DE60334501D1 - Olefinpolymere, herstellungsverfahren und benutzung davon - Google Patents
Olefinpolymere, herstellungsverfahren und benutzung davonInfo
- Publication number
- DE60334501D1 DE60334501D1 DE60334501T DE60334501T DE60334501D1 DE 60334501 D1 DE60334501 D1 DE 60334501D1 DE 60334501 T DE60334501 T DE 60334501T DE 60334501 T DE60334501 T DE 60334501T DE 60334501 D1 DE60334501 D1 DE 60334501D1
- Authority
- DE
- Germany
- Prior art keywords
- trialkylboron
- molecular weight
- copolymer resin
- manufacturing
- olefin polymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004519 manufacturing process Methods 0.000 title 1
- 229920000098 polyolefin Polymers 0.000 title 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 abstract 2
- 229920006026 co-polymeric resin Polymers 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 239000000026 Pentaerythritol tetranitrate Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000001844 chromium Chemical class 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000004711 α-olefin Substances 0.000 abstract 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L9/00—Rigid pipes
- F16L9/12—Rigid pipes of plastics with or without reinforcement
- F16L9/127—Rigid pipes of plastics with or without reinforcement the walls consisting of a single layer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/139—Open-ended, self-supporting conduit, cylinder, or tube-type article
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Materials For Medical Uses (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/640,868 US6525148B1 (en) | 2000-08-18 | 2000-08-18 | Polymerization catalyst systems and processes therefor and therewith |
PCT/US2003/005456 WO2004076499A1 (en) | 2000-08-18 | 2003-02-24 | Olefin polymers, method of making, and use thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
DE60334501D1 true DE60334501D1 (de) | 2010-11-18 |
Family
ID=24570003
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE60334501T Expired - Lifetime DE60334501D1 (de) | 2000-08-18 | 2003-02-24 | Olefinpolymere, herstellungsverfahren und benutzung davon |
Country Status (11)
Country | Link |
---|---|
US (4) | US6525148B1 (de) |
EP (1) | EP1601701B1 (de) |
CN (2) | CN101429300B (de) |
AT (1) | ATE483736T1 (de) |
AU (1) | AU2003215387A1 (de) |
CA (1) | CA2516668C (de) |
DE (1) | DE60334501D1 (de) |
ES (1) | ES2369458T3 (de) |
HK (1) | HK1085491A1 (de) |
MX (1) | MXPA05009043A (de) |
WO (1) | WO2004076499A1 (de) |
Families Citing this family (59)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6495638B2 (en) * | 1998-12-30 | 2002-12-17 | Phillips Petroleum Company | Process to produce polymers |
US7041617B2 (en) | 2004-01-09 | 2006-05-09 | Chevron Phillips Chemical Company, L.P. | Catalyst compositions and polyolefins for extrusion coating applications |
US6525148B1 (en) * | 2000-08-18 | 2003-02-25 | Phillips Petroleum Company | Polymerization catalyst systems and processes therefor and therewith |
US7829646B2 (en) * | 2000-08-18 | 2010-11-09 | Chevron Phillips Chemical Company Lp | Olefin polymers, method of making, and use thereof |
AU2002356678B2 (en) * | 2001-11-23 | 2007-02-01 | Basell Polyolefine Gmbh | Plastic pipes of polyolefins |
GB0326415D0 (en) * | 2003-11-12 | 2003-12-17 | Solvay | Polymer of ethylene |
US6935185B2 (en) * | 2003-12-16 | 2005-08-30 | Fina Technology, Inc. | Accelerated method to determine or predict failure time in polyethylenes |
US7288596B2 (en) * | 2003-12-22 | 2007-10-30 | Univation Technologies, Llc | Polyethylene compositions having improved tear properties |
US20050154159A1 (en) * | 2004-01-09 | 2005-07-14 | Deslauriers Paul J. | Olefin polymers, method of making, and use thereof |
BR122015023066B1 (pt) * | 2004-04-22 | 2018-01-09 | Chevron Phillips Chemical Company Lp | Polymer Composition |
US7307133B2 (en) | 2004-04-22 | 2007-12-11 | Chevron Phillips Chemical Company Lp | Polymers having broad molecular weight distributions and methods of making the same |
US7112643B2 (en) * | 2004-04-22 | 2006-09-26 | Chevron Phillips Chemical Company Lp | Polymers having low levels of long chain branching and methods of making the same |
AU2012201734B2 (en) * | 2004-04-22 | 2013-05-30 | Chevron Phillips Chemical Company Lp | Chromium based polymerization catalyst, the method to prepare it and polymers prepared therewith |
US7696280B2 (en) * | 2004-04-30 | 2010-04-13 | Chevron Phillips Chemical Company, Lp | HDPE resins for use in pressure pipe and related applications |
US7193017B2 (en) * | 2004-08-13 | 2007-03-20 | Univation Technologies, Llc | High strength biomodal polyethylene compositions |
US20060155082A1 (en) * | 2005-01-10 | 2006-07-13 | Mcdaniel Max P | Process for producing polymers |
US7312279B2 (en) * | 2005-02-07 | 2007-12-25 | Univation Technologies, Llc | Polyethylene blend compositions |
DE102005019393A1 (de) * | 2005-04-25 | 2006-10-26 | Basell Polyolefine Gmbh | Polyethylenformmassen für Spritzgussanwendungen |
DE102005019395A1 (de) * | 2005-04-25 | 2006-10-26 | Basell Polyolefine Gmbh | Formmasse aus Polyethylen zur Folienherstellung und Verfahren zum Herstellen der Formmasse in Gegenwart eines Mischkatalysators |
US7312283B2 (en) † | 2005-08-22 | 2007-12-25 | Chevron Phillips Chemical Company Lp | Polymerization catalysts and process for producing bimodal polymers in a single reactor |
US7595364B2 (en) | 2005-12-07 | 2009-09-29 | Univation Technologies, Llc | High density polyethylene |
US7589162B2 (en) * | 2006-02-22 | 2009-09-15 | Chevron Philips Chemical Company Lp | Polyethylene compositions and pipe made from same |
DE602008001250D1 (de) * | 2007-02-01 | 2010-06-24 | Basell Polyolefine Gmbh | Einmodus-copolymer von ethylen zum spritzgiessen und verfahren zu dessen herstellung |
US7754834B2 (en) * | 2007-04-12 | 2010-07-13 | Univation Technologies, Llc | Bulk density promoting agents in a gas-phase polymerization process to achieve a bulk particle density |
US7897539B2 (en) * | 2007-05-16 | 2011-03-01 | Chevron Phillips Chemical Company Lp | Methods of preparing a polymerization catalyst |
US8475898B2 (en) | 2007-08-29 | 2013-07-02 | Equistar Chemicals, Lp | Polyolefin resin blends for crack-resistant pipe |
US7638456B2 (en) | 2007-12-18 | 2009-12-29 | Chevron Phillips Chemical Company Lp | Methods of preparing a polymerization catalyst |
US8258246B2 (en) * | 2008-01-31 | 2012-09-04 | Fina Technology, Inc. | Preparation of supported chromium catalyst and polymerization process |
US20140179882A9 (en) * | 2008-02-21 | 2014-06-26 | Univation Technologies, Llc | Systems and Methods for Fabricating Polymers |
US8211988B2 (en) * | 2008-04-30 | 2012-07-03 | Chevron Phillips Chemical Company Lp | Methods of preparing a polymerization catalyst |
AU2009308801B2 (en) * | 2008-10-31 | 2015-05-07 | Chevron Phillips Chemical Company Lp | Oligomerization catalyst system and process for oligomerizing olefins |
US7951881B2 (en) | 2009-02-27 | 2011-05-31 | Chevron Phillips Chemical Company Lp | Polyethylene film having improved barrier properties and methods of making same |
US8852748B2 (en) | 2009-02-27 | 2014-10-07 | Chevron Phillips Chemical Company Lp | Polyethylene film having improved barrier properties and methods of making same |
US8369367B1 (en) * | 2009-03-26 | 2013-02-05 | Gao Peiliang | Tunable laser system |
US20100326017A1 (en) * | 2009-06-25 | 2010-12-30 | Darla Kindel | Protective Cover |
EP2451848A1 (de) | 2009-07-09 | 2012-05-16 | Union Carbide Chemicals & Plastics Technology LLC | Verbesserter betrieb im kondensationsmodus bei einem verfahren zur polyolefinherstellung mit katalsatoren auf chrombasis |
US8399580B2 (en) | 2010-08-11 | 2013-03-19 | Chevron Philips Chemical Company Lp | Additives to chromium catalyst mix tank |
CN103270054B (zh) * | 2010-12-24 | 2016-05-11 | 日本聚乙烯株式会社 | 具有改良了的支化度分布的聚乙烯 |
US20140127438A1 (en) | 2012-11-08 | 2014-05-08 | Robert L. Sherman, Jr. | Stabilized high-density polyethylene composition with improved resistance to deterioration and stabilizer system |
US10246528B2 (en) | 2014-01-09 | 2019-04-02 | Chevron Phillips Chemical Company Lp | Chromium (III) catalyst systems with activator-supports |
CN106467584B (zh) * | 2015-08-21 | 2019-08-20 | 中国石油化工股份有限公司 | 一种用于乙烯聚合的催化剂组分、其制备方法及应用 |
BR112019015300B1 (pt) * | 2017-02-13 | 2023-03-28 | Univation Technologies, Llc | Polímero à base de etileno, processo para copolimerizar etileno e uma ou mais alfa-olefinas em um único reator de polimerização de olefinas e artigo |
GB201704447D0 (en) * | 2017-03-21 | 2017-05-03 | Asterope Ltd | Wire coating determination |
CN108690150B (zh) * | 2017-04-07 | 2020-11-10 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂体系及烯烃聚合方法 |
US11360011B2 (en) | 2017-10-11 | 2022-06-14 | Chevron Phillips Chemical Company, Lp | Processes for predicting small scale steady state (S4) critical temperatures |
KR102285480B1 (ko) * | 2017-12-20 | 2021-08-03 | 주식회사 엘지화학 | 폴리에틸렌 공중합체 및 이의 제조 방법 |
US11225568B2 (en) | 2017-12-20 | 2022-01-18 | Lg Chem, Ltd. | Polyethylene copolymer and method for preparing same |
EP3898722A1 (de) * | 2018-12-20 | 2021-10-27 | SABIC Global Technologies B.V. | Rohre mit beständigkeit gegen erhöhte temperaturen mit einem polymer auf ethylenbasis |
CN109956845B (zh) * | 2019-04-12 | 2020-09-15 | 西南化工研究设计院有限公司 | 一种丙烯聚合制备壬烯的工艺方法 |
US11377541B2 (en) * | 2019-07-26 | 2022-07-05 | Chevron Phillips Chemical Company Lp | Blow molding polymers with improved cycle time, processability, and surface quality |
WO2022115754A1 (en) | 2020-11-30 | 2022-06-02 | Saudi Arabian Oil Company | Catalyst systems |
WO2022115750A1 (en) | 2020-11-30 | 2022-06-02 | Saudi Arabian Oil Company | Catalyst systems |
US11612883B2 (en) | 2020-11-30 | 2023-03-28 | Saudi Arabian Oil Company | Catalyst systems |
WO2022115749A1 (en) | 2020-11-30 | 2022-06-02 | Saudi Arabian Oil Company | Catalyst systems |
US11458462B2 (en) | 2020-11-30 | 2022-10-04 | Saudi Arabian Oil Company | Catalyst systems |
WO2022191882A1 (en) | 2021-03-12 | 2022-09-15 | Saudi Arabian Oil Company | Catalyst systems |
WO2023027749A1 (en) | 2021-08-26 | 2023-03-02 | Saudi Arabian Oil Company | Catalyst systems |
US11639321B1 (en) | 2022-08-31 | 2023-05-02 | Saudi Arabian Oil Company | Catalyst systems that include meta-alkoxy substituted n-aryl bis-diphosphinoamine ligands |
US11623901B1 (en) | 2022-08-31 | 2023-04-11 | Saudi Arabian Oil Company | Catalyst systems that include silyl ether moieties |
Family Cites Families (36)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5582103A (en) * | 1978-12-15 | 1980-06-20 | Mitsubishi Petrochem Co Ltd | Production of alpha-olefin polymer |
US4737280A (en) | 1980-09-17 | 1988-04-12 | Phillips Petroleum Company | Separation of solid polymers and liquid diluent |
US4364842A (en) | 1980-12-31 | 1982-12-21 | Phillips Petroleum Company | Phosphate supported chromium catalyst |
US4364854A (en) | 1980-12-31 | 1982-12-21 | Phillips Petroleum Company | Acid gelling aluminum phosphate from concentrated mass and catalyst containing same |
US4444962A (en) | 1980-12-31 | 1984-04-24 | Phillips Petroleum Company | Polymerization process using catalysts with acid gelled aluminum phosphate base |
US4444964A (en) | 1980-12-31 | 1984-04-24 | Phillips Petroleum Company | Polymerization process using phosphate supported chromium catalyst |
US4444968A (en) | 1980-12-31 | 1984-04-24 | Phillips Petroleum Company | Olefin polymerization with phosphate supported zerovalent chromium |
US4364855A (en) | 1980-12-31 | 1982-12-21 | Phillips Petroleum Company | Production of aluminum phosphate from concentrated mass |
US4504638A (en) | 1980-12-31 | 1985-03-12 | Phillips Petroleum Company | Ethylene polymers made from phosphate supported chromium catalyst |
US4444965A (en) | 1980-12-31 | 1984-04-24 | Phillips Petroleum Company | Olefin polymerization using chromium on an aluminum phosphate produced from a concentrated mass |
US4397765A (en) | 1980-12-31 | 1983-08-09 | Phillips Petroleum Company | Phosphated alumina or aluminum phosphate chromium catalyst |
US4397785A (en) * | 1981-03-27 | 1983-08-09 | The Dow Chemical Company | Preparation of 3,3'5,5'-tetratertiary butyl diphenoquinone |
US4424341A (en) | 1981-09-21 | 1984-01-03 | Phillips Petroleum Company | Separation of solid polymers and liquid diluent |
US4501885A (en) | 1981-10-14 | 1985-02-26 | Phillips Petroleum Company | Diluent and inert gas recovery from a polymerization process |
US4444966A (en) | 1982-05-05 | 1984-04-24 | Phillips Petroleum Company | Polymerization using phosphated alumina or aluminum phosphate chromium catalyst |
US4659690A (en) * | 1983-12-23 | 1987-04-21 | Phillips Petroleum Company | Acid agglomeration of refractory gel in polar organic diluent |
US4806513A (en) * | 1984-05-29 | 1989-02-21 | Phillips Petroleum Company | Silicon and fluorine-treated alumina containing a chromium catalyst and method of producing same |
US4547479A (en) | 1984-07-02 | 1985-10-15 | Phillips Petroleum Company | Polyphosphate in chromium catalyst support |
US4668808A (en) | 1984-08-13 | 1987-05-26 | Phillips Petroleum Company | Polychromium compounds and processes to make same |
US4613484A (en) | 1984-11-30 | 1986-09-23 | Phillips Petroleum Company | Loop reactor settling leg system for separation of solid polymers and liquid diluent |
US4596862A (en) * | 1984-12-24 | 1986-06-24 | Phillips Petroleum Company | Olefin polymerization using chromium on fluorided aluminophosphate |
CN1036853C (zh) * | 1985-04-01 | 1997-12-31 | 菲利浦石油公司 | 催化剂在烯烃聚合中的应用 |
US4654855A (en) * | 1985-04-05 | 1987-03-31 | Northrop Corporation | Pulsed gas laser using acoustic diodes for circulation of the gas |
US4681266A (en) * | 1986-01-21 | 1987-07-21 | Phillips Petroleum Company | Method of particulating agglomerated catalyst materials |
US5010152A (en) * | 1987-01-08 | 1991-04-23 | Phillips Petroleum Company | Polymerization process utilizing chromium on an acid agglomerated refractory gel |
US4960748A (en) * | 1987-07-20 | 1990-10-02 | Phillips Petroleum Company | Alumina phosphated with partial ester |
US5171801A (en) | 1989-10-06 | 1992-12-15 | Phillips Petroleum Company | Process for olefin polymerization |
US5221720A (en) * | 1991-01-02 | 1993-06-22 | Phillips Petroleum Company | Fluorided aluminas, catalysts, and polymerization processes |
US5137997A (en) * | 1991-04-22 | 1992-08-11 | Phillips Petroleum Company | Olefin polymerization catalysts and processes |
AU650787B2 (en) | 1991-12-09 | 1994-06-30 | Phillips Petroleum Company | Process for preparing a pillared chain silicate clay |
DE19515678B4 (de) | 1995-04-28 | 2007-12-27 | Basell Polyolefine Gmbh | Rohr aus Polyethylen mit verbesserten mechanischen Eigenschaften |
US6111037A (en) * | 1996-10-31 | 2000-08-29 | Chevron Chemical Company Llc | Silica-modified aluminophosphate compositions, catalysts, method of preparing same and polymerization processes |
US6174981B1 (en) * | 1998-12-17 | 2001-01-16 | Phillips Petroleum Company | Polymerization process |
CA2356686A1 (en) * | 1998-12-29 | 2000-07-06 | Chevron Phillips Chemical Company Lp | Improved chromate ester catalyst and method of using same to produce high performance polyethylene products |
US6465586B2 (en) * | 1999-11-12 | 2002-10-15 | Mcdaniel Max P. | Polymerization catalyst and process |
US6525148B1 (en) * | 2000-08-18 | 2003-02-25 | Phillips Petroleum Company | Polymerization catalyst systems and processes therefor and therewith |
-
2000
- 2000-08-18 US US09/640,868 patent/US6525148B1/en not_active Expired - Lifetime
-
2002
- 2002-12-16 US US10/321,801 patent/US6875835B2/en not_active Expired - Lifetime
-
2003
- 2003-02-24 WO PCT/US2003/005456 patent/WO2004076499A1/en not_active Application Discontinuation
- 2003-02-24 MX MXPA05009043A patent/MXPA05009043A/es active IP Right Grant
- 2003-02-24 CN CN200710112616.8A patent/CN101429300B/zh not_active Expired - Fee Related
- 2003-02-24 CA CA2516668A patent/CA2516668C/en not_active Expired - Fee Related
- 2003-02-24 AU AU2003215387A patent/AU2003215387A1/en not_active Abandoned
- 2003-02-24 DE DE60334501T patent/DE60334501D1/de not_active Expired - Lifetime
- 2003-02-24 CN CN03826022.0A patent/CN100577693C/zh not_active Expired - Fee Related
- 2003-02-24 EP EP03711212A patent/EP1601701B1/de not_active Expired - Lifetime
- 2003-02-24 ES ES03711212T patent/ES2369458T3/es not_active Expired - Lifetime
- 2003-02-24 AT AT03711212T patent/ATE483736T1/de not_active IP Right Cessation
- 2003-02-24 US US10/373,648 patent/US6867278B2/en not_active Expired - Lifetime
-
2005
- 2005-03-02 US US10/997,727 patent/US7208441B2/en not_active Expired - Lifetime
-
2006
- 2006-05-12 HK HK06105506.0A patent/HK1085491A1/xx not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
US20030199648A1 (en) | 2003-10-23 |
AU2003215387A1 (en) | 2004-09-17 |
MXPA05009043A (es) | 2005-11-23 |
US6875835B2 (en) | 2005-04-05 |
WO2004076499A1 (en) | 2004-09-10 |
US20030236366A1 (en) | 2003-12-25 |
US20050288470A1 (en) | 2005-12-29 |
EP1601701B1 (de) | 2010-10-06 |
EP1601701A1 (de) | 2005-12-07 |
US6867278B2 (en) | 2005-03-15 |
ATE483736T1 (de) | 2010-10-15 |
CN101429300A (zh) | 2009-05-13 |
HK1085491A1 (en) | 2006-08-25 |
CN1745109A (zh) | 2006-03-08 |
US6525148B1 (en) | 2003-02-25 |
EP1601701A4 (de) | 2008-09-24 |
CN100577693C (zh) | 2010-01-06 |
ES2369458T3 (es) | 2011-12-01 |
CA2516668A1 (en) | 2004-09-10 |
US7208441B2 (en) | 2007-04-24 |
CA2516668C (en) | 2012-01-03 |
CN101429300B (zh) | 2011-08-17 |
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