DE4021865C2 - - Google Patents

Description

The invention relates to a method for composting from fall, according to the preamble of claim 1.

A method of this type is known from DE-PS 36 37 393. In this process, the hygienization of the compost is too waste can be improved.

The production of compost from municipal waste should basically have a killing effect for organisms close that diseases in plants, animals and humans can cause. This killing effect can be called "hygieni sation ". Because in cavities the in the container Waste to be brought in or waste mixtures climatic conditions gene can arise in which certain pathogens arise de Organisms should multiply quickly, those for waste treatment used procedures all necessary for "hygienization" Features.

Hygiene can be achieved through the following features: Climate control taking biological growth into account Curve; this is explained in DE-PS 36 37 393. Germ killing  through the influence of heat (see "Rubbish and Waste", K.H. Knoll, E. Schmidt-Verlag, 5th delivery 1965, chapter 5112, or D. Shrub, Chapter 5113). Germ killing by extreme climatic Changes between high and low humidity and promotion the formation of microorganisms that act hygienizing Metabolic products (e.g. phenols, cresols or alde hyde).

The pasteurization of sewage sludge has been around for a long time Time hot steam used (Rödiger, urban hygiene 1958 H 9 S 178). In horticultural companies, it is common that in Soil improvers for plant sub strate with hot steam to remove phytopathogenic to kill germs.

The above-mentioned measures for "sanitation" have so far been possible can only be adhered to securely in that the necessary Liche heat was supplied in the form of external heat energy. A The imperfect exception was composting Rent (cf. DE-OS 30 46 646) or in so-called red drums (see Dano biostabilizer composting plant Duisburg-Huckingen) or Red silos (cf. DE-OS 24 33 367), with a "largely" Hygiene should be achieved in that during the Rotte the wastes to be mixed several times to make the rotting material from the cooler zones in the - only certain - zones higher temperatures prevailing inside the compost clog. The measures required for this are very, however time consuming. Achieve that in practical composting operations The shortest hygienization times are 4 weeks pure rental process, two weeks for combined processes from rotting drums or rotting silos with subsequent rental rotting and a week at red silos with heat recovery from the Exhaust air to the fresh air.  

From DE-PS 32 04 471 is a method for aerobic decomposition known organic material with air supply, the extracted air (circulating air) with the required amount of Fresh air mixed and the mixed air the material of un ten is supplied.

In DE-AS 38 30 177 a method for composting or ganic waste described in rents, in which the min At least one lease of air extracted from the rest of the rents Pressure is supplied.

DE-OS 36 07 920 describes a method for composting of organic waste in two process stages, the Ab The second stage is the one intended for the first stage Fresh air is added.

From DE-OS 34 20 732 a hot rotting plant is known in which the excess amount of heat in a simple way can be dissipated that the circulating air via lines one Heat exchanger system is supplied in which the excess Heat is withdrawn and used for other purposes.

From DE-OS 29 44 519 it is known to also return air (Circulating air) into the reactor for aerobic composting ren.

DE-OS 28 10 911 describes a method for treating com Postable substances described in a rent, in which the surrendered gases at least partially returned to the rent will.

The object of the invention is in a method of  the specified way to sanitize the rotting material chen.

According to the invention, this object is achieved by the characterizing Features of claim 1 solved. With the air recirculation mode Hygenization of the rotting material after degradation of the biologically easier decomposable components of the waste and thus after the phase of the highest biological activity. The one from the pack Exhaust air that escapes becomes rotten good hygienic after degradation of the biodegradable Be parts of the falls were fed again. The procedure is in in a closed container. With air recirculation for the purpose of hygiene is after the phase of the highest biological activity started. This phase of at most biolo is the phase with the highest release of Metabolic products, especially the highest water vapor free settlement.

Advantageous further developments are in the dependent claims wrote.

The rotting material is preferably not rearranged.

The recirculation mode can be carried out several times or continuously will.

The present invention assumes that for the first time "perfect" hygienization in a closed (container) Rottesilo preferably without rearrangement and also in the Randzo  nen of the rotting material is achieved in a direct manner in that the exhaust air emerging from the rotting material is circulated becomes. The circulation of the exhaust air in the circuit preferably begins immediately after the phase of highest biological activity. This phase of the highest biological activity can be determined from the Steam release can be detected. This means that the Circulation of the exhaust air in the circuit after the phase with the highest steam release can begin. The one from the pack well escaping, steam-containing hot exhaust air is preferred se circulated several times in the cycle, so again to the rotting material guided. It is also possible to extract the fresh air to mix in air. The exhaust air is circulated through Blower powered by electrical power and / or photovoltaic can be driven electricity. A safe hygiene Sation is according to the inventive method in only one Day reachable. The hot steam-exhaust air mixture is over an air distribution system in the entire rotting mix so that all particles to be hygienized come into contact with it.

Another advantage of the method according to the invention is in that it is relatively quick to sanitize leads. The rotting material does not have to be removed from the composting container be removed; rather, the hygienization takes place in the same container ter instead. It is not necessary to rearrange the rotting material Lich. Hygiene is also carried out in the edges of the rotting mixed.

Another advantage of the operation of temporary exhaust air return leadership in air recirculation for hygienization is that that are toxic to many organisms in higher concentrations de Carbon dioxide first in the circulating air and then in Condensate is enriched. The pH value of the condensate from the Water vapor carried in the exhaust air drops, and that in the  Airborne odorants are carried - similar to one Suds washer - in the condensate on the surfaces of the waste parts fixed. If after the recirculation mode on drying with Fresh air is switched in the exiting exhaust air no more unpleasant smells.

A temperature increase on the surfaces of the waste parts is achieved in that the exhaust air is plentiful existing water vapor condenses on these surfaces. Hereby When circulating the air, the temperature rises at all with the Um air coming in contact so high that the as organisms classified as pathogenic are killed. This is particularly significant or advantageous when composting the organic matter mainly from woody fiber parts stand, which with decreasing water content a sinking heat conduction to have ability. The temperature increase described the surface of the waste parts is then particularly important. The Surface temperature of the waste parts follows the course of the Saturation curve of the "i-x diagram" for moist air.

After performing the recirculation mode for sanitation the moisture present in the rotting material due to fresh air leadership are removed. This process is in DE-PS 26 37 393. Then the composting by dry then brought to a standstill when it is biologically lighter degradable organic components of the waste are broken down have been and if the sanitation according to the invention by Exhaust air return has been carried out. It arises dry, biologically inactive and storable compost.

The after the recirculation mode for sanitation in the Rotting material (rotting mixture) can still contain free water by using those that still exist in the compost (compost mix)  Heat (condensation heat) can be evaporated. After implementation of the recirculation mode can in the exhaust air contained heat via an air-to-air heat exchanger can be transferred to the fresh air. Furthermore can after performing the recirculation mode Fresh air can be heated by another heat source.

Since in the course of the destruction of the majority of the organ during hygienization, the so-called "Biochemical oxyhydrogen reaction" (see "General Microbio logie ", Schlegel, Thieme-Verlag, 5th edition 1981, page 205, as well as the older, unpublished patent application P 39 35 249) caused heat development due to microbiological activity drops to a minimum, can or must Completion of the whole process most of the bio Water to be evaporated thermally removed from the rotting mixture (killed organisms can no longer evaporate heat to produce). Those in the rotting mix after hygienization free water is still available through economical use the amount of condensation heat still present in the rotting mixture, preferably with the help of a heat recovery direction, evaporates. As a result, the compost is rotted dries, biologically inactive and environmentally friendly (see also DE-PS 36 37 393).

Waste water, for example liquid manure and / or seepage, can be added to the compost water, preferably from biological processes will. The wastewater can pass through the tank once or be pumped several times. The waste water can on the walls of the Be be distributed and / or sprinkled. With the wastewater it is preferably nutrient-rich, external resulting wastewater. This can be on the walls of the container distributed and / or sprinkled over a large area.  

The compost or the compost-like one that emerged after the procedure had been carried out organic residual substance can be compacted, which is preferred happens under pressure. This compression serves as prevention of moisture penetration. It is the intrusion of Moisture from the ambient air and / or water ver prevents. This increases the shelf life. It is also possible, that the compost and / or the compost-like residual substance with is provided with a moisture-repellent covering. Also this improves the shelf life of the end product.

It is advantageous if the CO2 content during air recirculation is measured in the air and if the recirculation mode un is broken when the CO2 content reaches a certain limit exceeds. Instead, it is also possible to check the O2 content to measure and to interrupt the recirculation mode if the O2 Salary falls below a certain limit. Too high CO2 content or a too low O2 content can namely Endanger the feasibility of hygienization. The measurement of the The CO2 content or the O2 content can take place continuously. However, it is also possible that the measurement takes place at certain times stands. If the CO2 content is too high or too low recirculation mode is interrupted chen. Fresh air is then supplied. It is also possible, to reduce the recirculation mode in such a way that only one Part of the recirculated air is supplied and fresh air at the same time is mixed. The interruption of air recirculation can certain period of time. This period of time can, according to experience be determined. But it is also possible during the above-mentioned interruption of the recirculation mode continues Measure CO2 content and / or O2 content and with the recirculated air start operating again as soon as the CO2 content  has fallen below the further limit value and / or as soon as the O2 content has exceeded a certain additional limit.

An embodiment of the invention is described below described in detail in the accompanying drawing. In the drawing shows:

Fig. 1 shows the course of the temperature over time in a rotting container and

Fig. 2 is an ix diagram.

The waste rotting mixture is on an air-permeable surface of a closed rotting container piled up so that a air-permeable structure of the waste parts to be composted stands. After closing the filling opening of the rotting container or its filling openings, the process sequence is started tet. The oxygen required for aerobic degradation can be Fresh air supply or by supplying pure oxygen is successful Air transport is provided by one or more blowers, the Motors via solar power or via the usual mains connection or both are driven. The waste parts to be composted are the substrate on which the microorganisms live. It exists made from biodegradable and biodegradable Carbon dioxide-hydrogen compounds. The supply of Sauer Substance allows aerobic organisms (bacteria and fungi) to  dissolve the aforementioned connections and not only the to gain energy necessary for their own existence, but also as a result of a so-called "Biochemical oxyhydrogen reaction" (O + H2 = OH + H + Free Ener gie) release a resulting amount of thermal energy. The large amount of energy released in a very short time (57 Kcal / mol) minus those for the self-assembly of the microorganisms cells required amount of energy (4.8 Kcal / mol) leads to a Heat build-up and thus for steam formation in the microclimate. Because the heat can only be removed with a certain time delay, forms on the surfaces that delimit the microclimate room the colder surfaces by falling below the dew point sat, the temperature of which rises as the Body warmed below the surface.

The warming is naturally limited by the fact that the organisms themselves can only withstand certain temperatures can (desired prerequisite for hygienization). Without "External influence" they reduce their metabolism, hence the Release energy into the surrounding microclimate and secure it so their continued existence (e.g. spore formation).

Through controlled technical intervention, a constant material and generation change are maintained until the more readily available substrate is running out (end of technical regulated composting). Before this is completely used up, at the first signs of a decrease in metabolic intensity activity (exceeding the maxima in the metabolism pro product quantities) initiated the sanitation phase. Here are by circulating the air, the metabolic products in the circulating air flow jams. The water vapor returned to the red mixture was condensed s now also from those waste particles (especially in the Marginal zones of the compost mixture), which were previously characterized by biological  Hydrolysis with immediate heat dissipation only dried, however have not yet been sterilized. With moist heat one can faster and more effective disinfection than with dry heat. By falling below the dew point the surface of these waste parts increases here through transfer the temperature of the condensation energy now also above the temperature tolerable by pathogenic organisms. The organiz Men are now being killed. The duration of the exposure times of the hot, moist exhaust air / water vapor mixture on the patho organisms are generally based on those in the Expected mixture of pathogenic microorganisms, their The duration of the kill was determined scientifically (see pre mentioned literature reference "Rubbish and Waste").

When the sanitation is complete, Umluftbe switched to fresh air mode and the by Rückkon remaining residual moisture is discharged from the rotting material. During this phase, an air-to-air heat is first applied exchanger - correspond to the efficiency of the heat exchanger the - part of the slowly sinking exhaust air heat to the fresh air transfer. By adding another heat source, at for example a parallel operated silo silo, the end drying process can be accelerated. If the from the Rottegut discharged exhaust air has the same temperature as that fresh air supplied, the biodegradation is easy degradable organic waste components ended, and now The resulting "compost" is taken from the red silo.

The operation of the composting carried out in this way enables further towards the evaporation of nutrient-rich, externally falling waste water, for example manure or leachate from biological Processes. The liquids remain in circulation for as long pumped through the red silo and spread over a large area on the walls of the  Container (reactor) sprinkles until the water has evaporated. The nutrients and solids then remain biologically unreactive greedy, back in the compost.

Fig. 1 shows the temperature curves of a rotten body cross section. Curve 1 represents the exhaust air temperature, curve 2 the temperature prevailing in the top of the container, curve 3 the temperature prevailing in the center of the wall of the container, curve 4 the temperature prevailing in the center of the container, curve 5 the temperature on the wall of the container Container prevailing temperature and curve 6 the prevailing tempera ture at the bottom of the container. The time in days is plotted on the horizontal axis. The temperature is shown in ° C. From Fig. 1 it is apparent that even at the most critical point of the reactor, namely the bottom (curve or measurement point 6), the temperature of 60 ° C for several days can be exceeded time. From Fig. 1, which shows the sanitation phase, it is clear that this sanitation phase is actually feasible over four days. In practice, however, usually only three days are required, possibly even less.

The surface temperature of the waste parts follows the course of the saturation characteristic of the "ix diagram" for moist air in accordance with the illustration in FIG. 2. There, the heat content (enthalpy) i in kcal per kg of dry air is above the absolute humidity (water content) × applied in grams per kg dry air. The air temperature (dry thermometer) T is given in degrees C. A barometer reading of 760 mm Hg is assumed. The entered point A denotes the state of the exhaust air when it leaves the rotting mixture. The point B, which is also carried, denotes the state on the surface of the waste parts after the exhaust air impinges as recirculating air. At point A the temperature is 69 ° C. The enthalpy i is about 98.5 kcal / kg, the absolute humidity is about 132 g / kg.

At point B, the enthalpy i is also approximately 98.5 kcal / kg. The absolute humidity there is about 138 g / kg Temperature is 58 ° C.

The invention relates to a method and an apparatus for Partial disinfection when composting organic waste in an enclosed space with no movement of waste and up to the fringes. The composting is carried out according to the "general my growth curve of microorganisms on a food sub strat "(cf. DE-PS 36 37 393). It comes after the Reaching the highest metabolic intensity through heat build-up with moist heat from microbial metabolism almost to Standstill. The standstill of rotting can be achieved that the temperature in the rotting body up to the edge zones and up for the greatest possible killing of vegetative cells above 60 ° C increases. The damp heat will live to kill them the cells formed by storing and returning this heat becomes effective. The moist microbial The heat generated will cause the temperature to rise faster Rotting mix used. The one after killing vegetative cells in the rotting mixture remaining heat energy becomes Wasserver steaming and thus used to dry the rotting mixture. After killing vegetative cells, it is used for further drying and thus additional sterilization required thermal energy largely via suitable heat exchangers from the exhaust air transfer the supply air. This can cause additional heat sources be used. As an energy source for moving the air through the rotting mixture can use mains electricity and / or solar electricity will. Combustion heat, condensation can be used as thermal energy heat, geothermal and / or solar heat can be used. The compost Manufacture takes place using a control loop.

Claims (12)

1. A method for composting waste, in which the rotting is introduced well into a closed container and is broken down microbially with the supply of air and in which the exhaust air emerging from the rotting material is fed to the rotting material again (recirculation mode), characterized in that with the Recirculation mode to hygenize the rotting material after the biodegradable constituents of the waste have been broken down and thus after the phase of maximum biological activity is started. 2. The method according to claim 1, characterized in that the Rottengut is not shifted. 3. The method according to claim 1 or 2, characterized in that the recirculation mode is repeated several times or continuously to be led. 4. The method according to any one of the preceding claims, characterized characterized in that after the recirculation mode the moisture present in the rotting material due to fresh air leadership is removed. 5. The method according to any one of the preceding claims, characterized characterized in that after the recirculation mode Free water still present in the rotting material (rotting mixture)  quantity by using the heat still present in the rotting crop is evaporated. 6. The method according to any one of the preceding claims, characterized characterized in that after the recirculation mode the heat contained in the exhaust air via an air-to-air heat is transferred to the fresh air. 7. The method according to any one of the preceding claims, characterized characterized in that after the recirculation mode the fresh air is heated by another heat source. 8. The method according to any one of the preceding claims, characterized characterized in that the Rottegut waste water, in particular Liquid manure and / or leachate 9. The method according to claim 8, characterized in that the Waste water pumped through the tank one or more times becomes. 10. The method according to claim 8 or 9, characterized in that the waste water is distributed on the walls of the container. 11. The method according to any one of the preceding claims, characterized characterized in that ent after performing the method standing compost is compressed under pressure. 12. The method according to any one of the preceding claims, characterized characterized in that ent after performing the method standing compost with a moisture-repellent covering is provided.