DE60128938D1 - Zeolithe und deren verwendung - Google Patents

Zeolithe und deren verwendung

Info

Publication number
DE60128938D1
DE60128938D1 DE60128938T DE60128938T DE60128938D1 DE 60128938 D1 DE60128938 D1 DE 60128938D1 DE 60128938 T DE60128938 T DE 60128938T DE 60128938 T DE60128938 T DE 60128938T DE 60128938 D1 DE60128938 D1 DE 60128938D1
Authority
DE
Germany
Prior art keywords
zeolite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60128938T
Other languages
English (en)
Other versions
DE60128938T2 (de
Inventor
Rudolf A Overbeek
Der Puil Nelleke Van
Chuen Y Yeh
Lawrence L Murrell
Yun-Feng Chang
Philip Jay Angevine
Johannes Hendrik Koegler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lummus Technology LLC
Original Assignee
ABB Lummus Global Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=22913491&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE60128938(D1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by ABB Lummus Global Inc filed Critical ABB Lummus Global Inc
Application granted granted Critical
Publication of DE60128938D1 publication Critical patent/DE60128938D1/de
Publication of DE60128938T2 publication Critical patent/DE60128938T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/04—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof using at least one organic template directing agent, e.g. an ionic quaternary ammonium compound or an aminated compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C10G29/205—Organic compounds not containing metal atoms by reaction with hydrocarbons added to the hydrocarbon oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/60—Synthesis on support
    • B01J2229/64—Synthesis on support in or on refractory materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/05—Nuclear magnetic resonance [NMR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
DE60128938T 2000-10-20 2001-10-19 Zeolithe und deren verwendung Expired - Lifetime DE60128938T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US24211000P 2000-10-20 2000-10-20
US242110P 2000-10-20
PCT/US2001/049938 WO2002032812A2 (en) 2000-10-20 2001-10-19 Improved zeolites and molecular sieves and the use thereof

Publications (2)

Publication Number Publication Date
DE60128938D1 true DE60128938D1 (de) 2007-07-26
DE60128938T2 DE60128938T2 (de) 2008-02-21

Family

ID=22913491

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60128938T Expired - Lifetime DE60128938T2 (de) 2000-10-20 2001-10-19 Zeolithe und deren verwendung

Country Status (18)

Country Link
US (1) US6809055B2 (de)
EP (1) EP1328475B1 (de)
JP (1) JP4315679B2 (de)
KR (1) KR100776468B1 (de)
CN (2) CN1250453C (de)
AR (1) AR031026A1 (de)
AT (1) ATE364575T1 (de)
AU (1) AU2002232753A1 (de)
BR (1) BR0114699A (de)
CA (1) CA2426034C (de)
DE (1) DE60128938T2 (de)
DK (1) DK1328475T3 (de)
ES (1) ES2289007T3 (de)
MX (1) MXPA03003283A (de)
RU (1) RU2278818C2 (de)
SG (1) SG155033A1 (de)
WO (1) WO2002032812A2 (de)
ZA (1) ZA200302826B (de)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6844479B2 (en) * 2000-10-20 2005-01-18 Abb Lummus Global Inc. Alkylation process
US7098161B2 (en) * 2000-10-20 2006-08-29 Abb Lummus Global Inc. Method of treating zeolite
US7371910B2 (en) * 2000-10-20 2008-05-13 Lummus Technology Inc. Process for benzene alkylation and transalkylation of polyalkylated aromatics over improved zeolite beta catalyst
ATE345165T1 (de) * 2002-06-28 2006-12-15 Haldor Topsoe As Verwendung eines zeolith beta enthaltender katalysators in kohlenwasserstoffumwandlungsverfahren
US7985400B2 (en) * 2004-01-26 2011-07-26 Lummus Technology Inc. Method for making mesoporous or combined mesoporous and microporous inorganic oxides
EP1656993A1 (de) * 2004-11-03 2006-05-17 Albemarle Netherlands B.V. Alkylierungskatalysator, seine Herstellung und Verwendung
US7348465B2 (en) * 2005-02-08 2008-03-25 Shell Oil Company Selective alkylation of aromatic hydrocarbons
EP2035140A1 (de) 2006-05-08 2009-03-18 ExxonMobil Chemical Patents, Inc., A Corporation of the State of Delaware Verbesserte katalysatorzusammensetzung
US7919421B2 (en) * 2006-12-21 2011-04-05 Exxonmobil Chemical Patents Inc. Catalyst composition, the method of manufacturing and the process of use thereof in aromatics alkylation
US8314280B2 (en) * 2009-03-20 2012-11-20 Lummus Technology Inc. Process for the production of olefins
EP2540384B1 (de) 2010-02-25 2022-02-16 NGK Insulators, Ltd. Verfahren zur herstellung eines zeolith-films
CN101792153B (zh) * 2010-03-02 2012-03-07 黑龙江大学 硅镓酸盐分子筛Ga-ZSM-12的合成方法
DE102012006541A1 (de) * 2012-04-02 2013-10-02 Clariant Produkte (Deutschland) Gmbh Wasserstoffoxidationskatalysator, Verwendung desselben und Verfahren zur Wasserstoffrekombination
US9914672B2 (en) 2012-10-19 2018-03-13 Lummus Technology Inc. Conversion of alcohols to distillate fuels
KR102262349B1 (ko) * 2013-07-04 2021-06-08 토탈 리서치 앤드 테크놀로지 펠루이 기공성 물질에 침적된 소규모 분자체 결정을 포함하는 촉매 조성물
AU2017325716B2 (en) 2016-09-16 2020-01-30 Lummus Technology Llc Fluid catalytic cracking process and apparatus for maximizing light olefin yield and other applications
SG11201906864VA (en) 2017-02-28 2019-09-27 Exxonmobil Chemical Patents Inc Catalyst compositions and their use in aromatic alkylation processes
CN108218654A (zh) * 2018-02-12 2018-06-29 安徽海德化工科技有限公司 一种利用异丁醇制备异辛烷的方法
WO2020157216A1 (en) * 2019-01-31 2020-08-06 Basf Se Catalyzed process for the dimerization of alkenes
SG11202110638PA (en) 2019-04-03 2021-10-28 Lummus Technology Inc Staged fluid catalytic cracking processes incorporating a solids separation device for upgrading naphtha range material
WO2021003269A1 (en) 2019-07-02 2021-01-07 Lummus Technology Llc Fluid catalytic cracking processes and apparatus
WO2021011252A1 (en) 2019-07-15 2021-01-21 Lummus Technology Llc Fluid catalytic cracking process and apparatus for maximizing light olefin yield and other applications
CN112850739B (zh) * 2021-03-12 2023-07-25 许昌学院 一种大晶粒ltj沸石及其制备方法
CN113233950A (zh) * 2021-05-21 2021-08-10 重庆华峰化工有限公司 一种环己烯制备甲基环戊烯的方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4104294A (en) * 1977-11-10 1978-08-01 Union Carbide Corporation Crystalline silicates and method for preparing same
US4554145A (en) 1984-04-16 1985-11-19 Mobil Oil Corporation Preparation of crystalline silicate zeolite Beta
US4554185A (en) * 1984-05-15 1985-11-19 Marine Shield Corporation Anti-fouling coating composition, process for applying same and coating thereby obtained
US4994250A (en) * 1989-09-29 1991-02-19 Union Oil Company Of California Process for synthesizing a molecular sieve having the offretite structure and containing aluminum and gallium
US4746763A (en) * 1987-04-22 1988-05-24 Uop Inc. Process for producing aromatic compounds from C2 -C6 aliphatic hydrocarbons
US5258570A (en) 1988-03-30 1993-11-02 Uop Activated zeolite beta and its use for hydrocarbon conversion
US5116794A (en) * 1988-03-30 1992-05-26 Uop Method for enhancing the activity of zeolite beta
US4927525A (en) * 1988-08-30 1990-05-22 Mobil Oil Corporation Catalytic reforming with improved zeolite catalysts
FR2660578B1 (fr) 1990-04-09 1994-09-23 Elf Aquitaine Catalyseur a base d'une faujasite de haut rapport si:al de synthese et son application aux reactions de catalyse acide realisees sur des charges hydrocarbonees.
CN1041399C (zh) * 1994-12-30 1998-12-30 中国石油化工总公司 一种含稀土的结晶硅酸铝沸石
DE69706319T2 (de) * 1996-12-18 2002-05-16 Bp Corp. North America Inc., Chicago Verfahren zur herstellung eines gleichmässig imprägnierten extrudatkatalysators
US5895828A (en) * 1997-06-04 1999-04-20 Phillips Petroleum Company Hydrocarbon conversion catalyst composition and processes therefor and therewith
US6004527A (en) * 1997-09-29 1999-12-21 Abb Lummus Global Inc. Method for making molecular sieves and novel molecular sieve compositions
US6090991A (en) 1999-02-27 2000-07-18 Fina Technology, Inc. Gas phase alkylation method and catalyst

Also Published As

Publication number Publication date
EP1328475B1 (de) 2007-06-13
KR20040012674A (ko) 2004-02-11
MXPA03003283A (es) 2004-01-26
RU2278818C2 (ru) 2006-06-27
KR100776468B1 (ko) 2007-11-16
WO2002032812A3 (en) 2003-01-16
WO2002032812A2 (en) 2002-04-25
CN1501887A (zh) 2004-06-02
CA2426034C (en) 2008-02-19
CN100384730C (zh) 2008-04-30
SG155033A1 (en) 2009-09-30
CN1250453C (zh) 2006-04-12
BR0114699A (pt) 2003-11-18
AU2002232753A1 (en) 2002-04-29
ZA200302826B (en) 2004-07-12
EP1328475A2 (de) 2003-07-23
US20020111522A1 (en) 2002-08-15
CA2426034A1 (en) 2002-04-25
AR031026A1 (es) 2003-09-03
DE60128938T2 (de) 2008-02-21
US6809055B2 (en) 2004-10-26
JP4315679B2 (ja) 2009-08-19
JP2004511416A (ja) 2004-04-15
ES2289007T3 (es) 2008-02-01
DK1328475T3 (da) 2007-10-08
CN1830784A (zh) 2006-09-13
ATE364575T1 (de) 2007-07-15

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8363 Opposition against the patent