DE659120C - Preparations for making permanent waves - Google Patents
Preparations for making permanent wavesInfo
- Publication number
- DE659120C DE659120C DEC51086D DEC0051086D DE659120C DE 659120 C DE659120 C DE 659120C DE C51086 D DEC51086 D DE C51086D DE C0051086 D DEC0051086 D DE C0051086D DE 659120 C DE659120 C DE 659120C
- Authority
- DE
- Germany
- Prior art keywords
- preparations
- permanent waves
- making permanent
- aldehydes
- ketones
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/04—Preparations for permanent waving or straightening the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/23—Sulfur; Selenium; Tellurium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/35—Ketones, e.g. benzophenone
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Inorganic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Mittel zur Herstellung von Dauerwellen Gegenstand des Patents 655 845 bilden Mittel zur Herstellung von Dauerwellen, bei denen sauer reagierende Stoffe an Stelle von alkalischen für die Dauerwellflüssigkeit verwendet werden. Als besonders geeignet wurden hierzu saure Sulfite bezeichnet. So gut sich diese Lösungen bewährt haben, so ist ihr Gebrauch doch mit einer gewissen Unbequemlichkeit verbunden, insofern, als die betreffenden Lösungen stechend nasch Schwefligsäuregas riechen. Ihre Verarbeitung in der Praxis hat sich jedenfalls nicht als sehr angenehm herausgestellt. Ein weiterer Mangel dieser bisulfithaltigen Mittel besteht darin; daß sie nur beschränkt haltbar sind, da sie langsam freie schweflige Säure abgeben, die, z. B. bei jedem Öffnen der Vorratsflasche, entweicht, wodurch die Mittel- einen Teil ihrer Wirksamkeit verlieren.Means for making permanent waves the subject of patent 655 845 form means for the production of permanent waves, in which acidic reacting substances can be used instead of alkaline for the permanent wave liquid. As special Acid sulphites were designated as suitable for this purpose. As well as these solutions have proven themselves their use is associated with a certain inconvenience, insofar as when the solutions in question smell pungent, sulphurous acid gas. Your processing in practice it has in any case not proven to be very pleasant. Another The deficiency of these bisulfite-containing agents consists in this; that they only have a limited shelf life are, as they slowly give off free sulfurous acid which, e.g. B. with each opening the storage bottle, escapes, making the central part of its effectiveness lose.
Es wurde nun gefunden, daß sich die Bisulfite in Form ihrer nahezu geruchlosen Anlagerungsprodukte an Aldehyde und Ketone mit gleich guteiri praktischem Erfolg als Mittel zur Herstellung von Dauerwellen verwenden lassen. Diese Verbindungen reagieren in Lösung ebenfalls schwach sauer.- Die Anlagerungsprodukte können in bekannter Weise hergestellt werden. So wird z. B. eine gesättigte wäßrige Lösung von i Mol Natxiumbisulfit mit i Mol Aceton versetzt. Beim Umrühren und Stehen in der Kälte scheidet sich die Anlagerungsverbindung als kristallinische Masse ab, die durch Filtration abgeschieden wird.It has now been found that the bisulfites in the form of their almost Odorless addition products to aldehydes and ketones with equally good practicality Having success used as a means of making perms. These connections also react slightly acidic in solution - the addition products can in be produced in a known manner. So z. B. a saturated aqueous solution of 1 mole of sodium bisulfite mixed with 1 mole of acetone. When stirring and standing in In the cold, the attachment compound separates out as a crystalline mass, which is deposited by filtration.
Die Produkte werden als Lösungen, pastenfö,rmi,ge oder als feste Präparate in den Handel gebracht. Letztere, gegebenenfalls auch die Pasten, sind vor Gebrauch entsprechend aufzulösen. Benutzt werden können alle herstellbaren Anlagerungsverbindungen beliebiger Ketone und Aldehyde, soweit nicht ein unerwünscht starker Geruch oder zu hoher Preis der höheren Glieder deren Verwendung ,ausschließt. Mit Vorteil verwendet man die niederen Ketone und Aldehyde, da diese verhältnismäßig schwach riechen und beim Gebrauch jedenfalls keim festhaftenden Geruch hinterlassen. Vor allen Dingen ist der prozentuale Gehalt an wirksamer Bisulfitverbindung in diesen Stoffen am größten.The products are available as solutions, pastes, liquids or solid preparations put on the market. The latter, and possibly also the pastes, are prior to use to resolve accordingly. All additive compounds that can be produced can be used Any ketones and aldehydes, unless there is an undesirably strong odor or too high a price for the higher members to exclude their use. Used with advantage the lower ketones and aldehydes, as these smell relatively weak and In any case, leave a stubborn smell after use. Above all is the percentage of active bisulfite compounds in these substances biggest.
Es hat sich ;als vorteilhaft herausgestellt, diese Verbindungen gegen vorzeitige Spaltung zu schützen durch Zusatz geeigneter Stabilisatoren. Vorgeschlagen werden hierzu mehrwertige Alkohole, wie Glykol, Glycerin, ferner Zuckerlösungen, Polysaccharide (lösliche Stärke, Dextrin, Pflanzenschleim), Eiweißlösungen (Gelatine), Celluloseäther und andere synthetische Schleimstoffe.It has been found advantageous to oppose these compounds to protect premature cleavage by adding suitable stabilizers. Proposed polyhydric alcohols such as glycol, glycerine, and sugar solutions are used for this purpose, Polysaccharides (soluble starch, dextrin, plant slime), protein solutions (gelatine), Cellulose ethers and other synthetic mucilages.
Weiter können diese Dauerwellösungen Netzmittel, z. B. solche der in den Beispielen angegebenen Art, enthalten, um gleichmäßige Wirkungen zu erzielen.You can continue with these permanent wave solutions Wetting agents, e.g. B. those of the type indicated in the examples, contain in order to achieve uniform effects to achieve.
Für die Zusammensetzung der Mittel seien folgende Beispiele angegeben: i. Aceton-Bisulfit-Verbindung, hergestellt aus Aceton und Natriumbisulfit mit einem Zusatz von i % Fettalkoholsulfonat. Das Mittel wird in 5 o;oiger wäßriger Lösung angewendet.The following examples are given for the composition of the agents: i. Acetone bisulfite compound made from acetone and sodium bisulfite with a Addition of i% fatty alcohol sulfonate. The agent is in 5 o; oiger aqueous solution applied.
z. 7o Teile Aceton-Natriumbisulfit-V erbindung, 7o Teile Glycerin, 7 Teile Natriumverbindung des ölsäure-Äthionsäur-ekondensats.z. 7o parts acetone-sodium bisulphite compound, 7o parts glycerine, 7 parts of sodium compound of oleic acid-ethionic acid condensate.
Die Bestandteile. werden zu einer Paste verxie ben, die im Verhältnis i : i o mit Wasser verdünnt angewendet wird.The parts. are verxie ben into a paste that is proportionate i: i o is used diluted with water.
3. Eine frisch bereitete Mischung aus molekularen Mengen von Acetaldehyd einerseits, Ammonium-, Natrium- oder K.aliumbisulfit andererseits wird mit 5o% Glycerin und 1/2 ojo Methylcellulose angerieben und diese Paste in io%iger wäßriger Lösung verwendet. An Stelle des Acetaldehyds lassen sich höhere Aldehyde, wie Propionaldehyd, Milchsäurealdehyd, Glycerinaldehyd, ferner aromatische Aldehyde, an Stelle des Acetons höhere Ketone, auch aromatische, verwenden. -3. A freshly prepared mixture of molecular amounts of acetaldehyde on the one hand, ammonium, sodium or potassium bisulfite on the other hand is made with 50% glycerine and 1/2 ojo methylcellulose rubbed and this paste in 10% aqueous solution used. Instead of acetaldehyde, higher aldehydes such as propionaldehyde, Lactic acid aldehyde, glyceraldehyde, and also aromatic aldehydes, instead of acetone use higher ketones, including aromatic ones. -
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEC51086D DE659120C (en) | 1935-11-23 | 1935-11-23 | Preparations for making permanent waves |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEC51086D DE659120C (en) | 1935-11-23 | 1935-11-23 | Preparations for making permanent waves |
GB112136A GB468845A (en) | 1936-01-13 | 1936-01-13 | Improvements in and relating to the permanent waving of hair |
Publications (1)
Publication Number | Publication Date |
---|---|
DE659120C true DE659120C (en) | 1938-04-26 |
Family
ID=25970468
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DEC51086D Expired DE659120C (en) | 1935-11-23 | 1935-11-23 | Preparations for making permanent waves |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE659120C (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1012435B (en) * | 1951-11-05 | 1957-07-18 | Wella Ag | Permanent wave agent for cold wave or hot wave processes |
DE971559C (en) * | 1949-11-07 | 1959-02-19 | Haarfarben | Means for producing cold permanent waves |
FR2845904A1 (en) * | 2002-10-22 | 2004-04-23 | Oreal | Composition for the permanent deformation of hair comprises an aldehyde bisulfite combination as reducing agent |
FR2845902A1 (en) * | 2002-10-22 | 2004-04-23 | Oreal | Composition for the permanent deformation of hair comprises an alkaline bisulfite combination of acetone, acetaldehyde, propionaldehyde, lactaldehyde or glyceraldehyde, or a salt |
FR2845903A1 (en) * | 2002-10-22 | 2004-04-23 | Oreal | Composition for the permanent deformation of hair comprises a bisulfite combination of a ketone or one of its salts |
-
1935
- 1935-11-23 DE DEC51086D patent/DE659120C/en not_active Expired
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE971559C (en) * | 1949-11-07 | 1959-02-19 | Haarfarben | Means for producing cold permanent waves |
DE1012435B (en) * | 1951-11-05 | 1957-07-18 | Wella Ag | Permanent wave agent for cold wave or hot wave processes |
FR2845904A1 (en) * | 2002-10-22 | 2004-04-23 | Oreal | Composition for the permanent deformation of hair comprises an aldehyde bisulfite combination as reducing agent |
FR2845902A1 (en) * | 2002-10-22 | 2004-04-23 | Oreal | Composition for the permanent deformation of hair comprises an alkaline bisulfite combination of acetone, acetaldehyde, propionaldehyde, lactaldehyde or glyceraldehyde, or a salt |
FR2845903A1 (en) * | 2002-10-22 | 2004-04-23 | Oreal | Composition for the permanent deformation of hair comprises a bisulfite combination of a ketone or one of its salts |
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