DE60219317T2 - Mikrofasern aus aliphatischem polyester, mikrofibrillierte gegenstände und ihre verwendung - Google Patents
Mikrofasern aus aliphatischem polyester, mikrofibrillierte gegenstände und ihre verwendung Download PDFInfo
- Publication number
- DE60219317T2 DE60219317T2 DE60219317T DE60219317T DE60219317T2 DE 60219317 T2 DE60219317 T2 DE 60219317T2 DE 60219317 T DE60219317 T DE 60219317T DE 60219317 T DE60219317 T DE 60219317T DE 60219317 T2 DE60219317 T2 DE 60219317T2
- Authority
- DE
- Germany
- Prior art keywords
- film
- microfibers
- microfibrillated
- aliphatic polyester
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003658 microfiber Substances 0.000 title claims abstract description 76
- 229920003232 aliphatic polyester Polymers 0.000 title claims abstract description 61
- 229920001410 Microfiber Polymers 0.000 claims abstract description 75
- 238000000034 method Methods 0.000 claims abstract description 74
- 239000012530 fluid Substances 0.000 claims abstract description 39
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 32
- 239000000203 mixture Substances 0.000 claims description 29
- 230000008569 process Effects 0.000 claims description 22
- -1 poly (oxyethylene glycolate Chemical compound 0.000 claims description 14
- 229920006126 semicrystalline polymer Polymers 0.000 claims description 11
- 229920001577 copolymer Polymers 0.000 claims description 9
- 229920001519 homopolymer Polymers 0.000 claims description 6
- 239000005014 poly(hydroxyalkanoate) Substances 0.000 claims description 6
- REKYPYSUBKSCAT-UHFFFAOYSA-N 3-hydroxypentanoic acid Chemical compound CCC(O)CC(O)=O REKYPYSUBKSCAT-UHFFFAOYSA-N 0.000 claims description 5
- 229920000954 Polyglycolide Polymers 0.000 claims description 5
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Polymers OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims description 4
- 108700005457 microfibrillar Proteins 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 150000007513 acids Chemical class 0.000 claims description 3
- 239000007795 chemical reaction product Substances 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims description 3
- 210000001724 microfibril Anatomy 0.000 claims description 3
- 229920001610 polycaprolactone Polymers 0.000 claims description 3
- 239000004632 polycaprolactone Substances 0.000 claims description 3
- 229920002463 poly(p-dioxanone) polymer Polymers 0.000 claims description 2
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- 239000000622 polydioxanone Substances 0.000 claims description 2
- 229920000903 polyhydroxyalkanoate Polymers 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 18
- 239000011159 matrix material Substances 0.000 abstract description 14
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- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
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- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
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- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 3
- JJTUDXZGHPGLLC-IMJSIDKUSA-N 4511-42-6 Chemical compound C[C@@H]1OC(=O)[C@H](C)OC1=O JJTUDXZGHPGLLC-IMJSIDKUSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 3
- NGEWQZIDQIYUNV-UHFFFAOYSA-N L-valinic acid Natural products CC(C)C(O)C(O)=O NGEWQZIDQIYUNV-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
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- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 3
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- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 2
- WSFYPFLCEFLXOZ-UHFFFAOYSA-N 2-decylbutanedioic acid Chemical compound CCCCCCCCCCC(C(O)=O)CC(O)=O WSFYPFLCEFLXOZ-UHFFFAOYSA-N 0.000 description 2
- GHPVDCPCKSNJDR-UHFFFAOYSA-N 2-hydroxydecanoic acid Chemical compound CCCCCCCCC(O)C(O)=O GHPVDCPCKSNJDR-UHFFFAOYSA-N 0.000 description 2
- JYZJYKOZGGEXSX-UHFFFAOYSA-N 2-hydroxymyristic acid Chemical compound CCCCCCCCCCCCC(O)C(O)=O JYZJYKOZGGEXSX-UHFFFAOYSA-N 0.000 description 2
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
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- 125000002947 alkylene group Chemical group 0.000 description 2
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- BMRWNKZVCUKKSR-UHFFFAOYSA-N butane-1,2-diol Chemical compound CCC(O)CO BMRWNKZVCUKKSR-UHFFFAOYSA-N 0.000 description 2
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- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
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- 235000011187 glycerol Nutrition 0.000 description 2
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
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- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
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- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- JJTUDXZGHPGLLC-UHFFFAOYSA-N lactide Chemical compound CC1OC(=O)C(C)OC1=O JJTUDXZGHPGLLC-UHFFFAOYSA-N 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 150000007527 lewis bases Chemical class 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
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- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
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- 229920000520 poly(3-hydroxybutyrate-co-3-hydroxyvalerate) Polymers 0.000 description 1
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- 229920002961 polybutylene succinate Polymers 0.000 description 1
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- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
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Classifications
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/42—Formation of filaments, threads, or the like by cutting films into narrow ribbons or filaments or by fibrillation of films or filaments
- D01D5/423—Formation of filaments, threads, or the like by cutting films into narrow ribbons or filaments or by fibrillation of films or filaments by fibrillation of films or filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
- D01F6/625—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters derived from hydroxy-carboxylic acids, e.g. lactones
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
- Y10T428/24994—Fiber embedded in or on the surface of a polymeric matrix
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2904—Staple length fiber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
- Y10T428/2967—Synthetic resin or polymer
- Y10T428/2969—Polyamide, polyimide or polyester
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2973—Particular cross section
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2973—Particular cross section
- Y10T428/2976—Longitudinally varying
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/298—Physical dimension
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Biological Depolymerization Polymers (AREA)
- Polyesters Or Polycarbonates (AREA)
- Artificial Filaments (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Nonwoven Fabrics (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US29881701P | 2001-06-15 | 2001-06-15 | |
| US298817P | 2001-06-15 | ||
| PCT/US2002/015078 WO2002103094A1 (en) | 2001-06-15 | 2002-05-10 | Aliphatic polyester microfibers, microfibrillated articles and use thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60219317D1 DE60219317D1 (de) | 2007-05-16 |
| DE60219317T2 true DE60219317T2 (de) | 2008-01-03 |
Family
ID=23152108
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60219317T Expired - Lifetime DE60219317T2 (de) | 2001-06-15 | 2002-05-10 | Mikrofasern aus aliphatischem polyester, mikrofibrillierte gegenstände und ihre verwendung |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6645618B2 (https=) |
| EP (1) | EP1404905B1 (https=) |
| JP (1) | JP2005511899A (https=) |
| AT (1) | ATE358737T1 (https=) |
| DE (1) | DE60219317T2 (https=) |
| ES (1) | ES2283545T3 (https=) |
| WO (1) | WO2002103094A1 (https=) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT522596B1 (de) * | 2019-11-04 | 2020-12-15 | Lenzing Plastics Gmbh & Co Kg | Zahnseide |
Families Citing this family (84)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7105124B2 (en) * | 2001-06-19 | 2006-09-12 | Aaf-Mcquay, Inc. | Method, apparatus and product for manufacturing nanofiber media |
| US6890649B2 (en) * | 2002-04-26 | 2005-05-10 | 3M Innovative Properties Company | Aliphatic polyester microfibers, microfibrillated articles and use thereof |
| US7364607B2 (en) * | 2002-05-20 | 2008-04-29 | Toyo Boseki Kabushiki Kaisha | Wrought fiber sheet and filter unit |
| ES2340927T3 (es) * | 2003-02-13 | 2010-06-11 | Teijin Limited | Fibra porosa, estructura de fibras porosa y procedimiento de fabricacion de la misma. |
| TW200427889A (en) | 2003-03-31 | 2004-12-16 | Teijin Ltd | Non-woven fabric and process for producing the same |
| JP3739003B2 (ja) * | 2003-05-08 | 2006-01-25 | 西川ゴム工業株式会社 | 生分解性樹脂組成物 |
| US20040260034A1 (en) | 2003-06-19 | 2004-12-23 | Haile William Alston | Water-dispersible fibers and fibrous articles |
| US8513147B2 (en) | 2003-06-19 | 2013-08-20 | Eastman Chemical Company | Nonwovens produced from multicomponent fibers |
| US7892993B2 (en) | 2003-06-19 | 2011-02-22 | Eastman Chemical Company | Water-dispersible and multicomponent fibers from sulfopolyesters |
| US9561309B2 (en) * | 2004-05-27 | 2017-02-07 | Advanced Cardiovascular Systems, Inc. | Antifouling heparin coatings |
| US20060014462A1 (en) * | 2004-07-16 | 2006-01-19 | Jones William R Iii | Reusable microfiber non-woven cleaning fabric |
| US7074483B2 (en) * | 2004-11-05 | 2006-07-11 | Innegrity, Llc | Melt-spun multifilament polyolefin yarn formation processes and yarns formed therefrom |
| US20060166578A1 (en) * | 2005-01-21 | 2006-07-27 | Myers Kasey R | Process for creating fabrics with branched fibrils and such fibrillated fabrics |
| WO2006099020A2 (en) * | 2005-03-09 | 2006-09-21 | The University Of Tennessee Research Foundation | Barrier stent and use thereof |
| US7445834B2 (en) * | 2005-06-10 | 2008-11-04 | Morin Brian G | Polypropylene fiber for reinforcement of matrix materials |
| US7850810B2 (en) * | 2005-07-29 | 2010-12-14 | Gore Enterprise Holdings, Inc. | Method of making porous self-cohered web materials |
| US20070027551A1 (en) * | 2005-07-29 | 2007-02-01 | Farnsworth Ted R | Composite self-cohered web materials |
| US7655584B2 (en) * | 2005-07-29 | 2010-02-02 | Gore Enterprise Holdings, Inc. | Highly porous self-cohered web materials |
| US7655288B2 (en) * | 2005-07-29 | 2010-02-02 | Gore Enterprise Holdings, Inc. | Composite self-cohered web materials |
| US20070026040A1 (en) * | 2005-07-29 | 2007-02-01 | Crawley Jerald M | Composite self-cohered web materials |
| US8048503B2 (en) * | 2005-07-29 | 2011-11-01 | Gore Enterprise Holdings, Inc. | Highly porous self-cohered web materials |
| US7604668B2 (en) * | 2005-07-29 | 2009-10-20 | Gore Enterprise Holdings, Inc. | Composite self-cohered web materials |
| US20070026039A1 (en) * | 2005-07-29 | 2007-02-01 | Drumheller Paul D | Composite self-cohered web materials |
| US8057887B2 (en) * | 2005-08-17 | 2011-11-15 | Rampart Fibers, LLC | Composite materials including high modulus polyolefin fibers |
| US7648607B2 (en) * | 2005-08-17 | 2010-01-19 | Innegrity, Llc | Methods of forming composite materials including high modulus polyolefin fibers |
| US7892633B2 (en) * | 2005-08-17 | 2011-02-22 | Innegrity, Llc | Low dielectric composite materials including high modulus polyolefin fibers |
| CA2628295C (en) * | 2005-11-02 | 2016-02-23 | Birgit Riesinger | Absorptive element to be mounted on human or animal skin surfaces |
| US7718036B2 (en) * | 2006-03-21 | 2010-05-18 | Georgia Pacific Consumer Products Lp | Absorbent sheet having regenerated cellulose microfiber network |
| US8187422B2 (en) | 2006-03-21 | 2012-05-29 | Georgia-Pacific Consumer Products Lp | Disposable cellulosic wiper |
| US8540846B2 (en) | 2009-01-28 | 2013-09-24 | Georgia-Pacific Consumer Products Lp | Belt-creped, variable local basis weight multi-ply sheet with cellulose microfiber prepared with perforated polymeric belt |
| US8187421B2 (en) | 2006-03-21 | 2012-05-29 | Georgia-Pacific Consumer Products Lp | Absorbent sheet incorporating regenerated cellulose microfiber |
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| US20070238167A1 (en) * | 2006-04-04 | 2007-10-11 | 3M Innovative Properties Company | Flat microfibers as matrices for cell growth |
| US9134471B2 (en) | 2006-06-28 | 2015-09-15 | 3M Innovative Properties Company | Oriented polymeric articles and method |
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| US8691321B2 (en) | 2006-10-20 | 2014-04-08 | Orbusneich Medical, Inc. | Bioabsorbable polymeric composition and medical device background |
| US7959942B2 (en) | 2006-10-20 | 2011-06-14 | Orbusneich Medical, Inc. | Bioabsorbable medical device with coating |
| US9539065B2 (en) | 2006-10-23 | 2017-01-10 | 3M Innovative Properties Company | Assemblies, methods, and kits including a compressible material |
| US20080096150A1 (en) | 2006-10-23 | 2008-04-24 | 3M Innovative Properties Company | Dental articles, methods, and kits including a compressible material |
| WO2008053552A1 (fr) * | 2006-11-01 | 2008-05-08 | Fujitsu Limited | Appareil de communication sans fil et procédé de communication sans fil |
| WO2008065453A1 (en) * | 2006-12-01 | 2008-06-05 | Innovia Films Limited | Film |
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| US20080200890A1 (en) * | 2006-12-11 | 2008-08-21 | 3M Innovative Properties Company | Antimicrobial disposable absorbent articles |
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| CN101878332B (zh) * | 2007-09-28 | 2012-09-05 | 自然工作有限责任公司 | 聚交酯立体络合物共轭纤维 |
| EP2231913B1 (en) * | 2007-12-19 | 2013-01-23 | Tepha, Inc. | Medical devices containing melt-blown non-wovens of poly-r-hydroxybutyrate and copolymers |
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| US20100151575A1 (en) * | 2008-12-15 | 2010-06-17 | Colter David C | Method of Making Conditioned Media from Kidney Derived Cells |
| US9487893B2 (en) | 2009-03-31 | 2016-11-08 | 3M Innovative Properties Company | Dimensionally stable nonwoven fibrous webs and methods of making and using the same |
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| US20110236666A1 (en) * | 2010-03-26 | 2011-09-29 | Hall Mark J | Melt-extruded film |
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| US9273417B2 (en) | 2010-10-21 | 2016-03-01 | Eastman Chemical Company | Wet-Laid process to produce a bound nonwoven article |
| EP3649980B1 (en) | 2010-12-30 | 2021-08-11 | 3M Innovative Properties Co. | Bondable dental assemblies including a compressible material |
| AU2012275534A1 (en) * | 2011-06-27 | 2014-01-23 | The Research Foundation For The State University Of New York | Fiber mats coated with nanogrid visible spectrum photocatalysts |
| US9802187B2 (en) | 2011-06-30 | 2017-10-31 | 3M Innovative Properties Company | Non-woven electret fibrous webs and methods of making same |
| US8840757B2 (en) | 2012-01-31 | 2014-09-23 | Eastman Chemical Company | Processes to produce short cut microfibers |
| CN104136570A (zh) | 2012-04-27 | 2014-11-05 | 株式会社吴羽 | 坑井处理流体用聚乙醇酸树脂短纤维 |
| WO2013184836A1 (en) | 2012-06-05 | 2013-12-12 | Metabolix, Inc. | Low glass transition polyhydroxyalkanoates for modification of biodegradable polymers |
| CA2887807A1 (en) | 2012-10-12 | 2014-04-17 | 3M Innovative Properties Company | Multi-layer articles |
| JP6109334B2 (ja) | 2012-12-14 | 2017-04-05 | スリーエム イノベイティブ プロパティズ カンパニー | 不織布エレクトレット繊維ウェブ及びその製造方法 |
| US9303357B2 (en) | 2013-04-19 | 2016-04-05 | Eastman Chemical Company | Paper and nonwoven articles comprising synthetic microfiber binders |
| JP6542787B2 (ja) | 2013-11-26 | 2019-07-10 | スリーエム イノベイティブ プロパティズ カンパニー | 寸法安定性メルトブローン不織布繊維構造とその製造方法及び製造装置 |
| US9605126B2 (en) | 2013-12-17 | 2017-03-28 | Eastman Chemical Company | Ultrafiltration process for the recovery of concentrated sulfopolyester dispersion |
| US9598802B2 (en) | 2013-12-17 | 2017-03-21 | Eastman Chemical Company | Ultrafiltration process for producing a sulfopolyester concentrate |
| US9732184B2 (en) * | 2014-07-29 | 2017-08-15 | W. L. Gore & Associates, Inc. | Process for producing articles formed from polylactic acid and articles made therefrom |
| CA2979700A1 (en) | 2015-03-16 | 2016-09-22 | 3M Innovative Properties Company | Coalescing elements in copper production |
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| CN108463506A (zh) | 2015-11-17 | 2018-08-28 | Cj第制糖株式会社 | 具有可控生物降解速率的聚合物共混物 |
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| US10131579B2 (en) * | 2015-12-30 | 2018-11-20 | Exxonmobil Research And Engineering Company | Polarity-enhanced ductile polymer fibers for concrete micro-reinforcement |
| CN111819245A (zh) | 2017-12-28 | 2020-10-23 | 3M创新有限公司 | 包含阻燃聚合物的陶瓷涂覆的纤维以及制备非织造结构的方法 |
| CN113490773B (zh) * | 2019-02-28 | 2024-03-22 | 3M创新有限公司 | 微层/纳米层长丝 |
| WO2020174419A1 (en) * | 2019-02-28 | 2020-09-03 | 3M Innovative Properties Company | Novel nano-ribbons from multilayer coextruded film |
| CN112111862B (zh) * | 2020-09-04 | 2021-09-21 | 杭州恒邦实业有限公司 | 一种基于无纺布的覆膜纸制备工艺 |
| WO2022144843A1 (en) | 2020-12-30 | 2022-07-07 | 3M Innovative Properties Company | Bondable orthodontic assemblies and methods for bonding |
Family Cites Families (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3565985A (en) | 1969-04-10 | 1971-02-23 | Dow Chemical Co | Method of preparing multilayer plastic articles |
| BE758156R (fr) | 1970-05-13 | 1971-04-28 | Ethicon Inc | Element de suture absorbable et sa |
| DE2853398C3 (de) | 1978-12-11 | 1981-09-17 | Unilever N.V., Rotterdam | Verfahren und Vorrichtung zum simultanen biaxialen Recken einer Folienbahn aus Kunststoff |
| DE2920514A1 (de) | 1979-05-21 | 1980-11-27 | Unilever Nv | Dynamisch belastbare polypropylenfolie |
| US4643734A (en) | 1983-05-05 | 1987-02-17 | Hexcel Corporation | Lactide/caprolactone polymer, method of making the same, composites thereof, and prostheses produced therefrom |
| US4853602A (en) | 1985-12-24 | 1989-08-01 | E. I. Dupont De Nemours And Company | System for using synchronous secondaries of a linear motor to biaxially draw plastic films |
| US4675582A (en) | 1985-12-24 | 1987-06-23 | E. I. Du Pont De Nemours And Company | System useful for controlling multiple synchronous secondaries of a linear motor along an elongated path |
| US4744365A (en) | 1986-07-17 | 1988-05-17 | United States Surgical Corporation | Two-phase compositions for absorbable surgical devices |
| US4825111A (en) | 1987-11-02 | 1989-04-25 | E. I. Du Pont De Nemours And Company | Linear motor propulsion system |
| US5072493A (en) | 1988-06-22 | 1991-12-17 | E. I. Du Pont De Nemours And Company | Apparatus for drawing plastic film in a tenter frame |
| US5051225A (en) | 1988-06-22 | 1991-09-24 | E. I. Du Pont De Nemours And Company | Method of drawing plastic film in a tenter frame |
| US5036262A (en) | 1989-09-13 | 1991-07-30 | E. I. Du Pont De Nemours And Company | Method of determining control instructions |
| US5320624A (en) | 1991-02-12 | 1994-06-14 | United States Surgical Corporation | Blends of glycolide and/or lactide polymers and caprolactone and/or trimethylene carbonate polymers and absorbable surgical devices made therefrom |
| BR9206560A (pt) | 1991-10-01 | 1995-03-28 | Minnesota Mining & Mfg | Fita compósita, e, processo para a fabricacão de fita adesiva sensível a pressão por processamento por fusão |
| US5589122A (en) | 1991-10-01 | 1996-12-31 | Minnesota Mining And Manufacturing Company | Method of making double-sided pressure-sensitive adhesive tape |
| CA2106262C (en) | 1992-10-01 | 2003-11-18 | Ralph H. Bland | Tear resistant multilayer films and articles incorporating such films |
| US5338822A (en) | 1992-10-02 | 1994-08-16 | Cargill, Incorporated | Melt-stable lactide polymer composition and process for manufacture thereof |
| BR9305661A (pt) | 1992-10-02 | 1996-11-26 | Cargill Inc | Pano de polímero de lactideo estável em fusao e processo para a sua fabricaçao |
| US5389324A (en) | 1993-06-07 | 1995-02-14 | The Dow Chemical Company | Layer thickness gradient control in multilayer polymeric bodies |
| DE69526727D1 (de) | 1994-02-28 | 2002-06-20 | Procter & Gamble | Rührverfahren zur herstellung biologisch abbaubarer fibrillen |
| US5714573A (en) | 1995-01-19 | 1998-02-03 | Cargill, Incorporated | Impact modified melt-stable lactide polymer compositions and processes for manufacture thereof |
| US5633343A (en) | 1995-06-30 | 1997-05-27 | Ethicon, Inc. | High strength, fast absorbing, melt processable, gycolide-rich, poly(glycolide-co-p-dioxanone) copolymers |
| CA2195384C (en) | 1996-01-19 | 2007-06-05 | Kung Liu Cheng | Absorbable polymer blends and surgical articles fabricated therefrom |
| FI105040B (fi) | 1996-03-05 | 2000-05-31 | Neste Oy | Polylaktidikalvot |
| US5998549A (en) | 1996-05-31 | 1999-12-07 | 3M Innovative Properties Company | Durable, low surface energy compounds and articles, apparatuses, and methods for using the same |
| US5698322A (en) | 1996-12-02 | 1997-12-16 | Kimberly-Clark Worldwide, Inc. | Multicomponent fiber |
| US5883199A (en) | 1997-04-03 | 1999-03-16 | University Of Massachusetts | Polyactic acid-based blends |
| US6506873B1 (en) | 1997-05-02 | 2003-01-14 | Cargill, Incorporated | Degradable polymer fibers; preparation product; and, methods of use |
| US5952433A (en) | 1997-07-31 | 1999-09-14 | Kimberly-Clark Worldwide, Inc. | Modified polyactide compositions and a reactive-extrusion process to make the same |
| DE69832617T2 (de) | 1997-07-31 | 2006-08-03 | Kimberly-Clark Worldwide, Inc., Neenah | Modifizierte polylactidzusammensetzungen, wasserempfindliche, biologisch abbaubare filme und faser aus polylactiden und polyvinylalkohol und ihre herstellungsverfahren |
| US6075118A (en) | 1997-07-31 | 2000-06-13 | Kimberly-Clark Worldwide, Inc. | Water-responsive, biodegradable film compositions comprising polylactide and polyvinyl alcohol, and a method for making the films |
| US6114495A (en) | 1998-04-01 | 2000-09-05 | Cargill Incorporated | Lactic acid residue containing polymer composition and product having improved stability, and method for preparation and use thereof |
| US6225388B1 (en) | 1998-08-31 | 2001-05-01 | Kimberly-Clark Worldwide, Inc. | Biodegradable thermoplastic composition with improved wettability |
| US6093792A (en) | 1998-09-16 | 2000-07-25 | University Of Massachusetts | Bioresorbable copolymers |
| US6630231B2 (en) | 1999-02-05 | 2003-10-07 | 3M Innovative Properties Company | Composite articles reinforced with highly oriented microfibers |
| US6110588A (en) | 1999-02-05 | 2000-08-29 | 3M Innovative Properties Company | Microfibers and method of making |
| US6331343B1 (en) | 1999-05-07 | 2001-12-18 | 3M Innovative Properties Company | Films having a fibrillated surface and method of making |
| US6586073B2 (en) | 1999-05-07 | 2003-07-01 | 3M Innovative Properties Company | Films having a microfibrillated surface and method of making |
| ATE286548T1 (de) | 1999-09-15 | 2005-01-15 | Fiber Innovation Technology Inc | Teilbare mehrkomponentenfasern aus polyester |
-
2002
- 2002-04-26 US US10/132,964 patent/US6645618B2/en not_active Expired - Lifetime
- 2002-05-10 WO PCT/US2002/015078 patent/WO2002103094A1/en not_active Ceased
- 2002-05-10 ES ES02725997T patent/ES2283545T3/es not_active Expired - Lifetime
- 2002-05-10 DE DE60219317T patent/DE60219317T2/de not_active Expired - Lifetime
- 2002-05-10 JP JP2003505400A patent/JP2005511899A/ja active Pending
- 2002-05-10 AT AT02725997T patent/ATE358737T1/de not_active IP Right Cessation
- 2002-05-10 EP EP02725997A patent/EP1404905B1/en not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT522596B1 (de) * | 2019-11-04 | 2020-12-15 | Lenzing Plastics Gmbh & Co Kg | Zahnseide |
| AT522596A4 (de) * | 2019-11-04 | 2020-12-15 | Lenzing Plastics Gmbh & Co Kg | Zahnseide |
Also Published As
| Publication number | Publication date |
|---|---|
| ATE358737T1 (de) | 2007-04-15 |
| US6645618B2 (en) | 2003-11-11 |
| US20020192449A1 (en) | 2002-12-19 |
| WO2002103094A1 (en) | 2002-12-27 |
| EP1404905A1 (en) | 2004-04-07 |
| ES2283545T3 (es) | 2007-11-01 |
| JP2005511899A (ja) | 2005-04-28 |
| DE60219317D1 (de) | 2007-05-16 |
| EP1404905B1 (en) | 2007-04-04 |
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