DE3776387D1 - Verfahren zur dimerisierung eines niedrigen alkylacrylates und katalytische zusammensetzung. - Google Patents

Verfahren zur dimerisierung eines niedrigen alkylacrylates und katalytische zusammensetzung.

Info

Publication number
DE3776387D1
DE3776387D1 DE8787420078T DE3776387T DE3776387D1 DE 3776387 D1 DE3776387 D1 DE 3776387D1 DE 8787420078 T DE8787420078 T DE 8787420078T DE 3776387 T DE3776387 T DE 3776387T DE 3776387 D1 DE3776387 D1 DE 3776387D1
Authority
DE
Germany
Prior art keywords
dimerizing
alkyl acrylate
low alkyl
catalytic composition
palladium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE8787420078T
Other languages
German (de)
English (en)
Inventor
Pierre Grenouillet
Denis Neibecker
Igor Tkatchenko
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhodia Chimie SAS
Original Assignee
Rhone Poulenc Chimie SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone Poulenc Chimie SA filed Critical Rhone Poulenc Chimie SA
Application granted granted Critical
Publication of DE3776387D1 publication Critical patent/DE3776387D1/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255—Phosphorus containing compounds
    • B01J31/0267—Phosphines or phosphonium compounds, i.e. phosphorus bonded to at least one carbon atom, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, the other atoms bonded to phosphorus being either carbon or hydrogen
    • B01J31/0268—Phosphonium compounds, i.e. phosphine with an additional hydrogen or carbon atom bonded to phosphorous so as to result in a formal positive charge on phosphorous
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0225—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/465—Preparation of carboxylic acid esters by oligomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/593—Dicarboxylic acid esters having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
DE8787420078T 1986-03-27 1987-03-20 Verfahren zur dimerisierung eines niedrigen alkylacrylates und katalytische zusammensetzung. Expired - Fee Related DE3776387D1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8604644A FR2596390B1 (fr) 1986-03-27 1986-03-27 Procede de (co)dimerisation catalytique d'un acrylate d'alkyle inferieur et composition catalytique

Publications (1)

Publication Number Publication Date
DE3776387D1 true DE3776387D1 (de) 1992-03-12

Family

ID=9333761

Family Applications (1)

Application Number Title Priority Date Filing Date
DE8787420078T Expired - Fee Related DE3776387D1 (de) 1986-03-27 1987-03-20 Verfahren zur dimerisierung eines niedrigen alkylacrylates und katalytische zusammensetzung.

Country Status (8)

Country Link
US (2) US4786623A (enExample)
EP (1) EP0243281B1 (enExample)
JP (1) JPS6317845A (enExample)
AT (1) ATE72225T1 (enExample)
DE (1) DE3776387D1 (enExample)
ES (1) ES2028121T3 (enExample)
FR (1) FR2596390B1 (enExample)
SU (1) SU1574168A3 (enExample)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2619564B1 (fr) * 1987-08-19 1989-12-08 Rhone Poulenc Chimie Perfectionnement au procede de dimerisation catalytique d'un acrylate d'alkyle
FR2652514A1 (fr) * 1989-06-22 1991-04-05 Rhone Poulenc Sante Nouveau catalyseur a base de palladium et son emploi.
US5099061A (en) * 1990-09-11 1992-03-24 The University Of North Carolina At Chapel Hill Rhodium-catalyzed olefin dimerization
US5099048A (en) * 1990-09-11 1992-03-24 The University Of North Carolina At Chapel Hill Rhodium-catalyzed olefin dimerization
US5227561A (en) * 1991-08-23 1993-07-13 Shell Oil Company Co-dimerization of vinyl aromatics with α-monoolefins
EP0601705B1 (en) * 1992-12-07 1996-11-06 Ford Motor Company Limited Catalysts from organo-noble metal precursors
GB9306366D0 (en) * 1993-03-26 1993-05-19 Bp Chem Int Ltd Process for prepariang polyketones
DE10318697A1 (de) * 2003-04-24 2004-11-25 Basf Ag Verfahren zur Hydrierung einer monoolefinisch ungesättigten Verbindung
DE10328715A1 (de) * 2003-06-25 2005-01-13 Basf Ag Verfahren zur kontinuierlichen Herstellung einer Verbindung, die mindestens zwei funktionelle Gruppen trägt
DE10328713A1 (de) * 2003-06-25 2005-01-20 Basf Ag Verfahren zur Abtrennung eines Homogenkatalysators
DE10328714A1 (de) * 2003-06-25 2005-01-13 Basf Ag Verfahren zur Abtrennung eines Rhodium enthaltenden Homogenkatalysators
US8491238B2 (en) * 2008-01-30 2013-07-23 Holden America, Inc. Restraint device for a tire
EP3144064B1 (en) * 2009-03-04 2021-07-28 Chevron Phillips Chemical Company LP Selective hydrogenation catalyst and methods of making and using same
RU2466134C1 (ru) * 2011-06-24 2012-11-10 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Иркутский государственный университет" Способ получения катионных комплексов палладия
EP3838907A1 (en) 2019-12-20 2021-06-23 Polytechnyl S.A.S. Reactive phosporous contaning flame retardant and intrinsically flame retradant polymer obtainable by polycondensation with it

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2104626C2 (de) * 1970-02-09 1982-07-29 Mitsubishi Chemical Industries, Ltd., Tokyo Verfahren zur Herstellung eines Additionsproduktes eines konjugierten Diens und einer Verbindung mit endständiger Venylgruppe
US4243829A (en) * 1976-10-04 1981-01-06 Charles U. Pittman, Jr. Production of 1,7-octadiene from butadiene
US4318860A (en) * 1979-09-28 1982-03-09 Atlantic Richfield Company Preparation of unsaturated monester precursor for pelargonic acid
US4501822A (en) * 1982-01-26 1985-02-26 Celanese Corporation Hydroesterification of 1-alkene
FR2524341A1 (fr) * 1982-03-31 1983-10-07 Centre Nat Rech Scient Catalyseur de dimerisation et/ou de codimerisation de derives acryliques
US4519954A (en) * 1982-12-29 1985-05-28 The Standard Oil Company Leach resistant catalyst useful for the dimerization of acrylic compounds
US4451665A (en) * 1982-12-30 1984-05-29 E. I. Du Pont De Nemours And Company Process for dimerizing acrylates and methacrylates
DE3336691A1 (de) * 1983-10-08 1985-04-25 Studiengesellschaft Kohle mbH, 4330 Mülheim Verfahren zur katalytischen dimerisation von acrylsaeurederivaten und verwendung der erhaltenen dimeren
GB8428347D0 (en) * 1984-11-09 1984-12-19 Shell Int Research Dimerization of olefins

Also Published As

Publication number Publication date
JPH0548218B2 (enExample) 1993-07-20
ATE72225T1 (de) 1992-02-15
SU1574168A3 (ru) 1990-06-23
FR2596390B1 (fr) 1989-02-17
ES2028121T3 (es) 1992-07-01
US4889949A (en) 1989-12-26
EP0243281B1 (fr) 1992-01-29
EP0243281A2 (fr) 1987-10-28
JPS6317845A (ja) 1988-01-25
US4786623A (en) 1988-11-22
FR2596390A1 (fr) 1987-10-02
EP0243281A3 (en) 1989-03-29

Similar Documents

Publication Publication Date Title
ATE72225T1 (de) Verfahren zur dimerisierung eines niedrigen alkylacrylates und katalytische zusammensetzung.
BR9811017A (pt) "hidrogenólise de glicerol"
DE3766191D1 (de) Verfahren zur dimerisierung von alpha-olefinen.
ATE213285T1 (de) Verfahren und lösung zur gewährleistung eines konversionsüberzugs auf einer metalloberfläche
DE69728149D1 (de) Modifizierte liganden für den tie-2-rezeptor
DE69613968D1 (de) Verfahren zur addition von cyanwasserstoff in gegenwart von null-wertigem nickel, einer zweizähnigen phospor-verbindung und einer lewis-säure
ES2130452T3 (es) Derivados de ciclobutano utilizados como inhibidores de la escualeno-sintetasa y de la farnesiltransferasa proteica.
BR0010027A (pt) Composição, método para aplicação de uma composição, e, uso da composição
DE3783593D1 (de) Verfahren zum betreiben eines analysiergeraets.
DE69017346D1 (de) Verfahren zur Hydroformylierung von Olefinen.
MX168468B (es) Procedimiento para la obtencion de (+)1r-trans-2,2 dimetil-3-(2,2-diclorovinil)-ciclopropan-carboxilato de 2,3,5,6-tetrafluorbencilo
DE69534148D1 (de) Rechnersystem zur Ausführung von Verzweigungsbefehlen
KR970702844A (ko) 모노올레핀 하이드로시안화용 모노덴테이트 포스파이트 및 니켈 촉매 조성물(monodentate phosphite and nickel catalyst composition for monoolefin hydrocyanation)
DE3881677D1 (de) Verfahren zur behandlung von abgas durch bestrahlung mit elektronenstrahlen.
DE58900601D1 (de) Kampffahrzeug, insbesondere panzerhaubitze.
DE69020355D1 (de) Verfahren zur befestigung eines elastischen streifens.
DE69321918D1 (de) Zusammensetzung und verfahren zum abfangen von sauerstoff
DE3668560D1 (de) Verfahren zum reinigen, insbesondere entschwefelung von rauchgas.
DE69201572D1 (de) Verfahren zum Durchführen hochwirksamer Abscheidungen durch kapillare Elektrophorese.
DE3765527D1 (de) Verfahren zur oligomerisierung von olefinen.
DE3777118D1 (de) Verfahren zur hydroformylierung eines olefins.
DE3787855D1 (de) Verfahren zur rückkehr zum ursprung.
FI896319A7 (fi) Fosforipitoiset polymeeriseokset, jotka sisältävät vesiliukoisia moniarvoisia metalliyhdisteitä
AT372832B (de) Baukastensystem zur erstellung von baenken, tischen od. dgl.
ES2126597T3 (es) Sistema de sondas que permite efectuar la tipificacion hla dr, y procedimiento de tipificacion que utiliza dichas sondas.

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee