ES2041784T3 - Procedimiento para revalorizar olefinas ligeras en un reactor con lecho catalizador fluidizado turbulento. - Google Patents

Procedimiento para revalorizar olefinas ligeras en un reactor con lecho catalizador fluidizado turbulento.

Info

Publication number
ES2041784T3
ES2041784T3 ES198888300317T ES88300317T ES2041784T3 ES 2041784 T3 ES2041784 T3 ES 2041784T3 ES 198888300317 T ES198888300317 T ES 198888300317T ES 88300317 T ES88300317 T ES 88300317T ES 2041784 T3 ES2041784 T3 ES 2041784T3
Authority
ES
Spain
Prior art keywords
approximately
microns
bed
reactor
procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES198888300317T
Other languages
English (en)
Inventor
Amos Andrew Avidan
Tai-Sheng Chou
Hartley Owen
Jorge Luis Soto
Samuel Allen Tabak
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Application granted granted Critical
Publication of ES2041784T3 publication Critical patent/ES2041784T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00265—Part of all of the reactants being heated or cooled outside the reactor while recycling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1088—Olefins
    • C10G2300/1092—C2-C4 olefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4081—Recycling aspects
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/30—Aromatics
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Abstract

PROCEDIMIENTO CATALITICO EN LECHO FLUIDIZADO PARA LA TRANSFORMACION DE UNA FRACCION DE GAS OLEFINICO LIGERA, QUE CONTIENE ETENO, PARA PRODUCIR HIDROCARBUROS RICOS EN LIQUIDOS C5+, QUE COMPRENDE LAS ETAPAS DE MANTENER UN LECHO FLUIDIZADO DE PARTICULAS DE CATALIZADOR DE ZEOLITAS EN UN LECHO DE REACTOR TURBULENTO, A UNA TEMPERATURA DE 315 A 510 (GRADOS) C APROXIMADAMENTE, TENIENDO DICHO CATALIZADOR UNA DENSIDAD DE PARTICULAS APARENTE DE 0,9 A 1,6 G/CM3 APROXIMADAMENTE Y UN INTERVALO DE TAMAÑOS DE 1 A 500 MICRAS APROXIMADAMENTE Y UN TAMAÑO MEDIO DE PARTICULAS DE CATALIZADOR DE 20 A 100 MICRAS APROXIMADAMENTE, QUE CONTIENE 10 A 20 % EN PESO APROXIMADAMENTE DE PARTICULAS FINAS QUE TIENEN UN TAMAÑO DE PARTICULAS MENOR QUE 32 MICRAS; PASANDO LA ALIMENTACION CALIENTE HACIA ARRIBA A TRAVES DEL LECHO CATALITICO FLUIDIZADO EN CONDICIONES DE FLUJO TURBULENTO; MANTENIENDO LAS CONDICIONES DE LECHO FLUIDIZADO TURBULENTO A TRAVES DEL LECHO DEL REACTOR ENTRE LA VELOCIDAD DE TRANSICION Y LA VELOCID AD DE TRANSPORTE A UNA VELOCIDAD DE FLUIDO SUPERFICIAL DE 0,3 A 2 M/SG APROXIMADAMENTE; Y RECUPERAR EL PRODUCTO HIDROCARBONADO QUE CONTIENE UNA CANTIDAD MAYORITARIA DE HIDROCARBUROS C5+ Y QUE CONTIENE ALCANOS Y ALQUENOS C3-C5 EN LA RELACION 0,2:1 A 5:1 APROXIMADAMENTE.
ES198888300317T 1987-01-23 1988-01-15 Procedimiento para revalorizar olefinas ligeras en un reactor con lecho catalizador fluidizado turbulento. Expired - Lifetime ES2041784T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/006,407 US4746762A (en) 1985-01-17 1987-01-23 Upgrading light olefins in a turbulent fluidized catalyst bed reactor

Publications (1)

Publication Number Publication Date
ES2041784T3 true ES2041784T3 (es) 1993-12-01

Family

ID=21720711

Family Applications (1)

Application Number Title Priority Date Filing Date
ES198888300317T Expired - Lifetime ES2041784T3 (es) 1987-01-23 1988-01-15 Procedimiento para revalorizar olefinas ligeras en un reactor con lecho catalizador fluidizado turbulento.

Country Status (15)

Country Link
US (1) US4746762A (es)
EP (1) EP0276095B1 (es)
JP (1) JP2557440B2 (es)
CN (1) CN1014400B (es)
AU (1) AU613599B2 (es)
BR (1) BR8800175A (es)
CA (1) CA1279659C (es)
DE (1) DE3872531D1 (es)
ES (1) ES2041784T3 (es)
FI (1) FI85691C (es)
MA (1) MA21165A1 (es)
PH (1) PH24511A (es)
PT (1) PT86599B (es)
TR (1) TR23518A (es)
ZA (1) ZA88463B (es)

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US4899014A (en) * 1985-05-14 1990-02-06 Avidan Amos A Upgrading propene-ethene mixtures in a turbulent fluidized catalyst bed reactor
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US4873385A (en) * 1987-01-23 1989-10-10 Mobil Oil Corp. Single zone oligomerization of lower olefins to distillate under low severity in a fluid bed with tailored activity
US4827069A (en) * 1988-02-19 1989-05-02 Mobil Oil Corporation Upgrading light olefin fuel gas and catalytic reformate in a turbulent fluidized bed catalyst reactor
US4827046A (en) * 1988-04-11 1989-05-02 Mobil Oil Corporation Extraction of crude methanol and conversion of raffinate
US4877921A (en) * 1988-04-20 1989-10-31 Harandi Mohsen N Single zone oligomerization of olefins in a super-dense phase turbulent fluid bed
US4899015A (en) * 1988-07-28 1990-02-06 Mobil Oil Corp. Process for olefins to gasoline conversion
US4873389A (en) * 1988-08-04 1989-10-10 Mobil Oil Corp. Conversion of light olefins to gasoline using low-temperature catalyst regeneration
US5053570A (en) * 1988-09-22 1991-10-01 Mobil Oil Corporation Fluid bed paraffin aromatization
US5034565A (en) * 1988-09-26 1991-07-23 Mobil Oil Corporation Production of gasoline from light olefins in a fluidized catalyst reactor system
US4939314A (en) * 1988-12-19 1990-07-03 Mobil Oil Corporation Method for on-stream low-pressure regeneration of an oligomerization catalyst from a fluid-bed reactor operating at high pressure with hydrocarbons in a non-liquid phase
US5012026A (en) * 1989-02-14 1991-04-30 Mobil Oil Corp. Turbulent fluid bed paraffin conversion process
US5164071A (en) * 1989-04-17 1992-11-17 Mobil Oil Corporation Fluidized catalyst process for upgrading olefins
US5059735A (en) * 1989-05-04 1991-10-22 Mobil Oil Corp. Process for the production of light olefins from C5 + hydrocarbons
US4956509A (en) * 1989-10-16 1990-09-11 Mobil Oil Corp. Integrated paraffin upgrading and catalytic cracking processes
US5043517A (en) * 1989-10-30 1991-08-27 Mobil Oil Corporation Upgrading light olefin fuel gas in a fluidized bed catalyst reactor and regeneration of the catalyst
US5043499A (en) * 1990-02-15 1991-08-27 Mobil Oil Corporation Fluid bed oligomerization of olefins
GB2250027A (en) * 1990-07-02 1992-05-27 Exxon Research Engineering Co Process and apparatus for the simultaneous production of olefins and catalytically cracked hydrocarbon products
US5545788A (en) * 1991-06-19 1996-08-13 Mobil Oil Corporation Process for the alkylation of benzene-rich reformate using MCM-49
US5338436A (en) * 1991-10-21 1994-08-16 Mobil Oil Corp. Dewaxing process
ATE155454T1 (de) * 1992-01-30 1997-08-15 Exxon Chemical Patents Inc Alkenoligomerisierung
US5401391A (en) * 1993-03-08 1995-03-28 Mobil Oil Corporation Desulfurization of hydrocarbon streams
US5482617A (en) * 1993-03-08 1996-01-09 Mobil Oil Corporation Desulfurization of hydrocarbon streams
US5414172A (en) * 1993-03-08 1995-05-09 Mobil Oil Corporation Naphtha upgrading
DE69423881T2 (de) * 1993-03-08 2000-12-07 Mobil Oil Corp., Fairfax Benzolreduktion in benzin durch alkylierung mit höheren olefinen
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EP1061117A1 (en) * 1999-06-16 2000-12-20 Fina Research S.A. Production of olefins
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US20030194356A1 (en) 2002-04-11 2003-10-16 Meier Paul F. Desulfurization system with enhanced fluid/solids contacting
US20040031729A1 (en) * 2002-08-16 2004-02-19 Meier Paul F Desulfurization system with enhanced fluid/solids contacting
EP1424318A1 (en) * 2002-11-26 2004-06-02 Akzo Nobel N.V. Alkylation process using a reactor comprising multiple catalyst beds
US6759489B1 (en) 2003-05-20 2004-07-06 Eastern Petrochemical Co. Fluidized bed methods for making polymers
US6800664B1 (en) * 2003-05-23 2004-10-05 Conocophillips Company Conjoined reactor system
US7790943B2 (en) * 2006-06-27 2010-09-07 Amt International, Inc. Integrated process for removing benzene from gasoline and producing cyclohexane
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ES2711342T3 (es) * 2007-08-24 2019-05-03 Grace W R & Co Sistema catalítico autolimitante con proporción de aluminio con respecto a SCA controlada
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Also Published As

Publication number Publication date
EP0276095B1 (en) 1992-07-08
PH24511A (en) 1990-07-18
ZA88463B (en) 1989-09-27
CA1279659C (en) 1991-01-29
CN88100267A (zh) 1988-12-21
JP2557440B2 (ja) 1996-11-27
AU613599B2 (en) 1991-08-08
FI85691C (fi) 1992-05-25
PT86599A (pt) 1988-02-01
FI880310A (fi) 1988-07-24
JPS63225694A (ja) 1988-09-20
TR23518A (tr) 1990-03-01
PT86599B (pt) 1991-12-31
CN1014400B (zh) 1991-10-23
BR8800175A (pt) 1988-08-30
FI85691B (fi) 1992-02-14
DE3872531T2 (es) 1993-02-04
EP0276095A1 (en) 1988-07-27
DE3872531D1 (de) 1992-08-13
FI880310A0 (fi) 1988-01-22
AU1008588A (en) 1988-07-28
MA21165A1 (fr) 1988-10-01
US4746762A (en) 1988-05-24

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