DE59607205D1 - Verfahren zur Herstellung von stabilisierten Olefinpolymeren - Google Patents

Verfahren zur Herstellung von stabilisierten Olefinpolymeren

Info

Publication number
DE59607205D1
DE59607205D1 DE59607205T DE59607205T DE59607205D1 DE 59607205 D1 DE59607205 D1 DE 59607205D1 DE 59607205 T DE59607205 T DE 59607205T DE 59607205 T DE59607205 T DE 59607205T DE 59607205 D1 DE59607205 D1 DE 59607205D1
Authority
DE
Germany
Prior art keywords
preparation
olefin polymers
amt
pref
reached
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE59607205T
Other languages
German (de)
English (en)
Inventor
Dr Rotzinger
Thomas Schmutz
Martin Brunner
Werner Stauffer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba Spezialitaetenchemie Holding AG
Ciba SC Holding AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Spezialitaetenchemie Holding AG, Ciba SC Holding AG filed Critical Ciba Spezialitaetenchemie Holding AG
Application granted granted Critical
Publication of DE59607205D1 publication Critical patent/DE59607205D1/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/527—Cyclic esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Electrical Control Of Ignition Timing (AREA)
  • Valve Device For Special Equipments (AREA)
DE59607205T 1995-06-29 1996-06-18 Verfahren zur Herstellung von stabilisierten Olefinpolymeren Expired - Fee Related DE59607205D1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH191295 1995-06-29

Publications (1)

Publication Number Publication Date
DE59607205D1 true DE59607205D1 (de) 2001-08-09

Family

ID=4221505

Family Applications (1)

Application Number Title Priority Date Filing Date
DE59607205T Expired - Fee Related DE59607205D1 (de) 1995-06-29 1996-06-18 Verfahren zur Herstellung von stabilisierten Olefinpolymeren

Country Status (12)

Country Link
US (2) US5703149A (enExample)
EP (1) EP0755948B1 (enExample)
JP (1) JPH0912621A (enExample)
KR (1) KR100420981B1 (enExample)
AT (1) ATE202789T1 (enExample)
BR (1) BR9602944A (enExample)
CA (1) CA2180073A1 (enExample)
DE (1) DE59607205D1 (enExample)
ES (1) ES2159009T3 (enExample)
NO (1) NO311978B1 (enExample)
TW (1) TW338046B (enExample)
ZA (1) ZA965517B (enExample)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6593485B1 (en) 1994-10-06 2003-07-15 Clariant Finance (Bvi) Limited Stabilizer composition
BR9711653A (pt) 1996-09-04 1999-08-24 Dow Chemical Co Processo para inibir a deteriora-Æo em um pol¡mero composi-Æo e artigo desta
CA2237231C (en) 1998-05-08 2006-08-08 Nova Chemicals Ltd. Heterogeneous metallocene catalyst
NL1012219C2 (nl) * 1998-06-19 2000-04-13 Ciba Sc Holding Ag Werkwijze voor de polymersitie van overzadigde polyalkylpiperidinen.
IL133922A (en) * 1999-02-01 2005-03-20 Ciba Sc Holding Ag Compositions comprising polyolefins produced by polymerization over a metallocene catalyst and a stabilizer mixture and a method for stabilizing said polyolefins
DE10028432A1 (de) * 2000-06-13 2001-12-20 Basell Polyolefine Gmbh Auf calciniertes Hydrotalcit geträgerter Katalysatorfeststoff zur Olefinpolymerisation
US6518344B1 (en) * 2000-08-18 2003-02-11 Ferro Corporation Flame retarded polyolefin composition
US6747077B2 (en) 2000-10-17 2004-06-08 Ciba Specialty Chemicals Corporation Stabilized metallocene polypropylene
GB0111443D0 (en) 2001-05-10 2001-07-04 Borealis Tech Oy Olefin polymerisation process
US6767937B2 (en) * 2001-10-03 2004-07-27 Eastman Kodak Company Stabilizer system for polymer components of displays
US20050288510A1 (en) * 2002-08-07 2005-12-29 Dietmar Mader Beta-nucleating, light stabilizing agents for polypropylene
JP4866624B2 (ja) * 2005-03-09 2012-02-01 日本ポリプロ株式会社 オレフィン重合用固体触媒成分、オレフィン重合用触媒、およびこれを用いたポリオレフィンの製造方法
JP4969070B2 (ja) * 2005-03-11 2012-07-04 株式会社Ａｄｅｋａ 安定化されたポリマーの製造方法
EP1881012B1 (en) * 2005-05-12 2014-04-02 Japan Polypropylene Corporation Catalysts for olefin polymerization, process for production of the catalysts, and method for preservation thereof
US20070105992A1 (en) * 2005-11-07 2007-05-10 Hayder Zahalka Cycloalkyl phosphites as stabilizers for thermoplastic resins
JP5596327B2 (ja) * 2009-01-28 2014-09-24 株式会社Ａｄｅｋａ 食品・医療・水道用パイプ用途のポリオレフィン系樹脂組成物
JP5322681B2 (ja) * 2009-02-09 2013-10-23 株式会社Ａｄｅｋａ 安定化されたポリマーの製造方法
CN103210130A (zh) 2010-11-16 2013-07-17 株式会社Adeka 聚合物的长期稳定化方法以及无纺布、弹性体组合物的制造方法
KR101966269B1 (ko) 2011-03-02 2019-04-05 가부시키가이샤 아데카 라미네이트 필름 및 도장 부재용 수지 조성물의 제조 방법
JP2013199551A (ja) 2012-03-23 2013-10-03 Adeka Corp 家電材料用及び自動車内装材料用オレフィン樹脂組成物の製造方法
KR102064629B1 (ko) * 2012-04-27 2020-01-08 더블유.알. 그레이스 앤드 캄파니-콘. 활성제 조성물, 이들의 제조, 및 촉매에서 이들의 용도
CN105683278B (zh) 2013-10-21 2018-06-15 株式会社Adeka 经稳定化的聚合物的制造方法
US10934423B2 (en) 2017-07-06 2021-03-02 Basf Se Stabilized polyolefin compositions comprising benzofuranones and organophosphorus stabilizers
IL284165B2 (en) 2018-12-21 2026-04-01 Basf Se Polypropylene preparation
CN111423658A (zh) * 2020-04-10 2020-07-17 天津大学 一种极性翻转工况下聚丙烯电缆材料及其制备方法、用途
JP7553342B2 (ja) 2020-12-11 2024-09-18 日置電機株式会社 増幅回路及び測定装置

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4170589A (en) * 1978-02-22 1979-10-09 Union Carbide Corporation Catalytic polymerization of ethylene with supported chromium [II] catalyst in the presence of a phenolic antioxidant
AU555386B2 (en) * 1981-09-24 1986-09-25 Mobil Oil Corp. Organo-metallic-zeolite catalyst
IT1207491B (it) * 1985-01-30 1989-05-25 Himont Inc Procedimento per preparare polimeri olefinici, termicamente stabili.
US4659685A (en) * 1986-03-17 1987-04-21 The Dow Chemical Company Heterogeneous organometallic catalysts containing a supported titanium compound and at least one other supported organometallic compound
EP0672689A1 (en) * 1990-06-22 1995-09-20 Exxon Chemical Patents Inc. Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization
TW218884B (enExample) * 1991-05-01 1994-01-11 Mitsubishi Kakoki Kk
DE69224463T2 (de) * 1991-11-28 1998-07-09 Showa Denko Kk Neues Metallocen und Verfahren zur Herstellung von Polyolefinen unter Verwendung desselben
MX9207621A (es) * 1992-01-21 1993-07-01 Ciba Geigy Ag Nuevos bisfenolfosfitos de cicloalquilideno
FI112233B (fi) * 1992-04-01 2003-11-14 Basell Polyolefine Gmbh Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö
EP0578838A1 (en) * 1992-04-29 1994-01-19 Hoechst Aktiengesellschaft Olefin polymerization catalyst, process for its preparation, and its use
US5240894A (en) * 1992-05-18 1993-08-31 Exxon Chemical Patents Inc. Method for making and using a supported metallocene catalyst system
GB2276387B (en) * 1993-03-25 1996-10-02 Sandoz Ltd Stabilizing polyolefins with phosphorus compounds
AU6596694A (en) * 1993-06-28 1995-01-05 Union Carbide Chemicals & Plastics Technology Corporation Use of lewis bases for activity reduction in metallocene catalyzed olefin polymerization process
IT1264946B1 (it) * 1993-07-16 1996-10-17 Ciba Geigy Spa Derivati del 2,2,6,6-tetrametil-4-piperidinolo utili come stabilizzanti alla luce ed all'ossidazione per materiali organici.
EP0644206B1 (en) * 1993-09-16 1997-12-29 Showa Denko Kabushiki Kaisha Olefin polymerization catalyst and process for preparing polyolefin
WO1996004318A1 (en) * 1994-08-05 1996-02-15 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
WO1996013531A1 (en) * 1994-10-31 1996-05-09 W.R. Grace & Co.-Conn. Preparation of modified polyolefin catalysts and in situ preparation of supported metallocene and ziegler-natta/metallocene polyolefin catalysts

Also Published As

Publication number Publication date
US5955522A (en) 1999-09-21
KR970001382A (ko) 1997-01-24
ES2159009T3 (es) 2001-09-16
US5703149A (en) 1997-12-30
JPH0912621A (ja) 1997-01-14
ZA965517B (en) 1996-12-30
EP0755948A3 (de) 1998-01-07
NO962762D0 (no) 1996-06-28
ATE202789T1 (de) 2001-07-15
EP0755948B1 (de) 2001-07-04
NO311978B1 (no) 2002-02-25
NO962762L (no) 1996-12-30
CA2180073A1 (en) 1996-12-30
TW338046B (en) 1998-08-11
EP0755948A2 (de) 1997-01-29
BR9602944A (pt) 1998-04-28
KR100420981B1 (ko) 2004-07-15

Similar Documents

Publication Publication Date Title
ATE202789T1 (de) Verfahren zur herstellung von stabilisierten olefinpolymeren
DE59409990D1 (de) Verfahren zur Herstellung von Polyolefinen
DE68911812D1 (de) Katalysatorbestandteil für Olefinpolymerisation, Verfahren zur Herstellung davon, Olefinpolymerisationskatalysator und Verfahren zur Polymerisation von Olefinen.
ATE169612T1 (de) Verfahren zur herstellung von essigsäure
DE69423237D1 (de) Verfahren zur herstellung eines katalysators für die polymerisation von olefinen
ATE179177T1 (de) Verfahren zur herstellung einer verbrückten metallocenverbindung und einer katalysatorkomponente sowie verfahren für die polymerisation von olefinen
ATE258194T1 (de) Katalysatorsysteme und verfahren zur herstellung von polyolefinen mit breiter molekulargewichtverteilung
EP0611772A3 (en) Catalyst component for alpha-olefin polymerization and process for producing alpha-olefin polymers using the same.
EP0611773A3 (en) Catalyst component for alpha-olefin polymerization and process for producing alpha-olefin polymers using the same.
DE68913226D1 (de) Verfahren zur Herstellung von Ethylenpolymeren.
ATE129257T1 (de) Verfahren zur herstellung von homopolymerisaten des propylens mit breitem molmassenverhältnis.
DE69617981D1 (de) Verfahren zur herstellung einer festen titankatalysatorkomponente zur polymerisation von olefinen sowie verfahren zur herstellung von polyolefinen
DE69606530D1 (de) Verfahren zur herstellung von lldpe polymeren
EP0589350A3 (de) Verfahren zur Herstellung eines Trägerkatalysators für die Polymerisation von a-Olefinen.
DE69109500D1 (de) Verfahren zur Herstellung einer Stryrolpolymerzusammensetzung.
DE69217327D1 (de) Mittel zur Verhinderung von Polymerverkrustung, Polymerisationsgefäss, in dem die Verkrustung vermieden wird und Verfahren zur Herstellung von Polymeren unter Benutzung dieses Gefässes
ATE166077T1 (de) Metallocen(co)polymere, verfahren zu ihrer herstellung und ihre verwendung als katalysatoren; metallocene hierfür.
ATE528327T1 (de) Verfahren zur polymerisierung von olefine.
DE3773795D1 (de) Verfahren zur herstellung von amorphen alpha-olefin-polymeren.
ATE159269T1 (de) Verfahren zur herstellung von polymeren basierend auf kohlenmonoxyd und olefinen
DE50112718D1 (de) Verfahren zur herstellung von übergangsmetallverbindungen und deren verwendung zur polymerisation von olefinen
ATE169307T1 (de) Verfahren zur herstellung eines ziegler-natta- katalysators
DE69407522D1 (de) Katalysator zur Polymerisation von Olefin und Verfahren zur Herstellung von Polyolefin
DE69410757D1 (de) Alphaolefinpolymere, Katalysator zur Alphaolefinpolymeristation und Verfahren zur Herstellung von Alphaolefinpolymeren
ATE175682T1 (de) Katalysatorkomponente für olefinpolymerisation, verfahren zur deren herstellung und verfahren zur polymerisation von olefinen unter anwendung derselben

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee