DE346768T1 - Mit aminofunktionellen silanen grundierte polyesterfolien und deren folienlaminate. - Google Patents

Mit aminofunktionellen silanen grundierte polyesterfolien und deren folienlaminate.

Info

Publication number
DE346768T1
DE346768T1 DE198989110443T DE89110443T DE346768T1 DE 346768 T1 DE346768 T1 DE 346768T1 DE 198989110443 T DE198989110443 T DE 198989110443T DE 89110443 T DE89110443 T DE 89110443T DE 346768 T1 DE346768 T1 DE 346768T1
Authority
DE
Germany
Prior art keywords
film
adhesion
stretching
group
promoting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE198989110443T
Other languages
English (en)
Inventor
Howard Wayne Taylors South Carolina 29687 Swofford
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CNA Holdings LLC
Original Assignee
Hoechst Celanese Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst Celanese Corp filed Critical Hoechst Celanese Corp
Publication of DE346768T1 publication Critical patent/DE346768T1/de
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10018—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising only one glass sheet
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B32B27/365—Layered products comprising a layer of synthetic resin comprising polyesters comprising polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/12—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
    • C08J5/124—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives using adhesives based on a macromolecular component
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/042—Coating with two or more layers, where at least one layer of a composition contains a polymer binder
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/0427—Coating with only one layer of a composition containing a polymer binder
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/514—Oriented
    • B32B2307/518—Oriented bi-axially
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554—Wear resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2329/00—Polyvinylalcohols, polyvinylethers, polyvinylaldehydes, polyvinylketones or polyvinylketals
    • B32B2329/06—PVB, i.e. polyinylbutyral
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2367/00—Polyesters, e.g. PET, i.e. polyethylene terephthalate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2483/02—Polysilicates
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31652—Of asbestos
    • Y10T428/31663—As siloxane, silicone or silane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31652—Of asbestos
    • Y10T428/31667—Next to addition polymer from unsaturated monomers, or aldehyde or ketone condensation product
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31786—Of polyester [e.g., alkyd, etc.]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Laminated Bodies (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
  • Joining Of Glass To Other Materials (AREA)
  • Paints Or Removers (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Claims (14)

HOECHST CELANESE CORPORATION 0 346 76 Somerville, N.J. 08876/USA EPA 89110443.2 - 1 - 15. März 1990 EP-OS 0 346 768 WLJ-DC.Ho-bl Patentansprüche
1. Orientierte, selbsttragende hochfeste Folie, die auf einer oder beiden Seiten durchgehend mit einem haftvermittelnden Beschichtungsgemisch beschichtet ist, dadurch gekennzeichnet, daß das Beschichtungsgemisch aus dem Trockenrückstand einer hydrolysierten Aminosilanverbindung besteht, die im nicht-hydrolysierten Zustand die folgende Formel hat:
10
XSi(R2)a(R3)b
worin
X ein Rest ist, ausgewählt aus der Gruppe bestehend aus H2NR1HNR1 - und H2NR1HNR1HNR1 -, wobei
R jeweils gleiche oder verschiedene Gruppen bezeichnet, ausgewählt aus der Gruppe bestehend aus C1-Cg-AIkYl und -Phenyl,
1g
R2 eine hydrolysierbare Gruppe, ausgewählt aus der Gruppe bestehend aus C1-C8-AIkOXy, einer Ace-
toxygruppe und einem Halogenid, R eine nicht-reaktionsfähige, nicht-hydrolysierbare Gruppe, ausgewählt aus der Gruppe bestehend aus C1-C3-AIkYl und Phenyl, a eine ganze Zahl von 1 bis 3 und
b eine ganze Zahl von 0 bis 2 bedeuten, wobei die Summe aus a und b 3 ist, und daß das haftvermittelnde Beschichtungsgemisch in einem solchen Gewicht aufgebracht ist, daß es eine verbesserte Haftung von anderen Polymeren an der Folie bewirkt.
HOECHST CELANESE CORPORATION Somerville, N.J. 08876/USA
2. Folie nach Anspruch 1, dadurch gekennzeichnet, da/3 die Aminosilanverbindung ausgewählt ist aus der Gruppe bestehend aus:
N-(2-Aminoethyl-3-aminopropyl)methyl-dimethoxysilan, N-(2-Aminoethyl-3-aminopropyl)trimethoxysilan, N-(2-Aminoethyl-3-aminopropyl)tris-( 2-ethylhexoxy)silan, 6-(Aminohexylaminopropyl)-trimethoxysilan, (Aminoethylaminomethyl phenethyl)-trimethoxysilan und N-(2-Aminoethyl-2-aminoethyl-3-aminopropyl)~ trimethoxysilan.
3. Folie nach Anspruch 1 oder 2, dadurch gekennzeichnet, daß die Aminosilanverbindung im nicht-hydrolysierten
Zustand die folgende Formel hat:
H2NR1NHR1Si(R2)a(R3)b
worin R1 jeweils gleiche oder verschiedene Alkylreste mit 1 bis 3 Kohlenstoffatomen bezeichnet, R2 eine C1-C3-AIkoxygruppe, a = 3 und b = 0 ist.
4. Folie nach Anspruch 3, dadurch gekennzeichnet, da/3 die Aminosilanverbindung N-2-(Aminoethyl-3-aminopropyl)-
trimethoxysilan ist.
5. Folie nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, da/3 die Folie eine Polyester folie, Vorzugs-
HOECHST CELANESE CORPORATION 0 3 A 6 7 6
Somerville, N.J. 08876/USA
weise eine biaxial orientierte Polyethylenterephthalatfolie ist.
6. Folie nach Anspruch 5, dadurch gekennzeichnet, da/3 zur Herstellung der Folie eine Polyesterschmelze zu einer im wesentlichen amorphen Folie extrudiert wird, die Folie anschließend durch aufeinanderfolgendes Strecken in zwei Richtungen orientiert und dann thermofixiert wird, wobei das haftvermittelnde Beschichtungsgemisch vor dem Strecken der Folie in einer Richtung oder nach dem Strecken in einer Richtung, jedoch vor dem Strecken in der zur ersten Streckrichtung senkrecht verlaufenden Richtung oder nach dem Strecken in beiden Richtungen als wäßrige Lösung auf die Folie aufgebracht wird.
7. Folie nach Anspruch 6, dadurch gekennzeichnet, daß die Folie vor dem Aufbringen des haftvermittelnden Beschichtungsgemischs einer Coronaentladungsbehandlung unterzogen wird.
8. Folie nach Anspruch 6 oder 7, dadurch gekennzeichnet, daß das haftvermittelnde Beschichtungsgemisch nach dem Strecken in einer Richtung, jedoch vor dem Strecken in der zur ersten Streckrichtung senkrecht verlaufenden Richtung aufgebracht wird.
9. Folie nach einem der Ansprüche 1 bis 8, dadurch gekennzeichnet, daß das haftvermittelnde Beschichtungsgemisch in einem Flächengewicht im Bereich von etwa
HOECHST CELANESE CORPORATION
Somerville, N.J. 08876/USA
0,5 mg/m2 bis etwa 100 mg/m2, bezogen auf ihr Trockengewicht, auf die Folie aufgebracht ist.
10. Polyesterfolie nach Anspruch 5, bei der eine Folie aus einem anderen Polymeren mit der haftvermittelnd beschichteten Oberfläche der Polyesterfolie haftend verbunden ist, dadurch gekennzeichnet, da/3 dieses Polymere Poly(vinylbutyral) oder Polyethylen oder Polyurethan ist.
11. Schichtstoffmaterial bestehend aus einer Glasplatte, einer an der Glasplatte haftenden Polyvinylbutyral)-Folie und der mit ihrer haftvermittelnd beschichteten Oberfläche an der Poly(vinylbutyral)-Folie haftenden Polyesterfolie nach Anspruch 5.
12. Schichtstoffmaterial nach Anspruch 11, dadurch gekennzeichnet, da/3 dieses Material eine zweite, an der haftvermittelnd beschichteten Folie haftende Folie aus Polyvinylbutyral enthält, sowie eine zweite, an dem PoIyvinylbutyral haftende Glasplatte.
13. Schichtstoffmaterial nach Anspruch 12, dadurch gekennzeichnet, daß die haftvermittelnd beschichtete Folie auf einer Seite eine dünne Metall- oder Metalloxidbe-Schichtung trägt.
14. Material nach Anspruch 11, dadurch gekennzeichnet, daß die der haftvermittelnd beschichteten Oberfläche der Polyesterfolie gegenüberliegende Oberfläche mit einer abriebfesten Beschichtung versehen ist.
DE198989110443T 1988-06-15 1989-06-09 Mit aminofunktionellen silanen grundierte polyesterfolien und deren folienlaminate. Pending DE346768T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/207,069 US4898786A (en) 1988-06-15 1988-06-15 Polyester film primed with an aminofunctional silane, and film laminates thereof

Publications (1)

Publication Number Publication Date
DE346768T1 true DE346768T1 (de) 1990-07-05

Family

ID=22769081

Family Applications (2)

Application Number Title Priority Date Filing Date
DE198989110443T Pending DE346768T1 (de) 1988-06-15 1989-06-09 Mit aminofunktionellen silanen grundierte polyesterfolien und deren folienlaminate.
DE68924100T Expired - Fee Related DE68924100T2 (de) 1988-06-15 1989-06-09 Mit aminofunktionellen Silanen grundierte Folien und deren Folienlaminate.

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE68924100T Expired - Fee Related DE68924100T2 (de) 1988-06-15 1989-06-09 Mit aminofunktionellen Silanen grundierte Folien und deren Folienlaminate.

Country Status (15)

Country Link
US (1) US4898786A (de)
EP (1) EP0346768B1 (de)
JP (1) JPH0625273B2 (de)
KR (1) KR930010655B1 (de)
CN (1) CN1038658A (de)
AU (1) AU605738B2 (de)
BR (1) BR8902879A (de)
CA (1) CA1328585C (de)
DE (2) DE346768T1 (de)
DK (1) DK290789A (de)
FI (1) FI892945A (de)
IE (1) IE891916L (de)
MX (1) MX169509B (de)
NO (1) NO892475L (de)
ZA (1) ZA894480B (de)

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US5082738A (en) * 1988-06-15 1992-01-21 Hoechst Celanese Corporation Polyester film primed with an aminofunctional silane, and film laminates thereof
US5064722A (en) * 1988-06-15 1991-11-12 Hoechst Celanese Corporation In-line aminosilane coated polyester film for glazing products
US4939035A (en) * 1988-09-06 1990-07-03 Hoechst Celanese Corporation Extrusion coatable polyester film having an aminofunctional silane primer, and extrusion coated laminates thereof
US5100722A (en) * 1988-11-25 1992-03-31 Nichias Corporation Glass fiber-reinforced resin composite materials
EP0673310A4 (de) * 1992-12-09 1995-12-06 Hoechst Ag Biaxial mit einem funktionellen silan grundiertes, orientiertes copolyesterfilm und solche verbundfolien.
US5434007A (en) * 1993-09-20 1995-07-18 Dow Corning Corporation Silane coated flavor/aroma barrier film
US5474730A (en) * 1993-06-09 1995-12-12 Hoechst Celanese Corporation Production of highly birefringent film
US5445866A (en) * 1993-10-19 1995-08-29 Minnesota Mining And Manufacturing Company Water-based transparent image recording sheet
US5464900A (en) * 1993-10-19 1995-11-07 Minnesota Mining And Manufacturing Company Water soluble organosiloxane compounds
US5728224A (en) * 1995-09-13 1998-03-17 Tetra Laval Holdings & Finance S.A. Apparatus and method for manufacturing a packaging material using gaseous phase atmospheric photo chemical vapor deposition to apply a barrier layer to a moving web substrate
JPH09323392A (ja) * 1996-06-05 1997-12-16 Teijin Ltd シリコーン易接着性フイルム及びその製造法
US7238401B1 (en) 2000-06-09 2007-07-03 3M Innovative Properties Company Glazing element and laminate for use in the same
DE10140131B4 (de) 2001-08-16 2007-05-24 Wacker Polymer Systems Gmbh & Co. Kg Silan-modifizierte Polyvinylacetale
DE10140130A1 (de) 2001-08-16 2003-03-06 Wacker Polymer Systems Gmbh Polyvinylacetale mit verbesserter Haftung
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US8372937B2 (en) 2004-03-23 2013-02-12 Sika Technology Ag Two-component adhesion promoter composition and use of packaging comprising two compartments
DE502005003889D1 (de) * 2004-04-27 2008-06-12 Mitsubishi Polyester Film Gmbh Weisse, dampfsterilisierbare und extrusionsbeschichtbare Polyesterfolie
DE102004030979A1 (de) * 2004-06-26 2006-01-19 Mitsubishi Polyester Film Gmbh Extrusionsbeschichtbare Polyesterfolie enthaltend Poly(m-xylol-adipinamid)
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EP0346768B1 (de) 1995-09-06
CN1038658A (zh) 1990-01-10
DK290789D0 (da) 1989-06-14
BR8902879A (pt) 1990-02-01
IE891916L (en) 1989-12-15
DE68924100D1 (de) 1995-10-12
DK290789A (da) 1989-12-16
FI892945A (fi) 1989-12-16
JPH0238432A (ja) 1990-02-07
AU3593089A (en) 1989-12-21
JPH0625273B2 (ja) 1994-04-06
KR930010655B1 (ko) 1993-11-05
EP0346768A2 (de) 1989-12-20
FI892945A0 (fi) 1989-06-15
KR910000872A (ko) 1991-01-30
AU605738B2 (en) 1991-01-17
ZA894480B (en) 1990-02-28
EP0346768A3 (de) 1991-07-17
DE68924100T2 (de) 1996-05-09
US4898786A (en) 1990-02-06
MX169509B (es) 1993-07-08
CA1328585C (en) 1994-04-19
NO892475L (no) 1989-12-18
NO892475D0 (no) 1989-06-14

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