DE3901062A1 - Carbon dioxide-absorbing composition - Google Patents
Carbon dioxide-absorbing compositionInfo
- Publication number
- DE3901062A1 DE3901062A1 DE3901062A DE3901062A DE3901062A1 DE 3901062 A1 DE3901062 A1 DE 3901062A1 DE 3901062 A DE3901062 A DE 3901062A DE 3901062 A DE3901062 A DE 3901062A DE 3901062 A1 DE3901062 A1 DE 3901062A1
- Authority
- DE
- Germany
- Prior art keywords
- heavy metal
- carbon dioxide
- calcium hydroxide
- mass according
- absorbing composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/62—Carbon oxides
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- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D9/00—Composition of chemical substances for use in breathing apparatus
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0222—Compounds of Mn, Re
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0225—Compounds of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt
- B01J20/0229—Compounds of Fe
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0233—Compounds of Cu, Ag, Au
- B01J20/0237—Compounds of Cu
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/024—Compounds of Zn, Cd, Hg
- B01J20/0244—Compounds of Zn
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0274—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
- B01J20/0288—Halides of compounds other than those provided for in B01J20/046
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0274—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
- B01J20/0296—Nitrates of compounds other than those provided for in B01J20/04
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/041—Oxides or hydroxides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3014—Kneading
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3028—Granulating, agglomerating or aggregating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/42—Materials comprising a mixture of inorganic materials
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Health & Medical Sciences (AREA)
- Pulmonology (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Gas Separation By Absorption (AREA)
Abstract
Description
Kohlendioxid-Absorptionsmassen auf der Basis von Calciumhydroxid werden in Sauerstoff-Kreislaufgeräten verwendet, um das exhalierte Kohlendioxid aus dem Atemkreislauf zu entfernen.Carbon dioxide absorption masses based on Calcium hydroxide are used in oxygen rebreathers used to remove the exhaled carbon dioxide Remove breathing circuit.
Ein solches Sauerstoff-Kreislaufgerät ist z. B. in der DE-PS 12 43 984 beschrieben.Such an oxygen cycle device is such. B. in the DE-PS 12 43 984 described.
Zu Beginn der Beatmung, wenn die Absorptionsmasse noch nicht durch die Reaktionswärme aufgeheizt ist, verläuft die Reaktion zwischen Calciumhydroxid und Kohlendioxid ziemlich träge. Dies kann bei Fluchtgeräten, die bereits sofort nach dem Anlegen sehr stark beatmet werden, zu einem anfänglichen Ansteigen der CO2-Konzentration im Atemkreislauf führen. Erst mit zunehmender Erwärmung der Absorptionsmasse geht die CO2-Konzentration wieder zurück. Dies kann jedoch, vor allem bei niedrigen Außentemperaturen, eine längere Zeit dauern. Erhöhte CO2-Konzentrationen in der Einatemluft bedeuten aber, vor allem unter einer Streßsituation während einer Flucht, eine Erschwernis der Atmung des Gerätträgers. Aus der DE-OS 23 16 214 ist ein Atemkalk bekannt, dem Glykol zugesetzt ist. Dieses Glykol dient in erster Linie dazu, der Austrocknung des Atemkalks entgegenzuwirken. Zusätzlich erhöht der Glykolzusatz die Reaktionsfähigkeit des Atemkalks bei Temperaturen unter 0°C. Bei höheren Temperaturen gibt es keinen Effekt hinsichtlich erhöhter Reaktionsgeschwindigkeit.At the beginning of ventilation, when the absorption mass has not yet been heated up by the heat of reaction, the reaction between calcium hydroxide and carbon dioxide is rather slow. This can lead to an initial increase in the CO 2 concentration in the breathing circuit in escape devices that are very heavily ventilated immediately after being put on. The CO 2 concentration only drops again as the absorption mass heats up. However, this can take a long time, especially when the outside temperature is low. Increased CO 2 concentrations in the inhaled air mean, especially under a stressful situation during an escape, an difficulty in breathing the device wearer. From DE-OS 23 16 214 a soda lime is known, the glycol is added. This glycol primarily serves to counteract the drying out of the soda lime. The addition of glycol increases the reactivity of the soda lime at temperatures below 0 ° C. At higher temperatures there is no effect regarding increased reaction speed.
Die vorliegende Erfindung hat zum Ziel, die Reaktionsfähigkeit des Calciumhydroxids so weit zu steigern, daß auch bei starker Beatmung kurz nach dem Anlegen des Fluchtgerätes sowohl bei niedrigen als auch bei höherer Umgebungstemperatur keine erhöhten CO2-Konzentrationen auftreten.The aim of the present invention is to increase the reactivity of the calcium hydroxide to such an extent that, even in the case of strong ventilation, shortly after the escape device is put on, there are no increased CO 2 concentrations either at low or at a higher ambient temperature.
Dieses Ziel wird dadurch erreicht, daß dem Calciumhydroxid 0,1 bis 10 Gew.-% eines Schwermetallsalzes und/oder eines Schwermetalloxids zugesetzt werden.This goal is achieved in that the Calcium hydroxide 0.1 to 10 wt .-% of one Heavy metal salt and / or a heavy metal oxide be added.
Die Schwermetalle wirken als Katalysator bei der Umsetzung von Calciumhydroxid mit Kohlendioxid und beschleunigen somit die Reaktion. Dies macht sich besonders bemerkbar, solange die Absorptionsmasse noch kalt ist. Sie verlieren ihre Wirksamkeit nicht, wenn die Absorptionsmasse durch Gebrauch erwärmt wird.The heavy metals act as a catalyst in the Implementation of calcium hydroxide with carbon dioxide and thus accelerate the reaction. This is clear particularly noticeable as long as the absorption mass is still there is cold. They don't lose their effectiveness, though the absorption mass is heated by use.
Als Schwermetalle können Kupfer, Zink, Mangan oder Eisen verwendet werden. Neben den Oxiden dieser Metalle sind ihre Chloride und Nitrate anwendbar.Copper, zinc, manganese or Iron can be used. In addition to the oxides of these Metals are their chlorides and nitrates.
Eine besonders gute Wirksamkeit wird erzielt, wenn man das Schwermetallsalz und/oder Schwermetalloxid dem Löschwasser beigibt, so daß es sich während des Löschvorgangs in das Calciumhydroxid einbauen kann.A particularly good effectiveness is achieved when one the heavy metal salt and / or heavy metal oxide Extinguishing water adds, so that it is during the Extinguishing process can build into the calcium hydroxide.
Die Erfindung soll in folgendem Beispiel erläutert werden:The invention is illustrated in the following example will:
20 g Kupferchlorid werden in 2 Litern Wasser gelöst. Zu der Lösung wird unter Rühren 1 kg Calciumoxid gegeben. Nach dem vollständigen Einrühren wird die gebildete viskose Masse noch 1 Stunde lang geknetet. Dann wird die Masse auf einem Pastengranulator zu Teilchen von 4-5 mm Durchmesser granuliert und auf einen Wassergehalt von 16% getrocknet.20 g of copper chloride are dissolved in 2 liters of water. 1 kg of calcium oxide is added to the solution with stirring given. After stirring in completely, the kneaded viscous mass formed for 1 hour. Then the mass is added to a paste granulator Granules of 4-5 mm in diameter and granulated dried a water content of 16%.
Claims (7)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3901062A DE3901062A1 (en) | 1989-01-16 | 1989-01-16 | Carbon dioxide-absorbing composition |
SE8903867A SE8903867L (en) | 1989-01-16 | 1989-11-17 | CARBON-absorption mass |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3901062A DE3901062A1 (en) | 1989-01-16 | 1989-01-16 | Carbon dioxide-absorbing composition |
Publications (1)
Publication Number | Publication Date |
---|---|
DE3901062A1 true DE3901062A1 (en) | 1990-07-26 |
Family
ID=6372150
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE3901062A Ceased DE3901062A1 (en) | 1989-01-16 | 1989-01-16 | Carbon dioxide-absorbing composition |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE3901062A1 (en) |
SE (1) | SE8903867L (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2764518A1 (en) * | 1997-06-17 | 1998-12-18 | App De Protection Soc Nouv | A new multi-purpose filter system |
DE102011015723A1 (en) * | 2011-03-31 | 2012-10-04 | Dräger Safety AG & Co. KGaA | Sorbent granules and process for producing sorbent granules |
DE102018008430A1 (en) | 2018-10-26 | 2020-04-30 | Dräger Safety AG & Co. KGaA | Absorbent composition, device containing the absorbent composition and method for depleting carbon dioxide from gas mixtures |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB509403A (en) * | 1937-05-08 | 1939-07-11 | Spolek | Improved potash cartridges for oxygen respirators and life-saving apparatus |
DE893752C (en) * | 1941-12-06 | 1953-10-19 | Draegerwerk Ag | Process for producing an acidic gas, in particular carbonic acid, absorbing mass |
DE3721317A1 (en) * | 1987-06-27 | 1989-01-05 | Hoelter Heinz | Process for the preparation of reactive calcium hydroxides for exhaust gas purification |
-
1989
- 1989-01-16 DE DE3901062A patent/DE3901062A1/en not_active Ceased
- 1989-11-17 SE SE8903867A patent/SE8903867L/en not_active Application Discontinuation
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB509403A (en) * | 1937-05-08 | 1939-07-11 | Spolek | Improved potash cartridges for oxygen respirators and life-saving apparatus |
DE893752C (en) * | 1941-12-06 | 1953-10-19 | Draegerwerk Ag | Process for producing an acidic gas, in particular carbonic acid, absorbing mass |
DE3721317A1 (en) * | 1987-06-27 | 1989-01-05 | Hoelter Heinz | Process for the preparation of reactive calcium hydroxides for exhaust gas purification |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2764518A1 (en) * | 1997-06-17 | 1998-12-18 | App De Protection Soc Nouv | A new multi-purpose filter system |
DE102011015723A1 (en) * | 2011-03-31 | 2012-10-04 | Dräger Safety AG & Co. KGaA | Sorbent granules and process for producing sorbent granules |
US9314653B2 (en) | 2011-03-31 | 2016-04-19 | Dräger Safety AG & Co. KGaA | Sorbing granular material and process for producing sorbing granular material |
DE102011015723B4 (en) | 2011-03-31 | 2019-09-26 | Dräger Safety AG & Co. KGaA | Sorbent granules, use and method of solidifying a sorbent granule |
DE102018008430A1 (en) | 2018-10-26 | 2020-04-30 | Dräger Safety AG & Co. KGaA | Absorbent composition, device containing the absorbent composition and method for depleting carbon dioxide from gas mixtures |
WO2020083655A1 (en) | 2018-10-26 | 2020-04-30 | Dräger Safety AG & Co. KGaA | Absorbent composition, device containing the absorbent composition and method for depleting carbon dioxide from gas mixtures |
Also Published As
Publication number | Publication date |
---|---|
SE8903867D0 (en) | 1989-11-17 |
SE8903867L (en) | 1990-07-17 |
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Legal Events
Date | Code | Title | Description |
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OM8 | Search report available as to paragraph 43 lit. 1 sentence 1 patent law | ||
8110 | Request for examination paragraph 44 | ||
8131 | Rejection |