DE3872531T2 - - Google Patents
Info
- Publication number
- DE3872531T2 DE3872531T2 DE88300317T DE3872531T DE3872531T2 DE 3872531 T2 DE3872531 T2 DE 3872531T2 DE 88300317 T DE88300317 T DE 88300317T DE 3872531 T DE3872531 T DE 3872531T DE 3872531 T2 DE3872531 T2 DE 3872531T2
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- reactor
- reaction
- fluidized bed
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 claims description 69
- 238000006243 chemical reaction Methods 0.000 claims description 63
- 238000000034 method Methods 0.000 claims description 52
- 230000008569 process Effects 0.000 claims description 48
- 150000001336 alkenes Chemical class 0.000 claims description 47
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 42
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 39
- 239000002245 particle Substances 0.000 claims description 35
- 239000010457 zeolite Substances 0.000 claims description 34
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 33
- 229930195733 hydrocarbon Natural products 0.000 claims description 27
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 26
- 150000002430 hydrocarbons Chemical class 0.000 claims description 26
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims description 26
- 229910021536 Zeolite Inorganic materials 0.000 claims description 24
- 239000001294 propane Substances 0.000 claims description 21
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 20
- 239000001282 iso-butane Substances 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 13
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 11
- 239000004215 Carbon black (E152) Substances 0.000 claims description 10
- 239000000377 silicon dioxide Substances 0.000 claims description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 9
- 239000011148 porous material Substances 0.000 claims description 9
- 125000001931 aliphatic group Chemical group 0.000 claims description 8
- 230000003197 catalytic effect Effects 0.000 claims description 8
- 239000010419 fine particle Substances 0.000 claims description 8
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 6
- 238000005336 cracking Methods 0.000 claims description 6
- 230000002378 acidificating effect Effects 0.000 claims description 5
- 239000013078 crystal Substances 0.000 claims description 4
- 229910052914 metal silicate Inorganic materials 0.000 claims description 2
- 230000036961 partial effect Effects 0.000 claims description 2
- 230000001172 regenerating effect Effects 0.000 claims 1
- 239000007789 gas Substances 0.000 description 45
- 239000000047 product Substances 0.000 description 27
- 238000004231 fluid catalytic cracking Methods 0.000 description 13
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 12
- 239000003502 gasoline Substances 0.000 description 11
- 239000001257 hydrogen Substances 0.000 description 9
- 229910052739 hydrogen Inorganic materials 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 238000005243 fluidization Methods 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 8
- 238000006384 oligomerization reaction Methods 0.000 description 8
- 239000007787 solid Substances 0.000 description 7
- 239000005977 Ethylene Substances 0.000 description 6
- 230000008901 benefit Effects 0.000 description 6
- 150000002431 hydrogen Chemical class 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 230000008929 regeneration Effects 0.000 description 6
- 238000011069 regeneration method Methods 0.000 description 6
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 6
- 239000006227 byproduct Substances 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 241000196324 Embryophyta Species 0.000 description 4
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 238000005984 hydrogenation reaction Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical class CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000007848 Bronsted acid Substances 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 229910000323 aluminium silicate Inorganic materials 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 239000012263 liquid product Substances 0.000 description 3
- 229910000510 noble metal Inorganic materials 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000006356 dehydrogenation reaction Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000005194 fractionation Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 239000003915 liquefied petroleum gas Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 150000005673 monoalkenes Chemical class 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 230000003606 oligomerizing effect Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 125000004817 pentamethylene group Chemical class [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 230000026676 system process Effects 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical class CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 1
- SJVBYRCSPVTWOL-UHFFFAOYSA-N C=CCC.CC(C)C.C=CC Chemical compound C=CCC.CC(C)C.C=CC SJVBYRCSPVTWOL-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical class CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000007171 acid catalysis Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 235000013844 butane Nutrition 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000012084 conversion product Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 230000004069 differentiation Effects 0.000 description 1
- 230000000447 dimerizing effect Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 125000004836 hexamethylene group Chemical class [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000013386 optimize process Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 238000005120 petroleum cracking Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 230000003716 rejuvenation Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00265—Part of all of the reactants being heated or cooled outside the reactor while recycling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1088—Olefins
- C10G2300/1092—C2-C4 olefins
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4081—Recycling aspects
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/30—Aromatics
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/40—Ethylene production
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/006,407 US4746762A (en) | 1985-01-17 | 1987-01-23 | Upgrading light olefins in a turbulent fluidized catalyst bed reactor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3872531D1 DE3872531D1 (de) | 1992-08-13 |
| DE3872531T2 true DE3872531T2 (enExample) | 1993-02-04 |
Family
ID=21720711
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE8888300317T Expired - Lifetime DE3872531D1 (de) | 1987-01-23 | 1988-01-15 | Verfahren zur verwertung von leichten olefinen in einem wirbelschichtreaktor mit katalysator. |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US4746762A (enExample) |
| EP (1) | EP0276095B1 (enExample) |
| JP (1) | JP2557440B2 (enExample) |
| CN (1) | CN1014400B (enExample) |
| AU (1) | AU613599B2 (enExample) |
| BR (1) | BR8800175A (enExample) |
| CA (1) | CA1279659C (enExample) |
| DE (1) | DE3872531D1 (enExample) |
| ES (1) | ES2041784T3 (enExample) |
| FI (1) | FI85691C (enExample) |
| MA (1) | MA21165A1 (enExample) |
| PH (1) | PH24511A (enExample) |
| PT (1) | PT86599B (enExample) |
| TR (1) | TR23518A (enExample) |
| ZA (1) | ZA88463B (enExample) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4899014A (en) * | 1985-05-14 | 1990-02-06 | Avidan Amos A | Upgrading propene-ethene mixtures in a turbulent fluidized catalyst bed reactor |
| US4754100A (en) * | 1986-03-28 | 1988-06-28 | Mobil Oil Corporation | Catalytic conversion of C3 aliphatics to higher hydrocarbons |
| US4873385A (en) * | 1987-01-23 | 1989-10-10 | Mobil Oil Corp. | Single zone oligomerization of lower olefins to distillate under low severity in a fluid bed with tailored activity |
| US4827069A (en) * | 1988-02-19 | 1989-05-02 | Mobil Oil Corporation | Upgrading light olefin fuel gas and catalytic reformate in a turbulent fluidized bed catalyst reactor |
| US4827046A (en) * | 1988-04-11 | 1989-05-02 | Mobil Oil Corporation | Extraction of crude methanol and conversion of raffinate |
| US4877921A (en) * | 1988-04-20 | 1989-10-31 | Harandi Mohsen N | Single zone oligomerization of olefins in a super-dense phase turbulent fluid bed |
| US4899015A (en) * | 1988-07-28 | 1990-02-06 | Mobil Oil Corp. | Process for olefins to gasoline conversion |
| US4873389A (en) * | 1988-08-04 | 1989-10-10 | Mobil Oil Corp. | Conversion of light olefins to gasoline using low-temperature catalyst regeneration |
| US5053570A (en) * | 1988-09-22 | 1991-10-01 | Mobil Oil Corporation | Fluid bed paraffin aromatization |
| US5034565A (en) * | 1988-09-26 | 1991-07-23 | Mobil Oil Corporation | Production of gasoline from light olefins in a fluidized catalyst reactor system |
| US4939314A (en) * | 1988-12-19 | 1990-07-03 | Mobil Oil Corporation | Method for on-stream low-pressure regeneration of an oligomerization catalyst from a fluid-bed reactor operating at high pressure with hydrocarbons in a non-liquid phase |
| US5012026A (en) * | 1989-02-14 | 1991-04-30 | Mobil Oil Corp. | Turbulent fluid bed paraffin conversion process |
| US5164071A (en) * | 1989-04-17 | 1992-11-17 | Mobil Oil Corporation | Fluidized catalyst process for upgrading olefins |
| US5059735A (en) * | 1989-05-04 | 1991-10-22 | Mobil Oil Corp. | Process for the production of light olefins from C5 + hydrocarbons |
| US4956509A (en) * | 1989-10-16 | 1990-09-11 | Mobil Oil Corp. | Integrated paraffin upgrading and catalytic cracking processes |
| US5043517A (en) * | 1989-10-30 | 1991-08-27 | Mobil Oil Corporation | Upgrading light olefin fuel gas in a fluidized bed catalyst reactor and regeneration of the catalyst |
| US5043499A (en) * | 1990-02-15 | 1991-08-27 | Mobil Oil Corporation | Fluid bed oligomerization of olefins |
| GB2250027A (en) * | 1990-07-02 | 1992-05-27 | Exxon Research Engineering Co | Process and apparatus for the simultaneous production of olefins and catalytically cracked hydrocarbon products |
| US5545788A (en) * | 1991-06-19 | 1996-08-13 | Mobil Oil Corporation | Process for the alkylation of benzene-rich reformate using MCM-49 |
| US5338436A (en) * | 1991-10-21 | 1994-08-16 | Mobil Oil Corp. | Dewaxing process |
| EP0757976A3 (en) * | 1992-01-30 | 1998-01-28 | Exxon Chemical Patents Inc. | Alkene oligomerisation with crystals of H-ZSM or ZSM catalysts |
| EP0688308B1 (en) * | 1993-03-08 | 2000-04-05 | Mobil Oil Corporation | Benzene reduction in gasoline by alkylation with higher olefins |
| US5401391A (en) * | 1993-03-08 | 1995-03-28 | Mobil Oil Corporation | Desulfurization of hydrocarbon streams |
| US5414172A (en) * | 1993-03-08 | 1995-05-09 | Mobil Oil Corporation | Naphtha upgrading |
| US5482617A (en) * | 1993-03-08 | 1996-01-09 | Mobil Oil Corporation | Desulfurization of hydrocarbon streams |
| EP0920911A1 (en) * | 1997-12-05 | 1999-06-09 | Fina Research S.A. | Production of catalysts for olefin conversion |
| EP1061117A1 (en) * | 1999-06-16 | 2000-12-20 | Fina Research S.A. | Production of olefins |
| US6391985B1 (en) | 1999-10-21 | 2002-05-21 | Union Carbide Chemicals & Plastics Technology Corporation | High condensing mode polyolefin production under turbulent conditions in a fluidized bed |
| US20030194356A1 (en) | 2002-04-11 | 2003-10-16 | Meier Paul F. | Desulfurization system with enhanced fluid/solids contacting |
| US20040031729A1 (en) * | 2002-08-16 | 2004-02-19 | Meier Paul F | Desulfurization system with enhanced fluid/solids contacting |
| EP1424318A1 (en) * | 2002-11-26 | 2004-06-02 | Akzo Nobel N.V. | Alkylation process using a reactor comprising multiple catalyst beds |
| US6759489B1 (en) | 2003-05-20 | 2004-07-06 | Eastern Petrochemical Co. | Fluidized bed methods for making polymers |
| US6800664B1 (en) | 2003-05-23 | 2004-10-05 | Conocophillips Company | Conjoined reactor system |
| US7790943B2 (en) * | 2006-06-27 | 2010-09-07 | Amt International, Inc. | Integrated process for removing benzene from gasoline and producing cyclohexane |
| WO2009029487A1 (en) | 2007-08-24 | 2009-03-05 | Dow Global Technologies, Inc. | Self-limiting catalyst system with controlled aluminum rto sca ratio and method |
| CN102186889B (zh) | 2008-08-21 | 2013-11-06 | 陶氏环球技术有限责任公司 | 具有混合的选择性控制剂的催化剂组合物和使用它的聚合反应方法 |
| US8395006B2 (en) * | 2009-03-13 | 2013-03-12 | Exxonmobil Research And Engineering Company | Process for making high octane gasoline with reduced benzene content by benzene alkylation at high benzene conversion |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3907663A (en) * | 1973-10-01 | 1975-09-23 | Mobil Oil Corp | Conversion of hydrocarbons |
| US4046825A (en) * | 1974-05-15 | 1977-09-06 | Mobil Oil Corporation | Conversion of oxygenated compounds to gasoline |
| US4090949A (en) * | 1974-07-31 | 1978-05-23 | Mobil Oil Corportion | Upgrading of olefinic gasoline with hydrogen contributors |
| US4138440A (en) * | 1974-08-14 | 1979-02-06 | Mobil Oil Corporation | Conversion of liquid alcohols and ethers with a fluid mass of ZSM-5 type catalyst |
| US3960978A (en) * | 1974-09-05 | 1976-06-01 | Mobil Oil Corporation | Converting low molecular weight olefins over zeolites |
| US4070411A (en) * | 1975-03-26 | 1978-01-24 | Mobil Oil Corporation | Conversion of lower olefins to isobutane |
| US4283273A (en) * | 1976-11-18 | 1981-08-11 | Mobil Oil Corporation | Method and system for regenerating fluidizable catalyst particles |
| US4100218A (en) * | 1977-05-31 | 1978-07-11 | Mobil Oil Corporation | Ethane conversion process |
| US4227992A (en) * | 1979-05-24 | 1980-10-14 | Mobil Oil Corporation | Process for separating ethylene from light olefin mixtures while producing both gasoline and fuel oil |
| US4254295A (en) * | 1979-12-05 | 1981-03-03 | Mobil Oil Corporation | Oligomerization of olefins |
| US4417087A (en) * | 1982-04-30 | 1983-11-22 | Chevron Research Company | Fluidized oligomerization |
| US4417086A (en) * | 1982-04-30 | 1983-11-22 | Chevron Research Company | Efficient fluidized oligomerization |
| EP0113180B1 (en) * | 1982-12-01 | 1989-03-08 | Mobil Oil Corporation | Catalytic conversion of light-olefinic feedstocks in a fluidized-catalytic-cracking gas plant |
| NL8301747A (nl) * | 1983-05-17 | 1984-12-17 | Shell Int Research | Werkwijze voor de bereiding van middeldestillaten. |
| JPH068255B2 (ja) * | 1983-08-01 | 1994-02-02 | 昭和シェル石油株式会社 | 低級炭化水素からの液状炭化水素の製法 |
| US4487985A (en) * | 1983-08-26 | 1984-12-11 | Mobil Oil Corporation | Catalytic conversion with catalyst regeneration sequence |
| US4511747A (en) * | 1984-02-01 | 1985-04-16 | Mobil Oil Corporation | Light olefin conversion to heavier hydrocarbons with sorption recovery of unreacted olefin vapor |
| GB2156381A (en) * | 1984-03-27 | 1985-10-09 | Broken Hill Pty Co Ltd | Production of kerosene and distillate |
| US4605807A (en) * | 1984-04-27 | 1986-08-12 | Atlantic Richfield Company | Process for catalytic conversion of ethylene to higher hydrocarbons |
| GB8429007D0 (en) * | 1984-11-16 | 1984-12-27 | British Petroleum Co Plc | Aromatics from ethane/ethylene |
| US4547616A (en) * | 1984-12-28 | 1985-10-15 | Mobil Oil Corporation | Conversion of oxygenates to lower olefins in a turbulent fluidized catalyst bed |
| US4689205A (en) * | 1985-05-14 | 1987-08-25 | Mobil Oil Corporation | Multi-stage system for converting oxygenates to liquid hydrocarbons with aliphatic recycle |
| US4543435A (en) * | 1985-01-17 | 1985-09-24 | Mobil Oil Corporation | Multistage process for converting oxygenates to liquid hydrocarbons with ethene recycle |
| US4579999A (en) * | 1985-01-17 | 1986-04-01 | Mobil Oil Corporation | Multistage process for converting oxygenates to liquid hydrocarbons with aliphatic recycle |
-
1987
- 1987-01-23 US US07/006,407 patent/US4746762A/en not_active Expired - Lifetime
-
1988
- 1988-01-06 AU AU10085/88A patent/AU613599B2/en not_active Expired
- 1988-01-15 ES ES198888300317T patent/ES2041784T3/es not_active Expired - Lifetime
- 1988-01-15 EP EP88300317A patent/EP0276095B1/en not_active Expired - Lifetime
- 1988-01-15 DE DE8888300317T patent/DE3872531D1/de not_active Expired - Lifetime
- 1988-01-20 BR BR8800175A patent/BR8800175A/pt unknown
- 1988-01-21 CA CA000557017A patent/CA1279659C/en not_active Expired - Lifetime
- 1988-01-22 PT PT86599A patent/PT86599B/pt not_active IP Right Cessation
- 1988-01-22 JP JP63011021A patent/JP2557440B2/ja not_active Expired - Lifetime
- 1988-01-22 ZA ZA88463A patent/ZA88463B/xx unknown
- 1988-01-22 PH PH36384A patent/PH24511A/en unknown
- 1988-01-22 FI FI880310A patent/FI85691C/fi not_active IP Right Cessation
- 1988-01-22 TR TR56/88A patent/TR23518A/xx unknown
- 1988-01-22 MA MA21402A patent/MA21165A1/fr unknown
- 1988-01-23 CN CN88100267A patent/CN1014400B/zh not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| PT86599A (pt) | 1988-02-01 |
| AU613599B2 (en) | 1991-08-08 |
| FI880310A0 (fi) | 1988-01-22 |
| CN1014400B (zh) | 1991-10-23 |
| EP0276095B1 (en) | 1992-07-08 |
| DE3872531D1 (de) | 1992-08-13 |
| BR8800175A (pt) | 1988-08-30 |
| PH24511A (en) | 1990-07-18 |
| MA21165A1 (fr) | 1988-10-01 |
| JPS63225694A (ja) | 1988-09-20 |
| PT86599B (pt) | 1991-12-31 |
| FI85691C (fi) | 1992-05-25 |
| AU1008588A (en) | 1988-07-28 |
| FI85691B (fi) | 1992-02-14 |
| CN88100267A (zh) | 1988-12-21 |
| US4746762A (en) | 1988-05-24 |
| JP2557440B2 (ja) | 1996-11-27 |
| ZA88463B (en) | 1989-09-27 |
| FI880310A7 (fi) | 1988-07-24 |
| ES2041784T3 (es) | 1993-12-01 |
| CA1279659C (en) | 1991-01-29 |
| EP0276095A1 (en) | 1988-07-27 |
| TR23518A (tr) | 1990-03-01 |
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