DE649045C - Emulsifiable oils - Google Patents

Emulsifiable oils

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Publication number
DE649045C
DE649045C DEST53483D DEST053483D DE649045C DE 649045 C DE649045 C DE 649045C DE ST53483 D DEST53483 D DE ST53483D DE ST053483 D DEST053483 D DE ST053483D DE 649045 C DE649045 C DE 649045C
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Germany
Prior art keywords
oils
oil
pressure hydrogenation
mineral
emulsion
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Expired
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DEST53483D
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German (de)
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Standard Oil Development Co
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Standard Oil Development Co
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Publication of DE649045C publication Critical patent/DE649045C/en
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/017—Mixtures of compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/14—Synthetic waxes, e.g. polythene waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/17—Fisher Tropsch reaction products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/17—Fisher Tropsch reaction products
    • C10M2205/173—Fisher Tropsch reaction products used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/46—Textile oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01—Emulsions, colloids, or micelles
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Textile Engineering (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Lubricants (AREA)
  • Fats And Perfumes (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Colloid Chemistry (AREA)

Description

DEUTSCHES REICHGERMAN EMPIRE

AUSGEGEBEN AM
13. AUGUST 1937ISSUED ON
AUGUST 13, 1937

REICHSPATENTAMTREICH PATENT OFFICE

PATENTSCHRIFTPATENT LETTERING

KLASSE 23 c GRUPPECLASS 23c GROUP

Emulgierbare ÖleEmulsifiable oils

Patentiert im Deutschen Reiche vom 11. Mai 1935 abPatented in the German Empire on May 11, 1935

ist in Anspruch genommen.is used.

Es ist bekannt, daß man emulgierbare Öle, die zuweilen auch als 'wasserlösliche Öle bezeichnet werden, oder wässerige Emulsionen dieser aus Mineralölen oder deren Frak-S tionen und Emulgiermitteln herstellen kamm. Es wurde nun gefunden, daß man Öle dieser Art, die besonders leicht emulgierbar sind und mit Wasser besonders bestänidiigie Emulsionen bilden, erhält, wenn man als ÖleIt is known that emulsifiable oils, sometimes also called 'water-soluble oils are referred to, or aqueous emulsions of these from mineral oils or their Frak-S tions and emulsifying agents. It has now been found that one can use oils of this type, which are particularly easy to emulsify and are particularly stable with water Forming emulsions is obtained when one considers oils

ίο Druckhydrierungsprodukte von Mineralölen oder deren Fraktionen verwendet.ίο Pressure hydrogenation products of mineral oils or their fractions are used.

Die erfindungsgemäß verwendeten Öle erhält man besonders zweckmäßig durch Druckhydrierung von verhältnismäßig schweren Mineralöldestülaten, z. B. solchen von Schmierölcharakter, insbesondere solchen, die Viscositäten zwischen etwa 1,599 und 2,950E (50 und 100 Sek. Saybolt) bei 990 C haben. Die Druckhydrierung kann in beliebiger Weise durchgeführt werden. Es empfiehlt sich häufig, die Mineralöldestillate zusammen mit freiem Wasserstoff bei Drucken von etwa 245 at und Temperaturen oberhalb etwa 4000 über geeignete Katalysatoren zu leiten, wobei der Partialdruck des Wasserstoffes und der. Behandlungsdauer so gewählt werden, daß eine spaltende Hydrierung ohne Bildung wesentlicher Mengen von polymerisierten oder koksartigen Stoffen !eintritt. Die Wasserstoffmenge beträgt vorteilhaft etwa 145 cbm auf je iool des behandelten Öles, doch kann sie je nach der Dichte und dem Siedebereich des Ausgangsmaterials schwanken. Auch kann man eine größere Wasserstoffmenge anwenden, wenn man in bekannter Weise den Durchsatz und die Druck- und Temperaturbedingungen ändert. Der Durchsatz hängt ab von der Reaktionstemperatur und den anderen Arbeitsbedingungen, insbesondere vom Partialdruck des Wasserstoffes, und beträgt zweckmäßig etwa 0,5 Vol. Öl pro Volumen des mit Katalysator gefüllten Reaktionsraumes pro Stunde. Geeignete Katalysatoren sind beispielsweise die Oxyde oder Sulfide der Elemente der sechsten Gruppe des periodischen Systems, die auch Aktivatoren enthalten können, wie z. B. Erdälkalioxyde. Die Emulgierbarkeit der Druckhydrierungsprodukte hängt nicht nur von den bei der Druckhydrierung angewandten Arbeitsbedingungen, sondern auch von der Art des als Ausgangsmaterials verwendeten Mineralöles ab. Besonders gute. Produkte, die außerordentlich leicht emulgierbar sind, erhält man unter sonst gleichen Arbeitsbedingungen bei der Druckhydrierung aus Mineralölen, die wesentliche Mengen naphthenischer Kohlenwasserstoffe !enthalten, wie z. B. columbischen Ölen oder Pecosölen. Die Druckhydrierungsprodukte besitzen gegenüber aus Mineralölen unmittelbar durch Destillation !erhaltenen Ölen auch noch den weiteren Vorteil, daßThe oils used according to the invention are obtained particularly expediently by pressure hydrogenation of relatively heavy mineral oil distillates, eg. B. those of lubricating oil character, especially those that have viscosities between about 1.599 and 2.95 0 E (50 and 100 sec. Saybolt) at 99 0 C. The pressure hydrogenation can be carried out in any way. It is often advisable to pass the mineral oil distillates together with free hydrogen at pressures of about 245 atm and temperatures above about 400 0 over suitable catalysts, the partial pressure of the hydrogen and the. Treatment duration can be chosen so that a splitting hydrogenation occurs without the formation of substantial amounts of polymerized or coke-like substances! The amount of hydrogen is advantageously about 145 cbm per iool of the treated oil, but it can vary depending on the density and the boiling range of the starting material. A larger amount of hydrogen can also be used if the throughput and the pressure and temperature conditions are changed in a known manner. The throughput depends on the reaction temperature and the other working conditions, in particular the partial pressure of the hydrogen, and is expediently about 0.5 vol. Oil per volume of the reaction space filled with catalyst per hour. Suitable catalysts are, for example, the oxides or sulfides of the elements of the sixth group of the periodic table, which can also contain activators, such as. B. Erdälkalioxyde. The emulsifiability of the pressure hydrogenation products depends not only on the working conditions used in the pressure hydrogenation, but also on the type of mineral oil used as the starting material. Particularly good ones. Products which are extremely easy to emulsify are obtained under otherwise identical working conditions in the pressure hydrogenation from mineral oils which contain substantial amounts of naphthenic hydrocarbons! B. Columbian oils or pecos oils. Compared to oils obtained directly from mineral oils by distillation, the pressure hydrogenation products also have the further advantage that

ihr Schwefelgehalt sehr niedrig ist oder daß sie sogar völlig frei von Schwefel sind.their sulfur content is very low or that they are even completely free of sulfur.

Die anzuwendenden Fraktionen der Druckhydrierungsprodukte werden vorteilhaft vt/fi Paraffin befreit, sie werden dann mit eiiiiifi* geeigneten Menge des Emulgiermittels, z.^B. 5°,'ü eines öllösk'chen Mineral ölsulfonats, ge: mischt und bilden dann beim Vermischen! mit Wasser sehr leicht beständige Emulsionen.The fractions of the pressure hydrogenation products to be used are advantageously freed vt / fi paraffin; they are then mixed with a suitable amount of the emulsifying agent, e.g. 5 °, 'ü a öllösk'chen mineral ölsulfonats, ge: mixed and then form when mixed! Emulsions very easily stable with water.

ίο Vorzugsweise verwendet man Fraktionen der Druckhydrierungsprodukte, die eine Viskosität von etwa 2,80 bis 2,95" E (95 bis 100 Sek. Saybolt") bei 3S C besitzen.ίο It is preferable to use fractions of the Pressure hydrogenation products that have a viscosity of about 2.80 to 2.95 "E (95 to 100 sec. Saybolt ") at 3S C.

Die besonderen Eigenschaften der Druckhydrierungsprodukte bezüglich ihrer Emulgierbarkeit ergeben sich beispielsweise aus den folgenden Vergleichsversuchen, die mit verschiedenen Ölen durchgeführt wurden. Alle t: hatten etwa die gleiche Viscosität bei ; C und waren in der gleichen Weise vorlandelt, nämlich durch eine Behandlung mit Schwefelsäure in der für die Mineralölraffmation üblichen Weise. Als Emulgiermittel wurde bei den Vergleichsversuchen ein öllösliches Mineralölsulfonat verwendet. Dieses wurde mit dem Öl in den angegebenen Mengen vermischt, und die so erhaltenen Mischungen wurden mit der gleichen Menge Wasser bei gleicher Temperatur geschüttelt, um die Emulsionsbildung zu bewirken.The special properties of pressure hydrogenation products with regard to their emulsifiability result, for example, from the following comparative tests with different oils were carried out. All t: had about the same viscosity at ; C and were approached in the same way, namely by treatment with sulfuric acid in the mineral oil refining usual way. An oil-soluble mineral oil sulfonate was used as the emulsifying agent in the comparative experiments. This was mixed with the oil in the specified amounts, and the thus obtained Mixtures were shaken with the same amount of water at the same temperature, to cause emulsification.

Verwendetes Öl Viscosität in 0EUsed oil viscosity in 0 U

(Sek. Sayboltj(Sec. Sayboltj

bei 380 Cat 38 0 C

Ergebnis mit io° (, Emulgiermittel Result with io ° (, emulsifier

Ergebnis mit 5% Emulgiermittel Result with 5% emulsifier

Columbia (gemischt-basisch),Columbia (mixed-basic),

Coastal (naphthenisch)Coastal (naphthenic)

Pennsylvanisch (paraffinisch)Pennsylvania (paraffinic)

Druckhydrierungsprodukt aus ColumbiaölColumbia oil pressure hydrogenation product

Als Emulgiermittel kann man beliebige Stoffe dieser Art verwenden. Besonders gut geeignet sind die Athanolamine, ferner Athylenglykol und aus diesen Verbindungen hergestellte seifenartige Körper, insbesondere solche, die Mineralölsulfonate, wie sie beim Raffinieren von Kohlenwasserstoffen mit Schwefelsäure anfallen, enthalten. Die erfindungsgemäß erhaltenen emulgierbaren öle können außerdem auch andere Mineralöle oder fette Öle oder Wachse u. dgl. enthalten. Any substances of this type can be used as emulsifying agent. Particularly good The ethanolamines and also ethylene glycol are suitable and soap-like bodies made from these compounds, particularly those containing mineral oil sulfonates such as those found in US Pat Refining hydrocarbons containing sulfuric acid. According to the invention The emulsifiable oils obtained can also contain other mineral oils or fatty oils or waxes and the like.

Die löslichen Öle gemäß vorliegender Erfindung sind besonders geeignet für die Behandlung von Textilien, und zwar sowohl für die Behandlung der losen Fasern als auch bei den verschiedenen Arten der Garnherstellung und -behandlung, sowie beim Weben und Appretieren. Die Faserstoffe können beispielsweise Wolle, Haare, Baumwolle, Seide, Flachs, Jute, Ramie, Bast oder die verschiedenen Arten von Kunstseiden sein. Die Anwendung der löslichen Öle bietet große Vorteile beim Winden, Spinnen, Zwirnen, ferner beim Entbasten, Beuchen, Walken, beim Netzen, Färben und Drucken, Imprägnieren, Wasserdichtmachen und Appretieren. Die löslichen Öle können auch als Schmiermittel für Maschinenteile verwendet wer-2,38° (80 Sek.)
2,50" (84 Sek.)
2,56° (86 Sek.)
2,58° (87 Sek.)The soluble oils according to the present invention are particularly suitable for the treatment of textiles, both for the treatment of the loose fibers and in the various types of yarn manufacture and treatment, as well as in weaving and finishing. The fiber materials can be, for example, wool, hair, cotton, silk, flax, jute, ramie, bast or the various types of rayon. The use of the soluble oils offers great advantages in winding, spinning, twisting, and also in deboning, bucking, fulling, wetting, dyeing and printing, impregnation, waterproofing and finishing. The soluble oils can also be used as lubricants for machine parts.
2.50 "(84 sec.)
2.56 ° (86 sec.)
2.58 ° (87 sec.)

schlechte Emulsion sehr schlechte Emulsion schlechte Emulsionbad emulsion very bad emulsion bad emulsion

gute
Emulsionquality
emulsion

keine Emulsionno emulsion

keine Emulsionno emulsion

keineno

Emulsionemulsion

brauchbareuseful

Emulsionemulsion

den, insbesondere wo die Gefahr einer Verunreinigung der durch die Maschine laufenden Stoffe besteht und das Schmiermittel von diesen leicht entfernbar sein soll. Die löslichen Öle können auch für andere Zwecke, beispielsweise als Weichmachungsmittel oder in der Kautschukindustrie, ferner als Schneid- und Bohröle sowie als Rostschutzmittel Anwendung finden. Auch als Unkrautvertilgungsmittel, als Schädlingslx;kämpfuingsrnittel sowie zur Herstellung von Salben, Politurmitteln, Druckfarben und für viele andere Zwecke sind sie verwendbar.those, especially where there is a risk of contamination of the running through the machine Substances and the lubricant should be easily removable from these. the Soluble oils can also be used for other purposes, for example as emollients or in the rubber industry, also as cutting and drilling oils and as a rust inhibitor Find. Also as a herbicide, as a pest agent as well as for the production of ointments, polishes, printing inks and many others Purposes they are useful.

Ein gut lösliches Öl erhält man beispielsweise durch Vermischen von 900/0 eines durch Druckhydrierung von Mineralöl erhaltenen Öles mit 2,50/0 Triäthanolaminoleat und 7,5 °/0 öllöslichem Mineralölsulfonat. Wenn man 1 Teil dieser Mischung unter Rühren mit 2 Teilen Wasser vermischt, so bildet sich sehr leicht eine Emulsion von weißer Farbe, 110' die z. B. auf Wolle vor dem Reinigen und Kämmen aufgebracht werden kann.A well-soluble oil is obtained for example by mixing a 900/0 by pressure hydrogenation of petroleum oil obtained with 2,50 / 0 Triäthanolaminoleat and 7.5 ° / 0 Mineralölsulfonat oil-soluble. If 1 part of this mixture is mixed with 2 parts of water with stirring, an emulsion of white color is formed very easily, 110 'which z. B. can be applied to wool before cleaning and combing.

Claims (1)

Patentanspruch:Claim: Emulgierbare Öle oder Emulsionen dieser, dadurch gekennzeichnet, daß sie als Öle Druckhydrierungsprodukte von Mineralölen oder deren Fraktionen enthalten.Emulsifiable oils or emulsions of these, characterized in that they are used as Oils contain pressure hydrogenation products of mineral oils or their fractions.
DEST53483D 1934-05-11 1935-05-11 Emulsifiable oils Expired DE649045C (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US725083A US2049043A (en) 1934-05-11 1934-05-11 Soluble oils

Publications (1)

Publication Number Publication Date
DE649045C true DE649045C (en) 1937-08-13

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ID=24913091

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Country Status (4)

Country Link
US (1) US2049043A (en)
DE (1) DE649045C (en)
FR (2) FR788858A (en)
GB (1) GB452811A (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2481585A (en) * 1945-09-17 1949-09-13 Michael W Freeman Lubricating oil composition
US2512435A (en) * 1947-04-11 1950-06-20 Shell Dev Emulsions
US2511250A (en) * 1947-11-14 1950-06-13 Gulf Research Development Co Stabilized extreme pressure lubricants
US2695272A (en) * 1952-05-21 1954-11-23 Standard Oil Dev Co Soluble metalworking oil
US2865466A (en) * 1955-03-07 1958-12-23 Res Prod Corp Gas filter and adhesive therefor

Also Published As

Publication number Publication date
US2049043A (en) 1936-07-28
FR789626A (en) 1935-11-04
FR788858A (en) 1935-10-17
GB452811A (en) 1936-08-31

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