DE611045C - Process for making swimming soaps - Google Patents
Process for making swimming soapsInfo
- Publication number
- DE611045C DE611045C DEM118852D DEM0118852D DE611045C DE 611045 C DE611045 C DE 611045C DE M118852 D DEM118852 D DE M118852D DE M0118852 D DEM0118852 D DE M0118852D DE 611045 C DE611045 C DE 611045C
- Authority
- DE
- Germany
- Prior art keywords
- soap
- soaps
- swimming
- making
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/06—Inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/02—Floating bodies of detergents or of soaps
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Description
Verfahren zur Herstellung von Schwimmseifen Gegenstand des neuen Verfahrens ist die Herstellung einer Schwimmseife, welche sich wie seine gewöhnliche Kernseife durch Kühlung auch zu Platten verarbeiten läßt.Process for the production of swimming soaps The subject of the new process is the production of a swimming soap, which is like its ordinary curd soap can also be processed into panels by cooling.
Bisher erzeugte man S,chwimms;eifen in der Weise, daß man eine halbwarme oder gesottene Seife in flüssigem Zustand mit sauerstoffabgebenden Mitteln versetzte, wobei der freiwerdende Sauerstoff der Seife eine poröse Struktur verlieh. Sehr naheliegend war der Gedanke und ist jauch praktisch schon häufig durchgeführt worden, Metalle oder Metallverbindungen zur Gasentwicklung zu nehmen, wie z. B. Aluminium, Magnesium oder Zink, welche sich in dem freien Alkali der Seife unter Wasserstoffentwicklung lösen. Hierbei entstehen als Reaktionsprodukte zuerst die Metallhydroxyde (oder jauch Aluminat bzw. Zinkat), die sich mit der vorhandenen Seife zu Metallseifen umsetzen. Metallseifen setzen aber in geringen Mengen die Schaumkraft einer Seife herunter. Auch besteht die Gefahr, daß geringe Metallspuren, neingehüllt von der unlöslichen Metallseife, unzersetzt in der Seife verbleiben und beim Altern Ranziditätserscheinungen hervorrufen.So far, swimming pools have been produced by adding oxygen-releasing agents to a semi-warm or boiled soap in a liquid state, with the released oxygen giving the soap a porous structure. The idea was very obvious, and has already been practically carried out many times, to use metals or metal compounds to generate gas, such as. As aluminum, magnesium or zinc, which dissolve in the free alkali soap with evolution of hydrogen. The first reaction products are the metal hydroxides (or even aluminate or zincate), which react with the existing soap to form metal soaps. Small amounts of metal soaps reduce the foaming power of a soap. There is also the risk that small traces of metal, enveloped by the insoluble metal soap, remain undecomposed in the soap and cause symptoms of rancidity with aging.
Diese Nachteile - S.c aumkraftverminderung und Ranziditätsgefahr infolge uniersetzter Metallspuren - werden nach dem von der Erfinderin gefundenen Verfahren vermieden. Die Erfinderin verwendet zur Erzeugung der porösen Struktur in der Seife Silicium. Silicium löst sich in dem verdünnten Alkali der Seife unter Wassierstoffentwicklung Si +,2NaOH+H20=Na21Si03+ 2H2. E:s ,entstehen ¢ Atome Wassierstoff, ialso i bzw. 2 Atome mehr als bei Verwendung von drei-bzw. zweiwertigen Metallen.These disadvantages - reduced capacity and risk of rancidity as a result unieretzt metal traces - are made according to the method found by the inventor avoided. The inventor used to create the porous structure in the soap Silicon. Silicon dissolves in the diluted alkali of the soap with evolution of hydrogen Si +, 2NaOH + H2O = Na21Si03 + 2H2. E: s, arise ¢ atoms hydrogen, ialso i resp. 2 atoms more than when using three or more. divalent metals.
Das .entstehende Natriumsilikat 'ist für die Schaumkraft nicht nachteilig. Was.sierglas wurde ja zeitweise sehr viel als ideales Füllmittel für Seifen verwandt.The "resulting sodium silicate" is not disadvantageous for the foam power. Was.sierglas was at times very much used as the ideal filler for soaps.
Der Nachteil, daß die auf diesem oderanderem Wege erzeugte Schwimmseife beim Kühlen in Platten auf einer Kühlpresse ran der Oberfläche der Platten Blasen bildet, wird durch Zusatz von Lösungen von Caslein, Traganth, Pektin und ähnlichen organischen leim- oder gummiartigen Stoffen beseitigt. Die so erhaltenen Seifen lassen sich bei vorgewärmter Kühlpresse ohne Störung in einwandfreien Platten erhalten, und die aus den Platten (erhaltenen gepreßten, fertigen Stücke zeigen beim Altern weniger Schrumpfungserscheinungen und Formveränderungen als gewöhnliche Seifen ohne Zusatz von leim-oder gummiartigen Stoffen.The disadvantage that the floating soap produced in this or another way When cooling in plates on a cooling press, bubbles ran on the surface of the plates is formed by adding solutions of caslein, tragacanth, pectin and the like organic glue- or rubber-like substances are eliminated. The soaps thus obtained can be obtained in flawless panels with a preheated cooling press without interference, and the pressed finished pieces obtained from the plates (show on aging fewer signs of shrinkage and changes in shape than ordinary soaps without Addition of glue-like or rubber-like substances.
Aus.führ-ung;sb@@eispi@el i oo kg heiße flüssige Kernsteife werden unter Rühren mit 2o g Silicium versetzt und etwa 1/g Stunde gerührt; dann wird nach Zusatz von Farbe eine Lösung von .3 kg Casein in 8 kg kaltem HZ O, 0,3 kg Borax rund 6o g Salmiakgeist (o,9io) in die Seife eingetragen, die Masse homogen gerührt und in -eine angewärmte Kühlpresse gepreßt.Execution; sb @@ eispi @ el i oo kg of hot liquid core stiffness are mixed with 20 g of silicon while stirring and stirred for about 1 / g hour; Then, after the addition of paint, a solution of .3 kg of casein in 8 kg of cold HZ O, 0.3 kg of borax, around 60 g of ammonia (0.09) is added to the soap, the mass is stirred homogeneously and pressed into a heated cooling press .
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEM118852D DE611045C (en) | 1932-02-21 | 1932-02-21 | Process for making swimming soaps |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEM118852D DE611045C (en) | 1932-02-21 | 1932-02-21 | Process for making swimming soaps |
Publications (1)
Publication Number | Publication Date |
---|---|
DE611045C true DE611045C (en) | 1935-03-21 |
Family
ID=7329158
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DEM118852D Expired DE611045C (en) | 1932-02-21 | 1932-02-21 | Process for making swimming soaps |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE611045C (en) |
-
1932
- 1932-02-21 DE DEM118852D patent/DE611045C/en not_active Expired
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