ATE202789T1 - Verfahren zur herstellung von stabilisierten olefinpolymeren - Google Patents

Verfahren zur herstellung von stabilisierten olefinpolymeren

Info

Publication number
ATE202789T1
ATE202789T1 AT96810404T AT96810404T ATE202789T1 AT E202789 T1 ATE202789 T1 AT E202789T1 AT 96810404 T AT96810404 T AT 96810404T AT 96810404 T AT96810404 T AT 96810404T AT E202789 T1 ATE202789 T1 AT E202789T1
Authority
AT
Austria
Prior art keywords
olefin polymers
producing stabilized
stabilized olefin
amt
pref
Prior art date
Application number
AT96810404T
Other languages
German (de)
English (en)
Inventor
Bruno Dr Rotzinger
Thomas Schmutz
Martin Brunner
Werner Stauffer
Original Assignee
Ciba Sc Holding Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Sc Holding Ag filed Critical Ciba Sc Holding Ag
Application granted granted Critical
Publication of ATE202789T1 publication Critical patent/ATE202789T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/527—Cyclic esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Valve Device For Special Equipments (AREA)
  • Electrical Control Of Ignition Timing (AREA)
AT96810404T 1995-06-29 1996-06-18 Verfahren zur herstellung von stabilisierten olefinpolymeren ATE202789T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH191295 1995-06-29

Publications (1)

Publication Number Publication Date
ATE202789T1 true ATE202789T1 (de) 2001-07-15

Family

ID=4221505

Family Applications (1)

Application Number Title Priority Date Filing Date
AT96810404T ATE202789T1 (de) 1995-06-29 1996-06-18 Verfahren zur herstellung von stabilisierten olefinpolymeren

Country Status (12)

Country Link
US (2) US5703149A (enExample)
EP (1) EP0755948B1 (enExample)
JP (1) JPH0912621A (enExample)
KR (1) KR100420981B1 (enExample)
AT (1) ATE202789T1 (enExample)
BR (1) BR9602944A (enExample)
CA (1) CA2180073A1 (enExample)
DE (1) DE59607205D1 (enExample)
ES (1) ES2159009T3 (enExample)
NO (1) NO311978B1 (enExample)
TW (1) TW338046B (enExample)
ZA (1) ZA965517B (enExample)

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US6593485B1 (en) 1994-10-06 2003-07-15 Clariant Finance (Bvi) Limited Stabilizer composition
KR20000068400A (ko) * 1996-09-04 2000-11-25 그래햄 이. 테일러 폴리올레핀에 유리 라디칼 억제제를 혼입하여 열화를 억제하는방법
CA2237231C (en) 1998-05-08 2006-08-08 Nova Chemicals Ltd. Heterogeneous metallocene catalyst
NL1012219C2 (nl) * 1998-06-19 2000-04-13 Ciba Sc Holding Ag Werkwijze voor de polymersitie van overzadigde polyalkylpiperidinen.
IL133922A (en) * 1999-02-01 2005-03-20 Ciba Sc Holding Ag Compositions comprising polyolefins produced by polymerization over a metallocene catalyst and a stabilizer mixture and a method for stabilizing said polyolefins
DE10028432A1 (de) * 2000-06-13 2001-12-20 Basell Polyolefine Gmbh Auf calciniertes Hydrotalcit geträgerter Katalysatorfeststoff zur Olefinpolymerisation
US6518344B1 (en) * 2000-08-18 2003-02-11 Ferro Corporation Flame retarded polyolefin composition
ITMI20012085A1 (it) 2000-10-17 2003-04-09 Ciba Sc Holding Ag Polpropilene metallocene stabilizzato
GB0111443D0 (en) 2001-05-10 2001-07-04 Borealis Tech Oy Olefin polymerisation process
US6767937B2 (en) * 2001-10-03 2004-07-27 Eastman Kodak Company Stabilizer system for polymer components of displays
CA2491389A1 (en) * 2002-08-07 2004-02-19 Ciba Specialty Chemicals Holding Inc. Beta-nucleating, light stabilizing agents for polypropylene
JP4866624B2 (ja) * 2005-03-09 2012-02-01 日本ポリプロ株式会社 オレフィン重合用固体触媒成分、オレフィン重合用触媒、およびこれを用いたポリオレフィンの製造方法
JP4969070B2 (ja) * 2005-03-11 2012-07-04 株式会社Ａｄｅｋａ 安定化されたポリマーの製造方法
EP1881012B1 (en) * 2005-05-12 2014-04-02 Japan Polypropylene Corporation Catalysts for olefin polymerization, process for production of the catalysts, and method for preservation thereof
US20070105992A1 (en) * 2005-11-07 2007-05-10 Hayder Zahalka Cycloalkyl phosphites as stabilizers for thermoplastic resins
JP5596327B2 (ja) * 2009-01-28 2014-09-24 株式会社Ａｄｅｋａ 食品・医療・水道用パイプ用途のポリオレフィン系樹脂組成物
JP5322681B2 (ja) * 2009-02-09 2013-10-23 株式会社Ａｄｅｋａ 安定化されたポリマーの製造方法
KR102115865B1 (ko) 2010-11-16 2020-05-27 가부시키가이샤 아데카 폴리머의 장기 안정화 방법 및 부직포, 일래스터머 조성물의 제조 방법
JPWO2012117823A1 (ja) 2011-03-02 2014-07-07 株式会社Adeka ラミネートフィルムおよび塗装部材用樹脂組成物の製造方法
JP2013199551A (ja) 2012-03-23 2013-10-03 Adeka Corp 家電材料用及び自動車内装材料用オレフィン樹脂組成物の製造方法
ES2805782T3 (es) * 2012-04-27 2021-02-15 Grace W R & Co Composiciones de activador, su preparación y su uso en catalizadores
WO2015060257A1 (ja) 2013-10-21 2015-04-30 株式会社Adeka 安定化されたポリマーの製造方法
US10913841B2 (en) 2017-07-06 2021-02-09 Basf Se Stabilized polyolefin compositions comprising benzofuranones and hindered phenolic antioxidants
EP3898809B1 (en) * 2018-12-21 2025-11-12 Basf Se A polypropylene composition
CN111423658A (zh) * 2020-04-10 2020-07-17 天津大学 一种极性翻转工况下聚丙烯电缆材料及其制备方法、用途
JP7553342B2 (ja) 2020-12-11 2024-09-18 日置電機株式会社 増幅回路及び測定装置

Family Cites Families (17)

* Cited by examiner, † Cited by third party
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US4170589A (en) * 1978-02-22 1979-10-09 Union Carbide Corporation Catalytic polymerization of ethylene with supported chromium [II] catalyst in the presence of a phenolic antioxidant
AU555386B2 (en) * 1981-09-24 1986-09-25 Mobil Oil Corp. Organo-metallic-zeolite catalyst
IT1207491B (it) * 1985-01-30 1989-05-25 Himont Inc Procedimento per preparare polimeri olefinici, termicamente stabili.
US4659685A (en) * 1986-03-17 1987-04-21 The Dow Chemical Company Heterogeneous organometallic catalysts containing a supported titanium compound and at least one other supported organometallic compound
JP2954351B2 (ja) * 1990-06-22 1999-09-27 エクソン・ケミカル・パテンツ・インク オレフィン重合用のアルミニウムを含まないモノシクロペンタジエニルメタロセン触媒
TW218884B (enExample) * 1991-05-01 1994-01-11 Mitsubishi Kakoki Kk
DE69224463T2 (de) * 1991-11-28 1998-07-09 Showa Denko Kk Neues Metallocen und Verfahren zur Herstellung von Polyolefinen unter Verwendung desselben
MX9207621A (es) * 1992-01-21 1993-07-01 Ciba Geigy Ag Nuevos bisfenolfosfitos de cicloalquilideno
FI112233B (fi) * 1992-04-01 2003-11-14 Basell Polyolefine Gmbh Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö
EP0578838A1 (en) * 1992-04-29 1994-01-19 Hoechst Aktiengesellschaft Olefin polymerization catalyst, process for its preparation, and its use
US5240894A (en) * 1992-05-18 1993-08-31 Exxon Chemical Patents Inc. Method for making and using a supported metallocene catalyst system
GB2276387B (en) * 1993-03-25 1996-10-02 Sandoz Ltd Stabilizing polyolefins with phosphorus compounds
AU6596694A (en) * 1993-06-28 1995-01-05 Union Carbide Chemicals & Plastics Technology Corporation Use of lewis bases for activity reduction in metallocene catalyzed olefin polymerization process
IT1264946B1 (it) * 1993-07-16 1996-10-17 Ciba Geigy Spa Derivati del 2,2,6,6-tetrametil-4-piperidinolo utili come stabilizzanti alla luce ed all'ossidazione per materiali organici.
DE69407522T2 (de) * 1993-09-16 1998-05-14 Showa Denko Kk Katalysator zur Polymerisation von Olefin und Verfahren zur Herstellung von Polyolefin
WO1996004318A1 (en) * 1994-08-05 1996-02-15 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
WO1996013531A1 (en) * 1994-10-31 1996-05-09 W.R. Grace & Co.-Conn. Preparation of modified polyolefin catalysts and in situ preparation of supported metallocene and ziegler-natta/metallocene polyolefin catalysts

Also Published As

Publication number Publication date
EP0755948A3 (de) 1998-01-07
KR970001382A (ko) 1997-01-24
BR9602944A (pt) 1998-04-28
CA2180073A1 (en) 1996-12-30
DE59607205D1 (de) 2001-08-09
TW338046B (en) 1998-08-11
KR100420981B1 (ko) 2004-07-15
NO962762L (no) 1996-12-30
JPH0912621A (ja) 1997-01-14
US5703149A (en) 1997-12-30
NO311978B1 (no) 2002-02-25
EP0755948A2 (de) 1997-01-29
ZA965517B (en) 1996-12-30
ES2159009T3 (es) 2001-09-16
EP0755948B1 (de) 2001-07-04
US5955522A (en) 1999-09-21
NO962762D0 (no) 1996-06-28

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