DE602006013300D1 - Katalysatorzusammensetzung zur olefinpolymerisierung - Google Patents

Katalysatorzusammensetzung zur olefinpolymerisierung

Info

Publication number
DE602006013300D1
DE602006013300D1 DE602006013300T DE602006013300T DE602006013300D1 DE 602006013300 D1 DE602006013300 D1 DE 602006013300D1 DE 602006013300 T DE602006013300 T DE 602006013300T DE 602006013300 T DE602006013300 T DE 602006013300T DE 602006013300 D1 DE602006013300 D1 DE 602006013300D1
Authority
DE
Germany
Prior art keywords
olefin polymerization
catalyst composition
combining
catalyst system
intermediate composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
DE602006013300T
Other languages
German (de)
English (en)
Inventor
Thorsten Sell
Joerg Schottek
Nicola Stefanie Paczkowski
Andreas Winter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novolen Technology Holdings CV
Original Assignee
Novolen Technology Holdings CV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Novolen Technology Holdings CV filed Critical Novolen Technology Holdings CV
Publication of DE602006013300D1 publication Critical patent/DE602006013300D1/de
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/20—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of antimony, bismuth, vanadium, niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
DE602006013300T 2005-05-17 2006-04-27 Katalysatorzusammensetzung zur olefinpolymerisierung Active DE602006013300D1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/130,925 US7232869B2 (en) 2005-05-17 2005-05-17 Catalyst composition for olefin polymerization
PCT/US2006/016114 WO2006124231A1 (en) 2005-05-17 2006-04-27 Catalyst composition for olefin polymerization

Publications (1)

Publication Number Publication Date
DE602006013300D1 true DE602006013300D1 (de) 2010-05-12

Family

ID=36829739

Family Applications (1)

Application Number Title Priority Date Filing Date
DE602006013300T Active DE602006013300D1 (de) 2005-05-17 2006-04-27 Katalysatorzusammensetzung zur olefinpolymerisierung

Country Status (11)

Country Link
US (2) US7232869B2 (US07232869-20070619-C00011.png)
EP (1) EP1882000B1 (US07232869-20070619-C00011.png)
JP (1) JP2008545821A (US07232869-20070619-C00011.png)
KR (1) KR101190758B1 (US07232869-20070619-C00011.png)
CN (1) CN101384624B (US07232869-20070619-C00011.png)
AT (1) ATE462731T1 (US07232869-20070619-C00011.png)
BR (1) BRPI0610163A2 (US07232869-20070619-C00011.png)
DE (1) DE602006013300D1 (US07232869-20070619-C00011.png)
ES (1) ES2342106T3 (US07232869-20070619-C00011.png)
TW (1) TW200710110A (US07232869-20070619-C00011.png)
WO (1) WO2006124231A1 (US07232869-20070619-C00011.png)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005052654A1 (de) * 2005-11-04 2007-05-16 Ticona Gmbh Verfahren zur Herstellung von ultrahochmolekularen Polymeren unter Verwendung von speziellen verbrückten Metallocen-Katalysatoren
CA2670826C (en) 2006-12-14 2015-06-23 Albemarle Corporation Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins
KR101278336B1 (ko) * 2007-10-25 2013-06-25 루머스 노보렌 테크놀로지 게엠베하 안사-메탈로센 화합물의 라세모선택적 합성, 안사-메탈로센 화합물, 이를 포함하는 촉매, 그 촉매를 이용한 올레핀 폴리머 제조 공정, 그리고 올레핀 호모- 및 코폴리머
JP5598856B2 (ja) * 2007-10-25 2014-10-01 ルムス・ノボレン・テクノロジー・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング メタロセン化合物、それを含む触媒、その触媒を使用するオレフィンポリマーの製造プロセス、ならびにオレフィンホモポリマーおよびコポリマー
EP2172493A1 (en) 2008-10-02 2010-04-07 Total Petrochemicals Research Feluy Activating supports based on perfluorinated boronic acids
SG172454A1 (en) * 2008-12-31 2011-08-29 Lummus Novolen Technology Gmbh New metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo- and copolymers
EP2633104A1 (en) 2010-10-28 2013-09-04 Lummus Novolen Technology Gmbh Nonwoven and yarn polypropylene with additivation
US8895465B2 (en) * 2010-11-22 2014-11-25 Albemarle Corporation Activator compositions, their preparation, and their use in catalysis
EP2573091A1 (en) 2011-09-23 2013-03-27 Lummus Novolen Technology Gmbh Process for recycling of free ligand from their corresponding metallocene complexes
CN104334590B (zh) * 2012-02-08 2016-08-31 信实工业公司 用于制备uhmwpe的单中心催化剂在无机氧化物载体上的固定化
KR101549206B1 (ko) 2012-05-08 2015-09-02 주식회사 엘지화학 안사-메탈로센 화합물 및 이를 이용한 담지 촉매의 제조방법
KR101584350B1 (ko) * 2013-04-08 2016-01-13 한화케미칼 주식회사 대전 방지제를 포함하는 메탈로센 촉매 시스템 및 이를 이용한 폴리올레핀의 제조 방법
FR3039431B1 (fr) * 2015-07-29 2019-05-31 IFP Energies Nouvelles Nouvelle composition catalytique a base de nickel et d'un ligand de type phosphine complexe au nickel et son utilisation dans un procede d'oligomerisation des olefines
FR3042989A1 (fr) * 2015-10-30 2017-05-05 Ifp Energies Now Nouvelle composition catalytique a base de nickel en presence d'un activateur specifique et son utilisation dans un procede d'oligomerisation des olefines
FR3045414B1 (fr) * 2015-12-18 2019-12-27 IFP Energies Nouvelles Nouvelle composition catalytique a base de nickel et de ligand de type phosphine et d'une base de lewis et son utilisation dans un procede d'oligomerisation des olefines
CN108786919B (zh) * 2017-05-05 2020-07-21 中国石油化工股份有限公司 负载型茂金属催化剂及其制备方法和应用和丙烯酸甲酯的制备方法
CN108786918B (zh) * 2017-05-05 2020-07-24 中国石油化工股份有限公司 负载型茂金属催化剂及其制备方法和应用和丙烯酸甲酯的制备方法
US11161922B2 (en) 2017-10-31 2021-11-02 Exxonmobil Chemical Patents Inc. Toluene free silica supported single-site metallocene catalysts from in-situ supported MAO formation in aliphatic solvents
WO2019089145A1 (en) 2017-10-31 2019-05-09 Exxonmobil Chemical Patents Inc. Toluene free silica supported single-site metallocene catalysts from in-situ supported alumoxane formation in aliphatic solvents
KR102301666B1 (ko) * 2017-12-22 2021-09-14 주식회사 엘지화학 혼성 담지 메탈로센 촉매의 제조 방법, 상기 제조 방법으로 제조된 혼성 담지 메탈로센 촉매, 및 이를 이용하는 폴리올레핀의 제조 방법
KR102431269B1 (ko) 2018-11-02 2022-08-10 주식회사 엘지화학 신규 전이금속 화합물 및 이를 이용한 폴리프로필렌의 제조방법
US11352375B2 (en) 2018-12-28 2022-06-07 Braskem S.A. Auxiliaries for olefin polymerization process
US11866522B2 (en) 2018-12-28 2024-01-09 Braskem S.A. Process for introducing catalyst in a polymerization process
CN115368490B (zh) * 2021-05-20 2023-11-28 中国科学技术大学 硼烷助催化剂、合成方法及其应用

Family Cites Families (86)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3127133A1 (de) 1981-07-09 1983-01-27 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von polyolefinen und deren copolymerisaten
US5324800A (en) 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
US4937299A (en) 1983-06-06 1990-06-26 Exxon Research & Engineering Company Process and catalyst for producing reactor blend polyolefins
US4530914A (en) 1983-06-06 1985-07-23 Exxon Research & Engineering Co. Process and catalyst for producing polyethylene having a broad molecular weight distribution
DE3508887A1 (de) 1985-03-13 1986-09-25 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von optisch aktiven polyolefinen
US4808561A (en) 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4752597A (en) 1985-12-12 1988-06-21 Exxon Chemical Patents Inc. New polymerization catalyst
US5384299A (en) 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
EP0284708B1 (en) 1987-04-03 1996-01-31 Fina Technology, Inc. Metallocene catalyst systems for olefin polymerization having a silicon hydrocarbyl bridge.
DE3726067A1 (de) 1987-08-06 1989-02-16 Hoechst Ag Verfahren zur herstellung von 1-olefinpolymeren
US4931417A (en) 1987-11-09 1990-06-05 Chisso Corporation Transition-metal compound having a bis-substituted-cyclopentadienyl ligand of bridged structure
DE3742934A1 (de) 1987-12-18 1989-06-29 Hoechst Ag Verfahren zur herstellung einer chiralen, stereorigiden metallocen-verbindung
DE3808268A1 (de) 1988-03-12 1989-09-21 Hoechst Ag Verfahren zur herstellung eines 1-olefinpolymers
US5120867A (en) 1988-03-21 1992-06-09 Welborn Jr Howard C Silicon-bridged transition metal compounds
US5017714A (en) 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
US4871705A (en) 1988-06-16 1989-10-03 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst
DE3907964A1 (de) 1989-03-11 1990-09-13 Hoechst Ag Verfahren zur herstellung eines syndiotaktischen polyolefins
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5057475A (en) 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5026798A (en) 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US5239022A (en) 1990-11-12 1993-08-24 Hoechst Aktiengesellschaft Process for the preparation of a syndiotactic polyolefin
EP0485823B1 (de) 1990-11-12 1995-03-08 Hoechst Aktiengesellschaft 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation
US5243001A (en) 1990-11-12 1993-09-07 Hoechst Aktiengesellschaft Process for the preparation of a high molecular weight olefin polymer
ES2090209T3 (es) 1990-11-12 1996-10-16 Hoechst Ag Metalocenos con ligandos basados en derivados de indenilo sustituidos en posicion 2, procedimiento para su preparacion y su empleo como catalizadores.
US5436305A (en) 1991-05-09 1995-07-25 Phillips Petroleum Company Organometallic fluorenyl compounds, preparation, and use
DE4120009A1 (de) 1991-06-18 1992-12-24 Basf Ag Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen
TW300901B (US07232869-20070619-C00011.png) 1991-08-26 1997-03-21 Hoechst Ag
DE59210001D1 (de) 1991-10-15 2005-02-17 Basell Polyolefine Gmbh Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden
TW309523B (US07232869-20070619-C00011.png) 1991-11-30 1997-07-01 Hoechst Ag
TW318184B (US07232869-20070619-C00011.png) 1991-11-30 1997-10-21 Hoechst Ag
US5932669A (en) 1991-11-30 1999-08-03 Targor Gmbh Metallocenes having benzo-fused indenyl derivatives as ligands, processes for their preparation and their use as catalysts
CA2084017C (en) 1991-11-30 2006-11-21 Jurgen Rohrmann Metallocenes having benzo-fused indenyl derivatives as ligands, processes for their preparation and their use as catalysts
US5830821A (en) 1991-11-30 1998-11-03 Targor Gmbh Process for olefin preparation using metallocenes having benzo-fused indenyl derivatives as ligands
US5350723A (en) 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
US5240894A (en) 1992-05-18 1993-08-31 Exxon Chemical Patents Inc. Method for making and using a supported metallocene catalyst system
ES2113900T3 (es) 1992-06-13 1998-05-16 Targor Gmbh Proceso para la preparacion de catalizadores de metalocenos quirales, puenteados del tipo bisindenilo.
TW294669B (US07232869-20070619-C00011.png) 1992-06-27 1997-01-01 Hoechst Ag
ATE177436T1 (de) 1992-08-15 1999-03-15 Targor Gmbh Verfahren zur herstellung von polyolefinen
JP3307704B2 (ja) 1993-02-19 2002-07-24 三菱化学株式会社 α‐オレフィン重合体の製造法
CA2125246C (en) 1993-06-07 2001-07-03 Junichi Imuta Transition metal compound and olefin polymerization catalyst using the same
EP0812854B2 (en) 1993-06-07 2011-04-20 Mitsui Chemicals, Inc. Novel transition metal compound, olefin polymerization catalyst comprising said compound, process for olefin polymerization using said catalyst and propylene homo- and copolymer
JP3423378B2 (ja) 1993-11-12 2003-07-07 三井化学株式会社 新規な遷移金属化合物および該遷移金属化合物からなるオレフィン重合用触媒成分、該オレフィン重合用触媒成分を含むオレフィン重合用触媒ならびにオレフィンの重合方法
DE4344688A1 (de) 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
DE4344689A1 (de) 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
EP0766700B1 (en) 1994-06-24 2000-01-19 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
US6124230A (en) 1995-07-13 2000-09-26 Exxon Chemical Patents, Inc. Polymerization catalyst systems, their production and use
US6140432A (en) 1995-07-13 2000-10-31 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
US5635437A (en) 1995-07-28 1997-06-03 Exxon Chemicals Patents, Inc. Method for preparing metallocene catalyst systems
DE19544828A1 (de) 1995-12-01 1997-06-05 Hoechst Ag Hochmolekulare Copolymere
US5678812A (en) * 1996-02-14 1997-10-21 R. R. Donnelley & Sons Company Bindery apparatus with gathering conveyors and a method of make-ready
JP2000513399A (ja) 1996-06-17 2000-10-10 エクソン・ケミカル・パテンツ・インク オレフィン重合用の混合遷移金属触媒系
DE69738304T2 (de) 1996-12-09 2008-09-18 Mitsubishi Chemical Corp. Katalysator zur Alpha-Olefinpolymerisation
US6255515B1 (en) 1997-01-21 2001-07-03 Mitsubishi Chemical Corporation Processes for producing silicon- or germanium-containing organic compound, transition metal complex, catalyst for polymerization of α-olefin and α-olefin polymer
DE19757563A1 (de) 1997-03-07 1999-07-08 Targor Gmbh Geträgertes Katalysatorsystem, Verfahren zur Herstellung und seine Verwendung zur Polymerisation von Olefinen
US6228795B1 (en) 1997-06-05 2001-05-08 Exxon Chemical Patents, Inc. Polymeric supported catalysts
ATE398635T1 (de) 1997-06-05 2008-07-15 Exxonmobil Chem Patents Inc Katalysator auf polymerträger zur polymerisation von olefinen
DE19733017A1 (de) * 1997-07-31 1999-02-04 Hoechst Ag Chemische Verbindung
DE19804970A1 (de) * 1998-02-07 1999-08-12 Aventis Res & Tech Gmbh & Co Katalysatorsystem
JP4116148B2 (ja) 1998-06-08 2008-07-09 三菱化学株式会社 新規な遷移金属化合物、オレフィン重合用触媒成分およびα−オレフィン重合体の製造方法
DE19903306A1 (de) 1999-01-28 2000-08-03 Targor Gmbh Organometallverbindung, Katalysatorsystem enthaltend diese Organometallverbindung und seine Verwendung
DE19962814A1 (de) * 1999-12-23 2001-06-28 Targor Gmbh Neues Katalysatorsystem und dessen Verwendung
EP1250365A2 (de) 1999-12-23 2002-10-23 Basell Polypropylen GmbH Übergangsmetallverbindung, ligandensystem, katalysatorsystem und seine verwendung zur polymerisation und copolymerisation von olefinen
US6376411B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380121B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380122B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380330B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380120B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6399723B1 (en) 2000-06-30 2002-06-04 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380334B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376410B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376409B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380123B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380124B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376407B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376412B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376413B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380331B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376627B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376408B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
SG96700A1 (en) * 2001-09-27 2003-06-16 Sumitomo Chemical Co Catalyst component for addition polymerization, process for producing catalyst for addition polymerization and process for producing addition polymer
WO2004007569A1 (en) * 2002-07-15 2004-01-22 Basell Polyolefine Gmbh Preparation of catalyst systems
AU2003257456A1 (en) * 2002-07-15 2004-02-02 Basell Polyolefine Gmbh Preparation of supported catalyst systems
SG130016A1 (en) * 2002-09-24 2007-03-20 Sumitomo Chemical Co Modified particle, catalyst component for addition polymerization, catalyst for addition polymerization and process for producing addition polymer
US7592402B2 (en) 2004-04-30 2009-09-22 Sumitomo Chemical Company, Limited Process for producing modified particle; carrier; catalyst component for addition polymerization; process for producing catalyst for addition polymerization; and process for producing addition polymer

Also Published As

Publication number Publication date
KR20080033906A (ko) 2008-04-17
EP1882000A1 (en) 2008-01-30
JP2008545821A (ja) 2008-12-18
KR101190758B1 (ko) 2012-10-12
WO2006124231A1 (en) 2006-11-23
US7232869B2 (en) 2007-06-19
BRPI0610163A2 (pt) 2010-06-01
US20060264587A1 (en) 2006-11-23
US20070249799A1 (en) 2007-10-25
CN101384624B (zh) 2012-07-04
CN101384624A (zh) 2009-03-11
TW200710110A (en) 2007-03-16
US7468416B2 (en) 2008-12-23
ATE462731T1 (de) 2010-04-15
EP1882000B1 (en) 2010-03-31
ES2342106T3 (es) 2010-07-01

Similar Documents

Publication Publication Date Title
ATE462731T1 (de) Katalysatorzusammensetzung zur olefinpolymerisierung
BRPI0518701B8 (pt) Processos para a preparação de um sistema catalisador e para a polimerização de olefinas
ATE516311T1 (de) Trialkylaluminium-behandelter träger
DE602004029975D1 (de) Geträgerter hybridmetallocenkatalysator, herstellungsverfahren dafür und verfahren zur herstellung von polyolefinen damit
DE602005002130D1 (de) Metallorganisches gerüstmaterial, herstellung und verwendung
EA200970605A1 (ru) Ингибиторы mapk/erk-киназ
CY1109568T1 (el) Ενωσεις βενζο(d)ισοξαζολ-3-υλαμινης και η χρησιμοποιηση τους σαν προσδεματα υποδοχεα βανιλλοειδων
ATE544788T1 (de) Verbesserte saure aktivator-träger und katalysatoren für die olefinpolymerisation
MX337111B (es) Activadores de catalitizador de aluminoxano que contienen agentes carbocationes y uso de los mismos en catalizadores de poliolefina.
WO2006110234A3 (en) Propylene polymer catalyst donor component
WO2006096621A3 (en) Propylene polymer catalyst donor component
TW200704651A (en) Process for production of propylene copolymers
DE502006006249D1 (de) Synthese von phenylsubstituierten polyfluoranthenen und ihre verwendung
BRPI0812645A2 (pt) "composição e processo para formar artigo curado por umidade"
MY160247A (en) Catalyst support used for olefin polymerization and preparing method and application thereof
WO2013048848A3 (en) Dynamic modulation of metallocene catalysts
TW200740874A (en) Palladium catalyzed polymerization reaction
UY28731A1 (es) Compuestos quimicos
EA201071434A1 (ru) Высокоактивные катализаторы циглера-натта, способ получения катализаторов и их использование
BRPI0512310A (pt) compostos quìmicos
NO20071630L (no) Fremgangsmate for telomerisering av ikke-sykliske olefiner
SG155162A1 (en) Catalyst system for olefin polymerization, its production and use
TW200745758A (en) Base soluble polymers for photoresist compositions
CO5611202A2 (es) Componente catalitico solido y sistema catalitico del tipo ziegler-natta, proceso para su preparacion y su uso en la polimerizacion de alqu-1-enos
TW200745185A (en) Catalyst composition comprising group 4 transition metal complexes and method for preparing polyolefin using the same

Legal Events

Date Code Title Description
8364 No opposition during term of opposition