DE3766197D1 - Verfahren zur ueberfuehrung von c2 bis c12 aliphaten in aromaten ueber mit zink aktiviertem zeolith. - Google Patents

Verfahren zur ueberfuehrung von c2 bis c12 aliphaten in aromaten ueber mit zink aktiviertem zeolith.

Info

Publication number
DE3766197D1
DE3766197D1 DE8787306086T DE3766197T DE3766197D1 DE 3766197 D1 DE3766197 D1 DE 3766197D1 DE 8787306086 T DE8787306086 T DE 8787306086T DE 3766197 T DE3766197 T DE 3766197T DE 3766197 D1 DE3766197 D1 DE 3766197D1
Authority
DE
Germany
Prior art keywords
aromats
aliphates
converting
over
activated zeolite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE8787306086T
Other languages
English (en)
Inventor
Cynthia Ting-Wah Chu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Application granted granted Critical
Publication of DE3766197D1 publication Critical patent/DE3766197D1/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
    • C07C5/41—Catalytic processes
    • C07C5/415—Catalytic processes with metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
DE8787306086T 1986-09-08 1987-07-09 Verfahren zur ueberfuehrung von c2 bis c12 aliphaten in aromaten ueber mit zink aktiviertem zeolith. Expired - Fee Related DE3766197D1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/905,104 US4720602A (en) 1986-09-08 1986-09-08 Process for converting C2 to C12 aliphatics to aromatics over a zinc-activated zeolite

Publications (1)

Publication Number Publication Date
DE3766197D1 true DE3766197D1 (de) 1990-12-20

Family

ID=25420296

Family Applications (1)

Application Number Title Priority Date Filing Date
DE8787306086T Expired - Fee Related DE3766197D1 (de) 1986-09-08 1987-07-09 Verfahren zur ueberfuehrung von c2 bis c12 aliphaten in aromaten ueber mit zink aktiviertem zeolith.

Country Status (5)

Country Link
US (1) US4720602A (de)
EP (1) EP0259954B1 (de)
JP (1) JPS6369888A (de)
DE (1) DE3766197D1 (de)
ZA (1) ZA876090B (de)

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ZA874948B (en) * 1986-07-07 1989-02-22 Mobil Oil Corp Aromatisation of aliphatics over gallium-containing zeolites
US5019664A (en) * 1988-10-06 1991-05-28 Mobil Oil Corp. Process for the conversion of paraffins to olefins and/or aromatics and low acidity zeolite catalyst therefor
US4918256A (en) * 1988-01-04 1990-04-17 Mobil Oil Corporation Co-production of aromatics and olefins from paraffinic feedstocks
EP0330304A1 (de) * 1988-01-19 1989-08-30 Mobil Oil Corporation Verfahren zur Herstellung von aromatischen Kohlenwasserstoffen aus Alkanen
US4912273A (en) * 1988-01-19 1990-03-27 Mobil Oil Corp. Production of aromatic hydrocarbons from alkanes
US5019663A (en) * 1989-04-03 1991-05-28 Mobil Oil Corp. Heat balanced paraffin upgrading with co-fed oxygenate
US5087782A (en) * 1989-04-28 1992-02-11 Mobil Oil Corporation Dehydrocyclization of polyalpha-olefin lubricants
US5059735A (en) * 1989-05-04 1991-10-22 Mobil Oil Corp. Process for the production of light olefins from C5 + hydrocarbons
US4962250A (en) * 1990-01-24 1990-10-09 Mobile Oil Corp. Process for the conversion of paraffins to olefins and/or aromatics and non-acidic zeolite catalyst therefor
GB2250027A (en) * 1990-07-02 1992-05-27 Exxon Research Engineering Co Process and apparatus for the simultaneous production of olefins and catalytically cracked hydrocarbon products
US5105039A (en) * 1991-04-29 1992-04-14 Mobil Oil Corporation Process for producing lubricant fluids of improved stability
WO1993010066A1 (en) * 1991-11-22 1993-05-27 Mobil Oil Corporation Dehydrocyclization of polyalpha-olefin lubricants
US6323381B1 (en) * 1992-06-18 2001-11-27 Chevron Corporation Manufacture of high purity benzene and para-rich xylenes by combining aromatization and selective disproportionation of impure toluene
CN1048426C (zh) * 1994-06-20 2000-01-19 南开大学催化剂厂 Ｃ5链烃芳构化催化剂
KR100228997B1 (ko) * 1994-10-03 1999-11-01 테라사끼 이와오 방향족 탄화수소의 제조방법
US5866744A (en) * 1997-01-30 1999-02-02 Phillips Petroleum Company Process for converting a c9 + hydrocarbon to a C6 to C8 aromatic using a steamed, acid-leached, impregnated zeolite
AU7710598A (en) * 1997-07-15 1999-02-10 Phillips Petroleum Company High stability zeolite catalyst composition and hydrocarbon conversion process
US6156689A (en) * 1997-10-23 2000-12-05 Phillips Petroleum Company Catalyst composition comprising zinc compound or boron compound and hydrocarbon conversion process
US6004452A (en) * 1997-11-14 1999-12-21 Chevron Chemical Company Llc Process for converting hydrocarbon feed to high purity benzene and high purity paraxylene
US6084142A (en) * 1998-05-12 2000-07-04 Phillips Petroleum Company Method of making an improved zeolite catalyst, a product from such method, and the use thereof in the conversion of hydrocarbons
US6077984A (en) * 1998-09-01 2000-06-20 Phillips Petroleum Company Process for making zeolite containing zinc borate composition, the composition and the use thereof in hydrocarbon conversion
AU5815099A (en) * 1998-09-16 2000-04-03 Phillips Petroleum Company An improved zeolite
US6090272A (en) * 1998-12-28 2000-07-18 Phillips Petroleum Company Process for converting a cracked gasoline using a zeolite-based catalyst material
US7838708B2 (en) * 2001-06-20 2010-11-23 Grt, Inc. Hydrocarbon conversion process improvements
EP1302528B1 (de) * 2001-10-10 2008-05-21 Haldor Topsoe A/S Verfahren zur Entfernung von höheren Kohlenwasserstoffen aus Erdgas
US20050171393A1 (en) * 2003-07-15 2005-08-04 Lorkovic Ivan M. Hydrocarbon synthesis
WO2005021468A1 (en) * 2003-07-15 2005-03-10 Grt, Inc. Hydrocarbon synthesis
US7244867B2 (en) 2004-04-16 2007-07-17 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US8642822B2 (en) 2004-04-16 2014-02-04 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor
US20060100469A1 (en) 2004-04-16 2006-05-11 Waycuilis John J Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US8173851B2 (en) 2004-04-16 2012-05-08 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US20080275284A1 (en) 2004-04-16 2008-11-06 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US7674941B2 (en) * 2004-04-16 2010-03-09 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
CN101484406B (zh) 2006-02-03 2014-01-22 Grt公司 天然气转化为液体烃的连续方法
CN101395088B (zh) * 2006-02-03 2012-04-04 Grt公司 轻气体与卤素的分离方法
US8921625B2 (en) * 2007-02-05 2014-12-30 Reaction35, LLC Continuous process for converting natural gas to liquid hydrocarbons
EA201200888A1 (ru) * 2007-05-14 2013-02-28 Грт, Инк. Способ конверсии углеводородного сырья с электролитическим извлечением галогенов
CA2687589A1 (en) * 2007-05-24 2008-12-04 Grt, Inc. Zone reactor incorporating reversible hydrogen halide capture and release
US7982080B2 (en) * 2007-07-24 2011-07-19 Teng Xu Production of aromatics from aliphatics
US8282810B2 (en) 2008-06-13 2012-10-09 Marathon Gtf Technology, Ltd. Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
WO2010124041A1 (en) * 2009-04-22 2010-10-28 Grt, Inc. Process for converting hydrocarbon feedstocks with electrolytic and photoelectrocatalytic recovery of halogens
US8198495B2 (en) 2010-03-02 2012-06-12 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8367884B2 (en) 2010-03-02 2013-02-05 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8815050B2 (en) 2011-03-22 2014-08-26 Marathon Gtf Technology, Ltd. Processes and systems for drying liquid bromine
US8436220B2 (en) 2011-06-10 2013-05-07 Marathon Gtf Technology, Ltd. Processes and systems for demethanization of brominated hydrocarbons
US8829256B2 (en) 2011-06-30 2014-09-09 Gtc Technology Us, Llc Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons
US8802908B2 (en) 2011-10-21 2014-08-12 Marathon Gtf Technology, Ltd. Processes and systems for separate, parallel methane and higher alkanes' bromination
US9193641B2 (en) 2011-12-16 2015-11-24 Gtc Technology Us, Llc Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems
US9044723B2 (en) 2013-03-28 2015-06-02 Uop Llc Inclined baseplate in dehydrogenation reactor
CA2926152C (en) 2013-12-20 2020-08-18 Exxonmobil Research And Engineering Company Alumina bound catalyst for selective conversion of oxygenates to aromatics
WO2015094696A1 (en) 2013-12-20 2015-06-25 Exxonmobil Chemical Patents Inc. Process for converting oxygenates to aromatic hydrocarbons
RU2544241C1 (ru) 2014-01-22 2015-03-20 Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез" Способ получения ароматических углеводородов из природного газа и установка для его осуществления
RU2558955C1 (ru) 2014-08-12 2015-08-10 Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез" Способ получения концентрата ароматических углеводородов из жидких углеводородных фракций и установка для его осуществления
RU2550354C1 (ru) 2014-03-28 2015-05-10 Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез" Способ получения концентрата ароматических углеводородов из легких алифатических углеводородов и установка для его осуществления
RU2544017C1 (ru) 2014-01-28 2015-03-10 Ольга Васильевна Малова Катализатор и способ ароматизации с3-с4 газов, легких углеводородных фракций алифатических спиртов, а также их смесей
WO2017155424A1 (en) 2016-03-09 2017-09-14 Limited Liability Company "New Gas Technologies-Synthesis" (Llc "Ngt-Synthesis") Method and plant for producing high-octane gasolines
US11198822B2 (en) * 2019-04-10 2021-12-14 Exxonmobil Research And Engineering Company Processes to convert naphtha to heavier products

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Publication number Priority date Publication date Assignee Title
US3760024A (en) * 1971-06-16 1973-09-18 Mobil Oil Corp Preparation of aromatics
US4120910A (en) * 1976-12-27 1978-10-17 Mobil Oil Corporation Aromatization of ethane
US4097367A (en) * 1977-07-25 1978-06-27 Mobil Oil Corporation Conversion of olefinic naphtha
NL190066C (nl) * 1979-03-14 1993-10-18 Shell Int Research Werkwijze voor de bereiding van aromatische koolwaterstoffen en waterstof.
NL7904283A (nl) * 1979-05-31 1980-12-02 Philips Nv Koppelelement met een lichtbron en en lensvormig element.
CA1157450A (en) * 1980-03-18 1983-11-22 Martin F.M. Post Process for the preparation of crystalline aluminium silicates, crystalline aluminium silicates so prepared and process for the production of an aromatic hydrocarbon mixture
CA1153867A (en) * 1980-05-16 1983-09-20 Michael A. M. Boersma Process for the preparation of crystalline silicates, crystalline silicates so prepared and process for carrying out catalytic reactions
US4350835A (en) * 1981-02-19 1982-09-21 Mobil Oil Corporation Process for converting ethane to aromatics over gallium-activated zeolite
US4392989A (en) * 1981-05-11 1983-07-12 Mobil Oil Corporation Zinc-gallium zeolite
US4607130A (en) * 1981-11-21 1986-08-19 Mobil Oil Corporation Acid-catalyzed organic compound conversion
US4465884A (en) * 1982-08-17 1984-08-14 Mobil Oil Corporation Olefin processing
US4538017A (en) * 1984-08-01 1985-08-27 Cosden Technology, Inc. Conversion of paraffins to aromatics

Also Published As

Publication number Publication date
US4720602A (en) 1988-01-19
EP0259954B1 (de) 1990-11-14
JPS6369888A (ja) 1988-03-29
ZA876090B (en) 1989-04-26
EP0259954A1 (de) 1988-03-16

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee