T2 DE 69028979T2 DE 69028979 T DE69028979 T DE 69028979T DE 69028979 T DE69028979 T DE 69028979T DE 69028979 T2 DE69028979 T2 DE 69028979T2
- Authority
- DE
- Germany
- Prior art keywords
- olefin polymerization
- solid
- catalyst component
- titanium
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63904—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with another component of C08F4/62
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP34091689A JP2953525B2 (ja) | 1989-12-29 | 1989-12-29 | オレフィン重合用触媒およびオレフィンの重合方法 |
JP34090689A JP2953519B2 (ja) | 1989-12-29 | 1989-12-29 | オレフィン重合用触媒およびオレフィンの重合方法 |
JP34090889A JP2953520B2 (ja) | 1989-12-29 | 1989-12-29 | オレフィン重合用触媒およびオレフィンの重合方法 |
JP34091489A JP2953523B2 (ja) | 1989-12-29 | 1989-12-29 | オレフィン重合用触媒およびオレフィンの重合方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69028979D1 DE69028979D1 (de) | 1996-11-28 |
DE69028979T2 true DE69028979T2 (de) | 1997-03-20 |
Family
ID=27480594
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69028979T Expired - Fee Related DE69028979T2 (de) | 1989-12-29 | 1990-12-28 | Katalysator und Verfahren für die Olefinpolymerisation |
Country Status (7)
Country | Link |
---|---|
US (1) | US5120696A (de) |
EP (1) | EP0439964B1 (de) |
KR (1) | KR940006216B1 (de) |
AT (1) | ATE144539T1 (de) |
CA (1) | CA2033416C (de) |
DE (1) | DE69028979T2 (de) |
TW (1) | TW198726B (de) |
Families Citing this family (56)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5266544A (en) * | 1989-12-29 | 1993-11-30 | Mitsui Petrochemical Industries, Ltd. | Olefin polymerization catalyst and process for the polymerization of olefins |
US5099050A (en) * | 1991-04-15 | 1992-03-24 | Ethyl Corporation | Preparation of aluminoxanes |
DE69219206T2 (de) * | 1991-05-31 | 1997-08-28 | Mitsui Petrochemical Ind | Fester Katalysatorbestandteil, Katalysator und Verfahren für Olefinpolymerisation |
CA2072489C (en) * | 1991-06-27 | 2002-04-02 | Yoshio Tajima | Catalyst components for polymerization of olefins |
JPH061803A (ja) * | 1992-06-18 | 1994-01-11 | Mitsubishi Petrochem Co Ltd | オレフィンの重合法 |
CA2105889A1 (en) * | 1992-09-10 | 1994-03-11 | Yoshio Tajima | Catalyst component for the polymerization of olefins and process for preparing olefin polymers using same |
IT1255365B (it) * | 1992-09-15 | 1995-10-31 | Enichem Polimeri | Catalizzatore e procedimento per la polimerizzazione di alfa-olefine |
TW302375B (de) * | 1992-10-05 | 1997-04-11 | Mitsui Petroleum Chemicals Ind | |
US5939346A (en) * | 1992-11-02 | 1999-08-17 | Akzo Nobel N.V. | Catalyst system comprising an aryloxyaluminoxane containing an electron withdrawing group |
CA2103301C (en) * | 1992-11-18 | 2000-05-23 | Takashi Tashiro | Catalyst for olefin polymerization and process for olefin polymerization using the same |
EP0600482B1 (de) * | 1992-12-03 | 1998-04-08 | Mitsubishi Chemical Corporation | Harzzusammensetzung für Laminate |
EP0601495B1 (de) * | 1992-12-07 | 2002-04-24 | Mitsubishi Chemical Corporation | Harzzusammensetzung für extrudierte Formen |
BE1006438A3 (fr) * | 1992-12-17 | 1994-08-30 | Solvay | Systeme catalytique, utilisation de ce systeme catalytique pour la (co)polymerisation d'olefines, procede de preparation de ce systeme catalytique et procede de (co)polymerisation d'olefines. |
US5914376A (en) * | 1993-01-21 | 1999-06-22 | Targor Gmbh | Catalyst for the polymerization of olefins, process for the preparation thereof, and use thereof |
DE4330667A1 (de) * | 1993-09-10 | 1995-03-16 | Basf Ag | Verfahren zur Herstellung von mehrphasigen Homo- oder Copolymerisaten von C¶2¶-C¶1¶¶0¶-Alk-1-enen in einer Reaktionszone |
US5401816A (en) * | 1993-09-27 | 1995-03-28 | Phillips Petroleum Company | Transition metal catalyst, method of preparing catalyst, polymerization process employing catalyst, and polymer produced |
US6391817B1 (en) | 1993-12-28 | 2002-05-21 | Exxonmobil Chemical Patents Inc. | Method for producing a prepolymerized catalyst |
FR2717816B1 (fr) * | 1994-03-23 | 1996-04-26 | Atochem Elf Sa | Composante catalytique pour la polymérisation des oléfines obtenue par impregnation d'un prépolymère par une solution d'une composante catalytique. Prépolymère et polymère obtenus à partir de ladite composante catalytique. |
IT1269931B (it) * | 1994-03-29 | 1997-04-16 | Spherilene Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
IT1269837B (it) * | 1994-05-26 | 1997-04-15 | Spherilene Srl | Componenti e catalizzatori per la polimerizzazione delle olefine |
IT1270253B (it) * | 1994-06-20 | 1997-04-29 | Spherilene Srl | Copolimeri dell'etilene e procedimento per la preparazione di polimeri dell'etilene |
IT1270070B (it) * | 1994-07-08 | 1997-04-28 | Spherilene Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
JPH10505622A (ja) | 1994-09-08 | 1998-06-02 | モービル・オイル・コーポレーション | 単一の反応器内での広い/2モードのmwdの樹脂の触媒制御 |
US5622906A (en) * | 1994-09-16 | 1997-04-22 | Phillips Petroleum Company | Compositions useful for olefin polymerization and processes therefor and therewith |
US5525678A (en) * | 1994-09-22 | 1996-06-11 | Mobil Oil Corporation | Process for controlling the MWD of a broad/bimodal resin produced in a single reactor |
US5529965A (en) * | 1994-10-28 | 1996-06-25 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
US6506866B2 (en) | 1994-11-17 | 2003-01-14 | Dow Global Technologies Inc. | Ethylene copolymer compositions |
US6399533B2 (en) * | 1995-05-25 | 2002-06-04 | Basell Technology Company Bv | Compounds and catalysts for the polymerization of olefins |
US6166153A (en) * | 1995-07-18 | 2000-12-26 | Fina Technology, Inc. | Process for the syndiotactic propagation of olefins |
CA2181413A1 (en) * | 1995-07-18 | 1998-01-18 | Edwar S. Shamshoum | Process for the syndiotactic propagation of olefins |
NL1001014C2 (nl) * | 1995-08-21 | 1997-02-25 | Dsm Nv | Katalysatorsysteem voor het bereiden van een rubberachtig copolymeer. |
US6150483A (en) * | 1995-08-21 | 2000-11-21 | Dsm N.V. | Catalyst system for the preparation of a rubbery copolymer |
FR2738829B1 (fr) | 1995-09-19 | 1997-10-17 | Atochem Elf Sa | Prepolymere pour la polymerisation des olefines, associant plusieurs composantes catalytiques solides |
US6486089B1 (en) | 1995-11-09 | 2002-11-26 | Exxonmobil Oil Corporation | Bimetallic catalyst for ethylene polymerization reactions with uniform component distribution |
IT1282364B1 (it) * | 1996-01-16 | 1998-03-20 | Enichem Spa | Catalizzatore metallocenico supportato per la (co) polimerizzazione delle alfa-olefine |
US6395669B1 (en) | 1996-01-18 | 2002-05-28 | Equistar Chemicals, Lp | Catalyst component and system |
IT1282635B1 (it) * | 1996-02-16 | 1998-03-31 | Enichem Elastomers | Componente catalitico al vanadio e suo utilizzo nella preparazione di ep(d)m |
US6417130B1 (en) | 1996-03-25 | 2002-07-09 | Exxonmobil Oil Corporation | One pot preparation of bimetallic catalysts for ethylene 1-olefin copolymerization |
JPH09309926A (ja) | 1996-05-17 | 1997-12-02 | Dow Chem Co:The | エチレン共重合体の製造方法 |
JP2000514493A (ja) * | 1996-07-15 | 2000-10-31 | モービル・オイル・コーポレーション | 吹込成形およびフィルム用途用コモノマー前処理2金属系触媒 |
EP0996649A1 (de) * | 1997-07-08 | 2000-05-03 | BP Chemicals Limited | Geträgerter polymerisationskatalysator |
US6051525A (en) * | 1997-07-14 | 2000-04-18 | Mobil Corporation | Catalyst for the manufacture of polyethylene with a broad or bimodal molecular weight distribution |
US6153551A (en) | 1997-07-14 | 2000-11-28 | Mobil Oil Corporation | Preparation of supported catalyst using trialkylaluminum-metallocene contact products |
US6136747A (en) * | 1998-06-19 | 2000-10-24 | Union Carbide Chemicals & Plastics Technology Corporation | Mixed catalyst composition for the production of olefin polymers |
US6376416B1 (en) * | 1998-07-21 | 2002-04-23 | Japan Polychem Corporation | Olefin polymerization catalyst and process for producing olefin polymer |
CN1096474C (zh) * | 1998-12-30 | 2002-12-18 | 化学工业部北京化工研究院 | 用于合成宽分布乙烯聚合物的复合催化剂及其制法和应用 |
US6265037B1 (en) | 1999-04-16 | 2001-07-24 | Andersen Corporation | Polyolefin wood fiber composite |
KR20050035183A (ko) * | 2001-11-30 | 2005-04-15 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 비-단일 부위/단일 부위 촉매 복합물을 이용하여 제조된에틸렌/알파-올레핀 공중합체, 이의 제조 방법 및 용도 |
MY136330A (en) * | 2001-12-12 | 2008-09-30 | Basell Poliolefine Spa | Process for the polymerization of olefins |
DE10163075A1 (de) * | 2001-12-20 | 2003-07-10 | Basell Polyolefine Gmbh | Katalysatorsysteme von Typ der Ziegler-Natta-Katalysatoren und ein Verfahren zu deren Herstellung |
US20040005445A1 (en) * | 2002-07-02 | 2004-01-08 | Ou Yang David T. | Colored multi-layer films and decorative articles made therefrom |
US7193100B2 (en) * | 2003-12-31 | 2007-03-20 | Albemarle Corporation | Haloaluminoxane compositions, their preparation, and their use in catalysis |
US7335250B2 (en) | 2004-02-06 | 2008-02-26 | Ivoclar Vivadent Ag | Dental composites based on X-ray-opaque mixed oxides prepared by flame spraying |
US11091572B2 (en) | 2016-09-29 | 2021-08-17 | Dow Global Technologies Llc | Modified Ziegler-Natta (pro) catalysts and system |
KR102449474B1 (ko) | 2016-09-29 | 2022-10-11 | 다우 글로벌 테크놀로지스 엘엘씨 | 마그네슘 할라이드-담지 티탄 (전)촉매 |
CN111954685B (zh) | 2018-04-11 | 2023-08-08 | 三井化学株式会社 | 4-甲基-1-戊烯系聚合物粒子及4-甲基-1-戊烯系树脂的制造方法 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4295991A (en) * | 1978-09-26 | 1981-10-20 | Exxon Research & Engineering Co. | Titanium trichloride catalyst component and the process for the production thereof |
US4701432A (en) * | 1985-11-15 | 1987-10-20 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
US4659685A (en) * | 1986-03-17 | 1987-04-21 | The Dow Chemical Company | Heterogeneous organometallic catalysts containing a supported titanium compound and at least one other supported organometallic compound |
US5077255A (en) * | 1986-09-09 | 1991-12-31 | Exxon Chemical Patents Inc. | New supported polymerization catalyst |
KR930002411B1 (ko) * | 1988-09-14 | 1993-03-30 | 미쓰이세끼유 가가꾸고오교오 가부시끼가이샤 | 벤젠불용성 유기알루미늄 옥시화합물 및 그 제조방법 |
JP2893743B2 (ja) * | 1989-08-10 | 1999-05-24 | 三菱化学株式会社 | α―オレフイン重合体の製造 |
-
1990
- 1990-12-27 US US07/634,696 patent/US5120696A/en not_active Expired - Lifetime
- 1990-12-27 TW TW079110902A patent/TW198726B/zh active
- 1990-12-28 CA CA002033416A patent/CA2033416C/en not_active Expired - Fee Related
- 1990-12-28 DE DE69028979T patent/DE69028979T2/de not_active Expired - Fee Related
- 1990-12-28 AT AT90314399T patent/ATE144539T1/de not_active IP Right Cessation
- 1990-12-28 EP EP90314399A patent/EP0439964B1/de not_active Expired - Lifetime
- 1990-12-29 KR KR1019900022414A patent/KR940006216B1/ko not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
EP0439964B1 (de) | 1996-10-23 |
DE69028979D1 (de) | 1996-11-28 |
CA2033416A1 (en) | 1991-06-30 |
ATE144539T1 (de) | 1996-11-15 |
KR940006216B1 (ko) | 1994-07-13 |
US5120696A (en) | 1992-06-09 |
EP0439964A2 (de) | 1991-08-07 |
CA2033416C (en) | 1999-07-27 |
EP0439964A3 (en) | 1992-06-03 |
TW198726B (de) | 1993-01-21 |
KR910011919A (ko) | 1991-08-07 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8363 | Opposition against the patent | ||
8327 | Change in the person/name/address of the patent owner |
Owner name: MITSUI CHEMICALS, INC., TOKIO/TOKYO, JP |
|
8365 | Fully valid after opposition proceedings | ||
8339 | Ceased/non-payment of the annual fee |