DE699406C - Disinfectants and preservatives - Google Patents

Disinfectants and preservatives

Info

Publication number
DE699406C
DE699406C DE1938I0061887 DEI0061887D DE699406C DE 699406 C DE699406 C DE 699406C DE 1938I0061887 DE1938I0061887 DE 1938I0061887 DE I0061887 D DEI0061887 D DE I0061887D DE 699406 C DE699406 C DE 699406C
Authority
DE
Germany
Prior art keywords
disinfectants
preservatives
condensation products
amines
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE1938I0061887
Other languages
German (de)
Inventor
Dr Emmerich Valko
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Priority to DE1938I0061887 priority Critical patent/DE699406C/en
Application granted granted Critical
Publication of DE699406C publication Critical patent/DE699406C/en
Expired legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04—Sulfonic acids; Derivatives thereof
    • A01N41/08—Sulfonic acid halides; alpha-Hydroxy-sulfonic acids; Amino-sulfonic acids; Thiosulfonic acids; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
    • A01N35/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing aliphatically bound aldehyde or keto groups, or thio analogues thereof; Derivatives thereof, e.g. acetals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
    • A01N35/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical at least one of the bonds to hetero atoms is to nitrogen
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing within the same carbon skeleton a carboxylic group or a thio analogue, or a derivative thereof, and a carbon atom having only two bonds to hetero atoms with at the most one bond to halogen, e.g. keto-carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Description

Desinfektions- und Konservierungsmittel Es ist bekannt, daß höher molekulare Reste enthaltende Amine und Ammoniumhydroxyde bzw. ihre Salze konservierende und desinfizierende Eigenschaften besitzen.Disinfectants and Preservatives It is known to be higher Amines and ammonium hydroxides or their salts containing molecular residues and have disinfectant properties.

Es wurde nun' gefunden, daß Kondensationsprodukte aus einerseits primären oder sekundären Aminen, die im Molekül mindestens einen aliphatis,chen Rest mit mindestens 8 Kohlenstoffatomen enthalten,. und andererseits saure Gruppen, z. B. Sulfonsäüregruppen, enthaltenden Aldehyden oder Anlagerungsverbindungen von Formaldehyd an Bisulfite, Hydrosülfit@e oder Sulfoxylate oder Salze der genannten Kondensationsprodukte mit Vorteil als Diesintektions- und Konservierungsmittel verwendbar sind.It has now been found that condensation products from on the one hand primary or secondary amines which have at least one aliphatic radical in the molecule contain at least 8 carbon atoms. and on the other hand acidic groups, e.g. B. Sulphonic acid groups, aldehydes containing or addition compounds of formaldehyde to bisulfites, hydrosulfites or sulfoxylates or salts of the condensation products mentioned can be used with advantage as anti-infective agents and preservatives.

Geeignete Amine sind z. B. Decylamin, Dodecylamin, Hexad@ecylamin, Methyldodecylamin, Athyldodecylamin,. Propyldodecylamin, Oxäthyldodecylamin, Benzyldodecylamin oder Octodecenylamin. Als mit diesen Aminen zu kondensierende, saure Gruppen enthaltende Aldehyde .gindz. B. B.enzaldehyd-o-sulfonsäure, Benzaldehyd - m - sulfonsäure, -Phthalaldehydsäure, p-Aldehydo-o-kresotins!äure, Glyoxylsäure und Butyraldehyd-3-sulfonsäure geeignet; ferner können die Anlagerungsverbindungen des Formaldehyds an Bisulfite, z. B. das Natriums'alz der a.-Oxymethylensulfo:nsä,ure, öder an Hydrosulfihe oder Formaldehydnatrium-sulfoxylat mit Vorteil zur Kondensation mit dem Amin verwendet werden.Suitable amines are e.g. B. Decylamine, Dodecylamine, Hexad @ ecylamine, Methyldodecylamine, ethyldodecylamine ,. Propyldodecylamine, oxethyldodecylamine, benzyldodecylamine or octodecenylamine. As containing acidic groups to be condensed with these amines Aldehydes. B. zaldehyde-o-sulfonic acid, benzaldehyde - m - sulfonic acid, -phthalaldehyde acid, p-Aldehyde-o-cresotinic acid, glyoxylic acid and butyraldehyde-3-sulfonic acid are suitable; Furthermore, the addition compounds of formaldehyde to bisulfites, z. B. that Sodium salt of a.-oxymethylene sulfo: acid, acid, or hydrosulfite or sodium formaldehyde sulfoxylate can be used with advantage for condensation with the amine.

Die Herstellung der Kondensationsprodukte aus dien genannten Aminen und den genannten Aldehyden bzw. Formaldehydabkömmlingen geschieht z. B. durch Erwärmen von Gemischen der beiden Komponenten in wäßriger-oder alkoholischer Lösung. Sollen Kondensafionsprodukte der Amine mit SuIfonsäuregruppen enthaltenden Aldehyden verwendet werden, so kann deren Herstellung z. B. nach den Angaben in - der Patentschrift 656 4.a7, Seite i, Zeile 64 bis Seite a; Zeile i o geschehen. Die A.Idehydkomponente wird bei der Kondensation mit den Aminen zweckmäßig in Form löslicher Salze, z. B. der Natriumsalze, verwendet.The preparation of the condensation products from the amines mentioned and the aldehydes or formaldehyde derivatives mentioned happens, for. B. by heating of mixtures of the two components in aqueous or alcoholic solution. Should Condensation products the amines containing sulfonic acid groups Aldehydes are used, so their production can, for. B. according to the information in - the patent specification 656 4.a7, page i, line 64 to page a; Line i o happen. The aldehyde component is expediently in the form of the condensation with the amines soluble salts, e.g. B. the sodium salts are used.

Die Kondensationsprodukte sind in Form ihrer Natriumsalze in Wasser löslich oder emulgierbar. Sie können auch in die Form von Pasten, Pulvern, Stangen o. dgl. gebracht werden. Die wäßrigen Lösungen bzw. Emulsion-en, die auch bei alkalischer Reaktion beständig sind, zeigen ausgeprägte kapillaraktive Eigenschaften, wodurch die Desinfektionswirkung unterstützt wird. Die Kondensationsprodukte können auch im Gemisch mit anderen Stoffen, z. B. mit anderen Desinfektionsmitteln, ferner mit Seifen, Riechstoffen, Farbstoffen, Wachsen, anorganischem Salzen, z. B. mit Glaubersalz, oder Natriumphosphat, ferner mit Stärke, Dextrin, Milchzucker usw. verwendet werden. Beispiel 18,5 Gewichtsteile Dodecylamin werden zu einer Lösung von z i Gewichtsteilen des Natriumsalzes der Benzaldehyd-o-sulfonsäure in 5o Gewichtsteilen Wasser gegeben. Das Gemisch wird unter Rühren zum Sieden erhitzt, wobei das Amin unter Bildung des Kondensationsprodukts in Lösung geht. Die erhaltene Lösung besitzt noch nach Verdünnung auf das aooofache eine -ausgezeichnete entwicklungshemmende Wirkung gegenüber Bakterien.The condensation products are soluble or emulsifiable in water in the form of their sodium salts. They can also be made in the form of pastes, powders, rods or the like. The aqueous solutions or emulsions, which are stable even in the case of an alkaline reaction, show pronounced capillary-active properties, as a result of which the disinfecting effect is supported. The condensation products can also be mixed with other substances, e.g. B. with other disinfectants, also with soaps, fragrances, dyes, waxes, inorganic salts, z. B. Glauber's salt, or sodium phosphate, also with starch, dextrin, milk sugar, etc. can be used. Example 1 8.5 parts by weight of dodecylamine are added to a solution of zi parts by weight of the sodium salt of benzaldehyde-o-sulfonic acid in 50 parts by weight of water. The mixture is heated to boiling with stirring, the amine going into solution with formation of the condensation product. The solution obtained has an excellent development-inhibiting effect on bacteria even after dilution to a factor of 100.

Claims (1)

PATENTANSPRUCIi: Die Verwendung von Kondensationsprodukten aus einerseits primären oder sekundären Aminen, die mindestens :einen aliphatischen Rest mit mindestens 8 Kohlenstoffatomen im Molekül enthalten, und andererseits saure Gruppen. enthaltenden Aldehyden oder Anlagerungsverbindungen von Formaldehyd an Bisulfite, Hydrosulfite oder Sulfoiylate als Desinfektions-und Konservierungsmittel.PATENT CLAIMS: The use of condensation products on the one hand primary or secondary amines, the at least: one aliphatic radical with at least Contains 8 carbon atoms in the molecule, and on the other hand acidic groups. containing Aldehydes or addition compounds of formaldehyde on bisulfites, hydrosulfites or sulfoylates as disinfectants and preservatives.
DE1938I0061887 1938-07-12 1938-07-12 Disinfectants and preservatives Expired DE699406C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE1938I0061887 DE699406C (en) 1938-07-12 1938-07-12 Disinfectants and preservatives

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE1938I0061887 DE699406C (en) 1938-07-12 1938-07-12 Disinfectants and preservatives

Publications (1)

Publication Number Publication Date
DE699406C true DE699406C (en) 1940-11-28

Family

ID=7195549

Family Applications (1)

Application Number Title Priority Date Filing Date
DE1938I0061887 Expired DE699406C (en) 1938-07-12 1938-07-12 Disinfectants and preservatives

Country Status (1)

Country Link
DE (1) DE699406C (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE939949C (en) * 1948-10-02 1956-03-08 Elfriede Ella Baehr Germicidal and skin hardening agents
DE1148706B (en) * 1960-02-27 1963-05-16 Schuelke & Mayr Ges Mit Beschr Disinfectants and preservatives for technical purposes

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE939949C (en) * 1948-10-02 1956-03-08 Elfriede Ella Baehr Germicidal and skin hardening agents
DE1148706B (en) * 1960-02-27 1963-05-16 Schuelke & Mayr Ges Mit Beschr Disinfectants and preservatives for technical purposes

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