DE632060C - Process of selenium toning - Google Patents

Process of selenium toning

Info

Publication number
DE632060C
DE632060C DEG85379D DEG0085379D DE632060C DE 632060 C DE632060 C DE 632060C DE G85379 D DEG85379 D DE G85379D DE G0085379 D DEG0085379 D DE G0085379D DE 632060 C DE632060 C DE 632060C
Authority
DE
Germany
Prior art keywords
selenium
bath
iodine
toning
alkali
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEG85379D
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German (de)
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Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to DEG85379D priority Critical patent/DE632060C/en
Application granted granted Critical
Publication of DE632060C publication Critical patent/DE632060C/en
Expired legal-status Critical Current

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Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C5/00Photographic processes or agents therefor; Regeneration of such processing agents
    • G03C5/26Processes using silver-salt-containing photosensitive materials or agents therefor
    • G03C5/40Chemically transforming developed images
    • G03C5/46Toning

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)

Description

Verfahren der Selentonung Die schönen rotbraunen Tonungen, welche auf gewissen Papieren, z. B. Mimosa-Carbonbraun, mit Hydrochinonspezialentwicklern direkt erhalten werden, sind nur über die Kontaktkopie ° hinweg zugänglich, da die Braunentwicklung gegenüber der Schwarzentwicklung etwa zehnfache Überbelichtung erfordert und nur mit sehr feinkörnigen und unempfindlichen Emulsionen erzielt werdenkann.Process of selenium toning The beautiful red-brown toning, which on certain papers, e.g. B. Mimosa carbon brown, with special hydroquinone developers are obtained directly are only accessible via the contact copy °, since the Brown development compared to black development about ten times overexposure and can only be achieved with very fine-grained and insensitive emulsions.

Es hat sich nun gezeigt, däß sehr ansprechende rotbraune Tonungen auf sehr billige und einfache Weise erhalten werden, indem Vergrößerungspapiere, z. B. Mimosa Bromosa oder Orthotyp, umgetont werden. Das neue Verfahren besteht darin, daß solche Bromsilberpapiere nach Vertonung in einer Selenlösung (Selensulfat) mit einer sehr haltbaren und wirksamen jod-Jodkali-Lösung gebleicht und schließlich m einem Alkalisülfit-oder Alkalibad endgültig getont werden.It has now been shown that very appealing red-brown tones can be obtained in a very cheap and simple way by using enlarging papers, z. B. Mimosa Bromosa or Orthotyp to be toned. The new procedure exists that such bromide-silver papers after setting in a selenium solution (selenium sulfate) and finally bleached with a very durable and effective iodine-iodine-potassium solution Can be finally toned in an alkali sulphate or alkali bath.

Es ist zwar bekannt, daß im Selenbad nicht direkt tonende Bromsilberpapiere nach Vertonung im Selenbad und nachträglichem Behandeln in Lösungen von Ferrocyankalium, Bromkalium und Jodkalium rötliche Bilder ergeben. Die bekannten Bleichlösungen haben aber alle den Nachteil, daß sie sehr langsam arbeiten und daß sie vor allem außerordentlich wenig haltbar sind. Für den Verkauf sind sie also beispielsweise vollkommen ungeeignet. Eine praktische Bedeutung konnte das Verfahren der Selentonung nach dem Ausbleichverfahren erst durch das Auffinden einer haltbaren und schnell wirksamen Bleichlösung erlangen. Dies wurde durch die genannte Jod-Jodkali-Lösung erreicht.It is known that in the selenium bath, bromide silver papers do not directly tone after setting to music in a selenium bath and subsequent treatment in solutions of ferrocyanic potassium, Potassium bromide and potassium iodide produce reddish images. The well-known bleach solutions have but all of them have the disadvantage that they work very slowly and, above all, that they are extraordinary are not durable. For example, they are completely unsuitable for sale. The process of selenium toning after the bleaching process was of practical importance by finding a durable and fast-acting bleach solution. This was achieved with the iodine-iodine-potassium solution mentioned.

Nach dem neuen Verfahren kommen die schwarzen Silberbilder zunächst in ein übliches Selentonbad und werden etwa 15 Minuten darin belassen. Eine nennenswerte Tonverbesserung tritt hierdurch nicht ein. Die Bilder werden nun gewässert, in einer Jod-Jodkali-Lösung gebleicht, abgespült und vom anhaftenden Jod, z. B. in sulfithaltigem Wasser, befreit. Dieses Selenbild wird schließlich etwa 15 Minuten lang in ein Alkalisulfitbad oder in ein Alkalibad, z. B. Sodabad, gebracht, in welchem es sich rotbraun färbt. Als Färbebad können auch Schwefelalkalien und Erdalkalien dienen, die dunklere Farben erzeugen.According to the new process, the black silver images come first in a standard selenium bath and are left in it for about 15 minutes. A notable one This does not improve the sound. The pictures are now watered, in one Iodine-iodine-potassium solution bleached, rinsed and removed from the adhering iodine, e.g. B. in sulfite Water, exempt. This selenium picture is finally immersed in an alkali sulfite bath for about 15 minutes or in an alkali bath, e.g. B. Soda bath, brought in which it turns reddish brown. Alkaline sulfur and alkaline earths, which are darker in color, can also be used as a dye bath produce.

Beispiel Die schwarzen Silberbilder kommen 15 Minuten lang in ein unverdünntes Selenbad (Natriumselenosulfat), werden dann gewaschen und in einer :L/"-n-Jod-Jodkali-Lösung gebleicht. Hierauf kommen die abgespülten Bilder in ein 5- bis ioo;oiges Natriumsulfit-bzw. Sodabad evtl. nach vorheriger Klärung in eine Lösung, welche schweflige Säure enthält.Example The black silver images come in for 15 minutes undiluted selenium bath (sodium selenosulfate), are then washed and placed in a : L / "- n-iodine-iodine-potassium solution bleached. Then the rinsed pictures come in 5- to 100% sodium sulfite or. Soda bath possibly after prior clarification in a Solution containing sulphurous acid.

Claims (1)

PATENTANSPRUCH: Verfahren zur Selentonung von Silber= Bildern, die im Selenbad (Selenosulfät) nicht oder schlecht tonen, durch erstmalige Behandlung im Selenbad und unte Nachbehandlung mit jodierend wirkenden Lösungen, dadurch gekennzeichnet, daß man zur Nachbehandlung eine Lösung von Jod in Jodalkali benutzt, worauf die Endtonung in einem Bade von Alkalisulfit -.bzw. Alkali erfolgt.PATENT CLAIM: Process for selenium toning of silver = images that Do not tone or tone poorly in the selenium bath (selenosulphate) due to initial treatment in the selenium bath and after-treatment with iodine solutions, characterized by that a solution of iodine in iodine alkali is used for aftertreatment, whereupon the Final toning in a bath of alkali sulphite or Alkali takes place.
DEG85379D 1933-04-24 1933-04-25 Process of selenium toning Expired DE632060C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEG85379D DE632060C (en) 1933-04-24 1933-04-25 Process of selenium toning

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEG0085379 1933-04-24
DEG85379D DE632060C (en) 1933-04-24 1933-04-25 Process of selenium toning

Publications (1)

Publication Number Publication Date
DE632060C true DE632060C (en) 1936-07-02

Family

ID=25979174

Family Applications (1)

Application Number Title Priority Date Filing Date
DEG85379D Expired DE632060C (en) 1933-04-24 1933-04-25 Process of selenium toning

Country Status (1)

Country Link
DE (1) DE632060C (en)

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