DE3584847D1 - Verfahren zur herstellung von ethylenglycol. - Google Patents

Verfahren zur herstellung von ethylenglycol.

Info

Publication number
DE3584847D1
DE3584847D1 DE8585302392T DE3584847T DE3584847D1 DE 3584847 D1 DE3584847 D1 DE 3584847D1 DE 8585302392 T DE8585302392 T DE 8585302392T DE 3584847 T DE3584847 T DE 3584847T DE 3584847 D1 DE3584847 D1 DE 3584847D1
Authority
DE
Germany
Prior art keywords
ethylene glycol
producing ethylene
producing
glycol
ethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE8585302392T
Other languages
German (de)
English (en)
Inventor
Chun Fei Chueh
Stephen E Jacobson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Montvale Process Co Inc
Original Assignee
Montvale Process Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Montvale Process Co Inc filed Critical Montvale Process Co Inc
Application granted granted Critical
Publication of DE3584847D1 publication Critical patent/DE3584847D1/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/80—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C45/82—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/643—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/189—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms containing both nitrogen and phosphorus as complexing atoms, including e.g. phosphino moieties, in one at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
DE8585302392T 1984-04-05 1985-04-04 Verfahren zur herstellung von ethylenglycol. Expired - Fee Related DE3584847D1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/597,003 US4496781A (en) 1984-04-05 1984-04-05 Process for the production of ethylene glycol through the hydroformylation of glycol aldehyde

Publications (1)

Publication Number Publication Date
DE3584847D1 true DE3584847D1 (de) 1992-01-23

Family

ID=24389648

Family Applications (1)

Application Number Title Priority Date Filing Date
DE8585302392T Expired - Fee Related DE3584847D1 (de) 1984-04-05 1985-04-04 Verfahren zur herstellung von ethylenglycol.

Country Status (4)

Country Link
US (1) US4496781A (OSRAM)
EP (1) EP0158517B1 (OSRAM)
JP (1) JPS60218341A (OSRAM)
DE (1) DE3584847D1 (OSRAM)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4608444A (en) 1984-04-05 1986-08-26 The Halcon Sd Group, Inc. Process and accompanying catalysts for the hydroformylation of formaldehyde to glycol-aldehyde
US4847423A (en) * 1988-03-03 1989-07-11 Hoechst Celanese Corporation Hydroformylation of aqueous formaldehyde using a rhodium-tricyclohexylphosphine catalyst system
DE4023255A1 (de) * 1990-07-21 1992-01-23 Basf Ag Verfahren zur herstellung von glykolen, insbesondere propylenglykol aus formaldehyd
CA2510284C (en) * 2002-12-17 2011-06-14 Shell Internationale Research Maatschappij B.V. Hydroformylation process for the conversion of an ethylenically unsaturated compound to an alcohol
US7420093B2 (en) * 2006-09-29 2008-09-02 Eastman Chemical Company Process for the preparation of glycolaldehyde
US7615671B2 (en) 2007-11-30 2009-11-10 Eastman Chemical Company Hydrogenation process for the preparation of 1,2-diols
TWI630197B (zh) 2013-02-27 2018-07-21 丹麥商哈爾德杜薩公司 從包含低分子量羰基化合物之組成物移除甲醛的方法
CN106795081B (zh) * 2014-05-19 2018-12-28 爱荷华谷类推广协会 由糖类连续制备乙二醇的方法
US10086364B2 (en) 2014-06-26 2018-10-02 University Of Wyoming Methods of catalytic hydrogenation for ethylene glycol formation
US10800987B2 (en) 2014-06-27 2020-10-13 University Of Wyoming Composite iron-sodium catalyst for coal gasification
DK3160927T3 (da) * 2014-06-30 2022-06-13 Haldor Topsoe As Fremgangsmåde til fremstilling af ethylenglycol ud fra sukker
KR102044453B1 (ko) 2014-06-30 2019-11-13 할도르 토프쉐 에이/에스 당으로부터 에틸렌글리콜을 제조하는 방법
AU2017205691B2 (en) * 2016-01-07 2021-06-17 Haldor Topsøe A/S Process for the preparation of ethylene glycol from sugars
KR102737311B1 (ko) * 2016-01-07 2024-12-03 토프쉐 에이/에스 당으로부터 에틸렌글리콜의 제조를 위한 과정
CN105618035B (zh) * 2016-02-02 2018-05-11 中国科学院福建物质结构研究所 合成气制备乙醇醛所用的负载型铑催化剂及其制备方法
GB201604608D0 (en) * 2016-03-18 2016-05-04 Johnson Matthey Davy Technologies Ltd Process
EP3976734A4 (en) 2019-05-24 2023-03-15 Eastman Chemical Company CRACKING A C4-C7 FRACTION OF PYROLYTIC OIL
CN117700565A (zh) 2019-05-24 2024-03-15 伊士曼化工公司 回收成分纤维素酯
EP4004081B1 (en) 2019-07-29 2025-09-17 Eastman Chemical Company Recycle content cyclobutane diol polyester
US12338211B2 (en) 2019-07-29 2025-06-24 Eastman Chemical Company Recycle content (C4)alkanal
TWI870439B (zh) 2019-08-16 2025-01-21 丹麥商托普索公司 用於糖類熱解分裂的新型方法及床材料
US12312540B2 (en) 2019-10-31 2025-05-27 Eastman Chemical Company Pyrolysis method and system for recycled waste
EP4054998A4 (en) 2019-11-07 2024-04-03 Eastman Chemical Company PROPANOL WITH RECYCLED CONTENT
KR20220093368A (ko) 2019-11-07 2022-07-05 이스트만 케미칼 컴파니 재활용물 알파 올레핀 및 지방 알코올
EP4054996A4 (en) 2019-11-07 2024-03-27 Eastman Chemical Company Recycle content oxo alcohols & oxo plasticizers
KR20230152013A (ko) 2021-01-29 2023-11-02 브라스켐 에세.아. 결정화 제어가 증가된 2,4-fdca의 코폴리에스테르
CN118696023A (zh) * 2022-02-17 2024-09-24 伊士曼化工公司 回收成分单乙二醇
CN119173495A (zh) 2022-07-08 2024-12-20 托普索公司 使含氧化合物混合物冷凝的方法
CN121532473A (zh) 2023-07-17 2026-02-13 巴斯夫欧洲公司 新型冷却剂组合物

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IE45512B1 (en) * 1976-09-17 1982-09-08 Nat Distillers Chem Corp Ethylene glycol process
US4200765A (en) * 1976-09-17 1980-04-29 National Distillers And Chemical Corporation Glycol aldehyde and ethylene glycol processes
US4079085A (en) * 1976-10-21 1978-03-14 Chevron Research Company Process for preparing ethylene glycol and ethylene glycol ether
GB1568427A (en) * 1976-10-21 1980-05-29 Chevron Res Process for preparing glycol and methanol
US4382148A (en) * 1981-03-24 1983-05-03 Shell Oil Company Process for the preparation of glycol aldehyde
US4405814A (en) * 1981-08-05 1983-09-20 Monsanto Company Hydroformylation of formaldehyde with rhodium catalysts
US4405821A (en) * 1981-08-11 1983-09-20 National Distillers And Chemical Corporation Process for preparing glycolaldehyde and/or ethylene glycol
GB2114971A (en) * 1982-02-15 1983-09-01 Ici Plc Production of glycol aldehyde
US4477685A (en) * 1982-08-20 1984-10-16 Monsanto Company Hydroformylation process to prepare glycolaldehydes
JPS6038035A (ja) * 1983-06-28 1985-02-27 ザ・ハルコン・エス・デイ−・グル−プ・インコ−ポレ−テツド グリコ−ルアルデヒドの製法及びその触媒
US4608444A (en) * 1984-04-05 1986-08-26 The Halcon Sd Group, Inc. Process and accompanying catalysts for the hydroformylation of formaldehyde to glycol-aldehyde

Also Published As

Publication number Publication date
JPS60218341A (ja) 1985-11-01
US4496781A (en) 1985-01-29
EP0158517A3 (en) 1986-12-10
EP0158517A2 (en) 1985-10-16
JPH051769B2 (OSRAM) 1993-01-11
EP0158517B1 (en) 1991-12-11

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Legal Events

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8339 Ceased/non-payment of the annual fee