DE60014713D1 - Membranen aus pfropfpolymeren und ionenaustausch-membranen daraus - Google Patents

Membranen aus pfropfpolymeren und ionenaustausch-membranen daraus

Info

Publication number
DE60014713D1
DE60014713D1 DE60014713T DE60014713T DE60014713D1 DE 60014713 D1 DE60014713 D1 DE 60014713D1 DE 60014713 T DE60014713 T DE 60014713T DE 60014713 T DE60014713 T DE 60014713T DE 60014713 D1 DE60014713 D1 DE 60014713D1
Authority
DE
Germany
Prior art keywords
membranes
alpha
graft
graft polymers
beta
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE60014713T
Other languages
English (en)
Other versions
DE60014713T2 (de
Inventor
Charles Stone
E Steck
Biswajit Choudhury
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BDF IP Holdings Ltd
Original Assignee
Ballard Power Systems Inc
Siemens VDO Electric Drives Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ballard Power Systems Inc, Siemens VDO Electric Drives Inc filed Critical Ballard Power Systems Inc
Publication of DE60014713D1 publication Critical patent/DE60014713D1/de
Application granted granted Critical
Publication of DE60014713T2 publication Critical patent/DE60014713T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081After-treatment of organic or inorganic membranes
    • B01D67/0093Chemical modification
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081After-treatment of organic or inorganic membranes
    • B01D67/0093Chemical modification
    • B01D67/00931Chemical modification by introduction of specific groups after membrane formation, e.g. by grafting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06Organic material
    • B01D71/28Polymers of vinyl aromatic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06Organic material
    • B01D71/30Polyalkenyl halides
    • B01D71/32Polyalkenyl halides containing fluorine atoms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06Organic material
    • B01D71/30Polyalkenyl halides
    • B01D71/32Polyalkenyl halides containing fluorine atoms
    • B01D71/36Polytetrafluoroethene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06Organic material
    • B01D71/76Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74
    • B01D71/82Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74 characterised by the presence of specified groups, e.g. introduced by chemical after-treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20Manufacture of shaped structures of ion-exchange resins
    • C08J5/22Films, membranes or diaphragms
    • C08J5/2206Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218Synthetic macromolecular compounds
    • C08J5/2231Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2243Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231
    • C08J5/225Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231 containing fluorine
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/102Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/1039Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/1058Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties
    • H01M8/106Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties characterised by the chemical composition of the porous support
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/1069Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1086After-treatment of the membrane other than by polymerisation
    • H01M8/1088Chemical modification, e.g. sulfonation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2323/00Details relating to membrane preparation
    • B01D2323/38Graft polymerization
    • B01D2323/385Graft polymerization involving radiation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2327/18Homopolymers or copolymers of tetrafluoroethylene
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0065Solid electrolytes
    • H01M2300/0082Organic polymers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Sustainable Energy (AREA)
  • Sustainable Development (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transplantation (AREA)
  • Graft Or Block Polymers (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
DE60014713T 2000-02-14 2000-03-29 Membranen aus Pfropfpolymeren und Ionenaustauschmenbranen daraus Expired - Fee Related DE60014713T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US50376000A 2000-02-14 2000-02-14
US503760 2000-02-14
PCT/CA2000/000337 WO2001058576A1 (en) 2000-02-14 2000-03-29 Graft polymeric membranes and ion-exchange membranes formed therefrom

Publications (2)

Publication Number Publication Date
DE60014713D1 true DE60014713D1 (de) 2004-11-11
DE60014713T2 DE60014713T2 (de) 2005-10-13

Family

ID=24003391

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60014713T Expired - Fee Related DE60014713T2 (de) 2000-02-14 2000-03-29 Membranen aus Pfropfpolymeren und Ionenaustauschmenbranen daraus

Country Status (7)

Country Link
EP (1) EP1257348B1 (de)
JP (1) JP2003522224A (de)
AT (1) ATE278457T1 (de)
AU (1) AU2000234134A1 (de)
CA (1) CA2398836C (de)
DE (1) DE60014713T2 (de)
WO (1) WO2001058576A1 (de)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1137192C (zh) * 2001-05-11 2004-02-04 崔蔚 含无机纳米材料的有机复合材料、其制备方法及用途
CA2396166A1 (en) 2001-07-30 2003-01-30 Asahi Glass Engineering Co., Ltd. Anion exchanger and process for producing anion exchange membrane
CA2458630A1 (en) * 2001-08-27 2003-03-06 Ballard Power Systems Inc. Process for preparing graft copolymer membranes
US6828386B2 (en) * 2002-09-20 2004-12-07 Ballard Power Systems Inc. Process for preparing graft copolymers and membranes formed therefrom
DE112004001818T5 (de) 2003-09-29 2006-09-07 E.I. Du Pont De Nemours And Company, Wilmington Auf Basispolymere gepfropfte Trifluorstyrol enthaltende Verbindungen und ihre Verwendung als Polymer-Elektrolytmembranen
DE112004002849T5 (de) * 2004-05-07 2007-04-05 E.I. Du Pont De Nemours And Co., Wilmington Stabile Trifluorstyrolverbindungen und ihre Verwendung in Polymerelektrolytmembranen
US7829603B2 (en) 2004-05-07 2010-11-09 E.I. Du Pont De Nemours And Company Stable trifluorostyrene containing compounds grafted to base polymers, and their use as polymer electrolyte membranes
CN100412116C (zh) * 2005-02-07 2008-08-20 财团法人工业技术研究院 质子传导膜及其制法
JP5463506B2 (ja) 2005-03-16 2014-04-09 国立大学法人山口大学 グラフトポリマー、高分子電解質膜、これらの製造方法、及びそれを用いた燃料電池
WO2006102671A1 (en) * 2005-03-24 2006-09-28 E. I. Du Pont De Nemours And Company Process to prepare stable trifluorostyrene containing compounds grafted to base polymers using a solvent/water mixture
US20060264576A1 (en) * 2005-03-24 2006-11-23 Roelofs Mark G Process to prepare stable trifluorostyrene containing compounds grafted to base polymers
CN106994304B (zh) * 2017-05-08 2020-05-12 厦门大学 一种均相阳离子交换膜及其制备方法
JP2023554310A (ja) * 2020-12-11 2023-12-27 インテグリス・インコーポレーテッド 酸感受性溶媒のための膜

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4169023A (en) * 1974-02-04 1979-09-25 Tokuyama Soda Kabushiki Kaisha Electrolytic diaphragms, and method of electrolysis using the same
US4012303A (en) * 1974-12-23 1977-03-15 Hooker Chemicals & Plastics Corporation Trifluorostyrene sulfonic acid membranes
US4113922A (en) * 1974-12-23 1978-09-12 Hooker Chemicals & Plastics Corp. Trifluorostyrene sulfonic acid membranes
US5602185A (en) * 1993-09-21 1997-02-11 Ballard Power Systems Inc. Substituted trifluorostyrene compositions
US5422411A (en) * 1993-09-21 1995-06-06 Ballard Power Systems Inc. Trifluorostyrene and substituted trifluorostyrene copolymeric compositions and ion-exchange membranes formed therefrom
US6359019B1 (en) * 1997-11-12 2002-03-19 Ballard Power Systems Inc. Graft polymeric membranes and ion-exchange membranes formed therefrom

Also Published As

Publication number Publication date
EP1257348A1 (de) 2002-11-20
CA2398836A1 (en) 2001-08-16
CA2398836C (en) 2007-09-25
AU2000234134A1 (en) 2001-08-20
WO2001058576A1 (en) 2001-08-16
EP1257348B1 (de) 2004-10-06
DE60014713T2 (de) 2005-10-13
ATE278457T1 (de) 2004-10-15
JP2003522224A (ja) 2003-07-22

Similar Documents

Publication Publication Date Title
DE60014713D1 (de) Membranen aus pfropfpolymeren und ionenaustausch-membranen daraus
DE69803801D1 (de) Gepfropfte polymere membranen und daraus hergestellte ionenaustauscher membrane
DE69425503D1 (de) Trifluorostyrol und substituierte trifluorostyrol copolymere und daraus hergestellten ionenaustauschermembranen
WO2002093676A3 (en) Ion-exchange materials with improved ion conductivity
EP1091435A4 (de) Material für festen polyelektrolyten, geeignet für die verwendung in brennstoffzellen
ES555277A0 (es) Procedimiento de obtencion de una composicion de injerto para la liberacion controlada de macromoleculas
ATE215581T1 (de) Verbundmembranen
FR2360623B1 (de)
WO2000027513A3 (de) Polymerzusammensetzung, membran enthaltend diese, verfahren zu deren herstellung und deren verwendung
ATE431367T1 (de) Ein fluoriertes ionomeres vernetztes copolymer
EP1844090A4 (de) Neue protonenaustauschmembranen unter verwendung einer cycloadditionsreaktion zwischen azid- und alkinhaltigen komponenten
ATE400352T1 (de) Herstellung von polymergegenständen mit hydrophiler oberfläche
FI990324A0 (fi) Polymeerikalvo ja menetelmä sen valmistamiseksi
ATE409202T1 (de) Aromatisches nitril enthaltendes ionenleitendes sulfoniertes polymermaterial
ATE469936T1 (de) Modifiziertes polymer und modifizierte polymermembran
SG149827A1 (en) Ion conductive copolymers containing one or more hydrophobic oligomers
WO2000024796A8 (en) Novel ion-conducting materials suitable for use in electrochemical applications and methods related thereto
ES473406A1 (es) Procedimiento para la obtencion de copolimeros de acriloni- trilo conteniendo grupos sulfimida.
TW200604245A (en) Ion-conductive copolymers containing one or more ion-conducting oligomers
ATE463847T1 (de) Polymerelektrolytmembranen zur verwendung in brennstoffzellen
ATE411352T1 (de) Ionenleitende polymere und diese enthaltende membranen
DE69719560D1 (de) Polymerelektrolyt-membran-brennstoffzelle mit bipolarem platte mit polymeren angeformten vorsprüngen
WO2006047158A3 (en) Novel compositions of monomers, oligomers and polymers and methods for making the same
DE60218869D1 (de) Verfahren zur herstellung von pfropf-copolymer membranen
WO2002075835A3 (en) Polymer electrolyte membrane fuel cell

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8327 Change in the person/name/address of the patent owner

Owner name: BDF IP HOLDINGS LTD., VANCOUVER, BRITISH COLUM, CA

8339 Ceased/non-payment of the annual fee