DE482417C - Process for the production of a cleaning agent from soap and a fat solvent - Google Patents

Process for the production of a cleaning agent from soap and a fat solvent

Info

Publication number
DE482417C
DE482417C DEM80536D DEM0080536D DE482417C DE 482417 C DE482417 C DE 482417C DE M80536 D DEM80536 D DE M80536D DE M0080536 D DEM0080536 D DE M0080536D DE 482417 C DE482417 C DE 482417C
Authority
DE
Germany
Prior art keywords
soap
parts
production
cleaning agent
fat solvent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEM80536D
Other languages
German (de)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IND PROCESSES DEV Ltd
Original Assignee
IND PROCESSES DEV Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IND PROCESSES DEV Ltd filed Critical IND PROCESSES DEV Ltd
Application granted granted Critical
Publication of DE482417C publication Critical patent/DE482417C/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/06—Inorganic compounds
    • C11D9/18—Water-insoluble compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22—Organic compounds, e.g. vitamins
    • C11D9/24—Hydrocarbons
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
    • D06L1/02—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using organic solvents
    • D06L1/04—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using organic solvents combined with specific additives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Description

Die Erfindung betrifft die Herstellung von Reinigungsmassen, bei welchen einem Fettlösumgismittel Seife einverleibt wird. Bisher hat man zu diesem Zweck Seife mit verschiedenen Fettlösungsmitteln verwendet und gegebenenfalls verschiedene emulgierende Mittel benutzt. Man hat auch schon Reinigungsmittel aus Seife und hydrierten aromatischen Stoffen, wie Hydronaphthaline, vorgeschlagen, denen man gegebenenfalls auch Füllmittel, wie Wasserglas, Borax usw., zusetzte. The invention relates to the production of cleaning compositions in which a fat dissolving agent Soap is incorporated. So far, soap with various fat solvents has been used for this purpose optionally various emulsifying agents Funds used. There are also detergents made from soap and aromatic hydrogenated products Substances such as hydronaphthalenes, to which fillers such as water glass, borax, etc., were optionally added, have been proposed.

Es wurde nun gefunden, daß, wenn man der Seife hydrierte aromatische Fettlösungsmittel und ein natürliches kolloidales Silikat, wie Bentonit, welches die Formel H2Al2Si4O12 besitzt und an verschiedenen Stellen der Erde gefunden wird, einverleibt, man eine Reinigungsmasse erhält, die nicht nur waschende und fettlösende, sondern auch bleichende Wirkungen· hat. Dies rührt anscheinend davon her, daß das Bentonit katalytisch auf die aromatischen Kohlenwasserstoffe einwirkt und ihre Autoxydation bzw. die Bildung von Wasserstoffsuperoxyd auslöst. Die an sich bekannte Verwendung von koEoidalen Erdalkalisilikaten als Füllmittel für Seife kann hierbei außer Betracht bleiben, da dort die hydrierten aromatischen Kohlenwasserstoffe fehlen und daher die katalytische Wirkung nicht eintreten kann. Zweckmäßig benutzt man Fettiösuiiigsmittel mit einem Siedepunkt von mehr als ioo° C, wie Dekahydronaphthalin, Tetrahydroinaphthalin, Hexahydrobenzol usw. oder Emulsionen oder Gemische dieser Stoffe.It has now been found that if hydrogenated aromatic fat solvents and a natural colloidal silicate such as bentonite, which has the formula H 2 Al 2 Si 4 O 12 and is found in various parts of the world, are incorporated into the soap, a cleaning compound is obtained which not only has washing and degreasing, but also bleaching effects. This is apparently due to the fact that the bentonite has a catalytic effect on the aromatic hydrocarbons and triggers their autoxidation or the formation of hydrogen peroxide. The per se known use of KoEoidal alkaline earth metal silicates as a filler for soap can be disregarded here, since there the hydrogenated aromatic hydrocarbons are absent and therefore the catalytic effect cannot occur. It is expedient to use fatty solvents with a boiling point of more than 100 ° C., such as decahydronaphthalene, tetrahydroinaphthalene, hexahydrobenzene, etc., or emulsions or mixtures of these substances.

Man hat bereits eine Kombination von Seife, Kohlenwasserstoffen und kolloidalen Silikaten als Waschmittel vorgeschlagen. Nicht bekannt ist jedoch die Verwendung von Seife, hydrierten aromatischen Kohlenwasserstoffen und Bentonit, und die Erfindung ist in der Verwendung dieser Kombination als Waschmittel begründet, weil, wie bereits oben, ausgeführt, diese Kombination die überraschende Eigenschaft besitzt, dem Waschmittel außer der Waschwirkung noch eine starke Bleichwirkung zu erteilen.One already has a combination of soap, hydrocarbons and colloidal Suggested silicates as detergents. However, its use is not known of soap, hydrogenated aromatic hydrocarbons and bentonite, and the invention is justified in the use of this combination as a detergent because how already stated above, this combination has the surprising property that To give detergents a strong bleaching effect in addition to the washing effect.

Die Zusätze können in allen Mengenverhältnissen beigegeben werden, je nachdem man ein feistes Pulver, eine Paste oder eine dicke Emulsion erhalten will. Durch Zusatz von Borax wird die Struktur der Emulsion verbessert. Phenole und Alkohole können in bekannter Weise hinzugefügt werden. Das Resultat ist um so besser, wenn mehrere dieser Substanzen zugesetzt werden.The additives can be added in all proportions, depending on you want to get a thick powder, paste or thick emulsion. By addition borax improves the structure of the emulsion. Phenols and alcohols can be in can be added in a known manner. The result is so much the better if there are several of these Substances are added.

Beispiel 1example 1

30 Teile Fettsäure,30 parts of fatty acid,

25 Teile Dekahydroinaphthalin,25 parts of decahydroinaphthalene,

25 Teile Tetrahydronaphthaliin oder Tetrahydro- B-naphthol,25 parts of tetrahydronaphthalene or tetrahydro- B-naphthol,

ι Teil Phenol "öder Alkohol, ι Teil Bemtanit,
io Teile Wasser,ι part phenol "or alcohol, ι part bemtanite,
io parts of water,

8 Teile Natriumhydrat(spez. Gewicht 1,35), eine Spur eines Riechstoffes. Die verschiedenen Bestandteile werden in einem Mischapparat oder einer Mühle innig miteinander vermischt.8 parts of sodium hydrate (specific weight 1.35), a trace of a fragrance. The various components are in intimately mixed with one another in a mixer or a mill.

Beispiel 2Example 2

30 Teile harte Seife, 20 Teile Defcahydromaphthalin, 20 Teile Tetrahydrooaphthalin, 20 Teile Cyclohexanol, 2I/2 Teile dhloriiniertes Paraffin,30 parts of hard soap, 20 parts of defcahydromaphthalene, 20 parts of tetrahydrooaphthalene, 20 parts of cyclohexanol, 2I / 2 parts of chlorinated paraffin,

3 Teile Butylalkohol,3 parts butyl alcohol,

4 Teile Wasser,4 parts water,

Va Teil kolloidale Suspension von Ben- ao tonit,Va part of the colloidal suspension of Ben- ao tonite,

eine Spur von Terpinol.a trace of terpinol.

Die Bestandteile werden durch Umrühren in der Wärme innig miteinander vermischt.The components are intimately mixed with one another by stirring in the heat.

Beispiele von Fettsäuren, sulfonierten Ölen oder Sulfosäuren, welche man gleichfalls verwenden kann, sind Stearinsäure, Sulforicinölsiäure und Sulfoninaphthensäure.Examples of fatty acids, sulfonated oils or sulfonic acids, which are also used are stearic acid, sulforicinoleic acid and sulfoninaphthenic acid.

Claims (1)

Patentanspruch:Claim: Verfahren zur Herstellung eines Waschmittels aus Seife, Fettlösungsmitteln und kolloidalem Silikaten, dadurch gekennzeichnet, daß man als Fetüösungsmittel hydrierte aromatische Verbindungen, beispielsweise hydrierte Benzole oder hydrierte Naphthaline oder Naphthole, und als Silikat Bentonit verwendet.Process for the preparation of a detergent from soap, fat solvents and colloidal silicates, characterized in that the fat solvent is hydrogenated aromatic compounds, for example hydrogenated benzenes or hydrogenated naphthalenes or naphthols, and bentonite is used as a silicate.
DEM80536D 1922-11-14 1923-02-16 Process for the production of a cleaning agent from soap and a fat solvent Expired DE482417C (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3107822A GB215880A (en) 1922-11-14 1922-11-14 Improvements in or relating to agents or assistants for detersive, scouring, bleaching, dyeing and like operations

Publications (1)

Publication Number Publication Date
DE482417C true DE482417C (en) 1929-09-13

Family

ID=10317613

Family Applications (1)

Application Number Title Priority Date Filing Date
DEM80536D Expired DE482417C (en) 1922-11-14 1923-02-16 Process for the production of a cleaning agent from soap and a fat solvent

Country Status (2)

Country Link
DE (1) DE482417C (en)
GB (1) GB215880A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2433517A (en) * 1943-11-05 1947-12-30 Wyandotte Chemicals Corp Finish remover composition
US2531825A (en) * 1947-03-29 1950-11-28 Nat Lead Co Paint, varnish, and lacquer remover

Also Published As

Publication number Publication date
GB215880A (en) 1924-05-14

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