DE4102709C1 - Degreasing metal surfaces using aq. prepn. - contg. biologically degradable adducts of lower alkylene oxide(s), fatty alcohol(s) and cationic surfactants - Google Patents
Degreasing metal surfaces using aq. prepn. - contg. biologically degradable adducts of lower alkylene oxide(s), fatty alcohol(s) and cationic surfactantsInfo
- Publication number
- DE4102709C1 DE4102709C1 DE4102709A DE4102709A DE4102709C1 DE 4102709 C1 DE4102709 C1 DE 4102709C1 DE 4102709 A DE4102709 A DE 4102709A DE 4102709 A DE4102709 A DE 4102709A DE 4102709 C1 DE4102709 C1 DE 4102709C1
- Authority
- DE
- Germany
- Prior art keywords
- prepn
- metallic
- metal surfaces
- adducts
- fatty alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002184 metal Substances 0.000 title claims abstract description 17
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 17
- 150000002191 fatty alcohols Chemical class 0.000 title claims abstract description 8
- 125000002947 alkylene group Chemical group 0.000 title claims abstract description 5
- 238000005238 degreasing Methods 0.000 title claims description 12
- 239000003093 cationic surfactant Substances 0.000 title abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 5
- 239000010959 steel Substances 0.000 claims abstract description 5
- 229910021645 metal ion Inorganic materials 0.000 claims abstract description 4
- 238000000137 annealing Methods 0.000 claims abstract description 3
- 238000004140 cleaning Methods 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 11
- 239000000243 solution Substances 0.000 claims description 8
- 239000004094 surface-active agent Substances 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 7
- 239000008346 aqueous phase Substances 0.000 claims description 5
- -1 glycol ethers Chemical class 0.000 claims description 4
- 206010000496 acne Diseases 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 239000013527 degreasing agent Substances 0.000 claims description 3
- 150000001768 cations Chemical class 0.000 claims description 2
- 238000005237 degreasing agent Methods 0.000 claims description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 239000012459 cleaning agent Substances 0.000 claims 1
- 238000004064 recycling Methods 0.000 claims 1
- 238000002604 ultrasonography Methods 0.000 claims 1
- 238000005260 corrosion Methods 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 4
- 239000003112 inhibitor Substances 0.000 abstract description 3
- 239000008139 complexing agent Substances 0.000 abstract 1
- 150000002334 glycols Chemical class 0.000 abstract 1
- 239000004519 grease Substances 0.000 abstract 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 12
- 239000002736 nonionic surfactant Substances 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000008367 deionised water Substances 0.000 description 5
- 229910021641 deionized water Inorganic materials 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical class OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 150000002169 ethanolamines Chemical class 0.000 description 3
- 150000008282 halocarbons Chemical class 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 description 2
- 239000005711 Benzoic acid Chemical class 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- 235000010233 benzoic acid Nutrition 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical class OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 229920001983 poloxamer Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- GDXHBFHOEYVPED-UHFFFAOYSA-N 1-(2-butoxyethoxy)butane Chemical compound CCCCOCCOCCCC GDXHBFHOEYVPED-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 229920002257 Plurafac® Polymers 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 235000005505 Ziziphus oenoplia Nutrition 0.000 description 1
- 244000104547 Ziziphus oenoplia Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- HJMZMZRCABDKKV-UHFFFAOYSA-N carbonocyanidic acid Chemical compound OC(=O)C#N HJMZMZRCABDKKV-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 230000003467 diminishing effect Effects 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 239000004312 hexamethylene tetramine Substances 0.000 description 1
- 235000010299 hexamethylene tetramine Nutrition 0.000 description 1
- 238000011086 high cleaning Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- RJSZFSOFYVMDIC-UHFFFAOYSA-N tert-butyl n,n-dimethylcarbamate Chemical compound CN(C)C(=O)OC(C)(C)C RJSZFSOFYVMDIC-UHFFFAOYSA-N 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/24—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Detergent Compositions (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4102709A DE4102709C1 (en) | 1991-01-30 | 1991-01-30 | Degreasing metal surfaces using aq. prepn. - contg. biologically degradable adducts of lower alkylene oxide(s), fatty alcohol(s) and cationic surfactants |
| ITMI920066A IT1258774B (it) | 1991-01-30 | 1992-01-16 | Agente e metodo per il trattamento superficiale di metalli |
| AT0013992A AT403932B (de) | 1991-01-30 | 1992-01-29 | Mittel und verfahren zur oberflächenbehandlung von metallen |
| FR929200943A FR2672060B3 (fr) | 1991-01-30 | 1992-01-29 | Compositions aqueuses contenant notamment des produits d'addition d'oxydes d'alkylenes sur des alcools gras et leur procede d'utilisation pour le degraissage de metaux. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4102709A DE4102709C1 (en) | 1991-01-30 | 1991-01-30 | Degreasing metal surfaces using aq. prepn. - contg. biologically degradable adducts of lower alkylene oxide(s), fatty alcohol(s) and cationic surfactants |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE4102709C1 true DE4102709C1 (en) | 1992-07-30 |
Family
ID=6423993
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE4102709A Expired - Lifetime DE4102709C1 (en) | 1991-01-30 | 1991-01-30 | Degreasing metal surfaces using aq. prepn. - contg. biologically degradable adducts of lower alkylene oxide(s), fatty alcohol(s) and cationic surfactants |
Country Status (4)
| Country | Link |
|---|---|
| AT (1) | AT403932B (fr) |
| DE (1) | DE4102709C1 (fr) |
| FR (1) | FR2672060B3 (fr) |
| IT (1) | IT1258774B (fr) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0845025A1 (fr) * | 1995-07-25 | 1998-06-03 | Henkel Corporation | Composition et procede de degraissage de surfaces metalliques |
| FR2784390A1 (fr) * | 1998-10-09 | 2000-04-14 | Dehon Sa | Melange pour bain de preparation au sechage d'une piece mecanique et procede de sechage d'une piece mecanique a l'aide de ce melange |
| FR2784389A1 (fr) * | 1998-10-09 | 2000-04-14 | Dehon Sa | Melange pour bain de preparation au sechage d'une piece mecanique et procede de sechage d'une piece mecanique a l'aide de ce melange |
| EP1323817A1 (fr) * | 2001-12-24 | 2003-07-02 | Cognis Iberia, S.L. | Compositions cationiques de nettoyage de surfaces dures |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE69719422T2 (de) * | 1996-07-24 | 2003-10-02 | Sunstar Inc., Takatsuki | Waschmittelzusammensetzungen |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2712900A1 (de) * | 1977-03-24 | 1978-10-05 | Henkel Kgaa | Verfahren zur reinigung von metallen im spritzverfahren |
| US4174304A (en) * | 1975-08-01 | 1979-11-13 | Bullen Chemical Company Midwest, Inc. | Surfactant system |
| DE3208130A1 (de) * | 1982-03-06 | 1983-09-08 | Henkel KGaA, 4000 Düsseldorf | Spaltung von oel-in-wasser-emulsionen |
| DE3232915A1 (de) * | 1982-09-04 | 1984-03-08 | Bayer Ag, 5090 Leverkusen | Verfahren zur entfernung von oelen und fetten aus schuettguetern |
| DE3928604A1 (de) * | 1989-08-30 | 1991-03-07 | Henkel Kgaa | Verwendung ausgewaehlter gemische von polyglykolethern als schaumdrueckende zusaetze in schaumarmen reinigungsmitteln |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4725377A (en) * | 1985-11-15 | 1988-02-16 | Colgate-Palmolive Co. | Liquid dishwashing detergent composition for improved hand washing of dishes in cold water |
-
1991
- 1991-01-30 DE DE4102709A patent/DE4102709C1/de not_active Expired - Lifetime
-
1992
- 1992-01-16 IT ITMI920066A patent/IT1258774B/it active IP Right Grant
- 1992-01-29 FR FR929200943A patent/FR2672060B3/fr not_active Expired - Lifetime
- 1992-01-29 AT AT0013992A patent/AT403932B/de not_active IP Right Cessation
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4174304A (en) * | 1975-08-01 | 1979-11-13 | Bullen Chemical Company Midwest, Inc. | Surfactant system |
| DE2712900A1 (de) * | 1977-03-24 | 1978-10-05 | Henkel Kgaa | Verfahren zur reinigung von metallen im spritzverfahren |
| DE3208130A1 (de) * | 1982-03-06 | 1983-09-08 | Henkel KGaA, 4000 Düsseldorf | Spaltung von oel-in-wasser-emulsionen |
| DE3232915A1 (de) * | 1982-09-04 | 1984-03-08 | Bayer Ag, 5090 Leverkusen | Verfahren zur entfernung von oelen und fetten aus schuettguetern |
| DE3928604A1 (de) * | 1989-08-30 | 1991-03-07 | Henkel Kgaa | Verwendung ausgewaehlter gemische von polyglykolethern als schaumdrueckende zusaetze in schaumarmen reinigungsmitteln |
Non-Patent Citations (1)
| Title |
|---|
| Metalloberfläche 41/5(1987), S. 227-32 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0845025A1 (fr) * | 1995-07-25 | 1998-06-03 | Henkel Corporation | Composition et procede de degraissage de surfaces metalliques |
| EP0845025A4 (fr) * | 1995-07-25 | 2000-02-23 | Henkel Corp | Composition et procede de degraissage de surfaces metalliques |
| FR2784390A1 (fr) * | 1998-10-09 | 2000-04-14 | Dehon Sa | Melange pour bain de preparation au sechage d'une piece mecanique et procede de sechage d'une piece mecanique a l'aide de ce melange |
| FR2784389A1 (fr) * | 1998-10-09 | 2000-04-14 | Dehon Sa | Melange pour bain de preparation au sechage d'une piece mecanique et procede de sechage d'une piece mecanique a l'aide de ce melange |
| EP1323817A1 (fr) * | 2001-12-24 | 2003-07-02 | Cognis Iberia, S.L. | Compositions cationiques de nettoyage de surfaces dures |
Also Published As
| Publication number | Publication date |
|---|---|
| ITMI920066A0 (it) | 1992-01-16 |
| IT1258774B (it) | 1996-02-29 |
| FR2672060A1 (fr) | 1992-07-31 |
| FR2672060B3 (fr) | 1993-04-30 |
| ITMI920066A1 (it) | 1993-07-16 |
| AT403932B (de) | 1998-06-25 |
| ATA13992A (de) | 1997-11-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8100 | Publication of patent without earlier publication of application | ||
| D1 | Grant (no unexamined application published) patent law 81 | ||
| 8363 | Opposition against the patent | ||
| 8331 | Complete revocation |