DE69022189D1 - Verfahren zur Alkylierung von Benzol. - Google Patents
Verfahren zur Alkylierung von Benzol.Info
- Publication number
- DE69022189D1 DE69022189D1 DE69022189T DE69022189T DE69022189D1 DE 69022189 D1 DE69022189 D1 DE 69022189D1 DE 69022189 T DE69022189 T DE 69022189T DE 69022189 T DE69022189 T DE 69022189T DE 69022189 D1 DE69022189 D1 DE 69022189D1
- Authority
- DE
- Germany
- Prior art keywords
- beta zeolite
- alkylation
- benzene
- phenol
- alkylated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 title 3
- 230000029936 alkylation Effects 0.000 title 1
- 238000005804 alkylation reaction Methods 0.000 title 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- 229910021536 Zeolite Inorganic materials 0.000 abstract 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 abstract 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 2
- 239000010457 zeolite Substances 0.000 abstract 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 230000002152 alkylating effect Effects 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 229910052796 boron Inorganic materials 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229910052733 gallium Inorganic materials 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
- C07C37/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms by addition reactions, i.e. reactions involving at least one carbon-to-carbon unsaturated bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/86—Borosilicates; Aluminoborosilicates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
- C07C2/66—Catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/183—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself in framework positions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/87—Gallosilicates; Aluminogallosilicates; Galloborosilicates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/88—Ferrosilicates; Ferroaluminosilicates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT02241289A IT1237198B (it) | 1989-11-16 | 1989-11-16 | Processo per l'alchilazione di composti aromatici. |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69022189D1 true DE69022189D1 (de) | 1995-10-12 |
DE69022189T2 DE69022189T2 (de) | 1996-02-29 |
Family
ID=11195960
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69022189T Expired - Lifetime DE69022189T2 (de) | 1989-11-16 | 1990-11-08 | Verfahren zur Alkylierung von Benzol. |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP0432814B1 (de) |
AT (1) | ATE127440T1 (de) |
CA (1) | CA2030067C (de) |
DE (1) | DE69022189T2 (de) |
DK (1) | DK0432814T3 (de) |
ES (1) | ES2076298T3 (de) |
GR (1) | GR3017529T3 (de) |
IT (1) | IT1237198B (de) |
MX (1) | MX171434B (de) |
RU (1) | RU2094418C1 (de) |
Families Citing this family (38)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0538518A1 (de) * | 1991-10-16 | 1993-04-28 | Council of Scientific and Industrial Research | Verbessertes Verfahren zur Herstellung von Cumol |
DE4408772B4 (de) * | 1993-03-16 | 2006-09-07 | Mitsubishi Chemical Corp. | Verfahren zur Herstellung eines Polyoxyalkylenglykols und neues Metallaluminosilikat |
EP0776876B1 (de) * | 1994-08-03 | 2000-06-14 | Asahi Kasei Kogyo Kabushiki Kaisha | METHODE ZUR ALKYLIERUNG VON AROMATISCHEN KOHLENWASSERSTOFFEN IN FLÜSSIGER PHASE MIT beta-ZEOLITEN |
CN1066071C (zh) * | 1994-12-13 | 2001-05-23 | 大连理工大学 | 改性大孔沸石催化剂的制备及合成异丙基芳烃 |
CN1052666C (zh) * | 1994-12-26 | 2000-05-24 | 北京燕山石油化工公司化工二厂 | 合成异丙苯用沸石催化剂及使用该催化剂制备异丙苯的方法 |
IT1277680B1 (it) * | 1995-12-21 | 1997-11-11 | Enichem Spa | Procedimento per l'alchilazione di composti aromatici |
US6162416A (en) * | 1996-07-12 | 2000-12-19 | Uop Llc | Zeolite beta and its use in aromatic alkylation |
US5723710A (en) * | 1996-07-12 | 1998-03-03 | Uop | Zeolite beta and its use in aromatic alkylation |
EP0929502B1 (de) * | 1996-09-06 | 2001-08-01 | ExxonMobil Chemical Patents Inc. | Alkylierungsverfahren in dem zeolith beta verwendet wird |
CA2269554C (en) * | 1996-10-02 | 2006-11-21 | The Dow Chemical Company | A zeolite-based ethylbenzene process adaptable to an aluminum chloride-based ethylbenzene plant |
IT1295072B1 (it) | 1997-09-26 | 1999-04-27 | Snam Progetti | Procedimento per la produzione di stirene |
IT1313009B1 (it) * | 1999-07-13 | 2002-05-29 | Enichem Spa | Processo per la rigenerazione di catalizzatori zeolitici. |
DE10008924A1 (de) * | 2000-02-25 | 2001-09-06 | Phenolchemie Gmbh & Co Kg | Verfahren zur Herstellung von Phenol |
TW572784B (en) * | 2000-10-18 | 2004-01-21 | Fina Technology | Silica-supported alkylation catalyst |
CN100532506C (zh) * | 2001-11-16 | 2009-08-26 | 弗纳技术股份有限公司 | 载于二氧化硅上的烷基化催化剂 |
ES2206030B1 (es) | 2002-07-11 | 2005-08-01 | Universidad Politecnica De Valencia | Un catalizador zeolitico para alquilacion de compuestos aromaticos con olefinas, alcoholes o compuestos aromaticos polialquilados. |
US6995295B2 (en) | 2002-09-23 | 2006-02-07 | Exxonmobil Chemical Patents Inc. | Alkylaromatics production |
ITMI20041289A1 (it) | 2004-06-25 | 2004-09-25 | Enitecnologie Spa | Catalizzatore e processo per la preparazione di idrocarburi aromatici alchilati |
TW200616939A (en) * | 2004-08-13 | 2006-06-01 | Exxonmobil Chemical Patents Inc | Production of bisphenol-a |
JP2008537939A (ja) | 2005-03-31 | 2008-10-02 | エクソンモービル・ケミカル・パテンツ・インク | 多相アルキル芳香族の製造 |
ES2529036T3 (es) | 2005-03-31 | 2015-02-16 | Badger Licensing Llc | Producción de alquil-aromáticos utilizando alqueno diluido |
US7731839B2 (en) | 2005-05-27 | 2010-06-08 | Exxonmobil Chemical Patents Inc. | Process for reducing bromine index of hydrocarbon feedstocks |
US7425659B2 (en) | 2006-01-31 | 2008-09-16 | Exxonmobil Chemical Patents Inc. | Alkylaromatics production |
US7501547B2 (en) | 2006-05-10 | 2009-03-10 | Exxonmobil Chemical Patents Inc. | Alkylaromatics production |
KR101199663B1 (ko) | 2006-05-24 | 2012-11-08 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 모노 알킬화 방향족 화합물의 제조 방법 |
US7420098B2 (en) | 2007-01-12 | 2008-09-02 | Uop Llc | Dual zone aromatic alkylation process |
US7645913B2 (en) | 2007-01-19 | 2010-01-12 | Exxonmobil Chemical Patents Inc. | Liquid phase alkylation with multiple catalysts |
WO2008097737A1 (en) | 2007-02-09 | 2008-08-14 | Exxonmobil Chemical Patents Inc. A Corporation Of The State Of Delaware | Improved alkylaromatic production process |
US7745676B2 (en) | 2007-07-30 | 2010-06-29 | Exxonmobil Chemical Patents Inc. | Alkylaromatics production |
PL2217374T3 (pl) | 2007-11-02 | 2022-08-08 | Badger Licensing, Llc | Proces odmładzania kompozycji katalizatora |
IT1392325B1 (it) | 2008-09-11 | 2012-02-28 | Polimeri Europa Spa | Processo per l'alchilazione di benzene con isopropanolo o miscele di isopropanolo e propilene |
CA2740021C (en) | 2008-10-10 | 2013-09-10 | Exxonmobil Chemical Patents Inc. | Process for producing alkylaromatic compounds |
IT1392929B1 (it) | 2009-02-16 | 2012-04-02 | Polimeri Europa Spa | Processo integrato per la preparazione di etilbenzene e cumene |
IT1394721B1 (it) | 2009-06-10 | 2012-07-13 | Polimeri Europa Spa | Processo per l'alchilazione di benzene con etanolo o miscele di etanolo ed etilene |
IT1397885B1 (it) | 2009-12-23 | 2013-02-04 | Polimeri Europa Spa | Processo per preparare etilbenzene. |
ITMI20131704A1 (it) | 2013-10-15 | 2015-04-16 | Versalis Spa | Composizione catalitica e processo che la utilizza per l'alchilazione di idrocarburi aromatici con alcoli, o miscele di alcoli e olefine |
WO2020164545A1 (en) * | 2019-02-14 | 2020-08-20 | Basf Se | Aluminum-and Gallium Containing Zeolitic Material and Use Thereof in SCR |
RU2767907C1 (ru) * | 2021-05-25 | 2022-03-22 | Публичное акционерное общество "Нефтяная компания "Роснефть" (ПАО "НК "Роснефть") | Катализатор алкилирования бензола пропиленом в изопропилбензол и способ его получения |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4292457A (en) * | 1978-04-18 | 1981-09-29 | Standard Oil Company (Indiana) | Alkylation of aromatic hydrocarbons |
US4301316A (en) * | 1979-11-20 | 1981-11-17 | Mobil Oil Corporation | Preparing phenylalkanes |
DE3167118D1 (en) * | 1980-12-19 | 1984-12-13 | Ici Plc | Zeolites |
US4798816A (en) * | 1986-12-19 | 1989-01-17 | Union Oil Company Of California | Process for increasing the selectivity of an alkylation catalyst for monoalkylation |
US4871444A (en) * | 1987-12-02 | 1989-10-03 | Mobil Oil Corporation | Distillate fuel quality of FCC cycle oils |
US4891458A (en) * | 1987-12-17 | 1990-01-02 | Innes Robert A | Liquid phase alkylation or transalkylation process using zeolite beta |
-
1989
- 1989-11-16 IT IT02241289A patent/IT1237198B/it active IP Right Grant
-
1990
- 1990-11-08 DE DE69022189T patent/DE69022189T2/de not_active Expired - Lifetime
- 1990-11-08 ES ES90202956T patent/ES2076298T3/es not_active Expired - Lifetime
- 1990-11-08 EP EP90202956A patent/EP0432814B1/de not_active Expired - Lifetime
- 1990-11-08 AT AT90202956T patent/ATE127440T1/de not_active IP Right Cessation
- 1990-11-08 DK DK90202956.0T patent/DK0432814T3/da active
- 1990-11-13 MX MX023306A patent/MX171434B/es unknown
- 1990-11-15 RU SU904831733A patent/RU2094418C1/ru active
- 1990-11-15 CA CA002030067A patent/CA2030067C/en not_active Expired - Lifetime
-
1995
- 1995-09-26 GR GR950402647T patent/GR3017529T3/el unknown
Also Published As
Publication number | Publication date |
---|---|
ES2076298T3 (es) | 1995-11-01 |
EP0432814A1 (de) | 1991-06-19 |
CA2030067A1 (en) | 1991-05-17 |
IT8922412A0 (it) | 1989-11-16 |
RU2094418C1 (ru) | 1997-10-27 |
GR3017529T3 (en) | 1995-12-31 |
EP0432814B1 (de) | 1995-09-06 |
DE69022189T2 (de) | 1996-02-29 |
MX171434B (es) | 1993-10-26 |
CA2030067C (en) | 2003-10-14 |
IT1237198B (it) | 1993-05-26 |
ATE127440T1 (de) | 1995-09-15 |
DK0432814T3 (da) | 1995-11-27 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8363 | Opposition against the patent | ||
8365 | Fully valid after opposition proceedings |