DE69011409D1 - Verfahren zur Herstellung von wasserlöslichen Copolymeren von aliphatischer monoethylenisch ungesättigter Dicarbonsäure und ungesättigte Monomere. - Google Patents

Verfahren zur Herstellung von wasserlöslichen Copolymeren von aliphatischer monoethylenisch ungesättigter Dicarbonsäure und ungesättigte Monomere.

Info

Publication number
DE69011409D1
DE69011409D1 DE69011409T DE69011409T DE69011409D1 DE 69011409 D1 DE69011409 D1 DE 69011409D1 DE 69011409 T DE69011409 T DE 69011409T DE 69011409 T DE69011409 T DE 69011409T DE 69011409 D1 DE69011409 D1 DE 69011409D1
Authority
DE
Germany
Prior art keywords
preparation
water
dicarboxylic acid
soluble copolymers
unsaturated monomers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69011409T
Other languages
English (en)
Other versions
DE69011409T2 (de
Inventor
Kathleen Anne Hughes
Graham Swift
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rohm and Haas Co
Original Assignee
Rohm and Haas Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm and Haas Co filed Critical Rohm and Haas Co
Application granted granted Critical
Publication of DE69011409D1 publication Critical patent/DE69011409D1/de
Publication of DE69011409T2 publication Critical patent/DE69011409T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04Acids; Metal salts or ammonium salts thereof
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/08Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
    • C02F5/10Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/08Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
    • C02F5/10Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
    • C02F5/12Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/08Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
    • C02F5/10Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
    • C02F5/14Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing phosphorus
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/02Acids; Metal salts or ammonium salts thereof, e.g. maleic acid or itaconic acid
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Detergent Compositions (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
DE69011409T 1989-05-17 1990-05-17 Verfahren zur Herstellung von wasserlöslichen Copolymeren von aliphatischer monoethylenisch ungesättigter Dicarbonsäure und ungesättigte Monomere. Expired - Lifetime DE69011409T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US35337689A 1989-05-17 1989-05-17
US07/502,100 US5244988A (en) 1989-05-17 1990-03-30 Maleate polymerization process

Publications (2)

Publication Number Publication Date
DE69011409D1 true DE69011409D1 (de) 1994-09-15
DE69011409T2 DE69011409T2 (de) 1994-12-15

Family

ID=26997916

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69011409T Expired - Lifetime DE69011409T2 (de) 1989-05-17 1990-05-17 Verfahren zur Herstellung von wasserlöslichen Copolymeren von aliphatischer monoethylenisch ungesättigter Dicarbonsäure und ungesättigte Monomere.

Country Status (12)

Country Link
US (2) US5244988A (de)
EP (1) EP0398724B1 (de)
JP (1) JPH0692464B2 (de)
AT (1) ATE109804T1 (de)
BR (1) BR9002161A (de)
CA (1) CA2015980A1 (de)
DE (1) DE69011409T2 (de)
DK (1) DK0398724T3 (de)
ES (1) ES2057398T3 (de)
IE (1) IE64592B1 (de)
MX (1) MX172634B (de)
PT (1) PT94080A (de)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5055540A (en) * 1990-02-06 1991-10-08 Rohm And Haas Company Process for efficient molecular weight control in copolymerization
DE4300772C2 (de) * 1993-01-14 1997-03-27 Stockhausen Chem Fab Gmbh Wasserlösliche, biologisch abbaubare Copolymere auf Basis von ungesättigten Mono- und Dicarbonsäuren, Verfahren zu ihrer Herstellung und ihre Verwendung
US5866012A (en) * 1993-01-26 1999-02-02 National Starch And Chemical Investment Holding Corporation Multifunctional maleate polymers
DE69433465T2 (de) * 1993-01-26 2004-10-21 Nat Starch Chem Invest Verfahren zur Wasserbehandlung zur Verhinderung von Kesselsteinbildung
WO1994018296A1 (de) * 1993-02-05 1994-08-18 Henkel Kommanditgesellschaft Auf Aktien Gerüststoff für wasch- oder reinigungsmittel
US5410017A (en) * 1993-05-21 1995-04-25 Rohm And Haas Company Continuous thermal polycondensation process for preparing polypeptide polymers
US5451644A (en) * 1994-01-14 1995-09-19 Rohm And Haas Company Aqueous process for preparing water soluble polymers of monoethylenically unsaturated dicarboxylic acids
US6335404B1 (en) * 1994-04-05 2002-01-01 Rohm And Haas Company Aqueous process for preparing aqueous weight carboxyl containing polymers
YU48814B (sh) * 1994-07-18 2001-07-10 Dušan dr. Miljković Postupak za sintezu kopolimera maleinske i akrilne kiseline
EP0745662B1 (de) * 1994-12-15 2004-06-16 Nippon Shokubai Co., Ltd. Waschmittelbuilder, verfahren zu seiner herstellung und diesen enthaltende waschmittelzusammensetzung
WO1996020962A1 (en) * 1995-01-06 1996-07-11 Henkel Corporation Copolymer of vinyl sulfonic acid and method for treating leather
US5763553A (en) * 1997-01-03 1998-06-09 Miljkovic; Dusan A. Procedure for manufacturing and application of novel polycarboxilate types
AUPO976797A0 (en) 1997-10-14 1997-11-06 Orica Australia Pty Ltd Method and composition (III)
US6020297A (en) * 1999-04-06 2000-02-01 National Starch And Chemical Investment Holding Corporation Colorless polymaleates and uses thereof in cleaning compositions
TWI236483B (en) * 2000-07-07 2005-07-21 Nippon Catalytic Chem Ind Low molecular weight (methyl) acrylic acid (acrylate) polymer and preparation process and use thereof
GB0103192D0 (en) * 2001-02-09 2001-03-28 Ciba Spec Chem Water Treat Ltd Scale removal or prevention
DE10150190A1 (de) * 2001-10-12 2003-04-17 Tr Oil Services Aberdeen Verfahren zur Verringerung oder zur vollständigen Einstellung von Wasserzuflüssen bei einer unterirdischen Formation, und vernetzbare Copolymere zu dessen Durchführung
DE102004041127A1 (de) * 2004-08-24 2006-03-02 Basf Ag Verfahren zur Herstellung von carboxylatreichen Copolymeren aus monoethylenisch ungesättigten Mono- und Dicarbonsäuren sowie carboxylatreiche Copolymere mit niedrigem Neutralisationsgrad
US20060094636A1 (en) * 2004-11-01 2006-05-04 National Starch And Chemical Investment Holding Corp. Hydrophobically modified polymers
CN1786046A (zh) * 2005-11-21 2006-06-14 中国科学院长春应用化学研究所 二氧化碳-环氧化物共聚物的高分子封端剂及制法
CN100509683C (zh) * 2006-09-30 2009-07-08 江苏博特新材料有限公司 一种低分子量共聚物分散剂及其制备方法
JP5076864B2 (ja) * 2007-12-18 2012-11-21 東亞合成株式会社 アクリル酸(塩)/マレイン酸(塩)系共重合体水溶液およびその製造方法
US20160009855A1 (en) * 2012-02-10 2016-01-14 List Holding Ag Method for performing mechanical, chemical and/or thermal processes

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3178395A (en) * 1959-10-30 1965-04-13 Sinclair Research Inc Method for polymerizing vinyl monomers and maleic anhydride
US3646044A (en) * 1969-05-21 1972-02-29 Desoto Inc Precipitation copolymerization of maleic anhydride in aqueous medium
US3635915A (en) * 1969-11-28 1972-01-18 Deering Milliken Res Corp Copolymers of maleic acid and acrylic acid
US4314044A (en) * 1979-01-22 1982-02-02 Rohm And Haas Company Process for preparing low molecular weight water-soluble polymers
US4390670A (en) * 1981-02-09 1983-06-28 Pfizer Inc. Acrylate/maleate copolymers, their preparation and use as antiscalants
DE3147489A1 (de) * 1981-12-01 1983-06-09 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von copolymerisaten aus monoethylenisch ungesaettigten mono- und dicarbonsaeuren
DE3138574A1 (de) * 1981-09-28 1983-04-07 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von copolymerisaten aus monoethylenisch ungesaettigten mono- und dicarbonsaeuren
JPS5891709A (ja) * 1981-10-29 1983-05-31 フアイザ−・インコ−ポレ−テツド (メト)アクリル酸/イタコン酸共重合体、その製法およびスケ−ル防止剤
DE3233778A1 (de) * 1982-09-11 1984-03-15 Basf Ag, 6700 Ludwigshafen Verfahren einer kontinuierlichen herstellung von copolymerisaten aus monoethylenisch ungesaettigten mono- und dicarbonsaeuren
US4659793A (en) * 1986-03-03 1987-04-21 Alco Chemical Corporation Preparation of aqueous solutions of copolymers of dicarboxylic acids having a low dicarboxylic acid monomer content
DE3716543A1 (de) * 1987-05-16 1988-11-24 Basf Ag Verwendung von wasserloeslichen copolymerisaten, die monomere mit mindestens zwei ethylenisch ungesaettigten doppelbindungen einpolymerisiert enthalten, in wasch- und reinigungsmitteln
DE3717227A1 (de) * 1987-05-21 1988-12-01 Henkel Kgaa Phosphatfreies waschmittel mit reduzierter inkrustierungstendenz
US4871823A (en) * 1987-09-11 1989-10-03 S. C. Johnson & Son, Inc. 1-Alkene/excess maleic anhydride polymers

Also Published As

Publication number Publication date
BR9002161A (pt) 1991-08-13
PT94080A (pt) 1991-01-08
IE901781L (en) 1990-11-17
US5360570A (en) 1994-11-01
JPH03115314A (ja) 1991-05-16
DE69011409T2 (de) 1994-12-15
ES2057398T3 (es) 1994-10-16
US5244988A (en) 1993-09-14
IE64592B1 (en) 1995-08-23
EP0398724A2 (de) 1990-11-22
DK0398724T3 (da) 1994-10-03
ATE109804T1 (de) 1994-08-15
EP0398724B1 (de) 1994-08-10
EP0398724A3 (de) 1991-04-24
MX172634B (es) 1994-01-04
JPH0692464B2 (ja) 1994-11-16
CA2015980A1 (en) 1990-11-17

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