DE3582097D1 - Silberkatalysator fuer die herstellung von ethylenoxid aus ethylen und verfahren zu dessen herstellung. - Google Patents

Silberkatalysator fuer die herstellung von ethylenoxid aus ethylen und verfahren zu dessen herstellung.

Info

Publication number
DE3582097D1
DE3582097D1 DE8585110458T DE3582097T DE3582097D1 DE 3582097 D1 DE3582097 D1 DE 3582097D1 DE 8585110458 T DE8585110458 T DE 8585110458T DE 3582097 T DE3582097 T DE 3582097T DE 3582097 D1 DE3582097 D1 DE 3582097D1
Authority
DE
Germany
Prior art keywords
production
ethylene
silver catalyst
ethylene oxide
oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE8585110458T
Other languages
English (en)
Inventor
Naohiro C O Chuo Kenkyu Nojiri
Yukio C O Chuo Kenkyujo Sakai
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Petrochemical Co Ltd
Original Assignee
Mitsubishi Petrochemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP59173884A external-priority patent/JPH0777615B2/ja
Priority claimed from JP59191732A external-priority patent/JPS6171837A/ja
Priority claimed from JP59224877A external-priority patent/JPS61103545A/ja
Application filed by Mitsubishi Petrochemical Co Ltd filed Critical Mitsubishi Petrochemical Co Ltd
Application granted granted Critical
Publication of DE3582097D1 publication Critical patent/DE3582097D1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/681—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with arsenic, antimony or bismuth
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
DE8585110458T 1984-08-21 1985-08-20 Silberkatalysator fuer die herstellung von ethylenoxid aus ethylen und verfahren zu dessen herstellung. Expired - Lifetime DE3582097D1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP59173884A JPH0777615B2 (ja) 1984-08-21 1984-08-21 エチレンオキシド製造用銀触媒の製法
JP59191732A JPS6171837A (ja) 1984-09-14 1984-09-14 エチレンからエチレンオキシドを製造するための触媒
JP59224877A JPS61103545A (ja) 1984-10-25 1984-10-25 エチレンオキシド製造用銀触媒

Publications (1)

Publication Number Publication Date
DE3582097D1 true DE3582097D1 (de) 1991-04-18

Family

ID=27323866

Family Applications (1)

Application Number Title Priority Date Filing Date
DE8585110458T Expired - Lifetime DE3582097D1 (de) 1984-08-21 1985-08-20 Silberkatalysator fuer die herstellung von ethylenoxid aus ethylen und verfahren zu dessen herstellung.

Country Status (3)

Country Link
US (2) US4690913A (de)
EP (1) EP0172565B1 (de)
DE (1) DE3582097D1 (de)

Families Citing this family (44)

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US4820675A (en) * 1986-10-31 1989-04-11 Shell Oil Company Ethylene oxide catalyst & process for preparing the catalyst
IL84232A (en) * 1986-10-31 1992-06-21 Shell Int Research Catalyst and process for the catalytic production of ethylene oxide
US4833261A (en) * 1986-10-31 1989-05-23 Shell Oil Company Ethylene oxide process
US4808738A (en) * 1986-10-31 1989-02-28 Shell Oil Company Ethylene oxide process
GB8626687D0 (en) * 1986-11-07 1986-12-10 Shell Int Research Preparing silver catalyst
DE3643248A1 (de) * 1986-12-18 1988-06-30 Basf Ag Silberkatalysator, seine herstellung und verwendung
US4897498A (en) * 1988-01-28 1990-01-30 Eastman Kodak Company Selective monoepoxidation of olefins
US4912077A (en) * 1988-07-15 1990-03-27 Corning Incorporated Catalytically active materials and method for their preparation
US4964975A (en) * 1989-06-30 1990-10-23 Uop Reforming catalyst with homogeneous metals dispersion
US5173469A (en) * 1989-11-09 1992-12-22 Huels Aktiengesellschaft Silver catalyst suitable for oxidation of ethylene and process for the production of the catalyst
DE4311608A1 (de) * 1993-04-08 1994-12-15 Huels Chemische Werke Ag Silberkatalysator zur Oxidation von Ethylen zu Ethylenoxid und Verfahren zur Herstellung von Ethylenoxid
US5502020A (en) * 1993-04-14 1996-03-26 Mitsubishi Petrochemical Co., Ltd. Catalyst for production of ethylene oxide and process for producing the catalyst
EP0724479B1 (de) * 1993-08-23 2001-06-13 Shell Internationale Researchmaatschappij B.V. Ethylenoxidkatalysator
US5705661A (en) * 1995-09-25 1998-01-06 Mitsubishi Chemical Corporation Catalyst for production of ethylene oxide
EP1201301B1 (de) 2000-10-25 2005-03-30 Mitsubishi Chemical Corporation Verfahren zur Oxidation von Olefinen unter Verwendung eines Silber und Alkalimetall(e) enthaltenden Katalysator
KR101369619B1 (ko) 2005-06-07 2014-03-05 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 산화올레핀, 1,2-디올, 1,2-디올 에테르 또는 알칸올아민의제조방법, 이를 위한 촉매, 이 촉매의 제조방법
EP2617490A1 (de) * 2005-06-07 2013-07-24 Saint-Gobain Ceramics & Plastics Inc. Katalysatorträger und Verfahren zum Herstellen des Katalysatorträgers
US7553795B2 (en) * 2006-03-21 2009-06-30 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Activation of high selectivity ethylene oxide catalyst
DE102008011767B4 (de) 2008-02-28 2012-07-26 Basf Se Verfahren zur Herstellung von olefinisch ungesättigten Carbonylverbindungen durch oxidative Dehydrierung von Alkoholen
DE102008014910A1 (de) 2008-03-19 2009-09-24 Basf Se Verwendung eines geträgerten edelmetallhaltigen Katalysators zur oxidativen Dehydrierung
ES2391809T3 (es) 2008-10-08 2012-11-30 Basf Se Método para producir óxidos de alquileno
ES2502534T3 (es) 2009-06-09 2014-10-03 Basf Se Uso de lechos de catalizador estructurados para la producción de óxido de etileno
CN102145306B (zh) * 2010-02-05 2013-05-01 中国石油化工股份有限公司 通过选用不同粒度的水合氧化铝来调变氧化铝载体性能的方法、由此得到的载体及其应用
US8629079B2 (en) 2011-04-14 2014-01-14 Basf Se Process for producing a catalyst for the oxidation of ethylene to ethylene oxide
US8921587B2 (en) 2011-04-14 2014-12-30 Basf Se Process for producing a catalyst for the oxidation of ethylene to ethylene oxide
US8987482B2 (en) 2011-10-28 2015-03-24 Basf Se Process for producing a supported silver catalyst
WO2013164727A1 (de) 2012-05-04 2013-11-07 Basf Se Katalysator zur epoxidation von alkenen
EP3079810A4 (de) 2013-12-09 2017-05-31 Basf Se Katalysator zur epoxidation von alkenen
TWI697358B (zh) 2015-02-27 2020-07-01 美商科學設計有限公司 具有改進的銀顆粒大小和分佈密度的銀催化劑
CN109562358A (zh) 2016-08-08 2019-04-02 巴斯夫欧洲公司 用于将乙烯氧化成环氧乙烷的催化剂
WO2019020793A1 (en) 2017-07-28 2019-01-31 Basf Se PROCESS FOR PRODUCING A MOLDED CATALYST BODY COMPRISING SILVER APPLIED TO AN ALUMINUM CARRIER
TWI808125B (zh) 2018-02-07 2023-07-11 德商巴斯夫歐洲公司 有效地將乙烯氧化轉化為環氧乙烷之催化劑
EP3639924A1 (de) 2018-10-15 2020-04-22 Basf Se Katalysator zur herstellung von ethylenoxid durch gasphasenoxidation
EP3639923A1 (de) 2018-10-15 2020-04-22 Basf Se Verfahren zur herstellung von ethylenoxid durch gasphasenoxidation von ethylen
EP3659703A1 (de) 2018-11-28 2020-06-03 Basf Se Katalysator zur herstellung von ethylenoxid durch gasphasenoxidation
WO2021038027A1 (en) 2019-08-28 2021-03-04 Basf Se Process for preparing an epoxidation catalyst
WO2021191414A1 (en) 2020-03-27 2021-09-30 Basf Se Process for producing a silver-based epoxidation catalyst
EP3885038A1 (de) 2020-03-27 2021-09-29 Basf Se Verfahren zur herstellung eines epoxidierungskatalysators
US20230256415A1 (en) 2020-06-26 2023-08-17 Basf Se Production of porous alpha-alumina supports from boehmitic derived aluminas
WO2021260138A1 (en) 2020-06-26 2021-12-30 Basf Se Shaped catalyst body for the production of ethylene oxide
JP2023532004A (ja) 2020-06-26 2023-07-26 ビーエーエスエフ ソシエタス・ヨーロピア 多孔質アルファ－アルミナ触媒支持体を生成する方法
TW202239471A (zh) 2021-01-26 2022-10-16 德商巴斯夫歐洲公司 環氧化催化劑
WO2024079247A1 (en) 2022-10-12 2024-04-18 Basf Se Epoxidation catalyst
WO2024089254A1 (en) 2022-10-28 2024-05-02 Basf Se Process for the manufacture of a c4-olefin-derived chemical of interest, in particular citral, from renewably-sourced ethanol

Family Cites Families (22)

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Publication number Priority date Publication date Assignee Title
BE775697A (de) * 1970-12-02 1972-05-23 Shell Int Research
US3702259A (en) * 1970-12-02 1972-11-07 Shell Oil Co Chemical production of metallic silver deposits
US4356312A (en) * 1972-01-07 1982-10-26 Shell Oil Company Ethylene oxide process
BE793658A (fr) * 1972-01-07 1973-07-04 Shell Int Research Catalyseur utilisable pour la production d'oxyde d'ethylene
US4012425A (en) * 1972-01-07 1977-03-15 Shell Oil Company Ethylene oxide process
IT971362B (it) * 1972-11-30 1974-04-30 Sir Soc Italiana Resine Spa Procedimento per la produzione dell ossido di etilene mediante ossidazione dell etilene e cata lizzatore relativo
GB1491447A (en) * 1973-12-05 1977-11-09 Ici Ltd Alkylene oxide production and catalysts therefor
DE2454972A1 (de) * 1973-12-05 1975-06-12 Ici Ltd Katalysator und verfahren zur herstellung von alkylenoxiden
IT1006688B (it) * 1973-12-28 1976-10-20 Sir Soc Italiana Resine Spa Procedimento e catalizzazione per la produzione dell ossido di etile ne mediante ossidazione dell etile ne
US4212772A (en) * 1976-05-19 1980-07-15 Basf Aktiengesellschaft Catalyst for the manufacture of ethylene oxide
DE2640540B2 (de) * 1976-09-09 1978-10-19 Basf Ag, 6700 Ludwigshafen Katalysator zur Herstellung von Äthylenoxid
US4066575A (en) * 1976-07-26 1978-01-03 Halcon International, Inc. Process for the preparation of a supported silver catalyst
JPS5929293B2 (ja) * 1977-07-01 1984-07-19 株式会社日本触媒 酸化エチレン製造用銀担持触媒の製造方法
CA1162181A (en) * 1979-03-20 1984-02-14 Paul C. Ellgen Catalyst composition and process for oxidation of ethylene to ethylene oxide
US4342667A (en) * 1979-03-26 1982-08-03 The Halcon Sd Group, Inc. Process for preparing a silver catalyst
DE3264712D1 (en) * 1981-02-25 1985-08-22 Mitsubishi Petrochemical Co Silver-based catalyst for production of ethylene oxide
JPS57140654A (en) * 1981-02-25 1982-08-31 Mitsubishi Petrochem Co Ltd Silver catalyst for preparation of ethylene oxide
JPS57180434A (en) * 1981-04-30 1982-11-06 Mitsubishi Petrochem Co Ltd Silver catalyst for production of ethylene oxide
US4416181A (en) * 1981-04-03 1983-11-22 Remo, Inc. Pretuned head for drum or the like
BG37835A3 (en) * 1982-06-30 1985-08-15 Hoechst Ag,De Method for preparing silver catalyst
DE3224322A1 (de) * 1982-06-30 1984-01-05 Hoechst Ag, 6230 Frankfurt Silberkatalysatoren, verfahren zu ihrer herstellung und ihre verwendung zur herstellung von ethylenoxid
DE3310685A1 (de) * 1982-07-24 1984-02-09 Hoechst Ag, 6230 Frankfurt Silberkatalysatoren, verfahren zu ihrer herstellung und ihre verwendung zur herstellung von ethylenoxid

Also Published As

Publication number Publication date
EP0172565A3 (en) 1986-12-30
US4690913A (en) 1987-09-01
EP0172565B1 (de) 1991-03-13
US4786624A (en) 1988-11-22
EP0172565A2 (de) 1986-02-26

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